CN106192481A - A kind of leatherware coloring dyestuff binders - Google Patents

A kind of leatherware coloring dyestuff binders Download PDF

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Publication number
CN106192481A
CN106192481A CN201610653246.8A CN201610653246A CN106192481A CN 106192481 A CN106192481 A CN 106192481A CN 201610653246 A CN201610653246 A CN 201610653246A CN 106192481 A CN106192481 A CN 106192481A
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parts
dyestuff
leatherware
heated
adds
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CN201610653246.8A
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Inventor
丁希望
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Dongzhi County Yang Hu Zhen Hope Leather Factory
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Dongzhi County Yang Hu Zhen Hope Leather Factory
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Priority to CN201610653246.8A priority Critical patent/CN106192481A/en
Publication of CN106192481A publication Critical patent/CN106192481A/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/32—Material containing basic nitrogen containing amide groups leather skins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D06P1/48—Derivatives of carbohydrates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
    • D06P1/5242—Polymers of unsaturated N-containing compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613—Polyethers without nitrogen
    • D06P1/6138—Polymerisation products of glycols, e.g. Carbowax, Pluronics
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642—Compounds containing nitrogen
    • D06P1/649—Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6495—Compounds containing carbonamide -RCON= (R=H or hydrocarbons)
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341

Abstract

The invention discloses a kind of leatherware coloring dyestuff binders, relate to leatherware processing technique field, it is made up of the raw material of following parts by weight: terpene resin 15 20 parts, active hargil 10 15 parts, microwax 8 13 parts, linear low density polyethylene 6 11 parts, water-soluble chitosan 59 parts, hydrogenated rosin 48 parts, methoxy poly (ethylene glycol) 48 parts, petroleum coke 36 parts, ceramic 36 parts, adhesion promoter 24 parts, polyvinylpyrrolidone 24 parts, nanometer rubber powder 24 parts, polyacrylamide 12 parts, oleamide 12 parts, Borax 0.5 1 parts, butyl acetate 25 30 parts.Invention adhesives is not only good with remaining component compatibility of dyestuff, is effectively improved the dyestuff uniformity, and can significantly improve color firmness, resistance to water and the resistant of high or low temperature of dyestuff, thus expands dyestuff range in field of leather.

Description

A kind of leatherware coloring dyestuff binders
Technical field:
The present invention relates to leatherware processing technique field, be specifically related to a kind of leatherware coloring dyestuff binders.
Background technology:
In leather processing procedure, it usually needs leather is dyeed, leather is made to present various chromatic colour, with The color adapting to consumer uses demand.The tone that during leather coloring, leather to be given is bright-coloured and pure, also requires color and luster Uniformity, color firmness is high.But the color firmness of presently commercially available leather dye is general, this is mainly by dyestuff on leather Cohesive determines.For this problem, we develop a kind of leatherware coloring dyestuff binders, and the feature of environmental protection is strong, will It can significantly improve the color firmness of dyestuff after adding in dyestuff, thus the outward appearance improving leatherware uses quality.
Summary of the invention:
The technical problem to be solved is to provide a kind of resistance to water and resistant of high or low temperature is good and is conducive to improving The leatherware coloring dyestuff binders of dyestuff color firmness.
The technical problem to be solved uses following technical scheme to realize:
A kind of leatherware coloring dyestuff binders, is made up of the raw material of following parts by weight:
Terpene resin 15-20 part, active hargil 10-15 part, microwax 8-13 part, linear low density polyethylene 6-11 part, Water-soluble chitosan 5-9 part, hydrogenated rosin 4-8 part, methoxy poly (ethylene glycol) 4-8 part, petroleum coke 3-6 part, ceramic 3-6 Part, adhesion promoter 2-4 part, polyvinylpyrrolidone 2-4 part, nanometer rubber powder 2-4 part, polyacrylamide 1-2 part, oleic acid acyl Amine 1-2 part, Borax 0.5-1 part, butyl acetate 25-30 part；
Its preparation method comprises the steps:
(1) in butyl acetate, add terpene resin and linear low density polyethylene, be stirred continuously down and be heated to the shape that refluxes State isothermal holding 15min, adds hydrogenated rosin and petroleum coke, continues isothermal holding 15min, obtains material I；
(2) microwax is heated to 80-90 DEG C of insulation mixing 5min, is subsequently adding active hargil, ceramic and nanometer Rubber powder, continues to be heated to 120-130 DEG C of insulation mixing 10min, obtains material II；
(3) in material I, add material II, methoxy poly (ethylene glycol), adhesion promoter and polyacrylamide, then add Heat is to reflux state isothermal holding 10min, and process terminates the cooling of rear natural cooling, adds water-soluble after temperature is down to 50-60 DEG C Property chitosan, polyvinylpyrrolidone, oleamide and Borax, be sufficiently mixed uniformly.
Described adhesion promoter is made up of the raw material of following parts by weight: epoxide coal bituminous 10-15 part, C9 Petropols 7-12 part, polyethylene glycol oxide 5-8 part, rubber powder 5-8 part, super fine magnesia 4-7 part, polyoxylethylene abietate 4-7 part, hydrophobic Type nano silicon 3-5 part, glycerol trioleate 2-3 part, asbestos wool 1-2 part, glass powder 1-2 part, carbamide 0.5-1 part, receive Rice zinc oxide 0.5-1 part, its preparation method is: first to epoxide coal bituminous middle addition C9 Petropols, polyethylene glycol oxide and nanometer Zinc oxide, and it is heated to 120-130 DEG C of insulation mixing 15min, add rubber powder, polyoxylethylene abietate and hydrophobic type and receive Rice silicon dioxide, continues insulation mixing 10min, then lowers the temperature with 10 DEG C/min under ice-water bath, after temperature is down to 50-60 DEG C Add super fine magnesia, glycerol trioleate, asbestos wool, glass powder and carbamide, be sufficiently mixed uniformly.
The preparation method of described hydrophobic nano silicon dioxide is: 15 parts of tetraethyl orthosilicates add equivalent with volume ratio In the mixed solvent of 1:1 second alcohol and water preparation, stirring is micro-under microwave frequency 2450MHz, power 700W after forming homogeneous solution Ripple processes 5min, adds 1 part of polyoxyethylene lauryl ether, 0.5 part of beta-schardinger dextrin-and 0.5 part of titanate coupling agent, and mixing is all Continuing microwave treatment 5min after even, then stand 30min, and be dried 8h at 100-105 DEG C, gained solid abrasive becomes powder, Last roasting 3h at 550-600 DEG C.
The invention has the beneficial effects as follows: the present invention, with terpene resin as primary raw material, is aided with multiple auxiliary agent and prepares leather system Product coloring dyestuff binders, this binding agent is directly appended in dyestuff when using, not only good with remaining component compatibility of dyestuff, It is effectively improved the dyestuff uniformity, and color firmness, resistance to water and the resistant of high or low temperature of dyestuff can be significantly improved, thus expand Dyestuff range in field of leather.
Detailed description of the invention:
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot Close specific embodiment, the present invention is expanded on further.
Embodiment 1
(1) in 30 parts of butyl acetates, add 15 parts of terpene resins and 6 parts of linear low density polyethylene, be stirred continuously down and add Heat, to reflux state isothermal holding 15min, adds 4 parts of hydrogenated rosins and 3 parts of petroleum cokes, continues isothermal holding 15min, to obtain final product Material I；
(2) 10 parts of microwaxes are heated to 80-90 DEG C of insulation mixing 5min, are subsequently adding 10 parts of active hargil, 5 parts of potteries Micropowder and 2 parts of nanometer rubber powders, continue to be heated to 120-130 DEG C of insulation mixing 10min, obtain material II；
(3) in material I, material II, 4 parts of methoxy poly (ethylene glycol)s, 4 parts of adhesion promoters and 1 part of polyacrylamide are added Amine, is then heated to reflux state isothermal holding 10min, and process terminates the cooling of rear natural cooling, after temperature is down to 50-60 DEG C Add 6 parts of water-soluble chitosans, 3 parts of polyvinylpyrrolidones, 1 part of oleamide and 0.5 part of Borax, be sufficiently mixed uniformly.
Adhesion promoter is made up of the raw material of following parts by weight: first to 15 parts of epoxide coal bituminous 9 parts of C9 stones of middle addition Oleoresin, 5 parts of polyethylene glycol oxides and 0.5 part of nano zine oxide, and it is heated to 120-130 DEG C of insulation mixing 15min, add 5 Part rubber powder, 4 parts of polyoxylethylene abietate and 3 parts of hydrophobic nano silicon dioxide, continue insulation mixing 10min, then exist Lower the temperature with 10 DEG C/min under ice-water bath, add after temperature is down to 50-60 DEG C 4 parts of super fine magnesias, 2 parts of glycerol trioleate, 1 Part asbestos wool, 1 part of glass powder and 0.5 part of carbamide, be sufficiently mixed uniformly.
The preparation of hydrophobic nano silicon dioxide: 15 parts of tetraethyl orthosilicates are added equivalent with volume ratio 1:1 ethanol and In the mixed solvent of water preparation, stirring forms after homogeneous solution microwave treatment under microwave frequency 2450MHz, power 700W 5min, adds 1 part of polyoxyethylene lauryl ether, 0.5 part of beta-schardinger dextrin-and 0.5 part of titanate coupling agent, and mix homogeneously is follow-up Continuous microwave treatment 5min, then stands 30min, and is dried 8h at 100-105 DEG C, and gained solid abrasive becomes powder, finally in Roasting 3h at 550-600 DEG C.
Embodiment 2
(1) in 30 parts of butyl acetates, add 20 parts of terpene resins and 8 parts of linear low density polyethylene, be stirred continuously down and add Heat, to reflux state isothermal holding 15min, adds 6 parts of hydrogenated rosins and 3 parts of petroleum cokes, continues isothermal holding 15min, to obtain final product Material I；
(2) 8 parts of microwaxes are heated to 80-90 DEG C of insulation mixing 5min, are subsequently adding 10 parts of active hargil, 3 parts of potteries Micropowder and 2 parts of nanometer rubber powders, continue to be heated to 120-130 DEG C of insulation mixing 10min, obtain material II；
(3) in material I, material II, 5 parts of methoxy poly (ethylene glycol)s, 3 parts of adhesion promoters and 2 parts of polyacrylamides are added Amine, is then heated to reflux state isothermal holding 10min, and process terminates the cooling of rear natural cooling, after temperature is down to 50-60 DEG C Add 8 parts of water-soluble chitosans, 2 parts of polyvinylpyrrolidones, 1 part of oleamide and 0.5 part of Borax, be sufficiently mixed uniformly.
Adhesion promoter is made up of the raw material of following parts by weight: first to 15 parts of epoxide coal bituminous 7 parts of C9 stones of middle addition Oleoresin, 6 parts of polyethylene glycol oxides and 1 part of nano zine oxide, and it is heated to 120-130 DEG C of insulation mixing 15min, add 7 parts Rubber powder, 4 parts of polyoxylethylene abietate and 3 parts of hydrophobic nano silicon dioxide, continue insulation mixing 10min, then at ice Lower the temperature with 10 DEG C/min under water-bath, add after temperature is down to 50-60 DEG C 5 parts of super fine magnesias, 3 parts of glycerol trioleate, 1 part Asbestos wool, 1 part of glass powder and 0.5 part of carbamide, be sufficiently mixed uniformly.
The preparation of hydrophobic nano silicon dioxide: 15 parts of tetraethyl orthosilicates are added equivalent with volume ratio 1:1 ethanol and In the mixed solvent of water preparation, stirring forms after homogeneous solution microwave treatment under microwave frequency 2450MHz, power 700W 5min, adds 1 part of polyoxyethylene lauryl ether, 0.5 part of beta-schardinger dextrin-and 0.5 part of titanate coupling agent, and mix homogeneously is follow-up Continuous microwave treatment 5min, then stands 30min, and is dried 8h at 100-105 DEG C, and gained solid abrasive becomes powder, finally in Roasting 3h at 550-600 DEG C.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.The technology of the industry Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and Equivalent defines.

Claims (3)

1. a leatherware coloring dyestuff binders, it is characterised in that be made up of the raw material of following parts by weight:
Terpene resin 15-20 part, active hargil 10-15 part, microwax 8-13 part, linear low density polyethylene 6-11 part, water-soluble Property chitosan 5-9 part, hydrogenated rosin 4-8 part, methoxy poly (ethylene glycol) 4-8 part, petroleum coke 3-6 part, ceramic 3-6 part, attached Adhesion promoter 2-4 part, polyvinylpyrrolidone 2-4 part, nanometer rubber powder 2-4 part, polyacrylamide 1-2 part, oleamide 1-2 Part, Borax 0.5-1 part, butyl acetate 25-30 part；
Its preparation method comprises the steps:
(1) in butyl acetate, add terpene resin and linear low density polyethylene, be stirred continuously down and be heated to reflux state guarantor Temperature processes 15min, adds hydrogenated rosin and petroleum coke, continues isothermal holding 15min, obtains material I；
(2) microwax is heated to 80-90 DEG C of insulation mixing 5min, is subsequently adding active hargil, ceramic and nanometer rubber powder, Continue to be heated to 120-130 DEG C of insulation mixing 10min, obtain material II；
(3) in material I, add material II, methoxy poly (ethylene glycol), adhesion promoter and polyacrylamide, be then heated to Reflux state isothermal holding 10min, process terminates the cooling of rear natural cooling, adds water soluble shells after temperature is down to 50-60 DEG C Polysaccharide, polyvinylpyrrolidone, oleamide and Borax, be sufficiently mixed uniformly.
Leatherware coloring dyestuff binders the most according to claim 1, it is characterised in that described adhesion promoter Be made up of the raw material of following parts by weight: epoxide coal bituminous 10-15 part, C9 Petropols 7-12 part, polyethylene glycol oxide 5-8 part, Rubber powder 5-8 part, super fine magnesia 4-7 part, polyoxylethylene abietate 4-7 part, hydrophobic nano silicon dioxide 3-5 part, three Olein 2-3 part, asbestos wool 1-2 part, glass powder 1-2 part, carbamide 0.5-1 part, nano zine oxide 0.5-1 part, it is prepared Method is: first to epoxide coal bituminous middle addition C9 Petropols, polyethylene glycol oxide and nano zine oxide, and be heated to 120-130 DEG C insulation mixing 15min, adds rubber powder, polyoxylethylene abietate and hydrophobic nano silicon dioxide, continues insulation mixed Close 10min, then lower the temperature with 10 DEG C/min under ice-water bath, after temperature is down to 50-60 DEG C, adds super fine magnesia, three oleic acid Glyceride, asbestos wool, glass powder and carbamide, be sufficiently mixed uniformly.
Leatherware coloring dyestuff binders the most according to claim 2, it is characterised in that described hydrophobic nano two The preparation method of silicon oxide is: the mixing 15 parts of tetraethyl orthosilicates addition equivalent prepared with volume ratio 1:1 second alcohol and water is molten In agent, stirring forms after homogeneous solution microwave treatment 5min under microwave frequency 2450MHz, power 700W, adds 1 portion of Laurel Polyoxyethylenated alcohol, 0.5 part of beta-schardinger dextrin-and 0.5 part of titanate coupling agent, continue microwave treatment 5min, then after mix homogeneously Standing 30min, and be dried 8h at 100-105 DEG C, gained solid abrasive becomes powder, finally roasting 3h at 550-600 DEG C.
CN201610653246.8A 2016-08-10 2016-08-10 A kind of leatherware coloring dyestuff binders Withdrawn CN106192481A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106634158A (en) * 2017-01-11 2017-05-10 南平博士达节能科技有限公司 Nano coloring powder suitable for synthetic leather coating agent and preparation method thereof
CN106905753A (en) * 2017-03-20 2017-06-30 南平博士达节能科技有限公司 A kind of aqueous anti-pinhole agent suitable for synthetic leather
CN107034697A (en) * 2017-04-17 2017-08-11 东莞市科迪实业有限公司 Environmentally friendly dyeing liquor for the even dyeing of superfine fiber leather
CN107099185A (en) * 2017-04-25 2017-08-29 江西展邦科技有限公司 A kind of aqueous high temperature age resister suitable for synthetic leather
CN111909581A (en) * 2020-08-15 2020-11-10 温州市鹿城金米莉金足皮鞋厂 Wear-resistant leather shoes and processing technology thereof
CN112220159A (en) * 2019-07-14 2021-01-15 北京服装学院 Novel environment-friendly sole shoe material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102010602A (en) * 2010-09-30 2011-04-13 江西金安林产实业有限公司 Water-based tackifier resin emulsion and preparation method thereof
CN102470131A (en) * 2009-07-24 2012-05-23 帝国制药株式会社 Fentanyl-containing adhesive preparation for external use

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102470131A (en) * 2009-07-24 2012-05-23 帝国制药株式会社 Fentanyl-containing adhesive preparation for external use
CN102010602A (en) * 2010-09-30 2011-04-13 江西金安林产实业有限公司 Water-based tackifier resin emulsion and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106634158A (en) * 2017-01-11 2017-05-10 南平博士达节能科技有限公司 Nano coloring powder suitable for synthetic leather coating agent and preparation method thereof
CN106905753A (en) * 2017-03-20 2017-06-30 南平博士达节能科技有限公司 A kind of aqueous anti-pinhole agent suitable for synthetic leather
CN107034697A (en) * 2017-04-17 2017-08-11 东莞市科迪实业有限公司 Environmentally friendly dyeing liquor for the even dyeing of superfine fiber leather
CN107099185A (en) * 2017-04-25 2017-08-29 江西展邦科技有限公司 A kind of aqueous high temperature age resister suitable for synthetic leather
CN112220159A (en) * 2019-07-14 2021-01-15 北京服装学院 Novel environment-friendly sole shoe material
CN111909581A (en) * 2020-08-15 2020-11-10 温州市鹿城金米莉金足皮鞋厂 Wear-resistant leather shoes and processing technology thereof

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Application publication date: 20161207