CN106191515A - A kind of material of chemical nickel plating silicon-carbide particle and Copper-Aluminum compound and preparation method thereof - Google Patents
A kind of material of chemical nickel plating silicon-carbide particle and Copper-Aluminum compound and preparation method thereof Download PDFInfo
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- CN106191515A CN106191515A CN201610647166.1A CN201610647166A CN106191515A CN 106191515 A CN106191515 A CN 106191515A CN 201610647166 A CN201610647166 A CN 201610647166A CN 106191515 A CN106191515 A CN 106191515A
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- Prior art keywords
- nickel plating
- chemical nickel
- carbide particle
- copper
- aluminum compound
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C9/00—Alloys based on copper
- C22C9/01—Alloys based on copper with aluminium as the next major constituent
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/10—Alloys containing non-metals
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/10—Alloys containing non-metals
- C22C1/1005—Pretreatment of the non-metallic additives
- C22C1/101—Pretreatment of the non-metallic additives by coating
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/10—Alloys containing non-metals
- C22C1/1036—Alloys containing non-metals starting from a melt
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/10—Alloys containing non-metals
- C22C1/1036—Alloys containing non-metals starting from a melt
- C22C1/1047—Alloys containing non-metals starting from a melt by mixing and casting liquid metal matrix composites
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/0047—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
- C22C32/0052—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only carbides
- C22C32/0063—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only carbides based on SiC
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Composite Materials (AREA)
- Chemically Coating (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Abstract
The invention discloses a kind of chemical nickel plating silicon-carbide particle material with Copper-Aluminum compound and preparation method thereof, including: dispensing, melting, addition granule, insulated and stirred, the step of cooling；Pure carbofrax material is evenly distributed in existing alloy material by certain technological means, utilize carborundum high rigidity, high-wearing feature and good self-lubricating and the big performance of elevated temperature strength, the performance realizing composite promotes further, composite alloy new material obtained by the present invention has higher intensity hardness wearability and corrosion resistance, thus extends wearing piece product and the service life of offshore engineering equipment corrosion resistant products accessory that Aero-Space high intensity pressure-resistive products petroleum works set.
Description
Technical field
The present invention relates to field of compound material, be specifically related to the material of a kind of chemical nickel plating silicon-carbide particle and Copper-Aluminum compound
And preparation method thereof.
Background technology
Carborundum has purity height, particle diameter is little, be evenly distributed, specific surface area is big, high surface, apparent density are low, pole
Good mechanics, calorifics, electricity and chemical property, i.e. has a high rigidity, high-wearing feature and good self-lubricating, high thermoconductivity,
Low thermal coefficient of expansion and the feature such as elevated temperature strength is big.Known albronze is owing to having higher intensity and antifriction quality, good
Corrosion resistance, good in hot downforce processability, can electric welding and gas welding, be mainly used in such as axle bush, axle sleeve, ring flange, gear and
Other important anti-corrosion parts, wear part.But in terms of special applications, its performance is difficult to meet such as Aero-Space high intensity
Wearing piece product that pressure-resistive products petroleum works set and the demand of offshore engineering equipment corrosion resistant products accessory.
Summary of the invention
In sum, it is an object of the invention to provide the new material of a kind of chemical nickel plating silicon-carbide particle and Copper-Aluminum compound
And preparation method thereof, it is possible to make material have higher intensity, hardness, wearability and corrosion resistance.
It is an object of the invention to be achieved through the following technical solutions:
A kind of chemical nickel plating silicon-carbide particle and the preparation method of the material of Copper-Aluminum compound, comprise the following steps:
1) dispensing: weigh fine copper 1800 grams, fine aluminium 200 grams is placed in graphite crucible, the chemical nickel plating carbon of particle diameter 50 microns
Silicon carbide particle is standby；
2) melting: electric induction furnace is heated to 1200 degree, is incubated 10 minutes, degasification, slagging-off；
3) granule is added: the potassium fluorozirconate after being initially added into ground process when near 1080 degree of temperature processes carbonization
Silicon, does stir process simultaneously；
4) insulated and stirred: it is the semisolid stage that temperature is down to when 1042 degree, stirs 10 minutes；
5) cooling.
Further, the volume fraction of described chemical nickel plating silicon-carbide particle is 1%.
Further, the volume fraction of described chemical nickel plating silicon-carbide particle is 3%.
Further, the volume fraction of described chemical nickel plating silicon-carbide particle is 5%.
Present invention also offers the material of a kind of chemical nickel plating silicon-carbide particle and Copper-Aluminum compound, described material uses aforementioned
Method prepare.
The invention have the benefit that and the carbofrax material of chemical nickel plating is evenly distributed on by certain technological means
In existing alloy material, utilize carborundum high rigidity, high-wearing feature and good self-lubricating and the big performance of elevated temperature strength, real
The performance of existing composite promotes further.It is resistance to that composite alloy new material obtained by the present invention has higher intensity hardness
Mill property and corrosion resistance, thus extend wearing piece product that Aero-Space high intensity pressure-resistive products petroleum works set and
The service life of offshore engineering equipment corrosion resistant products accessory.
Detailed description of the invention
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described.
Obviously, described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under not making creative work premise, all
Belong to the scope of protection of the invention.
Embodiment 1
New material of a kind of chemical nickel plating silicon-carbide particle and Copper-Aluminum compound and preparation method thereof, comprises the following steps:
1) dispensing: weigh fine copper 1800 grams, fine aluminium 200 grams is placed in graphite crucible, the chemical nickel plating carbon of particle diameter 50 microns
Silicon carbide particle is standby, and wherein, the volume fraction of chemical nickel plating silicon-carbide particle is 1%；
2) melting: electric induction furnace is heated to 1200 degree, is incubated 10 minutes, degasification, slagging-off；
3) granule is added: the potassium fluorozirconate after being initially added into ground process when near 1080 degree of temperature processes carbonization
Silicon, does stir process simultaneously；
4) insulated and stirred: it is the semisolid stage that temperature is down to when 1042 degree, stirs 10 minutes；
5) cooling.
Embodiment 2
New material of a kind of chemical nickel plating silicon-carbide particle and Copper-Aluminum compound and preparation method thereof, comprises the following steps:
1) dispensing: weigh fine copper 1800 grams, fine aluminium 200 grams is placed in graphite crucible, the chemical nickel plating carbon of particle diameter 50 microns
Silicon carbide particle is standby, and wherein, the volume fraction of chemical nickel plating silicon-carbide particle is 3%；
2) melting: electric induction furnace is heated to 1200 degree, is incubated 10 minutes, degasification, slagging-off；
3) granule is added: the potassium fluorozirconate after being initially added into ground process when near 1080 degree of temperature processes carbonization
Silicon, does stir process simultaneously；
4) insulated and stirred: it is the semisolid stage that temperature is down to when 1042 degree, stirs 10 minutes；
5) cooling.
Embodiment 3
New material of a kind of chemical nickel plating silicon-carbide particle and Copper-Aluminum compound and preparation method thereof, comprises the following steps:
1) dispensing: weigh fine copper 1800 grams, fine aluminium 200 grams is placed in graphite crucible, the chemical nickel plating carbon of particle diameter 50 microns
Silicon carbide particle is standby, and wherein, the volume fraction of chemical nickel plating silicon-carbide particle is 5%；
2) melting: electric induction furnace is heated to 1200 degree, is incubated 10 minutes, degasification, slagging-off；
3) granule is added: the potassium fluorozirconate after being initially added into ground process when near 1080 degree of temperature processes carbonization
Silicon, does stir process simultaneously；
4) insulated and stirred: it is the semisolid stage that temperature is down to when 1042 degree, stirs 10 minutes；
5) cooling.
Experiment hardness result contrast:
Using Brinell hardness tester, 30 seconds dwell times, pressure head 5 millimeters, pressure 62.5 kilograms, in table, data are for often organizing experiment
Taking 3 test blocks, the meansigma methods that hardness is asked for 5 times is beaten in each test block.Design parameter see table:
Data show, along with the increase of enhancing phase volume fraction, Brinell hardness gradually strengthens, same volume mark condition
Under, the hardness number of silicon carbide sample processed through chemical nickel plating is apparently higher than the albronze material being not added with carborundum.
Embodiment provided above is the better embodiment of the present invention, is only used for the convenient explanation present invention, not to this
Bright make any pro forma restriction, any art has usually intellectual, if without departing from the carried skill of the present invention
In the range of art feature, utilize the Equivalent embodiments that the done local of disclosed technology contents is changed or modified, and
Without departing from the technical characteristic content of the present invention, all still fall within the range of the technology of the present invention feature.
Claims (5)
1. the preparation method of the material of a chemical nickel plating silicon-carbide particle and Copper-Aluminum compound, it is characterised in that: include following step
Rapid:
1) dispensing: weigh fine copper 1800 grams, fine aluminium 200 grams is placed in graphite crucible, the chemical nickel plating carborundum of particle diameter 50 microns
Granule is standby；
2) melting: electric induction furnace is heated to 1200 degree, is incubated 10 minutes, degasification, slagging-off；
3) granule is added: the potassium fluorozirconate after being initially added into ground process when near 1080 degree of temperature processes carborundum,
Do stir process simultaneously；
4) insulated and stirred: it is the semisolid stage that temperature is down to when 1042 degree, stirs 10 minutes；
5) cooling.
The preparation method of the material of chemical nickel plating silicon-carbide particle the most according to claim 1 and Copper-Aluminum compound, its feature
It is: the volume fraction of described chemical nickel plating silicon-carbide particle is 1%.
The preparation method of the material of chemical nickel plating silicon-carbide particle the most according to claim 1 and Copper-Aluminum compound, its feature
It is: the volume fraction of described chemical nickel plating silicon-carbide particle is 3%.
The preparation method of the material of chemical nickel plating silicon-carbide particle the most according to claim 1 and Copper-Aluminum compound, its feature
It is: the volume fraction of described chemical nickel plating silicon-carbide particle is 5%.
5. a chemical nickel plating silicon-carbide particle and the material of Copper-Aluminum compound, it is characterised in that described material uses claim
Prepared by the method according to any one of 1-4.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610647166.1A CN106191515A (en) | 2016-08-09 | 2016-08-09 | A kind of material of chemical nickel plating silicon-carbide particle and Copper-Aluminum compound and preparation method thereof |
| PCT/CN2016/108084 WO2018028092A1 (en) | 2016-08-09 | 2016-11-30 | Composite material of electroless nickel-plated silicon carbide particles and copper and aluminium, and preparation method therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610647166.1A CN106191515A (en) | 2016-08-09 | 2016-08-09 | A kind of material of chemical nickel plating silicon-carbide particle and Copper-Aluminum compound and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106191515A true CN106191515A (en) | 2016-12-07 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610647166.1A Pending CN106191515A (en) | 2016-08-09 | 2016-08-09 | A kind of material of chemical nickel plating silicon-carbide particle and Copper-Aluminum compound and preparation method thereof |
Country Status (2)
| Country | Link |
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| CN (1) | CN106191515A (en) |
| WO (1) | WO2018028092A1 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106636728A (en) * | 2016-12-19 | 2017-05-10 | 苏州天兼新材料科技有限公司 | Cast bronze alloy material and preparation method thereof |
| CN107312950A (en) * | 2017-06-22 | 2017-11-03 | 苏州天兼新材料科技有限公司 | A kind of Nickel-plated carbon copper silicon base alloy material and preparation method thereof |
| WO2018107846A1 (en) * | 2016-12-14 | 2018-06-21 | 苏州金仓合金新材料有限公司 | Nickel-plated silicon carbide particles and preparation method therefor |
| CN111020269A (en) * | 2019-12-09 | 2020-04-17 | 苏州列治埃盟新材料技术转移有限公司 | Novel high-strength nickel-plated silicon carbide copper-based alloy material for ocean engineering machinery |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190105455A (en) * | 2018-03-05 | 2019-09-17 | 삼성에스디아이 주식회사 | Conductive composition for electromagnetic shielding, electromagnetic shielding layer prepared therefrom, circuit board laminate comprising the same and method for forming the electromagnetic shielding layer |
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| CN101157993A (en) * | 2007-11-08 | 2008-04-09 | 北京科技大学 | Method for preparing high volume-fraction carborundum granule-reinforced copper-based composite material |
| CN105220006A (en) * | 2015-11-02 | 2016-01-06 | 苏州金仓合金新材料有限公司 | A kind of vehicle bearing Nickel-plated carbon silicon grain strengthens Cu-base composites and preparation method thereof |
| CN105586503A (en) * | 2015-12-29 | 2016-05-18 | 东南大学 | Copper-graphite composite material and preparation method thereof |
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| DE10324691A1 (en) * | 2003-05-30 | 2004-12-16 | Sgl Carbon Ag | Friction body made of metal-infiltrated, fiber-reinforced porous carbon |
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| CN105238948A (en) * | 2015-10-30 | 2016-01-13 | 苏州列治埃盟新材料技术转移有限公司 | High-strength nanoscale silicon carbide copper base alloy material and preparing method thereof |
| CN105238952A (en) * | 2015-11-02 | 2016-01-13 | 苏州金仓合金新材料有限公司 | Novel high-strength nanoscale silicon carbide copper base alloy material for ocean engineering |
-
2016
- 2016-08-09 CN CN201610647166.1A patent/CN106191515A/en active Pending
- 2016-11-30 WO PCT/CN2016/108084 patent/WO2018028092A1/en active Application Filing
Patent Citations (4)
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| CN101121974A (en) * | 2007-09-19 | 2008-02-13 | 洛阳理工学院 | High-strength high-conduction strengthened dispersion copper alloy and preparation method thereof |
| CN101157993A (en) * | 2007-11-08 | 2008-04-09 | 北京科技大学 | Method for preparing high volume-fraction carborundum granule-reinforced copper-based composite material |
| CN105220006A (en) * | 2015-11-02 | 2016-01-06 | 苏州金仓合金新材料有限公司 | A kind of vehicle bearing Nickel-plated carbon silicon grain strengthens Cu-base composites and preparation method thereof |
| CN105586503A (en) * | 2015-12-29 | 2016-05-18 | 东南大学 | Copper-graphite composite material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018107846A1 (en) * | 2016-12-14 | 2018-06-21 | 苏州金仓合金新材料有限公司 | Nickel-plated silicon carbide particles and preparation method therefor |
| CN106636728A (en) * | 2016-12-19 | 2017-05-10 | 苏州天兼新材料科技有限公司 | Cast bronze alloy material and preparation method thereof |
| CN107312950A (en) * | 2017-06-22 | 2017-11-03 | 苏州天兼新材料科技有限公司 | A kind of Nickel-plated carbon copper silicon base alloy material and preparation method thereof |
| CN111020269A (en) * | 2019-12-09 | 2020-04-17 | 苏州列治埃盟新材料技术转移有限公司 | Novel high-strength nickel-plated silicon carbide copper-based alloy material for ocean engineering machinery |
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| Publication number | Publication date |
|---|---|
| WO2018028092A1 (en) | 2018-02-15 |
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