CN106191552A - A kind of can the preparation method of anodic oxidation pack alloy - Google Patents

A kind of can the preparation method of anodic oxidation pack alloy Download PDF

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Publication number
CN106191552A
CN106191552A CN201610859316.5A CN201610859316A CN106191552A CN 106191552 A CN106191552 A CN 106191552A CN 201610859316 A CN201610859316 A CN 201610859316A CN 106191552 A CN106191552 A CN 106191552A
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content
less
anodic oxidation
molten metal
equal
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CN106191552B (en
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李新豪
陈苏坚
李升�
李旭涛
王永科
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Guangzhou Zhiyuan Alloy Product Co Ltd
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Guangzhou Zhiyuan Alloy Product Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/12Alloys based on aluminium with copper as the next major constituent
    • C22C21/14Alloys based on aluminium with copper as the next major constituent with silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/12Alloys based on aluminium with copper as the next major constituent
    • C22C21/16Alloys based on aluminium with copper as the next major constituent with magnesium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/12Alloys based on aluminium with copper as the next major constituent
    • C22C21/18Alloys based on aluminium with copper as the next major constituent with zinc

Abstract

The invention discloses a kind of can the preparation method of anodic oxidation pack alloy, comprise the steps: copper ingot and part aluminium ingot are put into smelting furnace fusing, the sample examination when liquation is warming up to more than 720 DEG C;Make molten metal be continuously heating to 900 DEG C 920 DEG C, add alterant several times;Stirring molten metal is until all alterants are completely melt;Add another part aluminium ingot;Add refining agent carry out refine when the temperature of alloy molten solution is at 750 DEG C-780 DEG C and removes the gred;It is sufficiently stirred for rear sample examination;It is passed through nitrogen degasification no less than 15 minutes to liquation;If the composition of chemical examination is in the range of setting, cast, during casting aluminium ingot, make molten metal temperature be maintained at 700 DEG C 730 DEG C, during casting pull-rod, make molten metal temperature be maintained at 730 DEG C 750 DEG C.Present invention solves the technical problem that and be to overcome existing pack alloy to cannot be carried out anodised shortcoming, it is provided that one can anodic oxidation pack alloy.

Description

A kind of can the preparation method of anodic oxidation pack alloy
Technical field
The present invention relates to field of aluminum alloys.Be specially a kind of can the preparation method of anodic oxidation pack alloy.
Background technology
Aluminium alloy is the metal material being widely used in each field, in order to enable aluminum alloy to more corrosion-resistant and enable aluminum alloy to zero Part is painted, it will usually is put by aluminium alloy and carries out anodic oxidation in the electrolytic solution, thus forms layer oxide film on its surface, to protect Protect aluminium alloy and improve the hardness of aluminium alloy.But, conventional diecasting alloys such as alusil alloy, aluminium copper and almag are Cannot be carried out anode oxidation coloration.In pack alloy, it is generally the case that the most a height of 6%-12% of content of silicon, copper Content is the highest.And the silicon of high-load can make oxide-film graying, copper can make oxide-film blushing, and can destroy electrolyte matter Amount.The too high speckle that also can make to produce black on oxide-film of iron content in alloy.Therefore, existing pack alloy due to The reason of its composition cannot be carried out anodic oxidation.
Summary of the invention
Present invention solves the technical problem that and be to overcome existing pack alloy to cannot be carried out anodised shortcoming, carry For a kind of can the preparation method of anodic oxidation pack alloy.
The present invention can the preparation method of anodic oxidation pack alloy, comprise the steps:
(1) composition carrying out proportioning, wherein, the content of silicon is less than or equal to 0.6%, and the content of ferrum is less than or equal to 0.3%, the content of copper is less than or equal to 1%, and the content of manganese is less than or equal to 0.3%, and the content of magnesium is less than or equal to 0.6%, the content of zinc is less than or equal to 0.6%, and the content of cobalt is 0.9%-1.5%, and the content of lead is less than or equal to 0.1%, The content of stannum is less than or equal to 0.2%, and the content of cadmium is less than or equal to 0.01%, and the content of the most each composition is all for according to weight The ratio calculated;
(2) clear up and the impurity that removes in smelting furnace, aluminium ingot and copper put into smelting furnace fusing, liquation be warming up to 720 DEG C with Time upper, the proportion of each composition of sample examination is the most within the limits prescribed;
(3) as each composition proportion within the limits prescribed, make molten metal be continuously heating to 900 DEG C-920 DEG C, point many Criticize and add alterant, and stir molten metal until all alterants are completely melt;
(4) the part metals liquation that step (3) obtains is poured into mould and carries out preheating casting, and aluminum casting obtained closes In ingot input smelting furnace reduction smelting furnace, the temperature of molten metal is to less than 780 DEG C;
(5) add refining agent when the temperature of alloy molten solution is at 750 DEG C-780 DEG C carry out refine and remove the gred;
(6) it is sufficiently stirred for rear sample examination;
(7) it is passed through nitrogen degasification to liquation;
(8) if the composition of chemical examination meets the proportioning in step (1) in step (6) into, molten metal is poured preheated mould Tool is cast.
As preferably, the aluminium alloy ingots put in liquation in step (4) makes melt temperature be reduced to less than 750 DEG C.
As preferably, step (7) is passed through nitrogen no less than 15 minutes to liquation.
As preferably, in step (3), alterant is divided into four batches and adds in molten metal, and every batch of alterant adds fashionable, molten The temperature of liquid is all not less than 900 DEG C, and liquation is stirred after adding liquation by every batch of alterant.
As preferably, it is 10% that the alterant added in step (3) accounts for the proportion of all the components.
As preferably, during casting aluminium ingot, molten metal temperature is made to be maintained at 700 DEG C-730 DEG C.
As preferably, during casting pull-rod, molten metal temperature is made to be maintained at 730 DEG C-750 DEG C.
The present invention can anodic oxidation pack alloy preparation method compared with prior art, there is following useful effect Really:
By the present invention provide can anodic oxidation pack alloy preparation method obtain can anodic oxidation die casting aluminium Alloy has good anodic oxidation effect, the most also has good corrosion resistance.It can anodic oxidation pack alloy liquid Phase temperature 660 DEG C, solid-state temperature is 657 DEG C.Under solid state shape, can the tensile strength of anodic oxidation pack alloy be 97MPa, percentage elongation is 35%, and hardness is 30HB, and comprcssive strength is 510MPa.Its die casting toughness is higher, and its toughness is better than The Mitsubishi trade mark is the index of the aluminium alloy of DM3, DM5, is adapted for outward appearance aura anodic oxidation, is highly suitable as decoration The material of the aspect parts such as parts, telecommunications material, fishing gear.What the present invention provided can the conductance of anodic oxidation pack alloy Rate is 58%IACS, and its electrical conductivity is better than the index of the aluminium alloy that the Mitsubishi trade mark is DM3, DMS1, therefore, and can be as preferably Cond aluminium material select.What the present invention provided the pyroconductivity of anodic oxidation pack alloy can be 234W/m DEG C, Its heat conductivity is better than the index of the aluminium alloy that the Mitsubishi trade mark is DM3, DMS1.Its high thermal conductivity can reduce heat abstractor Volume, it is achieved the miniaturization of thermal component, lightweight, be suitable to be applied on the heat sink assembly of high heating, such as converter, the back of the body Throw the aspects such as TV, hybrid electric vehicle, the heat abstractor of printer and other household electrical appliance.It addition, the present invention provide can Anodic oxidation pack alloy and through 3 hours resistance to Thermal test of 500 DEG C, finds that it does not occur significantly to change, has good Good heat resistance.
Detailed description of the invention
The present invention introduced below can the preparation method of anodic oxidation pack alloy, comprise the steps:
(1) composition carrying out proportioning, wherein, the content of silicon is less than or equal to 0.6%, and the content of ferrum is less than or equal to 0.3%, the content of copper is less than or equal to 1%, and the content of manganese is less than or equal to 0.3%, and the content of magnesium is less than or equal to 0.6%, the content of zinc is less than or equal to 0.6%, and the content of cobalt is 0.9%-1.5%, and the content of lead is less than or equal to 0.1%, The content of stannum is less than or equal to 0.2%, and the content of cadmium is less than or equal to 0.01%, and the content of the most each composition is all for according to weight The ratio calculated;
(2) clear up and the impurity that removes in smelting furnace, aluminium ingot and copper put into smelting furnace fusing, liquation be warming up to 720 DEG C with Time upper, the proportion of each composition of sample examination is the most within the limits prescribed;
(3) as each composition proportion within the limits prescribed, make molten metal be continuously heating to 900 DEG C-920 DEG C, point many Criticize and add alterant, and stir molten metal until all alterants are completely melt;
(4) the part metals liquation that step (3) obtains is poured into mould and carries out preheating casting, and aluminum casting obtained closes In ingot input smelting furnace reduction smelting furnace, the temperature of molten metal is to less than 780 DEG C, in the present embodiment, puts into molten in step (4) Aluminium alloy ingots in liquid makes melt temperature be reduced to less than 750 DEG C;
(5) add refining agent when the temperature of alloy molten solution is at 750 DEG C-780 DEG C carry out refine and remove the gred;
(6) it is sufficiently stirred for rear sample examination;
(7) it is passed through nitrogen degasification to liquation, in the present embodiment, step (7) is passed through nitrogen no less than 15 points to liquation Clock;
(8) if the composition of chemical examination meets the proportioning in step (1) in step (6) into, molten metal is poured preheated mould Tool is cast.
As preferably, in step (3), alterant is divided into four batches and adds in molten metal, and every batch of alterant adds fashionable, molten The temperature of liquid is all not less than 900 DEG C, and liquation is stirred after adding liquation by every batch of alterant.Add in step (3) is rotten It is 10% that agent accounts for the proportion of all the components.
As preferably, during casting aluminium ingot, make molten metal temperature be maintained at 700 DEG C-730 DEG C, during casting pull-rod, make metal melt Liquid temp is maintained at 730 DEG C-750 DEG C.
By the present invention provide can the preparation method of anodic oxidation pack alloy, can prepare one can anodic oxidation pressure Cast aluminium alloy, the content of its silicon be less than or equal to 0.6%, the content of ferrum be less than or equal to 0.3%, the content of copper less than or Person be equal to 1%, the content of manganese be less than or equal to 0.3%, the content of magnesium be less than or equal to 0.6%, the content of zinc less than or etc. In 0.6%, the content of cobalt is 0.9%-1.5%, and the content of lead is less than or equal to 0.1%, and the content of stannum is less than or equal to 0.2%, the content of cadmium is less than or equal to 0.01%, and the content of the most each composition is all for the ratio calculated according to weight.
In the first preferred version, the content of silicon is 0.3%-0.5%, and the content of ferrum is 0.25%-0.3%, copper Content can be 0.4%-0.8%, and the content of manganese is 0.2%-0.3%, and the content of magnesium is 0.1%-0.4%, and the content of zinc is 0.2-0.4%, the content of cobalt is 1.2%-1.5%, and the content of lead is 0.03%-0.05%, and the content of stannum is 0.05%- 0.1%, the content of cadmium is 0.004%-0.006%.
In the second preferred version, the content of silicon is 0.3%-0.45%, and the content of ferrum is 1.2%-1.4%, copper Content is 0.6%-0.78%, and the content of manganese is 2.5%-2.76%, and the content of magnesium is 0.3%-0.46%, and the content of zinc is 0.65%-0.8%, the content of lead is 0.04%-0.06%, and the content of stannum is 0.007%-0.01%, and the content of cadmium is 0.006%-0.008%.
In the third preferred version, the content of silicon is 0.25%-0.38%, and the content of ferrum is 1.6%-1.78%, copper Content be 0.7%-0.95%, the content of manganese is 2.0%-2.45%, and the content of magnesium is 0.3%-0.46%, and the content of zinc is 0.3%-0.6%, the content of lead is 0.02%-0.03%, and the content of stannum is 0.03%-0.06%, and the content of cadmium is 0.004%-0.005%.
In the 4th kind of preferred version, the content of silicon is 0.5%-0.58%, and the content of ferrum is 0.9%-1.1%, copper Content is 0.4%-0.55%, and the content of manganese is 1.6%-1.9%, and the content of magnesium is 0.25%-0.0.35%, the content of zinc 0.2%-0.4%, the content of lead is 0.01%-0.025%, and the content of stannum is 0.13%-0.028%, and the content of cadmium is 0.002%-0.003%.
Through test of many times, by the present invention provide can the preparation method of anodic oxidation pack alloy obtain can sun Pole oxidation pack alloy has good anodic oxidation effect, the most also has good corrosion resistance.It can anodic oxidation Pack alloy liquidus temperature 660 DEG C, solid-state temperature is 657 DEG C.Under solid state shape, can anodic oxidation pack alloy anti- Tensile strength is 97MPa, and percentage elongation is 35%, and hardness is 30HB, and comprcssive strength is 510MPa.Its die casting toughness is higher, material Toughness be better than the index of the aluminium alloy that the Mitsubishi trade mark is DM3, DM5, be adapted for outward appearance aura anodic oxidation, the suitableeest Cooperation is the material of the aspect parts such as decorative element, telecommunications material, fishing gear.What the present invention provided can anodic oxidation die casting aluminium The electrical conductivity of alloy is 58%IACS, and its electrical conductivity is better than the index of the aluminium alloy that the Mitsubishi trade mark is DM3, DMS1, therefore, Can select as the material of preferable cond aluminium.This pyroconductivity of anodic oxidation pack alloy can be 234W/m DEG C, Its heat conductivity is better than the index of Mitsubishi DM3, DMS1.Its high thermal conductivity can reduce the volume of heat abstractor, it is achieved dissipates The miniaturization of thermal part, lightweight, be suitable to be applied on high heating heat radiator parts, such as converter, back projection TV, hybrid power The aspects such as car, the heat abstractor of printer and other household electrical appliance.It addition, this can anodic oxidation pack alloy and through 3 The resistance to Thermal test of hours 500 DEG C, finds that it does not occur significantly to change, has good heat resistance.
Above example is only the exemplary embodiment of the present invention, is not used in the restriction present invention, protection scope of the present invention It is defined by the claims.Those skilled in the art are in the essence and protection domain of the present invention, and that makes the present invention is various Amendment or equivalent are also within the scope of the present invention.

Claims (7)

1. one kind can the preparation method of anodic oxidation pack alloy, it is characterised in that comprise the steps:
(1) composition carrying out proportioning, wherein, the content of silicon is less than or equal to 0.6%, and the content of ferrum is less than or equal to 0.3%, the content of copper is less than or equal to 1%, and the content of manganese is less than or equal to 0.3%, and the content of magnesium is less than or equal to 0.6%, the content of zinc is less than or equal to 0.6%, and the content of cobalt is 0.9%-1.5%, and the content of lead is less than or equal to 0.1%, The content of stannum is less than or equal to 0.2%, and the content of cadmium is less than or equal to 0.01%, and the content of the most each composition is all for according to weight The ratio calculated;
(2) clear up and the impurity that removes in smelting furnace, aluminium ingot and copper are put into smelting furnace fusing, when liquation is warming up to more than 720 DEG C The proportion of each composition of sample examination is the most within the limits prescribed;
(3) as each composition proportion within the limits prescribed, make molten metal be continuously heating to 900 DEG C-920 DEG C, points many batches add Enter alterant, and stir molten metal until all alterants are completely melt;
(4) the part metals liquation that step (3) obtains is poured into mould and carries out preheating casting, and aluminium alloy ingots casting obtained In input smelting furnace reduction smelting furnace, the temperature of molten metal is to less than 780 DEG C;
(5) add refining agent when the temperature of alloy molten solution is at 750 DEG C-780 DEG C carry out refine and remove the gred;
(6) it is sufficiently stirred for rear sample examination;
(7) it is passed through nitrogen degasification to liquation;
(8) if the composition of chemical examination meets the proportioning in step (1) in step (6), molten metal is poured into preheated mould and enters Row casting.
The most according to claim 1 can the preparation method of anodic oxidation pack alloy, it is characterised in that in step (4) The aluminium alloy ingots put in liquation makes melt temperature be reduced to less than 750 DEG C.
The most according to claim 1 can the preparation method of anodic oxidation pack alloy, it is characterised in that in step (7) It is passed through nitrogen no less than 15 minutes to liquation.
The most according to claim 1 can the preparation method of anodic oxidation pack alloy, it is characterised in that in step (3) In, alterant is divided into four batches and adds in molten metal, and every batch of alterant adds fashionable, and the temperature of liquation is all not less than 900 DEG C, every batch Liquation is stirred after adding liquation by alterant.
The most according to claim 1 can the preparation method of anodic oxidation pack alloy, it is characterised in that in step (3) It is 10% that the alterant added accounts for the proportion of all the components.
The most according to claim 1 can the preparation method of anodic oxidation pack alloy, it is characterised in that during casting aluminium ingot Molten metal temperature is made to be maintained at 700 DEG C-730 DEG C.
The most according to claim 1 can the preparation method of anodic oxidation pack alloy, it is characterised in that during casting pull-rod Molten metal temperature is made to be maintained at 730 DEG C-750 DEG C.
CN201610859316.5A 2016-09-27 2016-09-27 It is a kind of can anodic oxidation pack alloy preparation method Active CN106191552B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107058769A (en) * 2016-12-19 2017-08-18 新疆众和股份有限公司 A kind of preparation method of ZL105A aluminium alloys
CN107389505A (en) * 2017-07-24 2017-11-24 攀钢集团攀枝花钢铁研究院有限公司 Utilize the method for inner cylinder rotary process measurement high-titanium blast furnace slag viscosity
CN112921221A (en) * 2021-01-22 2021-06-08 佛山市南海盛达前亮铝业有限公司 High-strength aluminum material with excellent surface quality and forming method thereof

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Publication number Priority date Publication date Assignee Title
GB614898A (en) * 1946-08-13 1948-12-23 Robert Martin Bradbury A new aluminium base alloy
CN1290762A (en) * 2000-10-18 2001-04-11 西安工业学院 Aluminium-silicon alloy without, solidification shrinking and its casting technology
CN102965551A (en) * 2012-11-26 2013-03-13 中国铝业股份有限公司 Hypereutectic aluminium-silicon alloy and preparation method thereof
CN103194633A (en) * 2013-03-27 2013-07-10 成都阳光铝制品有限公司 Preparation process of modified electrophoretic aluminum alloy section
CN104946940A (en) * 2014-03-27 2015-09-30 比亚迪股份有限公司 Die casting aluminum alloy and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB614898A (en) * 1946-08-13 1948-12-23 Robert Martin Bradbury A new aluminium base alloy
CN1290762A (en) * 2000-10-18 2001-04-11 西安工业学院 Aluminium-silicon alloy without, solidification shrinking and its casting technology
CN102965551A (en) * 2012-11-26 2013-03-13 中国铝业股份有限公司 Hypereutectic aluminium-silicon alloy and preparation method thereof
CN103194633A (en) * 2013-03-27 2013-07-10 成都阳光铝制品有限公司 Preparation process of modified electrophoretic aluminum alloy section
CN104946940A (en) * 2014-03-27 2015-09-30 比亚迪股份有限公司 Die casting aluminum alloy and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107058769A (en) * 2016-12-19 2017-08-18 新疆众和股份有限公司 A kind of preparation method of ZL105A aluminium alloys
CN107389505A (en) * 2017-07-24 2017-11-24 攀钢集团攀枝花钢铁研究院有限公司 Utilize the method for inner cylinder rotary process measurement high-titanium blast furnace slag viscosity
CN112921221A (en) * 2021-01-22 2021-06-08 佛山市南海盛达前亮铝业有限公司 High-strength aluminum material with excellent surface quality and forming method thereof

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