CN106198314A - A kind of simple viscosity detecting device being applicable to water reducer and using method thereof - Google Patents

A kind of simple viscosity detecting device being applicable to water reducer and using method thereof Download PDF

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Publication number
CN106198314A
CN106198314A CN201610534491.7A CN201610534491A CN106198314A CN 106198314 A CN106198314 A CN 106198314A CN 201610534491 A CN201610534491 A CN 201610534491A CN 106198314 A CN106198314 A CN 106198314A
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CN
China
Prior art keywords
packing groove
water
reservoir
water reducer
filler
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CN201610534491.7A
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Chinese (zh)
Inventor
乔敏
高南箫
冉千平
刘冠男
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BOT NEW MATERIALS TAIZHOU Co Ltd
Sobute New Materials Co Ltd
Nanjing Bote Building Materials Co Ltd
Taizhou Jiangyan Bote New Materials Co Ltd
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BOT NEW MATERIALS TAIZHOU Co Ltd
Sobute New Materials Co Ltd
Nanjing Bote Building Materials Co Ltd
Taizhou Jiangyan Bote New Materials Co Ltd
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Priority to CN201610534491.7A priority Critical patent/CN106198314A/en
Publication of CN106198314A publication Critical patent/CN106198314A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N11/00Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties
    • G01N11/02Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties by measuring flow of the material
    • G01N11/04Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties by measuring flow of the material through a restricted passage, e.g. tube, aperture
    • G01N11/06Investigating flow properties of materials, e.g. viscosity, plasticity; Analysing materials by determining flow properties by measuring flow of the material through a restricted passage, e.g. tube, aperture by timing the outflow of a known quantity

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  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)

Abstract

The present invention provides a kind of simple viscosity detecting device being applicable to water reducer and using method thereof, and its structure includes apparatus main body and outer layer sleeve;Outer layer sleeve is thermostatted water sleeve pipe (8);Described apparatus main body is provided with reservoir (3) and packing groove (4), has middle siphunculus road to connect reservoir (3) and packing groove (4);One end, middle siphunculus road extension becomes charge door (1), and the other end is discharging opening, and discharge outlet is provided with discharge valve (7);In above reservoir, siphunculus road is provided with fluid level scale (2 1), is provided with lower fluid level scale (2 2) on the middle siphunculus of packing groove (4) and the centre of reservoir (3), is provided with filler supporting plate (6) in the middle siphunculus of packing groove (4) lower section.Use device of the present invention can realize the quick detection of water reducer mother solution performance.The detection method using device of the present invention has efficiently, environmental protection, high reliability.

Description

A kind of simple viscosity detecting device being applicable to water reducer and using method thereof
Technical field
The present invention relates to a kind of simple viscosity detecting device being applicable to water reducer and using method thereof, described device is special Under the conditions of being applicable to continuous prodution, the quick of water reducer mother solution performance detects.
Background technology
Water reducer is indispensable material and the core technology manufacturing modern concrete.Fast development along with China's capital construction And gradually the popularizing of commerical ready-mixed concrete, the demand of water reducer is increased year by year, at present, the market of China's water reducer product holds Amount reaches nearly ten million ton.
The production of water reducer includes that mother solution produces and finished product compounds two main process, wherein, the quality of water reducer mother solution It it is the deciding factor affecting end properties.On market, the water reducer mother solution of main flow includes polycarboxylic acids, sulfonated acetone formaldehyde condensation polymer Thing, naphthalene sulfonic acid formaldehyde condensation polymer, the water-soluble polymer such as sulfamic acid phenolformaldehyde condensate and melamino-formaldehyde condensation polymer.
During water reducer factory continuous prodution, need water reducer mother solution and finished product are carried out performance detection, tradition Detection method be by mixing concrete, measure water-reducing rate.But, there is a lot of drawback in the method: one is mixed concrete Needing 3~5 people's cooperatings, labor intensity is big, poor working environment.The raw materials such as two is to consume a large amount of cement, sandstone, have tested Finish and produce again substantial amounts of concrete rubbish and be difficult to process.Three is that testing result can be unstable because of material quality fluctuation.
The yield produced due to water reducer is huge, and human and material resources and Environmental costs that the problems referred to above cause are very important 's.It would therefore be highly desirable to develop the most feasible a kind of novel water reducer method for testing performance.
Summary of the invention
For prior art exist deficiency, the present invention provide a kind of simple viscosity detecting device being applicable to water reducer and Its using method, uses this device can realize the quick detection of water reducer mother solution performance.Use the inspection of device of the present invention Survey method has efficiently, environmental protection, high reliability.
The simple viscosity detecting device being applicable to water reducer of the present invention, its structure includes apparatus main body and outer layer jacket Pipe;Outer layer sleeve is thermostatted water sleeve pipe;
Described apparatus main body is provided with reservoir 3 and packing groove 4, has middle siphunculus road to connect reservoir 3 and packing groove 4;In logical Pipeline one end extension becomes charge door 1, and the other end is discharging opening, and discharge outlet is provided with discharge valve 7;Upper Fang Zhongtong at reservoir Pipeline is provided with fluid level scale 2-1, is provided with lower fluid level scale 2-2 on the middle siphunculus of the centre of packing groove 4 and reservoir 3, Middle siphunculus below packing groove 4 is provided with filler supporting plate 6.
It is placed with filler 5 in packing groove 4;
Thermostatted water sleeve pipe 8 wraps up reservoir 3 to packing groove 4 position;Thermostatted water sleeve pipe 8 is arranged over water outlet at reservoir 3 Mouthful, below packing groove 4, it is provided with water inlet.
Described filler 5 is divided into upper and lower two-layer, the particle size range of upper strata filler 5 5~10mm, the particle diameter of lower floor's filler 5 Scope is 2~5mm.
In principle, any absorption or the inert substance of chemical reaction is not occurred to can serve as filler with water reducer mother solution 5。
Described packing groove 4 capacity is 5~20mL;
The capacity of described reservoir 3 is 1~5 times of packing groove 4 capacity;
Preferably, described filler 5 is glass fragment, potsherd, stone, resin particle;
Described resin particle refers to PP resin particle or ABS resin granule.
Described filler supporting plate 6 is cavernous structure, and its mesh size is slightly less than filler 5 particle diameter.
The test philosophy of apparatus of the present invention is: equipped with filler 5 granule of particular design in apparatus of the present invention packing groove 4, when When sample is by packing groove 4, by the flow resistance by filler.The flow resistance that the sample of different viscosities is subject to is different, Viscosity is the biggest, and flow resistance is the biggest, and the corresponding delivery time is the longest.Test obtains delivery time data, i.e. reflects tested The viscosity of sample.
For taking into account mobility and discrimination, the described filler 5 voidage in packing groove 4 is 30~70%, suitably tests Water reducer mother solution mass concentration scope 5~20%;
The definition of described filler 5 voidage is:
When filler 5 voidage is too low or water reducer mother liquid concentration is too high, sample poor fluidity in a device, during outflow Between long, even can occur block packing groove 4 risk;Otherwise, when voidage is high or concentration is too low, device is to different viscosities sample Discrimination can decline.
The production of water reducer mother solution is by polyreaction by monomer, obtains the mistake with the polymer of certain molecular weight Journey.Both there are some researches show, its performance is played vital impact by the relative molecular mass of water reducer, typically at certain a part In amount is interval, water reducer performance can reach optimum, and too high or too low molecular weight all can damage water reducer performance.Additionally, for The water reducer sample of one fixed structure, under identical solution concentration, its solution viscosity can reflect molecular size range.In factory Under the conditions of continuous prodution, formula for a product and production technology determine that, its maximum variable affecting properties of product is i.e. molecule Whether amount reaches design load.For this situation, use the delivery time of apparatus of the present invention test water reducer sample, it is possible to table Levy its molecular weight ranges whether having reached manufacturing technique requirent, then evaluate its performance the most qualified.
Apparatus of the present invention are through particular design, by plant bulk ratio reasonable in design, double-deck filler 5 structure and suitable In filler 4 voidage and filler 5 granular size so that different viscosities routine water reducer mother solution product can be in apparatus of the present invention The differentiation effect that middle acquisition is good, is particularly well-suited to its viscosity measurements.
When using this device, thermostatted water passes in and out from the intake-outlet of warm water sleeve pipe.
The using method of apparatus of the present invention is: first, is disposed vertically apparatus of the present invention, and thermostatted water sleeve pipe 8 bottom in and top out is led to Enter the thermostatted water of 25 DEG C, close discharge valve 7;Then, detected sample is added from charge door 1 so that it is be full of packing groove 4 and storage Liquid bath 3, liquid level is concordant with upper fluid level scale 2-1;Finally, open discharge valve 7, make detected sample naturally flow out, use the second Table record liquid level is down to the time of lower fluid level scale 2-2 from upper fluid level scale 2-1, is the delivery time of this detection sample.
The concrete operation method that device of the present invention quickly detects water reducer mother solution performance in continuous prodution condition is:
1. selection standard certified products.Standard certified products should be that factory produces recently, through concrete water-reducing ratio experiment inspection It is qualified to survey, and the equivalent of products more than 20 batches of same model uniformly mixes, and represents the average behavior water of factory's certified products Flat.
Test detection sample and the solids content of standard certified products the most respectively.
3. dilution detection sample is with standard certified products to identical mass concentration, makes the mass concentration scope after dilution 5 ~20%.
4. use this device to test detection sample and the delivery time of standard certified products respectively.
5. whether judge sample passes according to delivery time relative standard deviation values, " │ delivery time relative standard deviation values │ 3.0% " time, it is determined that sample passes, " │ delivery time relative standard deviation values │ 3.0% ", it is determined that for failed sample, wherein:
The quick performance of the water reducer mother solution that apparatus of the present invention manufacture with polyreaction under the conditions of being applicable to continuous prodution Detection, described water reducer mother solution includes but not limited to polycarboxylate water-reducer (PCA), sulfonated acetone formaldehyde polycondensate (SAF), naphthalene sulphur Acid formaldehyde condensation products (SNF), sulfamic acid phenolformaldehyde condensate (SPF), melamino-formaldehyde condensation polymer (SMF).
The inventive method provides the benefit that: the most greatly simplified water reducer mother solution performance detection under the conditions of continuous prodution Process, improve labor efficiency, alleviate working strength;2. detection process need not consume the raw material such as cement, sandstone, does not produces Growing concrete rubbish, economizes on resources, and protects environment.3. testing result is reproducible, it is to avoid material quality in traditional method The detection error that fluctuation causes.4. detect complete sample can recycle, reduce waste.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of apparatus of the present invention, and including (1) charge door, (2-1) upper fluid level scale, under (2-2), liquid level is carved Degree, (3) reservoir, (4) packing groove, (5) filler, (6) filler supporting plate, (7) discharge valve, (8) thermostatted water sleeve pipe;
Detailed description of the invention
The method that in the embodiment of the present invention, water-reducing rate test specifies according to GB 8076-2008 is carried out, water reducer sample used Being thered is provided by Jiangsu Subotexin Material Co., Ltd, detected sample and corresponding standard certified products are on the same day, Test under same experiment material, to ensure result accuracy.The judgment criteria that whether qualified properties of sample is is: " │ test specimens Product water-reducing rate-standard certified products water-reducing rate │ 1.0% " time, it is determined that test sample is qualified, the most defective;
Device concrete structure of the present invention as it is shown in figure 1, be provided with reservoir 3 and packing groove 4 and thermostatted water sleeve pipe, Middle siphunculus road is had to connect reservoir 3 and packing groove 4;One end, middle siphunculus road extension becomes charge door 1, and the other end is discharging opening, discharging Discharge valve 7 it is provided with at Kou;In above reservoir, siphunculus road is provided with fluid level scale 2-1, at packing groove 4 and reservoir 3 The middle siphunculus of centre be provided with lower fluid level scale 2-2, the middle siphunculus below packing groove 4 is provided with filler supporting plate 6.
It is placed with filler 5 in packing groove 4;
Thermostatted water sleeve pipe 8 wraps up reservoir 3 to packing groove 4 position;Thermostatted water sleeve pipe 8 is arranged over water outlet at reservoir 3 Mouthful, below packing groove 4, it is provided with water inlet.
Described filler 5 is divided into upper and lower two-layer, the particle size range of upper strata filler 5 5~10mm, the particle diameter of lower floor's filler 5 Scope is 2~5mm.
Described filler 5 is glass fragment;
Described filler supporting plate 6 is cavernous structure, and its mesh size is slightly less than filler 5 particle diameter.
The detection operational approach of embodiment is:
Test detection sample and the solids content of standard certified products the most respectively.
2. the mass concentration that dilution detection sample is the most identical with standard certified products.
3. use this device to test detection sample and the delivery time of standard certified products respectively.
First, being disposed vertically Fig. 1 shown device, thermostatted water sleeve pipe 8 bottom in and top out is passed through the thermostatted water of 25 DEG C, closes discharging Valve 7;Then, detection sample is added from charge door 7 so that it is be full of packing groove 4 and reservoir 3, liquid level and upper fluid level scale 2-1 Concordant;Finally, open discharge valve 7, make detected sample naturally flow out, use stopwatch record liquid level from upper fluid level scale 2-1 It is down to the time of lower fluid level scale 2-2, is the delivery time of this detection sample.
4. whether judge sample passes according to delivery time relative standard deviation values, " │ delivery time relative standard deviation values │ 3.0% " time, it is determined that sample passes, " │ delivery time relative standard deviation values │ 3.0% ", it is determined that for failed sample, wherein:
Specific embodiment all uses above-mentioned operational approach, but the device parameter of each embodiment, water reducer kind, dilution After concentration be different.Table 1 lists apparatus of the present invention parameter used in each embodiment:
Invention device parameter used by each embodiment of table one
Table 2 is the testing result of each embodiment, the result tested including the inventive method testing result and water-reducing rate:
From the results shown in Table 2: " the │ delivery time relative deviation of the detection sample of embodiment 7,9,12,13,16 Value │ " more than 3.0%, it is judged to defective through the inventive method, detection sample " the │ delivery time relative deviation of remaining embodiment It is worth │ " less than 3.0%, judge it is qualified through the inventive method, this result and the conclusion phase one of use water-reducing rate method test Cause.
In embodiment 1~7, employing apparatus of the present invention of same size and filler, test sample is all PCA.Wherein, real Executing example 1, in 2,5,6, respectively the standard substance of PCA have been diluted to 5%, the mass concentration of 10%, 15%, 20%, through the present invention Device to test, their delivery time is 75.2s, 117.1s, 135.0s and 163.6s successively.It can be seen that in other conditions Under conditions of Yi Ding, along with the increase of polyalcohol water reducing agent concentration, its delivery time in apparatus of the present invention is to increase.
Embodiment 2,3, in 4, standard substance and detection sample have all been diluted to the mass concentration of 10%, close identical standard Lattice product, the delivery time using apparatus of the present invention retest to record is 117.1,117.3 and 116.9 respectively, and undulatory property is the least, The reproducible of this detection device detection sample is described.
Table 2: use the inventive method and water-reducing rate method of testing testing result
Above the finite number embodiment of the present invention is described in detail, but described content has been only the preferable of the present invention Embodiment, it is impossible to be considered the practical range for limiting the present invention.All impartial changes made according to the present patent application scope with Improve, within all should still belonging to the patent covering scope of the present invention.

Claims (10)

1. the simple viscosity detecting device being applicable to water reducer, it is characterised in that its structure includes apparatus main body and outer layer Sleeve pipe;Outer layer sleeve is thermostatted water sleeve pipe (8);
Described apparatus main body is provided with reservoir (3) and packing groove (4), has middle siphunculus road to connect reservoir (3) and packing groove (4); One end, middle siphunculus road extension becomes charge door (1), and the other end is discharging opening, and discharge outlet is provided with discharge valve (7);At reservoir In Shang Fang, siphunculus road is provided with fluid level scale (2-1), under being provided with on the middle siphunculus of packing groove (4) and the centre of reservoir (3) Fluid level scale (2-2), is provided with filler supporting plate (6) in the middle siphunculus of packing groove (4) lower section;
It is placed with filler (5) in packing groove (4);
Thermostatted water sleeve pipe (8) parcel reservoir (3) is to packing groove (4) position;Thermostatted water sleeve pipe (8) sets in reservoir (3) top There is outlet, be provided with water inlet in packing groove (4) lower section;
Described filler (5) is divided into upper and lower two-layer, the particle size range of upper strata filler 5~10mm, the particle size range of lower floor's filler 2~5mm;
Any absorption or the inert substance of chemical reaction is not occurred to can serve as filler (5) with water reducer mother solution.
It is applicable to the simple viscosity detecting device of water reducer the most according to claim 1, it is characterised in that described packing groove (4) capacity is 5~20mL;The capacity of described reservoir (3) is 1~5 times of packing groove 4 capacity.
It is applicable to the simple viscosity detecting device of water reducer the most according to claim 1, it is characterised in that described filler (5) It is glass fragment, potsherd, stone, resin particle.
It is applicable to the simple viscosity detecting device of water reducer the most according to claim 3, it is characterised in that described resin particle Refer to PP resin particle or ABS resin granule.
It is applicable to the simple viscosity detecting device of water reducer the most according to claim 1, it is characterised in that described filler supporting plate (6) being cavernous structure, its mesh size is less than filler (5) particle diameter.
It is applicable to the simple viscosity detecting device of water reducer the most according to claim 1, it is characterised in that described filler (5) Voidage in packing groove (4) is 30~70%.
7. being applicable to the using method of the simple viscosity detecting device of water reducer described in any one in claim 1-6, it is special Levying and be, first, be disposed vertically this device, thermostatted water sleeve pipe (8) bottom in and top out is passed through the thermostatted water of 25 DEG C, closes discharge valve (7);Then, detected sample is added from charge door (1) so that it is be full of packing groove (4) and reservoir (3), liquid level and upper liquid level Scale (2-1) is concordant;Finally, open discharge valve (7), make detected sample naturally flow out, use stopwatch record liquid level from upper Fluid level scale (2-1) is down to the time of lower fluid level scale (2-2), is the delivery time of this detection sample.
The most according to claim 7, method, it is characterised in that when using this device, thermostatted water is from the Inlet and outlet water of warm water sleeve pipe Mouth turnover.
Method the most according to claim 7, it is characterised in that the water reducer mother solution mass concentration scope of suitable test 5~ 20%.
10. according to method described in any one in claim 7-9, it is characterised in that concrete operation method is:
1) selection standard certified products.Standard certified products should be that factory produces recently, closes through concrete water-reducing ratio experiment detection Lattice, the equivalent of products more than 20 batches of same model uniformly mixes, and represents the average behavior level of factory's certified products;
2) test detects sample and the solids content of standard certified products respectively;
3) dilution detection sample and standard certified products are to the most identical mass concentration, make the mass concentration scope after dilution 5~ 20%;
4) this device is used to test detection sample and the delivery time of standard certified products respectively;
5) whether sample passes is judged according to delivery time relative standard deviation values, time " │ delivery time relative standard deviation values │ 3.0% ", Judge sample passes, " │ delivery time relative standard deviation values │ 3.0% ", it is determined that for failed sample, wherein:
CN201610534491.7A 2016-07-07 2016-07-07 A kind of simple viscosity detecting device being applicable to water reducer and using method thereof Pending CN106198314A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112540028A (en) * 2020-12-28 2021-03-23 西安特种设备检验检测院 Power law fluid viscosity parameter measuring device and measuring and calculating method

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JP2003172682A (en) * 2001-12-10 2003-06-20 Taisei Corp Container for flowing-down test
CN1645096A (en) * 2005-01-18 2005-07-27 武汉理工大学 Tester and testing method for high-sensitivity cement thick liquid flowability
CN102338728A (en) * 2010-07-21 2012-02-01 上海台界化工有限公司 Method for quickly comparing and detecting performance index of concrete water reducing agent
CN102353617A (en) * 2011-09-14 2012-02-15 武汉理工大学 Cement paste fluidity test device with high precision and high sensitivity and test method
CN102466608A (en) * 2010-11-01 2012-05-23 袁俊海 Determination method of limiting viscosity number of hydroxamic acid polyacrylamide
CN102778419A (en) * 2012-06-29 2012-11-14 江南大学 Device and method for determining fluidity of cement paste
CN203275179U (en) * 2013-04-03 2013-11-06 中国石油天然气股份有限公司 Multifunctional waterborne polymer colloid performance testing device
CN103439220A (en) * 2013-08-01 2013-12-11 杭州中旺科技有限公司 Jacket-type Z-shaped ubbelohde viscometer applicable to miniature full-automatic viscometer
CN104568660A (en) * 2014-12-22 2015-04-29 中铁成都工程检测咨询有限责任公司 Method for testing adaptability between water reducing agent and concrete and expansion degree test device
CN204330523U (en) * 2014-12-25 2015-05-13 郑州正佳能源环保科技有限公司 Be suitable for the determinator of polyacrylamide screen factor

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CN85202833U (en) * 1985-07-13 1987-01-07 中国科学院化学研究所 Gap viscosimeter
JP2003172682A (en) * 2001-12-10 2003-06-20 Taisei Corp Container for flowing-down test
CN1645096A (en) * 2005-01-18 2005-07-27 武汉理工大学 Tester and testing method for high-sensitivity cement thick liquid flowability
CN102338728A (en) * 2010-07-21 2012-02-01 上海台界化工有限公司 Method for quickly comparing and detecting performance index of concrete water reducing agent
CN102466608A (en) * 2010-11-01 2012-05-23 袁俊海 Determination method of limiting viscosity number of hydroxamic acid polyacrylamide
CN102353617A (en) * 2011-09-14 2012-02-15 武汉理工大学 Cement paste fluidity test device with high precision and high sensitivity and test method
CN102778419A (en) * 2012-06-29 2012-11-14 江南大学 Device and method for determining fluidity of cement paste
CN203275179U (en) * 2013-04-03 2013-11-06 中国石油天然气股份有限公司 Multifunctional waterborne polymer colloid performance testing device
CN103439220A (en) * 2013-08-01 2013-12-11 杭州中旺科技有限公司 Jacket-type Z-shaped ubbelohde viscometer applicable to miniature full-automatic viscometer
CN104568660A (en) * 2014-12-22 2015-04-29 中铁成都工程检测咨询有限责任公司 Method for testing adaptability between water reducing agent and concrete and expansion degree test device
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112540028A (en) * 2020-12-28 2021-03-23 西安特种设备检验检测院 Power law fluid viscosity parameter measuring device and measuring and calculating method

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