CN106190453A - A kind of anti-foaming gear oil - Google Patents

A kind of anti-foaming gear oil Download PDF

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Publication number
CN106190453A
CN106190453A CN201610500587.1A CN201610500587A CN106190453A CN 106190453 A CN106190453 A CN 106190453A CN 201610500587 A CN201610500587 A CN 201610500587A CN 106190453 A CN106190453 A CN 106190453A
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CN
China
Prior art keywords
parts
gear oil
oil
foaming
grades
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610500587.1A
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Chinese (zh)
Inventor
刘咏梅
王凤德
赵奕
崔晓静
高川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Bluestar Chengrand Chemical Co Ltd
Original Assignee
China Bluestar Chengrand Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Bluestar Chengrand Chemical Co Ltd filed Critical China Bluestar Chengrand Chemical Co Ltd
Priority to CN201610500587.1A priority Critical patent/CN106190453A/en
Publication of CN106190453A publication Critical patent/CN106190453A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/044Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02Hydroxy compounds
    • C10M2207/023Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/281Esters of (cyclo)aliphatic monocarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/18Anti-foaming property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/04Oil-bath; Gear-boxes; Automatic transmissions; Traction drives

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)

Abstract

The present invention relates to a kind of anti-foaming gear oil, belong to gear oil technical field.This gear oil includes following raw materials by weight: base oil 30 50 parts, 2,6 three grades of butyl 4 methylphenols 2 12 parts, double ten four carbon alcohols ester 1 10 parts, N, N' bis-salicylidene propane diamine 5 18 parts, dodecylbenzene sodium sulfonate 6 18 parts, cetyl amine hydrofluoride 0.5 6 parts, single Tryfac 5573 2 12 parts, glycerol trihydroxy polyethers 6 20 parts, phenethanol oleate 5 20 parts, triethyl phosphate 3 12 parts, dialkyl dithiophosphate 19 parts.A kind of anti-foaming gear oil that the present invention provides, substantially increases anti-foaming performance.

Description

A kind of anti-foaming gear oil
Technical field
The present invention relates to a kind of gear oil, it is more particularly related to a kind of anti-foaming gear oil, belong to gear oil Technical field.
Background technology
Gear oil is based on petroleum oil base oil or synthetic lubricant fluid, addition extreme pressure anti-wear additives and oiliness improver modulation A kind of important lubricating oil become.For various gear drives, with prevent tooth surface abrasion, abrade, sintering etc., extend it and make With the life-span, improve transmission power efficiency.Gear oil should have good wear-resistant, load resistance performance and suitable viscosity.Additionally, also Should have good thermal oxidation stability, anti-foaming property, water separable performance energy and rustless property.
State Intellectual Property Office discloses Publication No. CN105567401A in 2016.5.11, and entitled " one is taken out Oil machine reduction box dedicated gear oil " invention, a kind of oil pumping unit reduction gearbox dedicated gear of this disclosure of the invention oil, the matter of its raw material Amount part proportioning is for being in harmonious proportion base oil, cyclopentadienyl polyisobutylene, metallocene polyalphaolefin 150, polymethacrylates, extreme pressure anti-wear additives, clear Net agent, dispersant, BTA, defoamer, anti emulsifier T1001 form, and are wherein in harmonious proportion base oil by paraffin base oil 600SN, oil residues 150BS, hydrofined oil 250N form, and extreme pressure anti-wear additives is D2EHDTPA amine salt and double octyl group dithio phosphorus Acid zinc and/or the mixture of oil-soluble molybdenum.Speed reduction gear box of the present invention oil is superior to work in terms of physical and chemical index and serviceability Industry enclosed gear oil, has good extreme pressure and antiwear behavior, thermal oxidation stability, corrosion resistance and demulsification performance, full The use requirement of foot oil pumping in oil fields machine oil.
Above-mentioned existing gear oil has good extreme pressure and antiwear behavior, thermal oxidation stability, corrosion resistance and resists Emulsifiability, and add defoamer, but the performance of its anti-foaming also needs to improve.
Summary of the invention
Present invention seek to address that the problem that prior art middle gear oil anti-foaming performance still has much room for improvement, it is provided that Yi Zhongkang Foam gear oil, substantially increases anti-foaming performance.
In order to realize foregoing invention content, its concrete technical scheme is as follows:
A kind of anti-foaming gear oil, it is characterised in that: include following raw materials by weight:
Base oil 30-50 part
2,6-tri-grades of butyl-4-methylphenol 2-12 parts
Double ten four carbon alcohols ester 1-10 parts
N, N'-bis-salicylidene propane diamine 5-18 part
Dodecylbenzene sodium sulfonate 6-18 part
Cetyl amine hydrofluoride 0.5-6 part
Single Tryfac 5573 2-12 part
Glycerol trihydroxy polyethers 6-20 part
Phenethanol oleate 5-20 part
Triethyl phosphate 3-12 part
Dialkyl dithiophosphate 1-9 part.
Preferably, a kind of anti-foaming gear oil, it is characterised in that: include following raw materials by weight:
Base oil 33-39 part
2,6-tri-grades of butyl-4-methylphenol 5-11 parts
Double ten four carbon alcohols ester 2-9 parts
N, N'-bis-salicylidene propane diamine 7-13 part
Dodecylbenzene sodium sulfonate 8-12 part
Cetyl amine hydrofluoride 2-5 part
Single Tryfac 5573 3-10 part
Glycerol trihydroxy polyethers 8-15 part
Phenethanol oleate 10-18 part
Triethyl phosphate 6-11 part
Dialkyl dithiophosphate 2-8 part.
Preferably, a kind of anti-foaming gear oil, it is characterised in that: include following raw materials by weight:
Base oil 33-39 part
2,6-tri-grades of butyl-4-methylphenol 5-11 parts
Double ten four carbon alcohols ester 2-9 parts
N, N'-bis-salicylidene propane diamine 7-13 part
Dodecylbenzene sodium sulfonate 8-12 part
Cetyl amine hydrofluoride 2-5 part
Single Tryfac 5573 3-10 part
Glycerol trihydroxy polyethers 8-15 part
Phenethanol oleate 10-18 part
Triethyl phosphate 6-11 part
Dialkyl dithiophosphate 2-8 part.
The Advantageous Effects that the present invention brings:
The present invention solves the problem that prior art middle gear oil anti-foaming performance still has much room for improvement.The one that the present invention provides Anti-foaming gear oil, substantially increases anti-foaming performance.
Detailed description of the invention
Embodiment 1
A kind of anti-foaming gear oil, including following raw materials by weight:
Base oil 30 parts
2,6-tri-grades of butyl-4-methylphenols 2 parts
Double ten four carbon alcohols esters 1 part
N, N'-bis-salicylidene propane diamine 5 parts
Dodecylbenzene sodium sulfonate 6 parts
Cetyl amine hydrofluoride 0.5 part
Single Tryfac 5573 2 parts
Glycerol trihydroxy polyethers 6 parts
Phenethanol oleate 5 parts
Triethyl phosphate 3 parts
Dialkyl dithiophosphate 1 part.
Embodiment 2
A kind of anti-foaming gear oil, including following raw materials by weight:
Base oil 50 parts
2,6-tri-grades of butyl-4-methylphenols 12 parts
Double ten four carbon alcohols esters 10 parts
N, N'-bis-salicylidene propane diamine 18 parts
Dodecylbenzene sodium sulfonate 18 parts
Cetyl amine hydrofluoride 6 parts
Single Tryfac 5573 12 parts
Glycerol trihydroxy polyethers 20 parts
Phenethanol oleate 20 parts
Triethyl phosphate 12 parts
Dialkyl dithiophosphate 9 parts.
Embodiment 3
A kind of anti-foaming gear oil, including following raw materials by weight:
Base oil 40 parts
2,6-tri-grades of butyl-4-methylphenols 7 parts
Double ten four carbon alcohols esters 5.5 parts
N, N'-bis-salicylidene propane diamine 11.5 parts
Dodecylbenzene sodium sulfonate 12 parts
Cetyl amine hydrofluoride 3 parts
Single Tryfac 5573 7 parts
Glycerol trihydroxy polyethers 13 parts
Phenethanol oleate 12.5 parts
Triethyl phosphate 7.5 parts
Dialkyl dithiophosphate 5 parts.
Embodiment 4
A kind of anti-foaming gear oil, including following raw materials by weight:
Base oil 35 parts
2,6-tri-grades of butyl-4-methylphenols 10 parts
Double ten four carbon alcohols esters 9 parts
N, N'-bis-salicylidene propane diamine 12 parts
Dodecylbenzene sodium sulfonate 7 parts
Cetyl amine hydrofluoride 2 parts
Single Tryfac 5573 10 parts
Glycerol trihydroxy polyethers 18 parts
Phenethanol oleate 7 parts
Triethyl phosphate 4.5 parts
Dialkyl dithiophosphate 7 parts.
Embodiment 5
A kind of anti-foaming gear oil, including following raw materials by weight:
Base oil 33 parts
2,6-tri-grades of butyl-4-methylphenols 5 parts
Double ten four carbon alcohols esters 2 parts
N, N'-bis-salicylidene propane diamine 7 parts
Dodecylbenzene sodium sulfonate 8 parts
Cetyl amine hydrofluoride 2 parts
Single Tryfac 5573 3 parts
Glycerol trihydroxy polyethers 8 parts
Phenethanol oleate 10 parts
Triethyl phosphate 6 parts
Dialkyl dithiophosphate 2 parts.
Embodiment 6
A kind of anti-foaming gear oil, including following raw materials by weight:
Base oil 39 parts
2,6-tri-grades of butyl-4-methylphenols 11 parts
Double ten four carbon alcohols esters 9 parts
N, N'-bis-salicylidene propane diamine 13 parts
Dodecylbenzene sodium sulfonate 12 parts
Cetyl amine hydrofluoride 5 parts
Single Tryfac 5573 10 parts
Glycerol trihydroxy polyethers 15 parts
Phenethanol oleate 18 parts
Triethyl phosphate 11 parts
Dialkyl dithiophosphate 8 parts.
Embodiment 7
A kind of anti-foaming gear oil, including following raw materials by weight:
Base oil 36 parts
2,6-tri-grades of butyl-4-methylphenols 8 parts
Double ten four carbon alcohols esters 5.5 parts
N, N'-bis-salicylidene propane diamine 10 parts
Dodecylbenzene sodium sulfonate 10 parts
Cetyl amine hydrofluoride 3.5 parts
Single Tryfac 5573 6.5 parts
Glycerol trihydroxy polyethers 11.5 parts
Phenethanol oleate 14 parts
Triethyl phosphate 8.5 parts
Dialkyl dithiophosphate 5 parts.
Embodiment 8
A kind of anti-foaming gear oil, including following raw materials by weight:
Base oil 38 parts
2,6-tri-grades of butyl-4-methylphenols 10 parts
Double ten four carbon alcohols esters 4 parts
N, N'-bis-salicylidene propane diamine 11 parts
Dodecylbenzene sodium sulfonate 9 parts
Cetyl amine hydrofluoride 3 parts
Single Tryfac 5573 5 parts
Glycerol trihydroxy polyethers 12 parts
Phenethanol oleate 16 parts
Triethyl phosphate 7 parts
Dialkyl dithiophosphate 4.5 parts.

Claims (3)

1. an anti-foaming gear oil, it is characterised in that: include following raw materials by weight:
Base oil 30-50 part
2,6-tri-grades of butyl-4-methylphenol 2-12 parts
Double ten four carbon alcohols ester 1-10 parts
N, N'-bis-salicylidene propane diamine 5-18 part
Dodecylbenzene sodium sulfonate 6-18 part
Cetyl amine hydrofluoride 0.5-6 part
Single Tryfac 5573 2-12 part
Glycerol trihydroxy polyethers 6-20 part
Phenethanol oleate 5-20 part
Triethyl phosphate 3-12 part
Dialkyl dithiophosphate 1-9 part.
A kind of anti-foaming gear oil the most according to claim 1, it is characterised in that: include following in parts by weight Raw material:
Base oil 33-39 part
2,6-tri-grades of butyl-4-methylphenol 5-11 parts
Double ten four carbon alcohols ester 2-9 parts
N, N'-bis-salicylidene propane diamine 7-13 part
Dodecylbenzene sodium sulfonate 8-12 part
Cetyl amine hydrofluoride 2-5 part
Single Tryfac 5573 3-10 part
Glycerol trihydroxy polyethers 8-15 part
Phenethanol oleate 10-18 part
Triethyl phosphate 6-11 part
Dialkyl dithiophosphate 2-8 part.
3. according to claim 1 or 2 one kind of anti-foaming gear oil, it is characterised in that: include following in parts by weight former Material:
Base oil 33-39 part
2,6-tri-grades of butyl-4-methylphenol 5-11 parts
Double ten four carbon alcohols ester 2-9 parts
N, N'-bis-salicylidene propane diamine 7-13 part
Dodecylbenzene sodium sulfonate 8-12 part
Cetyl amine hydrofluoride 2-5 part
Single Tryfac 5573 3-10 part
Glycerol trihydroxy polyethers 8-15 part
Phenethanol oleate 10-18 part
Triethyl phosphate 6-11 part
Dialkyl dithiophosphate 2-8 part.
CN201610500587.1A 2016-06-30 2016-06-30 A kind of anti-foaming gear oil Pending CN106190453A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610500587.1A CN106190453A (en) 2016-06-30 2016-06-30 A kind of anti-foaming gear oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610500587.1A CN106190453A (en) 2016-06-30 2016-06-30 A kind of anti-foaming gear oil

Publications (1)

Publication Number Publication Date
CN106190453A true CN106190453A (en) 2016-12-07

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CN201610500587.1A Pending CN106190453A (en) 2016-06-30 2016-06-30 A kind of anti-foaming gear oil

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107164056A (en) * 2017-06-12 2017-09-15 苏州永创达电子有限公司 A kind of environmentally friendly high stable lubricating oil

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050059563A1 (en) * 2003-09-13 2005-03-17 Sullivan William T. Lubricating fluids with enhanced energy efficiency and durability
CN102212412A (en) * 2011-05-10 2011-10-12 天津理工大学 Water-based cutting fluid with grinding materials treated by surfactant and preparation method thereof
CN102604729A (en) * 2012-02-29 2012-07-25 石俊峰 Lubricant composition used for gear of wind turbine

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050059563A1 (en) * 2003-09-13 2005-03-17 Sullivan William T. Lubricating fluids with enhanced energy efficiency and durability
CN102212412A (en) * 2011-05-10 2011-10-12 天津理工大学 Water-based cutting fluid with grinding materials treated by surfactant and preparation method thereof
CN102604729A (en) * 2012-02-29 2012-07-25 石俊峰 Lubricant composition used for gear of wind turbine

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107164056A (en) * 2017-06-12 2017-09-15 苏州永创达电子有限公司 A kind of environmentally friendly high stable lubricating oil

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Application publication date: 20161207