CN106190360A - A kind of Vegetable Fuel Gasoline additive and method - Google Patents
A kind of Vegetable Fuel Gasoline additive and method Download PDFInfo
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- CN106190360A CN106190360A CN201610614931.XA CN201610614931A CN106190360A CN 106190360 A CN106190360 A CN 106190360A CN 201610614931 A CN201610614931 A CN 201610614931A CN 106190360 A CN106190360 A CN 106190360A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/1802—Organic compounds containing oxygen natural products, e.g. waxes, extracts, fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/16—Hydrocarbons
- C10L1/1608—Well defined compounds, e.g. hexane, benzene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/192—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention discloses a kind of Vegetable Fuel Gasoline additive and method, Vegetable Fuel Gasoline additive is made up of vegetable oil, alkane, cycloalkane, aromatic hydrocarbon, chitosan, chitosanase, zymosan, yeast and the ethanol of Different Weight ratio;Said components carries out successively after mixing in any order fermenting, filters, processed, forms Vegetable Fuel Gasoline additive finished product;After Vegetable Fuel Gasoline additive finished product is mixed according to the mass ratio of 5: 10000 with fuel oil, use in adding locomotive fuel tank to.The Vegetable Fuel Gasoline additive that the inventive method makes is dissolved in fuel oil; particle in fuel oil can be made fine to below 10 μm by 200 μm; the relative surface area making fuel particle increases; oxygen content in fuel oil increases severely; thus increase the combustion rate of fuel oil; reduction oil consumption, and reduce the discharge capacity of waste gas and the dust burnt the most completely further, be conducive to protecting environment.
Description
Technical field
The present invention relates to a kind of fuel oil additive, particularly relate to a kind of Vegetable Fuel Gasoline additive and method.
Background technology
At present, petroleum fuel Application comparison is extensive.The burn application of oil simply can be divided into directly burning to take its heat
Its employing produced kinetic energy of its blast that burns is made with utilizing machinery.No matter the burning of any form has been required for oxygen element ginseng
Entering, oxygen element determines the combustion efficiency of oil with the ratio of fuel itself and the composition of fuel itself.It is exemplified below, gasoline
Composition be mainly defat hydrocarbon and the cyclic hydrocarbon of four carbon to 12 carbon, be mainly used in the field such as aircraft, automobile.In locomotive engine
Deflagrating jar and aid system can make gasoline combustion blast and obtain its useful work.Due to in-engine limited space,
Moment before gasoline combustion explodes, air is typically only capable to move along the peripheral of petrol molecule, say, that oxygen can only
Play combustion-supporting effect on the palp border of petrol molecule, cause gasoline little with the contact area of oxygen molecule, incomplete combustion.General
Steaming oil combustion rate in locomotive engine typically only about 60%, not only capacity usage ratio is low, and has not burnt
Full waste gas can cause serious environmental pollution after being discharged in air.
Summary of the invention
In order to solve the weak point existing for above-mentioned technology, the invention provides a kind of Vegetable Fuel Gasoline additive and side
Method.
In order to solve above technical problem, the technical solution used in the present invention is: a kind of Vegetable Fuel Gasoline additive, by following
The raw material composition of weight ratio:
Vegetable oil is Semen Maydis oil or soybean oil or Oleum Ricini.
Alkane is butane or pentane or hexane or heptane or octane or nonane or decane or hendecane or dodecane.
Cycloalkane is Tetramethylene. or Pentamethylene. or hexamethylene or cycloheptane or cyclooctane or cyclononane or cyclodecane or ring ten
One alkane or cyclododecane.
Aromatic hydrocarbon is toluene or dimethylbenzene or naphthalene.
Zymosan is glucosan or mannan.
The manufacture method of a kind of Vegetable Fuel Gasoline additive, specifically comprises the following steps that
Weigh successively weight ratio be 35~the cycloalkane of the alkane of the vegetable oil of 40%, 10~15%, 12~13%, 13
~the zymosan of the chitosanase of the chitosan of the aromatic hydrocarbon of 15%, 4~6%, 2~3%, 2~3%, 0.03~0.05%
The ethanol of yeast, 4.95~21.97%, the said components weighed is joined in open fermentation tank in any order
Ferment;It is 22~25 DEG C that fermentation temperature controls, and in fermentation tank, the mixing speed of magnetic stirring bar controls is 30~35r/
Min, it is 48~72h that mixing time controls;In whipping process, often stirring 30min just stops stirring 1h;
After fermentation ends, use the drainage screen of more than 400 mesh that fermentation liquid is filtered, obtain the filtrate of clear;
Filtrate is placed in high temperature dehydration device, in 120 DEG C, filtrate is carried out under conditions of 2MPa processed, dewatering time controls
Being 2~4h, the filtrate after dehydration is Vegetable Fuel Gasoline additive finished product.
The using method of a kind of Vegetable Fuel Gasoline additive is: by above-mentioned Vegetable Fuel Gasoline additive with fuel oil according to 5:10000
Mass ratio mix after use;Fuel oil is gasoline or diesel oil or kerosene.
The Vegetable Fuel Gasoline additive that the inventive method makes is dissolved in fuel oil, and the particle in fuel oil can be made micro-by 200 μm
Carefully to below 10 μm, the relative surface area of fuel particle is made to increase, the oxygen content sharp increase in fuel oil, thus increase the burning of fuel oil
Rate, reduction oil consumption, and reduce the discharge capacity of waste gas and the dust burnt the most completely further, be conducive to protecting environment.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention is further detailed explanation.
In the present invention, a kind of Vegetable Fuel Gasoline additive is made up of the raw material of following weight ratio:
Wherein, vegetable oil is Semen Maydis oil or soybean oil or Oleum Ricini.Alkane is arbitrary four carbon to the strand of 12 carbon
Alkane, i.e. butane or pentane or hexane or heptane or octane or nonane or decane or hendecane or dodecane.Cycloalkane is any
The little Molecular Ring alkane of four carbon to 12 carbon, including Tetramethylene., Pentamethylene., hexamethylene, cycloheptane, cyclooctane, cyclononane, ring
Decane, ring hendecane, cyclododecane.Aromatic hydrocarbon is toluene or dimethylbenzene or naphthalene.Zymosan is glucosan or mannan.
The manufacture method of a kind of Vegetable Fuel Gasoline additive, specifically comprises the following steps that
Weigh successively weight ratio be 35~the cycloalkane of the alkane of the vegetable oil of 40%, 10~15%, 12~13%, 13
~the zymosan of the chitosanase of the chitosan of the aromatic hydrocarbon of 15%, 4~6%, 2~3%, 2~3%, 0.03~0.05%
The ethanol of yeast, 4.95~21.97%, the said components weighed is joined in open fermentation tank in any order
Ferment;It is 22~25 DEG C that fermentation temperature controls, and in fermentation tank, the mixing speed of magnetic stirring bar controls is 30~35r/
Min, it is 48~72h that mixing time controls;In whipping process, often stirring 30min just stops stirring 1h;
After fermentation ends, use the drainage screen of more than 400 mesh that fermentation liquid is filtered, obtain the filtrate of clear;
Filtrate is placed in high temperature dehydration device, in 120 DEG C, filtrate is carried out under conditions of 2MPa processed, dewatering time controls
Being 2~4h, the filtrate after dehydration is Vegetable Fuel Gasoline additive finished product.
The using method of a kind of Vegetable Fuel Gasoline additive is: by above-mentioned Vegetable Fuel Gasoline additive with fuel oil according to 5:10000
Mass ratio mix after use;Fuel oil is gasoline or diesel oil or kerosene.
Research find, gasoline by fuel injector when nozzle sprays into combustion chamber, before combustion in vapour collosol state, colloidal sol
State reduce further the contact area of petrol molecule and oxygen molecule, and the combustion rate making regular gasoline is relatively low.And by this
After the Vegetable Fuel Gasoline additive that bright method makes is attached to fuel oil surface, 200 μm particles in fuel oil can be made fine to 10 μm
Hereinafter, making the relative surface area of fuel particle increase, the oxygen content in fuel oil increases severely, thus increases the combustion rate of fuel oil, reduces
Oil consumption, and reduce the discharge capacity of waste gas and the dust burnt the most completely further, be conducive to protecting environment.Additionally, the present invention
Vegetable Fuel Gasoline additive, after mixing with fuel oil, it is also possible to effectively the fuel oil of collosol state is adsorbed, wraps up, make
It produces gaseousness " microexplosion " in combustion chamber, makes fuel oil secondary-atomizing, causes and burns completely, promotes engine further and moves
Power.Vehicle, after using the present invention first, can substantially feel that power strengthens, and particularly car is weak, old, load-carrying or sense during long journey
Feel becomes apparent from.
By specific examples below, manufacture method and the application of the present invention are further elaborated below:
Embodiment one:
The configuration of Vegetable Fuel Gasoline additive is carried out according to following weight when formula:
After above-mentioned composition is sequentially passed through fermentation, filtering, be dehydrated, add vapour with gasoline to the mass ratio of 5:10000
Mix in car oil case.The vehicle of test is 2015 sections of 1.6L automatic prevailing custom versions of upper vapor mass Santana.Test result shows,
Compared with when not using fuel oil additive, under the conditions of identical road conditions and mileage, with the addition of Vegetable Fuel Gasoline additive of the present invention
Gasoline oil consumption reduce 20%, the PM2.5 content of vehicle emission reduces 70%.
Embodiment two:
The configuration of Vegetable Fuel Gasoline additive is carried out according to following weight when formula:
After above-mentioned composition is sequentially passed through fermentation, filtering, be dehydrated, add vapour with diesel oil to the mass ratio of 5:10000
Mix in car oil case.Test vehicle be Austria speed A3 series 115 horsepowers of 4.2 meters of single breast boards gently block FD1040D63K4-5.
Test result shows, compared with when not using fuel oil additive, under the conditions of identical road conditions and mileage, with the addition of the present invention and plants
The diesel oil oil consumption of thing fuel oil additive reduces 15%, the PM2.5 content of vehicle emission reduces 50%.
Embodiment three:
The configuration of Vegetable Fuel Gasoline additive is carried out according to following weight when formula:
After above-mentioned composition is sequentially passed through fermentation, filtering, be dehydrated, add vapour with gasoline to the mass ratio of 5:10000
Mix in car oil case.The vehicle of test is modern auspicious 2010 sections of the three railway carriage or compartment 1.4LGS MT that receives in Beijing.Test result shows, with
Compare when not using fuel oil additive, under the conditions of identical road conditions and mileage, with the addition of Vegetable Fuel Gasoline additive of the present invention
Gasoline oil consumption reduces 30%, the PM2.5 content of vehicle emission reduces 90%.
Example four in real time:
The configuration of Vegetable Fuel Gasoline additive is carried out according to following weight when formula:
After above-mentioned composition is sequentially passed through fermentation, filtering, be dehydrated, add vapour with gasoline to the mass ratio of 5:10000
Mix in car oil case.The vehicle of test is 2009 sections of 1.8AT fashion types of FORD FOCUS.Test result shows, and does not makes
Compare during with fuel oil additive, under the conditions of identical road conditions and mileage, with the addition of the gasoline of Vegetable Fuel Gasoline additive of the present invention
Oil consumption reduces 26%, the PM2.5 content of vehicle emission reduces 60%.
Embodiment five:
The configuration of Vegetable Fuel Gasoline additive is carried out according to following weight when formula:
After above-mentioned composition is sequentially passed through fermentation, filtering, be dehydrated, add vapour with diesel oil to the mass ratio of 5:10000
Mix in car oil case.The vehicle of test is the all-cis 2009 sections of 2.8T short axle of the diesel oil Mobyneb low top JX493ZLQ3 of Ford.
Test result shows, compared with when not using fuel oil additive, under the conditions of identical road conditions and mileage, with the addition of the present invention and plants
The diesel oil oil consumption of thing fuel oil additive reduces 21%, the PM2.5 content of vehicle emission reduces 55%.
Embodiment six:
The configuration of Vegetable Fuel Gasoline additive is carried out according to following weight when formula:
After above-mentioned composition is sequentially passed through fermentation, filtering, be dehydrated, add vapour with gasoline to the mass ratio of 5:10000
Mix in car oil case.The vehicle of test is 2009 sections of standard types 6386AVF of Wuling Sunshine.Test result shows, and does not makes
Compare during with fuel oil additive, under the conditions of identical road conditions and mileage, with the addition of the gasoline of Vegetable Fuel Gasoline additive of the present invention
Oil consumption reduces 28%, the PM2.5 content of vehicle emission reduces 65%.
Embodiment seven:
The configuration of Vegetable Fuel Gasoline additive is carried out according to following weight when formula:
After above-mentioned composition is sequentially passed through fermentation, filtering, be dehydrated, add vapour with gasoline to the mass ratio of 5:10000
Mix in car oil case.2009 sections of SC6363BV4 states IV of the star that vehicle is Chang'an of test.Test result shows, and does not makes
Compare during with fuel oil additive, under the conditions of identical road conditions and mileage, with the addition of the gasoline of Vegetable Fuel Gasoline additive of the present invention
Oil consumption reduces 23%, the PM2.5 content of vehicle emission reduces 55%.
Embodiment eight:
The configuration of Vegetable Fuel Gasoline additive is carried out according to following weight when formula:
After above-mentioned composition is sequentially passed through fermentation, filtering, be dehydrated, add vapour with diesel oil to the mass ratio of 5:10000
Mix in car oil case.The vehicle of test is that east wind many profits card 4.15 meters of single storehouse grating of D6115 horsepower are gently blocked
DFA5040CCY11D2AC.Test result shows, compared with when not using fuel oil additive, in identical road conditions and mileage condition
Under, with the addition of that the diesel oil oil consumption of Vegetable Fuel Gasoline additive of the present invention reduces 19%, the PM2.5 content of vehicle emission reduces
65%.
Embodiment nine:
The configuration of Vegetable Fuel Gasoline additive is carried out according to following weight when formula:
After above-mentioned composition is sequentially passed through fermentation, filtering, be dehydrated, add vapour with gasoline to the mass ratio of 5:10000
Mix in car oil case.The vehicle of test is 2009 sections of 1.6SLAT of Ford Ke Luzi.Test result shows, and does not uses combustion
Compare during oil additive, under the conditions of identical road conditions and mileage, with the addition of the gasoline oil consumption of Vegetable Fuel Gasoline additive of the present invention
Reduce 18%, the PM2.5 content of vehicle emission reduces 50%.
Above-mentioned embodiment is not limitation of the present invention, and the present invention is also not limited to the example above, and this technology is led
Change that the technical staff in territory is made in the range of technical scheme, retrofit, add or replace, also belong to this
Bright protection domain.
Claims (8)
1. a Vegetable Fuel Gasoline additive, it is characterised in that: described Vegetable Fuel Gasoline additive is made up of the raw material of following weight ratio:
Vegetable Fuel Gasoline additive the most according to claim 1, it is characterised in that: described vegetable oil is Semen Maydis oil or soybean oil
Or Oleum Ricini.
Vegetable Fuel Gasoline additive the most according to claim 1, it is characterised in that: described alkane is butane or pentane or own
Alkane or heptane or octane or nonane or decane or hendecane or dodecane.
Vegetable Fuel Gasoline additive the most according to claim 1, it is characterised in that: described cycloalkane is Tetramethylene. or Pentamethylene.
Or hexamethylene or cycloheptane or cyclooctane or cyclononane or cyclodecane or ring hendecane or cyclododecane.
Vegetable Fuel Gasoline additive the most according to claim 1, it is characterised in that: described aromatic hydrocarbon be toluene or dimethylbenzene or
Naphthalene.
Vegetable Fuel Gasoline additive the most according to claim 1, it is characterised in that: described zymosan is glucosan or manna
Polysaccharide.
7. the manufacture method of a Vegetable Fuel Gasoline additive, it is characterised in that: specifically comprising the following steps that of described manufacture method
Weigh successively weight ratio be 35~the cycloalkane of the alkane of the vegetable oil of 40%, 10~15%, 12~13%, 13~
The zymosan of the chitosanase of the chitosan of aromatic hydrocarbon, 4~6%, 2~3%, 2~3%, 0.03~0.05% of 15%
The ethanol of yeast, 4.95~21.97%, joins in open fermentation tank by the said components weighed in any order
Row fermentation;It is 22~25 DEG C that fermentation temperature controls, and in fermentation tank, the mixing speed of magnetic stirring bar controls is 30~35r/min,
It is 48~72h that mixing time controls;In whipping process, often stirring 30min just stops stirring 1h;
After fermentation ends, use the drainage screen of more than 400 mesh that fermentation liquid is filtered, obtain the filtrate of clear;Will filter
Liquid is placed in high temperature dehydration device, in 120 DEG C, filtrate is carried out under conditions of 2MPa processed, dewatering time control be 2~
4h, the filtrate after dehydration is Vegetable Fuel Gasoline additive finished product.
8. the using method of a Vegetable Fuel Gasoline additive, it is characterised in that: described using method is:
Use after above-mentioned Vegetable Fuel Gasoline additive is mixed according to the mass ratio of 5:10000 with fuel oil;Described fuel oil is
Gasoline or diesel oil or kerosene.
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1493669A (en) * | 2002-10-29 | 2004-05-05 | 符树庆 | Vegeteble oil derivative liqid fuel oil environmental protection energy saving additive |
US20100058649A1 (en) * | 2008-09-10 | 2010-03-11 | Poet Research | Oil composition and method of recovering the same |
CN102250653A (en) * | 2011-05-20 | 2011-11-23 | 黄龙哲 | Energy-saving agent for biomass fuel oil |
WO2014143808A1 (en) * | 2013-03-15 | 2014-09-18 | Children's Medical Center Corporation | Hollow particles encapsulating a biological gas and methods of use |
CN104745251A (en) * | 2015-03-12 | 2015-07-01 | 黄龙哲 | Preparation method of biofuel oil energy-saving agent |
-
2016
- 2016-07-30 CN CN201610614931.XA patent/CN106190360A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1493669A (en) * | 2002-10-29 | 2004-05-05 | 符树庆 | Vegeteble oil derivative liqid fuel oil environmental protection energy saving additive |
US20100058649A1 (en) * | 2008-09-10 | 2010-03-11 | Poet Research | Oil composition and method of recovering the same |
CN102250653A (en) * | 2011-05-20 | 2011-11-23 | 黄龙哲 | Energy-saving agent for biomass fuel oil |
WO2014143808A1 (en) * | 2013-03-15 | 2014-09-18 | Children's Medical Center Corporation | Hollow particles encapsulating a biological gas and methods of use |
CN104745251A (en) * | 2015-03-12 | 2015-07-01 | 黄龙哲 | Preparation method of biofuel oil energy-saving agent |
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