CN106205910A - A kind of combined precision resistance band - Google Patents

A kind of combined precision resistance band Download PDF

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Publication number
CN106205910A
CN106205910A CN201610594409.XA CN201610594409A CN106205910A CN 106205910 A CN106205910 A CN 106205910A CN 201610594409 A CN201610594409 A CN 201610594409A CN 106205910 A CN106205910 A CN 106205910A
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China
Prior art keywords
band
constituent content
spliced
resistance
temperature
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CN201610594409.XA
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CN106205910B (en
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邹宏辉
李祥
陈冠霖
卢晓军
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XIAMEN TORCH SPECIALMETALS MATERIALS CO Ltd
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XIAMEN TORCH SPECIALMETALS MATERIALS CO Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01CRESISTORS
    • H01C3/00Non-adjustable metal resistors made of wire or ribbon, e.g. coiled, woven or formed as grids
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/05Alloys based on copper with manganese as the next major constituent

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Welding Or Cutting Using Electron Beams (AREA)
  • Conductive Materials (AREA)

Abstract

The invention discloses a kind of combined precision electric resistance alloy band, it is spliced by band A is parallel with band B, and wherein band A chemical composition is: Mn constituent content is 7.2~7.8wt%, and Si constituent content is 2.1~2.5wt%, Cu surplus;Band B chemical composition is: Mn constituent content is 7.2~7.8wt%, and Ni constituent content is 1.5~1.8wt%, Cu surplus.The present invention is by carrying out series connection splicing in proportion by two kinds of precision electrical resistance alloys with positive temperature drift and subzero temperature drift so that it is floats positive and negative counteracting 20~120 DEG C of temperature range temperature, thus has minimum resistance temperature drift.Compared with other traditional single alloy strip steel rolled stock, it is more stable that product involved in the present invention has resistance in using temperature range, the higher advantage of precision.

Description

A kind of combined precision resistance band
Technical field
The present invention relates to a kind of automatic deviation correction compound precision resistance band, belong to new material technology field.
Background technology
Cu-Mn-Ni system precision electrical resistance alloy is that high-precision electric apparatus prepares critical material, extensively applies intelligent electric meter, electricity Son and electrical measuring instrument manufacture field, such as the diverter etc. in intelligent electric meter.This alloy requires minimum resistance temperature drift coefficient (i.e. the resistance rate of change to temperature) and to copper thermoelectrical potential, and good corrosion resistance and welding technological properties.At present, Cu-Mn-Ni Being that precision resistance material mainly includes 6J8,6J12 and 6J13 alloy, its chemical composition is shown in Table 1.Mn is that precision electrical resistance alloy is main Alloying element, the interpolation of Mn element may result in raising and the reduction of temperature drift coefficient of resistance alloys rate.Mn is element alloyed most preferably Composition range is 11~13wt%, and now copper-manganese temperature drift coefficient is less.The addition of Ni element is primarily to reduce Cu-Mn-Ni The alloy thermoelectrical potential to fine copper, improves manganin antioxidation, corrosion resistance ability simultaneously, and material resistance is affected relatively by composition fluctuation Little.
Intelligent electric meter diverter groundwork interval is 20~100 DEG C, and the dynamic electric of existing single precision electrical resistance alloy Resistance still suffers from larger fluctuation in this temperature range, result in suitable error in dipping.
Table 1 Cu-Mn-Ni system's precision electrical resistance alloy chemical composition (wt%)
Summary of the invention
It is an object of the invention to provide a kind of combined precision electric resistance alloy band, to overcome 20~100 DEG C of temperature ranges In, the dynamic electric resistor of existing electric resistance alloy is larger fluctuation in this temperature range, the problem causing error in dipping.
For achieving the above object, the solution of the present invention is:
A kind of combined precision electric resistance alloy band, it is spliced by band A is parallel with band B, wherein band A chemistry one-tenth Being divided into: Mn constituent content is 7.2~7.8wt%, Si constituent content is 2.1~2.5wt%, Cu surplus;Band B chemical composition For: Mn constituent content is 7.2~7.8wt%, and Ni constituent content is 1.5~1.8wt%, Cu surplus.
Described band A and band B is to use high-power electron beam weldering mode is parallel is spliced into composite strip precision electrical resistance alloy Band.
Described band A is parallel with band B is spliced into composite strip, is then carried out by the composite strip spliced employing finish draw Outward appearance finishing, finally carries out vacuum seamless annealing and forms combined precision electric resistance alloy band.
After using such scheme, the present invention is existed by the resistivity using the band A and band B of heterogeneity metal material There is in temperature range 20~100 DEG C the dull contrary variation tendency of approximately linear, by the parallel welding of bi-material, sliceable Become a kind of compound precision resistance band, it is achieved band A and band B tandem working in diverter so that splicing tape resistance is total On body, temperature drift is in the trend of cancelling out each other, so that shunting utensil has higher sampling precision in operating temperature range, The measuring accuracy of intelligent electric meter is finally greatly improved.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Present invention is disclosed a kind of combined precision electric resistance alloy band, it is spliced by band A is parallel with band B, its Middle band A chemical composition is: Mn constituent content is 7.2~7.8wt%, and Si constituent content is 2.1~2.5wt%, Cu surplus;Band Material B chemical composition is: Mn constituent content is 7.2~7.8wt%, and Ni constituent content is 1.5~1.8wt%, Cu surplus.
This band A and band B is to use high-power electron beam weldering mode is parallel is spliced into composite strip, then will splice Composite strip uses finish draw to carry out outward appearance and obtains finishing, finally carries out vacuum seamless annealing and forms combined precision electric resistance alloy band.
Know-why: the resistance value of high concentration solid solution with the relation of temperature is:(wherein ρ M For matrix material resistivity, ρ s is solvent element resistivity, and T is temperature).Materials A and material B (being shown in Table 2) are due to chemical composition Difference, cause its temperature drift in 20~120 DEG C of temperature ranges to have contrary trend, by both alloy strip steel rolled stocks according to The size of its temperature drift coefficient carries out series connection splicing by different width ratio, can get overall temperature in 20~120 DEG C of temperature ranges Float the diverter that coefficient is close to zero.
Table 2
Mn/wt.% Ni/wt.% Si/wt.% Temperature drift factor alpha/
Band A 7.2~7.8 -- 2.2~2.5 -25
Band B 7.2~7.8 1.5~1.8 -- 24.6
The band A of the present invention has dull contrary change in temperature range 20~100 DEG C and becomes with the resistivity of band B Gesture, owing to the copper-manganese sheet in diverter is that vertical bandlet length direction intercepts rectangular particles, electric current is through copper-manganese sheet, band A It is series combination with band B, therefore both positive and negative temperature drift can be cancelled out each other, so that shunting utensil is in operating temperature range Inside there is higher sampling precision, be finally greatly improved the measuring accuracy of intelligent electric meter, the i.e. present invention will have positive temperature drift and Two kinds of precision electrical resistance alloys of subzero temperature drift carry out series connection splicing in proportion so that it is float positive and negative supporting 20~120 DEG C of temperature range temperature Disappear, thus there is minimum resistance temperature drift.Compared with other traditional single alloy strip steel rolled stock, the product involved by this technological invention It is more stable that product have resistance in using temperature range, the higher advantage of precision.
Embodiment one
It is 4.8~5.2mm that the most smelting → rolling → drawing forming obtains width, and thickness isElectricity Resistance alloy strip steel rolled stock A and band B, wherein band A chemical composition is: Mn constituent content is 7.6~7.8wt%, and Si constituent content is 2.3~2.5wt%, copper surplus;The chemical composition of band B is: Mn content 7.2~7.4wt.%, Ni constituent content be 1.50~ 1.65wt.%, Cu surplus.Band A and band B employing high-power electron beam is welded the parallel width that is spliced into isBand Material, in the range of wherein band A is maintained at 0.95~1.05 with band B relative width ratio.Then the bandlet finish draw spliced is become Specification isBand, makes outward appearance obtain finishing, finally carries out vacuum seamless annealing.20~120 Composite flat band carries out in DEG C temperature range temperature drift test, and concrete test specification is carried out by GB/T 6148-2005, calculates The temperature drift of compound bandlet is 2.16ppm.
Embodiment two
It is 4.8~5.2mm that the most smelting → rolling → drawing forming obtains width, and thickness isElectricity Resistance alloy strip steel rolled stock A and B, wherein band A chemical composition is: Mn constituent content is 7.2~7.5wt%, Si constituent content be 2.1~ 2.3wt%, copper surplus;The chemical composition of band B is: Mn content 7.2~7.4wt.%, Ni constituent content be 1.55~ 1.80wt.%, Cu surplus.Band A and band B employing high-power electron beam is welded the parallel width that is spliced into isBand Material, in the range of wherein band A is maintained at 0.95~1.05 with band B relative width ratio.Then the bandlet finish draw spliced is become Specification isBand, make outward appearance obtain finishing, finally carry out vacuum seamless annealing.20~120 Composite flat band carries out in DEG C temperature range temperature drift test, and concrete test specification is carried out by GB/T 6148-2005, calculates The temperature drift of compound bandlet is 1.87ppm.
The above, be only the embodiment of the present invention, not impose any restrictions the technical scope of the present invention, therefore every Any trickle amendment, equivalent variations and the modification made above example according to the technical spirit of the present invention, all still falls within this In the range of inventive technique scheme.

Claims (3)

1. a combined precision electric resistance alloy band, it is characterised in that: it is spliced by band A is parallel with band B, wherein carries Material A chemical composition is: Mn constituent content is 7.2~7.8wt%, and Si constituent content is 2.1~2.5wt%, Cu surplus;Band B Chemical composition is: Mn constituent content is 7.2~7.8wt%, and Ni constituent content is 1.5~1.8wt%, Cu surplus.
2. a kind of combined precision electric resistance alloy band as claimed in claim 1, it is characterised in that: described band A with band B is Mode is parallel is spliced into composite strip precision electrical resistance alloy band to use high-power electron beam to weld.
3. a kind of combined precision electric resistance alloy band as claimed in claim 1 or 2, it is characterised in that: described band A and band B is parallel is spliced into composite strip, then the composite strip spliced employing finish draw is carried out outward appearance finishing, finally carries out vacuum light Bright annealing forms combined precision electric resistance alloy band.
CN201610594409.XA 2016-07-26 2016-07-26 A kind of combined precision resistance band Active CN106205910B (en)

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CN106205910B CN106205910B (en) 2018-11-09

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022088248A1 (en) * 2020-10-27 2022-05-05 广东生益科技股份有限公司 Magnetic dielectric resin composition and application thereof

Citations (5)

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Publication number Priority date Publication date Assignee Title
CN1312397A (en) * 2001-02-22 2001-09-12 电子科技大学 Preparation Mn-Co film with low temperature coefficient of resistance
CN1512523A (en) * 2002-12-30 2004-07-14 上海精密科学仪器有限公司上表直流仪 Matching technology of zero temperature coefficient precision resistor
US20060049907A1 (en) * 2004-09-08 2006-03-09 Cyntec Company Current measurement using inductor coil with compact configuration and low TCR alloys
CN104240875A (en) * 2014-09-15 2014-12-24 北京东方计量测试研究所 Bunchy core wire alternating current-direct current difference calculating resistor
CN105586555A (en) * 2016-01-04 2016-05-18 厦门火炬特种金属材料有限公司 Reduction medium for bright annealing of Cu-Mn-Ni series precision resistance alloy strip and annealing method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1312397A (en) * 2001-02-22 2001-09-12 电子科技大学 Preparation Mn-Co film with low temperature coefficient of resistance
CN1512523A (en) * 2002-12-30 2004-07-14 上海精密科学仪器有限公司上表直流仪 Matching technology of zero temperature coefficient precision resistor
US20060049907A1 (en) * 2004-09-08 2006-03-09 Cyntec Company Current measurement using inductor coil with compact configuration and low TCR alloys
CN104240875A (en) * 2014-09-15 2014-12-24 北京东方计量测试研究所 Bunchy core wire alternating current-direct current difference calculating resistor
CN105586555A (en) * 2016-01-04 2016-05-18 厦门火炬特种金属材料有限公司 Reduction medium for bright annealing of Cu-Mn-Ni series precision resistance alloy strip and annealing method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张邦维,廖树帜: "《实用金属材料手册》", 31 January 2010, 湖南科学技术出版社 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2022088248A1 (en) * 2020-10-27 2022-05-05 广东生益科技股份有限公司 Magnetic dielectric resin composition and application thereof
CN114479418A (en) * 2020-10-27 2022-05-13 广东生益科技股份有限公司 Magnetic dielectric resin composition and application thereof
CN114479418B (en) * 2020-10-27 2023-08-11 广东生益科技股份有限公司 Magneto-dielectric resin composition and application thereof

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