CN106213689B - The button and preparation method thereof of UV resistant xanthochromia - Google Patents
The button and preparation method thereof of UV resistant xanthochromia Download PDFInfo
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- CN106213689B CN106213689B CN201610733727.XA CN201610733727A CN106213689B CN 106213689 B CN106213689 B CN 106213689B CN 201610733727 A CN201610733727 A CN 201610733727A CN 106213689 B CN106213689 B CN 106213689B
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- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
- A44B1/00—Buttons
- A44B1/02—Buttons characterised by their material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3472—Five-membered rings
- C08K5/3475—Five-membered rings condensed with carbocyclic rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/5399—Phosphorus bound to nitrogen
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
This application provides a kind of mixed slurries of UV resistant xanthochromia button comprising the ultraviolet absorber of 0.2~1.5 parts by weight, the unsaturated polyester resin of 95~99 parts by weight, the diluent of 0.6~1.2 parts by weight, the curing agent of 1.0~1.5 parts by weight.Present invention also provides a kind of preparation methods of UV resistant xanthochromia button, the following steps are included: obtaining mixed slurry after the curing agent for adding 1.0~1.5 parts by weight after the unsaturated polyester resin of the ultraviolet absorbing agent of 0.2~1.5 parts by weight, 95~99 parts by weight is mixed with the promotor of 0.6~1.2 parts by weight mixes；By mixed slurry after moulding process, UV resistant xanthochromia button is obtained.Two or more ultraviolet absorbing agent is added in the present invention in the mixed slurry for preparing UV resistant xanthochromia, makes button color fastness to light with higher.
Description
Technical field
The present invention relates to Fashion and Accessories technical fields more particularly to the button of UV resistant xanthochromia and preparation method thereof.
Background technique
Button is the fastener being connected on clothes for the both sides hem, and initial effect is for connection to the door of clothes
The flap, gradually to have more artistry and dicoration in addition to keeping its original function, i.e. button has become one kind for development
Personalized ornament.
Button presses the classification of its material, can be divided into natural class, chemical and other materials, in chemical knob among these
Button is divided into organic button, resin button, urea again and buckles, the mouth that paints, is electroplated and buckles and buckle by the emperor himself.The fast development of resin industry in recent years,
And resin button has again many advantages, such as wearability is good, heat-resisting quantity is good and kind is all kinds of, and color of light is vivid beautiful,
And resin button processing is easier, and speed of production is fast, and relative price is also relatively cheap, and it is each can also to produce many styles
It is different, the very strange button of shape.Thus, the resin button more and more favor by consumer and manufacturing enterprise.Currently,
Resin button is constantly in leading position in button production field.
Since the basic material of resin button is unsaturated polyester resin, resin button especially light-colored resin button is in length
In the illumination and wearing process of time, it is easy to happen xanthochromia, and influences the beauty of clothes, meanwhile, resin button is in production
After tested, to meet international color fastness to light testing standard.
In international trade regulation, ISO105B02 and AATCC16 are more common color fastness to light testing standards, this two
Kind standard is all made of xenon lamp color fastness to light instrument and is tested, and simulation is tested textile under conditions of natural environment and shone in sunlight
Fading extent under penetrating.Button is inseparable with clothes, and when test is also made as clothing detection, therefore the detection method of button is also adopted
It is tested with the standard of textile.And light fastness instrument mostly uses greatly xenon arc lamp pipe simulated solar irradiation, due to xenon arc fluorescent tube
Power is larger, and amount of heat can be generated in use, and the plastic products of test can not only fade, and the xanthochromia degree of light class product is more
Add obvious, especially white group button is obvious in 16 standard testing post yellowing degree of AATCC, when judgement can only at 3 grades hereinafter,
And standard must reach 3.5 grades or more, be unable to reach standard requirements.
Summary of the invention
Present invention solves the technical problem that being to provide a kind of button and preparation method thereof of UV resistant xanthochromia, the application
The UV resistant xanthochromia button of offer has preferable color fastness to light, and discoloration rank is higher.
In view of this, this application provides a kind of mixed slurries for being used to prepare UV resistant xanthochromia button, comprising:
The ultraviolet absorbing agent is selected from salicylic acid esters, benzophenone class, benzotriazole, group-substituted acrylonitrile, triazines
With two or more in hindered amines.
Preferably, further include in the mixed slurry 0.5~2 parts by weight diluent and 0.1~2 parts by weight mill base.
Preferably, the promotor is cobalt naphthenate or cobalt iso-octoate；The curing agent is methyl ethyl ketone peroxide and peroxide
Change one of cyclohexanone.
Preferably, the ultraviolet absorbing agent is selected from light stabilizer HPT, ultraviolet absorbing agent UV-4360, ultraviolet absorber
Two or more in GW-540 and phenyl salicylate.
Preferably, the content of the ultraviolet absorbing agent is 0.6~1.0 parts by weight.
Preferably, the content of the promotor is 0.8~1.0 parts by weight.
Present invention also provides a kind of preparation methods of UV resistant xanthochromia button, comprising the following steps:
By the ultraviolet absorbing agent of 0.2~1.5 parts by weight, the unsaturated polyester resin of 95~99 parts by weight and 0.6~1.2
The promotor of parts by weight adds the curing agent mixing of 1.0~1.5 parts by weight after being mixed after, mixed slurry is obtained；
By the mixed slurry after moulding process, UV resistant xanthochromia button is obtained.
Preferably, the molding technique includes centrifugal forming, cast molding or drop glue fill process.
Preferably, the diluent of 0.5~2 parts by weight and the color of 0.1~2 parts by weight are additionally added before the mixing
Slurry.
Present invention also provides a kind of buttons of UV resistant xanthochromia, by unsaturated polyester resin, light stabilizer, promotor
It is obtained after preparing with curing agent.
This application provides a kind of mixed slurries for being used to prepare paper sheet button comprising 0.2~1.5 parts by weight
Ultraviolet absorber, the unsaturated polyester resin of 95~99 parts by weight, the diluent of 0.6~1.2 parts by weight, 1.0~1.5 parts by weight
Curing agent；The ultraviolet absorbing agent is selected from salicylic acid esters, benzophenone class, benzotriazole, group-substituted acrylonitrile, triazines
With two or more in hindered amines.The application is added specific in the mixed serum for preparing UV resistant xanthochromia button
The ultraviolet absorbing agent of ratio, and by the way that two or more ultraviolet absorbing agent is added, make the button of preparation have compared with
High color fastness to light, xanthochromia degree is weaker, and discoloration rank is higher.
Detailed description of the invention
Fig. 1 is the photo of button A test front and back prepared by the embodiment of the present invention 1.
Specific embodiment
For a further understanding of the present invention, the preferred embodiment of the invention is described below with reference to embodiment, still
It should be appreciated that these descriptions are only further explanation the features and advantages of the present invention, rather than to the claims in the present invention
Limitation.
The embodiment of the invention discloses a kind of mixed slurries of UV resistant xanthochromia button, comprising:
The ultraviolet absorbing agent is selected from salicylic acid esters, benzophenone class, benzotriazole, group-substituted acrylonitrile, triazines
With two or more in hindered amines.
Raw material in herein described mixed slurry are unsaturated polyester resin, are used as it in ultraviolet resistance xanthochromia
The carrier of its component can enhance the binding force of ultraviolet absorbing agent and other components.In the present invention, the unsaturated polyester (UP) tree
Rouge is resin well known to those skilled in the art, is not particularly limited to this application, can be adjacent benzene-type resin, isophthalic
One of type resin and p-phenyl's resin are a variety of.The source of herein described unsaturated polyester resin can be commercially available production
Product can be to be prepared by method well known to those skilled in the art.The content of unsaturated polyester resin described herein
For 95~99 parts by weight, in certain embodiments, the content of the unsaturated polyester resin is preferably 96~98 parts by weight, more excellent
It is selected as 97 parts by weight.
The ultraviolet absorbing agent is ultraviolet absorber well known to those skilled in the art, not special to this application
Limitation, it is preferred that herein described ultraviolet absorbing agent is preferably selected from salicylic acid esters, benzophenone class, benzotriazole, replaces third
Two or more in alkene nitrile, triazines and hindered amines；Exemplary, it is steady that the ultraviolet absorbing agent is preferably selected from light
Determine two or more in agent HPT, ultraviolet absorbing agent UV-4360, ultraviolet absorber GW-540 and phenyl salicylate.On
The source for stating ultraviolet absorbing agent is not particularly limited, and can be commercial product, can also be ripe according to those skilled in the art
The means known are prepared.Herein described ultraviolet absorbing agent can make the color fastness to light of button preferable, weaken ultraviolet light pair
The destruction of color.The content of ultraviolet absorbing agent described herein is 0.2~1.5 parts by weight, in embodiment, described ultraviolet
The content of light absorbers is preferably 0.6~1.0 parts by weight, more preferably 0.7~0.9 parts by weight.
It further include promotor in herein described mixed slurry, the promotor is promotion well known to those skilled in the art
Agent is not particularly limited this application, exemplary, and herein described promotor is preferably cobalt naphthenate and/or isooctyl acid
Cobalt.The content of the promotor is 0.6~1.2 parts by weight, more preferably 0.8~1.0 parts by weight.Herein described mixed slurry
In curing agent to promote the solidification of mixed slurry.The curing agent be it is well known to those skilled in the art, herein without spy
Other limitation, exemplary, the curing agent is preferably selected from one of methyl ethyl ketone peroxide and cyclohexanone peroxide.The solidification
The content of agent is 1.0~1.5 parts by weight, more preferably 1.2~1.4 parts by weight.Herein described curing agent and the promotor
Content is very few, then resin solidification can be made incomplete, leads to the color fastness to light reduced performance of button.
It further include mill base and diluent in herein described mixed slurry, the mill base is used to adjust the face of mixed slurry
Color, the mill base be it is well known to those skilled in the art, this application is not particularly limited.The content of the mill base is
0.1~2 parts by weight, in embodiment, the content of the mill base are preferably 0.5~1 parts by weight.
Herein described diluent is used to adjust the viscosity of ultraviolet absorbing agent and unsaturated polyester resin.It is herein described
The content of diluent is 0.5~2 parts by weight, and in embodiment, the content of the diluent is 0.8~1.5 parts by weight, more preferably
For 1.0~1.3 parts by weight.
Present invention also provides a kind of preparation methods of UV resistant xanthochromia button, comprising the following steps:
By the ultraviolet absorbing agent of 0.2~1.5 parts by weight, the unsaturated polyester resin of 95~99 parts by weight and 0.6~1.2
The promotor of parts by weight adds the curing agent mixing of 1.0~1.5 parts by weight after being mixed after, mixed slurry is obtained；
By mixed slurry after moulding process, UV resistant xanthochromia button is obtained.
During preparing UV resistant xanthochromia button, raw material is mixed with to obtain mixed slurry first.Mixing slurry
The preparation of material not directly mixes all raw materials, and the application needs for curing agent to be finally added, unsaturated poly- to prevent
Ester resin generates gelatinization；Therefore the application first by unsaturated polyester resin, ultraviolet absorbing agent and promotor after mixing
Curing agent is added, obtains mixed slurry after mixing.The time stirred before the addition curing agent is preferably 20~30min.
The application obtains UV resistant Huang side button then by obtained mixed slurry after moulding process.The application
The moulding process includes centrifugal forming, cast molding or drop glue fill process, and above-mentioned technique is that those skilled in the art are ripe
The moulding process known is not particularly limited this application.It is exemplary, the centrifugal molding process specifically:
Mixed slurry obtained above is placed in centrifugal film bucket, gets rid of put down and be solidified into plate under the influence of centrifugal force,
Punching press, hardening, cutting and polishing are successively carried out again, obtain button finished product.
The technique of the cast molding specifically:
Mixed slurry is mixed, then the cast molding in aluminum pipe in stick machine mixer, is then successively demoulded, cut
It cuts, cut and polishes, obtain button finished product.
The technique of the drop glue filling specifically:
Mixed slurry is poured into adhesive dripping machine and is instilled in semi-finished product knob base, after solidification, then successively demoulded, cut and is thrown
Light obtains button finished product.
In above process, the solidification, punching press, hardening, cutting and polishing are skill well known to those skilled in the art
Art means, herein without particularly limiting.
Present invention also provides a kind of UV resistant xanthochromia button, the ultraviolet absorbers as described in above scheme, insatiable hunger
It is prepared with polyester resin, promotor and curing agent.
Button provided by the invention by the way that two or more ultraviolet absorbing agents is added in unsaturated polyester resin, and
By using the promotor of special ratios, curing agent, ultraviolet absorbing agent and unsaturated polyester resin, make the button being prepared
Photochromic fastness it is preferable, xanthochromia degree is weaker, discoloration rank it is higher.The experimental results showed that button provided by the invention is fast light
Color fastness can be to 4~5 grades.
For a further understanding of the present invention, below with reference to embodiment to the system of UV resistant xanthochromia button provided by the invention
Standby to be described in detail, herein without particularly limiting, protection scope of the present invention is not limited by the following examples.
Raw material in following embodiment is commercial product.
Embodiment 1
The ultraviolet light of the unsaturated polyester resin of 97 parts by weight, the light stabilizer HPT of 0.4 parts by weight, 0.3 parts by weight is inhaled
Receive agent UV-4360, the diluent of 1.3 parts by weight, the white pearlescent slurry of 1 parts by weight, the brightening agent of 0.02 parts by weight and 1.0 weight
The cobalt naphthenate of part stirs blender 30 minutes in charging basket, the materials weight of the good every sheet of THICKNESS CALCULATION according to product,
Then the methyl ethyl ketone peroxide that 1.0 parts by weight are added is stirred for 3~5 minutes, and obtained mixture is poured into centrifugal film bucket,
It gets rid of flat under the action of centrifugal force and is solidified into plate；The knob base of required specification is punched into clicking machine again, by obtained blank point
It is two parts；Portion solidifies after completing knob base in the saline solution of certain saturation degree, and resulting sample A is measured using hardness Barcol
Knob base hardness is tried, obtaining knob base hardness is 20~25 Pasteur, another is handled in post cure processes using conventional hot water, gained
Sample B tests knob base hardness using Bareol hardness meter, and obtaining knob base hardness is 10~12 Pasteur.
Embodiment 2
By the unsaturated polyester resin of 97 parts by weight, the diluent of 1.2 parts by weight, the white pigments of 1.2 parts by weight and 0.4 weight
The light stabilizer HPT for measuring part stirs blender 30 minutes in charging basket, is divided into 2 parts or more parts by bar pattern structure, respectively
The cobalt iso-octoate of 1.2 parts by weight and the cyclohexanone peroxide of 1.5 parts by weight is added, is uniformly mixed after stirring evenly through stick machine mixer
Close, further according to pattern structure in aluminum pipe cast molding at bar；The knob base of required thickness is cut into blank cutter again, is centainly being satisfied
With in the saline solution of degree complete knob base after solidify, gained sample C using Bareol hardness meter test knob base hardness, it is hard to obtain knob base
Degree is 22~26 Pasteur.
Embodiment 3
By the unsaturated polyester resin of 97 parts by weight, the diluent of 2 parts by weight, the white pigments of 1 parts by weight, 0.35 parts by weight
Light stabilizer GW-540 and 0.5 parts by weight phenyl salicylate in charging basket by blender stir 30 minutes, add 0.8 weight
The cobalt naphthenate of part is measured, the methyl ethyl ketone peroxide for adding 1.2 parts by weight after mixing evenly is again stirring for uniformly, pouring into adhesive dripping machine
Material placing device in, through drop gluing equipment orderly by resin instillation scrape in reeded semi-finished product knob base, complete under normal temperature conditions
Solidification places into the saline solution of certain saturation degree after completing drop glue knob base after 4-6 hours and solidifies, gained sample D use bar
Family name's hardometer tests knob base hardness, and obtaining knob base hardness is 18~20 Pasteur.
Comparative example 1
The component of the present embodiment vegetation button includes: the dilution of the unsaturated polyester resin of 97.7 parts by weight, 1.3 parts by weight
Agent, 1 parts by weight white pearlescent slurry and the brightening agents of 0.02 parts by weight, other technological parameters execute completely by real in forming process
Example 1 is applied, then solidification uses saline treatment, and resulting sample E tests knob base hardness using Bareol hardness meter, obtains knob base hardness
For 20~25 Pasteur.
Embodiment 4
By above embodiments and the resulting 5 kinds of knob bases of comparative example, required shape is cut into blank surface on moulding machine
Shape, then polishing obtains finished product button, then this four sections of buttons are carried out color fastness to light test with ISO 105B02 standard respectively,
Obtain following test result:
1 gained button A of embodiment: (as shown in FIG. 1, FIG. 1 is before the test of the button of the present embodiment for 4-5 grades of color fastness to light
Photo afterwards, left side button are the photo before test, and right side button is the photo after test)；
1 gained button B of embodiment: 3-4 grades of color fastness to light；
Embodiment 2 gained button C: 3-4 grades of color fastness to light；
Embodiment 3 gained button D: 4-5 grades of color fastness to light；
Comparative example 1 gained button E: 3.0 grades of color fastness to light.
The above description of the embodiment is only used to help understand the method for the present invention and its core ideas.It should be pointed out that pair
For those skilled in the art, without departing from the principle of the present invention, the present invention can also be carried out
Some improvements and modifications, these improvements and modifications also fall within the scope of protection of the claims of the present invention.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention.
Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention
It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one
The widest scope of cause.
Claims (5)
1. a kind of preparation method of UV resistant xanthochromia button, comprising the following steps:
By the ultraviolet absorbing agent of 0.2~1.5 parts by weight, the unsaturated polyester resin of 95~99 parts by weight, 0.6~1.2 weight
The mill base of the promotor of part, the diluent of 0.5~2 parts by weight and 0.1~2 parts by weight adds 1.0~1.5 weights after being mixed
After the curing agent mixing for measuring part, mixed slurry is obtained；
The mixed slurry is solidified in saline solution after the completion after moulding process, obtains UV resistant xanthochromia button；
The ultraviolet absorbing agent is selected from light stabilizer HPT, ultraviolet absorbing agent UV-4360, ultraviolet absorber GW-540 and water
Two or more in poplar acid phenenyl ester.
2. preparation method according to claim 1, which is characterized in that the promotor is cobalt naphthenate or cobalt iso-octoate；
The curing agent is one of methyl ethyl ketone peroxide and cyclohexanone peroxide.
3. preparation method according to claim 1, which is characterized in that the content of the ultraviolet absorbing agent is 0.6~1.0
Parts by weight.
4. preparation method according to claim 1, which is characterized in that the content of the promotor is 0.8~1.0 weight
Part.
5. preparation method according to claim 1, which is characterized in that the molding technique includes centrifugal forming, casting
Molding or drop glue fill process.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610733727.XA CN106213689B (en) | 2016-08-25 | 2016-08-25 | The button and preparation method thereof of UV resistant xanthochromia |
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| CN201610733727.XA CN106213689B (en) | 2016-08-25 | 2016-08-25 | The button and preparation method thereof of UV resistant xanthochromia |
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| CN106213689B true CN106213689B (en) | 2019-07-19 |
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| CN108654109B (en) * | 2018-04-08 | 2023-08-04 | 东莞市安普城塑胶有限公司 | Production process of flash color-changing sheet |
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| CN112011173A (en) * | 2020-08-31 | 2020-12-01 | 广东百卓鞋业有限公司 | Novel nonmetal shoe buckle |
| CN114262510B (en) * | 2022-01-17 | 2023-08-01 | 浙江飞素服饰有限公司 | Environment-friendly cereal resin button and preparation method thereof |
| CN115537005A (en) * | 2022-11-02 | 2022-12-30 | 广东溢达纺织有限公司 | Resin material, resin button and preparation method thereof |
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| CN105754312A (en) * | 2016-03-18 | 2016-07-13 | 广东溢达纺织有限公司 | Environment-friendly unsaturated polyester resin button and preparation method thereof |
| CN105747393A (en) * | 2016-04-15 | 2016-07-13 | 嘉善天路达工贸有限公司 | Production technology for resin buttons |
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| CN106213689A (en) | 2016-12-14 |
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Denomination of invention: Anti ultraviolet yellowing button and its preparation method Effective date of registration: 20210622 Granted publication date: 20190719 Pledgee: Industrial and Commercial Bank of China Limited Linhai Branch Pledgor: ZHEJIANG WEIXING INDUSTRIAL DEVELOPMAENT Co.,Ltd. Registration number: Y2021330000626 |
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Date of cancellation: 20221107 Granted publication date: 20190719 Pledgee: Industrial and Commercial Bank of China Limited Linhai Branch Pledgor: ZHEJIANG WEIXING INDUSTRIAL DEVELOPMAENT Co.,Ltd. Registration number: Y2021330000626 |