CN106198428A - A kind of portable boats and ships throat discharge waste gas sulfur dioxide detector - Google Patents

A kind of portable boats and ships throat discharge waste gas sulfur dioxide detector Download PDF

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Publication number
CN106198428A
CN106198428A CN201610629955.2A CN201610629955A CN106198428A CN 106198428 A CN106198428 A CN 106198428A CN 201610629955 A CN201610629955 A CN 201610629955A CN 106198428 A CN106198428 A CN 106198428A
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China
Prior art keywords
ultraviolet
sulfur dioxide
ships
waste gas
discharge waste
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CN201610629955.2A
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Chinese (zh)
Inventor
王新全
于翠荣
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Qingdao Academy for Opto Electronics Engineering
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Qingdao Academy for Opto Electronics Engineering
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Priority to CN201610629955.2A priority Critical patent/CN106198428A/en
Publication of CN106198428A publication Critical patent/CN106198428A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/33Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using ultraviolet light
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/01Arrangements or apparatus for facilitating the optical investigation
    • G01N21/03Cuvette constructions
    • G01N21/031Multipass arrangements
    • G01N2021/0314Double pass, autocollimated path
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/08Optical fibres; light guides
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/08Optical fibres; light guides
    • G01N2201/0826Fibre array at source, distributing

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

The present invention relates to a kind of portable boats and ships throat discharge waste gas sulfur dioxide detector, including ultraviolet source, Optic transmission fiber, opening gas sensing head, ultraviolet spectrometer, embedded computer, power supply, mainframe box, described ultraviolet source, ultraviolet spectrometer, embedded computer and power supply are placed in mainframe box, have between described opening gas sensing head and mainframe box and only Optic transmission fiber is connected biography light, described power supply is ultraviolet source, ultraviolet spectrometer and embedded computer are powered, this equipment uses difference absorption spectrum method and ultraviolet continuous light spectral analysis method to detect, do not discharged particulate matter and other gases in waste gas by steam and boats and ships to be affected, measurement result is more stable.

Description

A kind of portable boats and ships throat discharge waste gas sulfur dioxide detector
Technical field
The present invention relates to environmental monitoring technology field, particularly relate to a kind of portable boats and ships throat discharge waste gas dioxy Change sulfur content detector.
Background technology
Boats and ships discharge waste gas atmospheric pollution, particularly at harbour, straits and some course lines are intensive, boats and ships flow is big district Territory, has become as primary pollution source.Sulfur dioxide is the important pollutant in boats and ships discharge waste gas, mainly by bunker fuel oil The burning of sulfur-bearing thing produces.International Maritime Organization, for limiting sulfur dioxide (SO2) emissions, has carried out strict limit to bunker oil sulfur content System.Department of Transportation of China in Pearl River Delta, the Yangtze River Delta, Circum-Bohai Sea (Jing-jin-ji region) waters delimit boats and ships emission control district, formulate The pollutant emission control programs such as strict sulfur dioxide, started to perform on January 1st, 2016.Dioxy is discharged for boats and ships The control changing sulfur mainly has two ways, and one is to use low-sulphur fuel, such as low sulfur content distillate or liquefied natural gas etc., one Plant is that boats and ships discharge waste gas is carried out desulfurization process so that it is reach discharge standard.For strict sulfur dioxide (SO2) emissions controlling party The execution of case, it is desirable to have strict supervision measure, different Ship Types has different discharge standards, and this adds to supervision Difficulty.
Ship chimney mouth content of sulfur dioxide is carried out detection is one of maximally effective detection mode, and existing market does not also have Relevant equipment is for the content of sulfur dioxide detection of ship chimney mouth discharge waste gas.Therefore the portable set being correlated with it is badly in need of, It is capable of the detection of ship chimney mouth discharge waste gas content of sulfur dioxide, meets supervision demand.
Summary of the invention
In order to overcome above-mentioned the deficiencies in the prior art, the invention provides a kind of portable boats and ships throat discharge waste gas two Sulfur oxide content detector scheme, it is possible to make supervisor's convenient detection boats and ships discharge waste gas content of sulfur dioxide the most up to standard.
For achieving the above object, the present invention provides following technical scheme: a kind of portable boats and ships throat discharges waste gas two Sulfur oxide content detector, uses ultra-violet absorption spectrum technology to carry out the detection of sulfur dioxide concentration.Detector includes ultraviolet light Source, Optic transmission fiber, opening gas sensing head, ultraviolet spectrometer, embedded computer, power supply, mainframe box.Ultraviolet source, purple External spectrum instrument, embedded computer and power supply are placed in mainframe box.The ultraviolet light that ultraviolet source sends transmits through Optic transmission fiber To opening gas sensing head, light beam is anti-by solid back-reflections device after being absorbed by sulfur dioxide in opening gas sensing head Being emitted back towards Optic transmission fiber, the light of return enters ultraviolet spectrometer by Optic transmission fiber, and ultraviolet spectrometer obtains absorption spectrum, embedded Computer is analyzed gathering spectrum, calculates the concentration of sulfur dioxide.Power supply is ultraviolet source, ultraviolet spectrometer and embedding Formula computer power supply.In use, mainframe box can be carried with or be placed on home, operator by operator Being stretched into by opening gas sensing head with retractable support lever in the smoke evacuation of ship chimney mouth and detect, opening gas senses Head with have between mainframe box and only Optic transmission fiber is connected pass light.
The spectrum of above-mentioned ultraviolet source contains the ultraviolet spectral region of 280~310nm, can be selected for xenon flash lamp or ultraviolet LED light source, ultraviolet source is synchronized to drive by ultraviolet spectrometer.
The spectral response range of above-mentioned ultraviolet spectrometer covers 280~310nm, and resolution is better than 0.3nm, can use plane Grating or concave grating, as beam splitter, use line array CCD or linear array CMOS or PDA as electrooptical device.
Above-mentioned Optic transmission fiber uses big core diameter UV fiber, preferably synthetic quartz optical fiber, has foot in ultraviolet spectral range Enough spectral transmittances.Having two optical fiber, one end of first optical fiber connects light source, and one end of second optical fiber connects ultraviolet Spectrogrph, the other end of two optical fiber was placed in same protection sleeve pipe before stretching out mainframe box, and kept optical fiber head to put down Together.Connect from light source one end optical fiber also can be combined composition fibre bundle with multifiber, improve the energy passing light.
Above-mentioned opening gas sensing head uses exotic material, optional pottery or stainless steel material.Opening gas One end of sensing head connects Optic transmission fiber and collimating mirror, and a solid back-reflections device is laid in one end.Collimating mirror uses ultraviolet saturating The glass material that rate of crossing is good and thermal coefficient of expansion is little, preferably JGS1 melting quartz glass, one end of Optic transmission fiber is in collimation The position of focal plane of mirror so that the collimated rear outgoing of light transmitted from light source.Emergent light is backtracking after solid back-reflections device, Collimated mirror enters, after assembling, the optical fiber connecting ultraviolet spectrometer.Light beam transmits one between collimating mirror and solid back-reflections device Individual back and forth, absorbed by sulfur dioxide gas simultaneously.
Above-mentioned sulfur dioxide concentration computational methods are, will collect original spectrum and carry out pretreatment and high-pass filtering, and obtain Sulfur dioxide differential absorption cross-section, then carry out least square fitting with standard section, obtain ultimate density data.This method inverting Precision is high, can effectively remove the interference of other gas.
Compared with prior art, the invention has the beneficial effects as follows:
(1) use ultraviolet continuous light spectral analysis method to detect, do not disturbed by steam.
(2) using difference absorption spectrum method, not scattered by particulate matter in boats and ships discharge waste gas is affected, not by other gas The interference of body, measurement result is more stable.
(3) sensing head directly detects at ship chimney mouth, and measurement result is more accurate than remote measurement.
(4) volume is little, lightweight, power consumption is little, be easy to carry, and alleviates the burden of law enfrocement official.
Accompanying drawing explanation
Fig. 1 is that a kind of portable boats and ships throat discharges waste gas sulfur dioxide detector schematic diagram.
Fig. 2 is the sulfur dioxide gas spectral absorption cross section at ultraviolet light spectral coverage.
Fig. 3 is the sulfur dioxide gas difference absorption spectrum at ultraviolet light spectral coverage.
Fig. 4 is the sulfur dioxide gas difference absorption spectrum at ultraviolet spectral coverage of variable concentrations.
Detailed description of the invention
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in the embodiment of the present invention is carried out clear, complete Describe, it is clear that described embodiment is only a part of embodiment of the present invention rather than whole embodiments wholely.Based on Embodiment in the present invention, it is every other that those of ordinary skill in the art are obtained under not making creative work premise Embodiment, broadly falls into the scope of protection of the invention.
Embodiment 1
It is illustrated in figure 1 the principle signal of a kind of portable boats and ships throat discharge waste gas sulfur dioxide detector Figure.Detector mainly includes ultraviolet source 1, Optic transmission fiber 2, opening gas sensing head 3, ultraviolet spectrometer 4, embedding assembly Machine 5, power supply 6, mainframe box 7.Ultraviolet source 1, ultraviolet spectrometer 4, embedded computer 5 and power supply 6 are both placed in mainframe box 7 In.The ultraviolet light that ultraviolet source 1 sends is coupled into Optic transmission fiber 2, transmits to opening gas sensing head 3, light through Optic transmission fiber 2 Bundle is reflected back Optic transmission fiber 2 by solid back-reflections device 11 after being absorbed by sulfur dioxide in opening gas sensing head 3, returns Light enter ultraviolet spectrometer 4 by Optic transmission fiber 2, ultraviolet spectrometer 4 obtains absorption spectrum, and embedded computer 5 is to collection Spectrum is analyzed, and calculates the concentration of sulfur dioxide.Power supply 6 is ultraviolet source 1, ultraviolet spectrometer 4 and embedded computer 5 Power supply.In use, mainframe box 7 can be carried with or be placed on home by operator, and operator are with stretching Opening gas sensing head 3 is stretched in the smoke evacuation of ship chimney mouth and detects by contracting support bar, opening gas sensing head 3 with Have between mainframe box 7 and only Optic transmission fiber 2 connects biography light.
In the present embodiment, ultraviolet source 1 selects 10W xenon flash lamp, and it has stronger continuous purple between 280~310nm Outer light radiation, ultraviolet source 1 is triggered control by ultraviolet spectrometer 4, works asynchronously with ultraviolet spectrometer 4, so can effectively reduce Light source power consumption.Xenon flash lamp belongs to cold light source, can moment luminous, it is not necessary to preheating, luminous efficiency is high, is particularly suitable for portable setting Standby.Ultraviolet spectrometer 4 selects aberration correction concave holographic grating 12 as beam splitter, uses ultraviolet to strengthen line array CCD 13 and makees For photoelectric sensor, resolution is 0.1nm, this spectrogrph only one of which optical element, has that veiling glare is little, the efficiency of light energy utilization is high Advantage.Optic transmission fiber 2 uses the synthetic quartz optical fiber of anti-ultraviolet radiation, has two, and one end of first optical fiber connects purple Outer light source 1, one end of second optical fiber connects ultraviolet spectrometer 4, and the other end of two optical fiber was placed before stretching out mainframe box Enter in same protection sleeve pipe, and keep optical fiber head concordant.In order to improve the efficiency of light energy utilization of light source, at light source 1 and biography light light Increase ultraviolet lens 8 between fine 2, play the effect of converging light so that outgoing luminous energy coupled into optical fibres.Opening gas passes Sense 3 uses 316L stainless steel material.One end of open sensing head 3 connects Optic transmission fiber 2, places one after Optic transmission fiber 2 Individual collimating mirror 9, the JGS1 fused quartz glass material that collimating mirror 9 uses ultraviolet permeability good and thermal coefficient of expansion is little, pass light One end of optical fiber 2 is in the position of focal plane of collimating mirror 9 so that the collimated rear outgoing of light transmitted from ultraviolet source 1.Opening gas The other end of sensing head 3 lays the solid back-reflections device 11 of a JGS1 fused quartz material.In the middle of opening gas sensing head 3 Having an open cavity 10, light beam is absorbed by sulfur dioxide gas in time passing therebetween, and emergent light is through solid back-reflections Backtracking after device 11, more collimated mirror 9 post-concentration enters to connect the optical fiber of ultraviolet spectrometer 4.Embedded computer 5 is selected general Industry embedded computer, has controls, stores and data processing function, and can the work of control system.Power supply 6 uses lithium Ion battery, it is ensured that detector can work more than 5 hours continuously.
Be illustrated in figure 2 sulfur dioxide gas absorption cross-section between 240~320nm, it can be seen that 280~ Having obvious periodic modulation characteristic between 310nm, its modulation depth is linear with gas concentration.This characteristic can be utilized Use high-pass filtering method to extract the fast changing portion of absorption spectrum, filter out and comprise intensity of light source change, various scattering The low frequency variations part caused, i.e. differential absorption cross-section (Fig. 3) so that measurement result is not disturbed by other factors, Fig. 4 is dioxy Change differential absorption cross-section under sulfur variable concentrations.

Claims (9)

1. a portable boats and ships throat discharge waste gas sulfur dioxide detector, including ultraviolet source (1), Optic transmission fiber (2), opening gas sensing head (3), ultraviolet spectrometer (4), embedded computer (5), power supply (6), mainframe box (7), described Ultraviolet source (1), ultraviolet spectrometer (4), embedded computer (5) and power supply (6) are placed in series in mainframe box (7);Described It is connected by Optic transmission fiber (2) between opening gas sensing head (3) with mainframe box (7);Described power supply (6) is ultraviolet source (1), ultraviolet spectrometer (4) and embedded computer (5) power supply;It is characterized in that: the ultraviolet that described ultraviolet source (1) sends Light is through described Optic transmission fiber (2) transmission to described opening gas sensing head (3), and described ultraviolet light is by described open In gas sensing head (3), sulfur dioxide gas is reflected back described Optic transmission fiber (2) by solid back-reflections device (11) after absorbing, By the ultraviolet spectrometer (4) described in described Optic transmission fiber (2) entrance, described ultraviolet spectrometer (4) obtains absorption spectrum, The spectrum gathered is analyzed by described embedded computer (5), calculates the concentration of sulfur dioxide.
One the most according to claim 1 portable boats and ships throat discharge waste gas sulfur dioxide detector, it is special Levy and be: between described light source (1) and Optic transmission fiber (2), be provided with a ultraviolet lens (8).
One the most according to claim 1 portable boats and ships throat discharge waste gas sulfur dioxide detector, it is special Levy and be: in the middle of described opening gas sensing head (3), have an open cavity (10).
One the most according to claim 1 portable boats and ships throat discharge waste gas sulfur dioxide detector, it is special Levy and be: the Optic transmission fiber (2) described in the connection of one end of described opening gas sensing head (3) and collimating mirror (9), another End lays described solid back-reflections device (11).
One the most according to claim 1 portable boats and ships throat discharge waste gas sulfur dioxide detector, it is special Levy and be: described ultraviolet spectrometer (4) selects aberration correction concave holographic grating (12) as beam splitter, uses ultraviolet to increase Strong line array CCD (13) is as photoelectric sensor.
One the most according to claim 1 portable boats and ships throat discharge waste gas sulfur dioxide detector, it is special Levy and be: described ultraviolet source (1) selects xenon flash lamp or ultraviolet LED light source.
One the most according to claim 1 portable boats and ships throat discharge waste gas sulfur dioxide detector, it is special Levy and be: described Optic transmission fiber (2) uses big core diameter UV fiber.
One the most according to claim 1 portable boats and ships throat discharge waste gas sulfur dioxide detector, it is special Levy and be: described opening gas sensing head (3) uses exotic material.
One the most according to claim 1 portable boats and ships throat discharge waste gas sulfur dioxide detector, it is special Levy and be: it is will to collect original spectrum and carry out pre-place that described embedded computer (5) calculates the method for sulfur dioxide concentration Reason and high-pass filtering, obtain sulfur dioxide differential absorption cross-section, then carry out least square fitting with standard section, obtain the denseest Degrees of data.
CN201610629955.2A 2016-08-04 2016-08-04 A kind of portable boats and ships throat discharge waste gas sulfur dioxide detector Pending CN106198428A (en)

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Cited By (6)

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Publication number Priority date Publication date Assignee Title
CN107389880A (en) * 2017-09-08 2017-11-24 交通运输部天津水运工程科学研究所 A kind of ship tail gas mobile monitoring method
CN108169143A (en) * 2018-01-15 2018-06-15 杭州春来科技有限公司 Minimum discharge measuring system and equipment
CN109632681A (en) * 2018-12-29 2019-04-16 青岛海纳光电环保有限公司 Surrounding air sulfur dioxide detection device and detection method
CN110275477A (en) * 2018-03-16 2019-09-24 上海高菩环保科技有限公司 A kind of flue gas emission monitoring method and system
CN111308015A (en) * 2020-01-15 2020-06-19 交通运输部天津水运工程科学研究所 Automatic identification method for suspected peak of ship tail gas telemetry data
CN113533652A (en) * 2021-07-20 2021-10-22 厦门中源能链科技有限公司 Terminal for detecting and controlling carbon emission process and method thereof

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CN105548057A (en) * 2016-01-12 2016-05-04 中绿环保科技股份有限公司 Flue gas analysis and measurement method implemented through ultraviolet spectrum
CN105738306A (en) * 2016-04-13 2016-07-06 天津大学 Portable fire control emergency rescue multi-gas rapid remote sensor and detecting method
CN105784621A (en) * 2016-05-16 2016-07-20 青岛市光电工程技术研究院 Device for detecting sulfur dioxide in marine exhaust gas based on unmanned aerial vehicle platform
CN205898670U (en) * 2016-08-04 2017-01-18 青岛市光电工程技术研究院 Portable boats and ships chimney opening discharged waste gas sulfur dioxide content detector

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CN202177572U (en) * 2011-07-29 2012-03-28 天津同阳科技发展有限公司 Spectral measuring system for multi-component gas
CN202421062U (en) * 2011-12-15 2012-09-05 西安鼎研科技有限责任公司 Ultraviolet analyzer for measuring sulfur dioxide and nitrogen oxides
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107389880A (en) * 2017-09-08 2017-11-24 交通运输部天津水运工程科学研究所 A kind of ship tail gas mobile monitoring method
CN108169143A (en) * 2018-01-15 2018-06-15 杭州春来科技有限公司 Minimum discharge measuring system and equipment
CN110275477A (en) * 2018-03-16 2019-09-24 上海高菩环保科技有限公司 A kind of flue gas emission monitoring method and system
CN109632681A (en) * 2018-12-29 2019-04-16 青岛海纳光电环保有限公司 Surrounding air sulfur dioxide detection device and detection method
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CN111308015A (en) * 2020-01-15 2020-06-19 交通运输部天津水运工程科学研究所 Automatic identification method for suspected peak of ship tail gas telemetry data
CN113533652A (en) * 2021-07-20 2021-10-22 厦门中源能链科技有限公司 Terminal for detecting and controlling carbon emission process and method thereof

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