CN106189758A - Antifogging composition, antifogging sheet and antifogging coating - Google Patents
Antifogging composition, antifogging sheet and antifogging coating Download PDFInfo
- Publication number
- CN106189758A CN106189758A CN201510909500.1A CN201510909500A CN106189758A CN 106189758 A CN106189758 A CN 106189758A CN 201510909500 A CN201510909500 A CN 201510909500A CN 106189758 A CN106189758 A CN 106189758A
- Authority
- CN
- China
- Prior art keywords
- antifog
- particle
- adhesive
- chemical formula
- antifogging
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000203 mixture Substances 0.000 title claims abstract description 60
- 238000000576 coating method Methods 0.000 title claims description 61
- 239000011248 coating agent Substances 0.000 title claims description 49
- 239000002245 particle Substances 0.000 claims abstract description 71
- 238000010438 heat treatment Methods 0.000 claims abstract description 49
- 239000002105 nanoparticle Substances 0.000 claims abstract description 35
- 239000010937 tungsten Substances 0.000 claims abstract description 31
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 31
- 239000011347 resin Substances 0.000 claims abstract description 29
- 229920005989 resin Polymers 0.000 claims abstract description 29
- -1 polypropylene Polymers 0.000 claims abstract description 21
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004743 Polypropylene Substances 0.000 claims abstract description 10
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 10
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 10
- 239000004417 polycarbonate Substances 0.000 claims abstract description 10
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 10
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 8
- 229920001155 polypropylene Polymers 0.000 claims abstract description 8
- 239000011152 fibreglass Substances 0.000 claims abstract 2
- 230000008033 biological extinction Effects 0.000 claims description 54
- 239000000853 adhesive Substances 0.000 claims description 42
- 230000001070 adhesive effect Effects 0.000 claims description 42
- 239000000126 substance Substances 0.000 claims description 31
- 229910000906 Bronze Inorganic materials 0.000 claims description 28
- 239000010974 bronze Substances 0.000 claims description 28
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 28
- 239000003522 acrylic cement Substances 0.000 claims description 23
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 claims description 22
- 229910001930 tungsten oxide Inorganic materials 0.000 claims description 22
- 150000003657 tungsten Chemical class 0.000 claims description 19
- 239000008187 granular material Substances 0.000 claims description 17
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 15
- 229910052710 silicon Inorganic materials 0.000 claims description 15
- 239000010703 silicon Substances 0.000 claims description 15
- 239000011734 sodium Substances 0.000 claims description 15
- 239000011575 calcium Substances 0.000 claims description 14
- 239000000460 chlorine Substances 0.000 claims description 14
- 239000011777 magnesium Substances 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 13
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- 239000000741 silica gel Substances 0.000 claims description 10
- 229910002027 silica gel Inorganic materials 0.000 claims description 10
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 9
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 9
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 9
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 9
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 9
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- 229910052787 antimony Inorganic materials 0.000 claims description 9
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 9
- GVFOJDIFWSDNOY-UHFFFAOYSA-N antimony tin Chemical compound [Sn].[Sb] GVFOJDIFWSDNOY-UHFFFAOYSA-N 0.000 claims description 9
- 229910052788 barium Inorganic materials 0.000 claims description 9
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 9
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 9
- 229910052794 bromium Inorganic materials 0.000 claims description 9
- 229910052792 caesium Inorganic materials 0.000 claims description 9
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 9
- 229910052791 calcium Inorganic materials 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 229910052801 chlorine Inorganic materials 0.000 claims description 9
- 229910052731 fluorine Inorganic materials 0.000 claims description 9
- 239000011737 fluorine Substances 0.000 claims description 9
- 229910052733 gallium Inorganic materials 0.000 claims description 9
- 229910052744 lithium Inorganic materials 0.000 claims description 9
- 229910052749 magnesium Inorganic materials 0.000 claims description 9
- 229910052700 potassium Inorganic materials 0.000 claims description 9
- 239000011591 potassium Substances 0.000 claims description 9
- 229910052701 rubidium Inorganic materials 0.000 claims description 9
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 9
- 229910052712 strontium Inorganic materials 0.000 claims description 9
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 9
- 235000013339 cereals Nutrition 0.000 claims description 8
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 7
- MRNHPUHPBOKKQT-UHFFFAOYSA-N indium;tin;hydrate Chemical compound O.[In].[Sn] MRNHPUHPBOKKQT-UHFFFAOYSA-N 0.000 claims description 7
- 239000011630 iodine Substances 0.000 claims description 7
- 229910052740 iodine Inorganic materials 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- 239000004836 Glue Stick Substances 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 claims description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical group NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 5
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 claims description 5
- 238000004026 adhesive bonding Methods 0.000 claims description 5
- 229930016911 cinnamic acid Natural products 0.000 claims description 5
- 235000013985 cinnamic acid Nutrition 0.000 claims description 5
- 125000000524 functional group Chemical group 0.000 claims description 5
- 239000003365 glass fiber Substances 0.000 claims description 5
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims description 5
- 125000004469 siloxy group Chemical group [SiH3]O* 0.000 claims description 5
- 150000005846 sugar alcohols Polymers 0.000 claims description 5
- 229920001187 thermosetting polymer Polymers 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 229920002430 Fibre-reinforced plastic Polymers 0.000 claims description 4
- 235000007164 Oryza sativa Nutrition 0.000 claims description 4
- MPSXZBZUSOMAQW-UHFFFAOYSA-N acetic acid;prop-1-ene Chemical group CC=C.CC(O)=O MPSXZBZUSOMAQW-UHFFFAOYSA-N 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 235000009566 rice Nutrition 0.000 claims description 4
- 239000004568 cement Substances 0.000 claims description 3
- 238000013007 heat curing Methods 0.000 claims description 2
- 229910052738 indium Inorganic materials 0.000 claims description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims description 2
- 230000008023 solidification Effects 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims 3
- 241000209094 Oryza Species 0.000 claims 3
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- 229920000180 alkyd Polymers 0.000 claims 1
- 239000003292 glue Substances 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 19
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 abstract description 2
- SKRWFPLZQAAQSU-UHFFFAOYSA-N stibanylidynetin;hydrate Chemical compound O.[Sn].[Sb] SKRWFPLZQAAQSU-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000463 material Substances 0.000 description 21
- 239000000758 substrate Substances 0.000 description 17
- 239000003595 mist Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000005034 decoration Methods 0.000 description 9
- 239000011521 glass Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000005507 spraying Methods 0.000 description 5
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 238000010422 painting Methods 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 239000000779 smoke Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000013464 silicone adhesive Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 229920006305 unsaturated polyester Polymers 0.000 description 2
- 241000282326 Felis catus Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000004651 carbonic acid esters Chemical class 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000012994 photoredox catalyst Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 238000001029 thermal curing Methods 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
- KJAMZCVTJDTESW-UHFFFAOYSA-N tiracizine Chemical compound C1CC2=CC=CC=C2N(C(=O)CN(C)C)C2=CC(NC(=O)OCC)=CC=C21 KJAMZCVTJDTESW-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D169/00—Coating compositions based on polycarbonates; Coating compositions based on derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/68—Particle size between 100-1000 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2258—Oxides; Hydroxides of metals of tungsten
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nanotechnology (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
An anti-fog composition comprising: 90-99.999% by weight of resin; and 0.001-10 wt% of light-absorbing heating particles, wherein the resin is polycarbonate, polymethyl methacrylate, glass fiber reinforced plastic or polypropylene, and the light-absorbing heating particles are tungsten-containing oxide nanoparticles, indium tin oxide, antimony tin oxide or lanthanum hexaboride. The light-absorbing heating particles can effectively convert light energy into heat energy, so that the antifogging composition with the antifogging function can be directly prepared into various antifogging articles, and the effect of maintaining the durability of the antifogging is achieved.
Description
Technical field
The present invention is that a kind of antifog compositions, the present invention additionally comprises about a kind of compositions
Antifog plate made by this antifog compositions, and by the antifog painting made by this antifog compositions
Layer.
Background technology
Aqueous vapor in air can naturally be condensed in surface temperature and significantly be less than on the article of air, with
Forming the small-sized globule at body surface, such natural phenomena often causes much inconvenience for life,
Such as: morning window-glass attachment water smoke, and to shine upon and after evaporation drying, on glass
Formed irritating water stain；Not only in this, for living in the people in the low cold area of temperature, water smoke coagulates
The problem of knot more likely produces contingency, such as: being often condensed in glass for vehicle window fog is driving
One big secret worry of safety, therefore, the most effectively prevents fog to be condensed on article, has become suitable
Important problem.
It is said that in general, often utilize at present a fog remover or an electric heater with except mist, wherein, user
Being intended to be coated with an antifoggant except the article surface of mist to form an antifog film, this antifoggant comprises interface
Activating agent and organic solvent, after forming this antifog film, it is possible to reduce aqueous vapor is at the table of body surface
Surface tension, allows aqueous vapor be difficult at article surface and condenses formation drop, reach antifog effect whereby.
It addition, user can also utilize this electric heater to contact article surface, to improve the temperature of article surface
Degree, reduces the aqueous vapor in air and meets the cold situation generation being condensed in object.
But, the persistency of this antifoggant is the highest, is often coated with this antifoggant one section in article surface
After time, i.e. produce friction because of article and foreign object, cut and scrape, or suffer that heavy rain Washing makes this
Antifog film comes off, and then loses the anti-fog effect to article, therefore when using this antifoggant to prevent
Fog is when article surface is formed, it is necessary to spraying could maintain effectiveness the most repeatedly, but, by
Contain high volatile Organic substance solvent in this spray, repeatedly spray and even health can be produced
Raw negative effect.It addition, improve article temperature with this electric heater, it is necessary to constantly provide electric power with dimension
Hold article in a predetermined temperature, to prevent water gas from meeting condensation knot, consequently, it is possible in order to antifog and throw
Enter substantial amounts of energy cost, hence it is evident that run counter in current environmental protection trend.
In view of this, it is necessary to provide a kind of antifog compositions, antifog plate and antifogging coating, to solve
Certainly the past uses this antifoggant and this electric heater to be produced to prevent fog to be formed on article
Problem.
Summary of the invention
The present invention provides a kind of antifog compositions, and this antifog compositions can convert light energy into heat
Energy.
The present invention provides a kind of antifog plate, and this antifog plate is by aforesaid antifog compositions institute former.
The present invention provides a kind of antifogging coating, and this antifogging coating is by aforesaid antifog compositions institute shape
Become.
The present invention provides a kind of antifog compositions, and it comprises: be by weight percentage 90～
The resin of 99.999%, this resin is that polycarbonate, polymethyl methacrylate, glass fibre are strong
Change plastic cement or polypropylene；And be by weight percentage 0.001～10% extinction heating particle,
This extinction heating particle is tungstenic oxide nano-particles, tin indium oxide, antimony tin or six boronations
Lanthanum.
The antifog compositions of the present invention, wherein, this tungstenic oxide nano-particles choosing freely oxidation
Tungsten nanoparticle, and the group that tungsten bronze complex nanometer granule is formed.
The antifog compositions of the present invention, wherein, the chemical formula of this tungsten oxide nanometer particle is WOx,
Wherein, 2.2 x 3.
The antifog compositions of the present invention, wherein, the chemical formula of this tungsten bronze complex nanometer granule is
AyWOz, wherein, A is major element, 0.01 y 1,2.2 z 3.
The antifog compositions of the present invention, wherein, the chemical formula of this tungsten oxide nanometer particle is WO2.72。
The antifog compositions of the present invention, wherein, A be lithium (Li), sodium (Na), potassium (K),
Rubidium (Rb), caesium (Cs), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), aluminum (Al),
Gallium (Ga), carbon (C), silicon (Si), stannum (Sn), antimony (Sb), fluorine (F), chlorine (Cl),
Bromine (Br) or iodine (I).
The antifog compositions of the present invention, wherein, the chemical formula of this tungsten bronze complex nanometer granule
For Cs0.33WO3。
The antifog compositions of the present invention, wherein, the size of this tungstenic oxide nano-particles is
1nm～500nm.
The present invention provides a kind of antifog plate, and it comprises: be 90～99.999% by weight percentage
Resin, this resin be polycarbonate, polymethyl methacrylate, glass fibre reinforced plastic or
Polypropylene；And be by weight percentage 0.001～10% extinction heating particle, this extinction is sent out
Hot particle is scattered in this resin, and this extinction heating particle is tungstenic oxide nano-particles, oxidation
Indium stannum, antimony tin or lanthanum hexaboride.
The antifog plate of the present invention, wherein, the thickness of this antifog plate is 10 μm～10mm, and should
Antifog plate comprise by weight percentage 0.005～10% this extinction heating particle.
The antifog plate of the present invention, wherein, this tungstenic oxide nano-particles choosing freely tungsten oxide is received
Rice corpuscles, and the group that tungsten bronze complex nanometer granule is formed.
The antifog plate of the present invention, wherein, the chemical formula of this tungsten oxide nanometer particle is WOx, wherein,
2.2≦x≦3。
The antifog plate of the present invention, wherein, the chemical formula of this tungsten bronze complex nanometer granule is
AyWOz, wherein, A is major element, 0.01 y 1,2.2 z 3.
The antifog plate of the present invention, wherein, the chemical formula of this tungsten oxide nanometer particle is WO2.72。
The antifog plate of the present invention, wherein, A be lithium (Li), sodium (Na), potassium (K), rubidium (Rb),
Caesium (Cs), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), aluminum (Al), gallium (Ga),
Carbon (C), silicon (Si), stannum (Sn), antimony (Sb), fluorine (F), chlorine (Cl), bromine (Br) or
Iodine (I).
The antifog plate of the present invention, wherein, the chemical formula of this tungsten bronze complex nanometer granule is
Cs0.33WO3。
The antifog plate of the present invention, wherein, the size of this tungstenic oxide nano-particles is 1
Nm～500nm.
The present invention provides another kind of antifog compositions, and it comprises: be by weight percentage 90～
The sticker of 99.999%, this sticker is a monomer or the oligomer comprising this monomer, this monomer
There is a functional group of the group selecting free siloxy, acrylic, carbamate groups to be formed；
And be by weight percentage 0.001～10% extinction heating particle, this extinction heating particle be
Tungstenic oxide nano-particles, tin indium oxide, antimony tin or lanthanum hexaboride.
The antifog compositions of the present invention, wherein, this sticker be an oiliness acryl glue stick, one
Aqueous acryl glue stick, a Polyurethane glue stick or an organic liquid silica gel.
The antifog compositions of the present invention, wherein, this oiliness acryl glue stick is a thermoplasticity pressure gram
Power adhesive, a thermosetting acryl adhesive or a polyalcohols type acryl glue stick.
The antifog compositions of the present invention, wherein, this aqueous acryl glue stick is that an acrylic acid is gluing
Agent, a cinnamic acid adhesive or an acetate propylene acid adhesive.
The antifog compositions of the present invention, wherein, this organic liquid silica gel be an organic silicon adhesive,
Monomethyl organic silicone adhesive, an organosilicon alcohol acid adhesive or an acid-organosilicon crylic acid are gluing
Agent.
The antifog compositions of the present invention, wherein, this tungstenic oxide nano-particles choosing freely oxidation
Tungsten nanoparticle, and the group that tungsten bronze complex nanometer granule is formed.
The antifog compositions of the present invention, wherein, the chemical formula of this tungsten oxide nanometer particle is WO2.72。
The antifog compositions of the present invention, wherein, the chemical formula of this tungsten bronze complex nanometer granule is
AyWOz, wherein, A be lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs),
Magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), aluminum (Al), gallium (Ga), carbon (C),
Silicon (Si), stannum (Sn), antimony (Sb), fluorine (F), chlorine (Cl), bromine (Br) or iodine (I),
And 0.01 y 1,2.2 z 3.
The antifog compositions of the present invention, wherein, the chemical formula of this tungsten bronze complex nanometer granule is
Cs0.33WO3。
The antifog compositions of the present invention, wherein, the particle diameter of this extinction heating particle is 1nm～500
nm。
The present invention provides a kind of antifogging coating, comprises: be 90～99.999% by weight percentage
Sticker, this sticker is a monomer or the oligomer comprising this monomer, and this monomer has and is selected from
One functional group of the group being made up of siloxy, acrylic, carbamate groups；And with weight
Amount percentages is the extinction heating particle of 0.001～10%, and this extinction heating particle is tungstenic oxygen
Compound nanoparticle, tin indium oxide, antimony tin or lanthanum hexaboride, wherein, this extinction heating grain
Son is scattered in this sticker, and via heat cure or ultraviolet light polymerization to be collectively forming an antifog painting
Layer.
The antifogging coating of the present invention, wherein, the thickness of this antifogging coating is 100nm～10mm.
The antifogging coating of the present invention, wherein, this sticker is an oiliness acryl glue stick, a water
Property acryl glue stick, a Polyurethane glue stick or an organic liquid silica gel.
The antifogging coating of the present invention, wherein, this oiliness acryl glue stick is a thermoplasticity acryl
Adhesive, a thermosetting acryl adhesive or a polyalcohols type acryl glue stick.
The antifogging coating of the present invention, wherein, this aqueous acryl glue stick be an acrylic acid adhesive,
One cinnamic acid adhesive or an acetate propylene acid adhesive.
The antifogging coating of the present invention, wherein, this organic liquid silica gel be an organic silicon adhesive, one
Methylsiloxane ketone adhesive, an organosilicon alcohol acid adhesive or an acid-organosilicon crylic acid adhesive.
The antifogging coating of the present invention, wherein, this tungstenic oxide nano-particles choosing freely tungsten oxide
Nanoparticle, and the group that tungsten bronze complex nanometer granule is formed.
The antifogging coating of the present invention, wherein, the chemical formula of this tungsten oxide nanometer particle is WO2.72。
The antifogging coating of the present invention, wherein, the chemical formula of this tungsten bronze complex nanometer granule is
AyWOz, wherein, A be lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs),
Magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), aluminum (Al), gallium (Ga), carbon (C),
Silicon (Si), stannum (Sn), antimony (Sb), fluorine (F), chlorine (Cl), bromine (Br) or iodine (I),
And 0.01 y 1,2.2 z 3.
The antifogging coating of the present invention, wherein, the chemical formula of this tungsten bronze complex nanometer granule is
Cs0.33WO3。
The antifog compositions of the present invention comprise be by weight percentage 0.001～10% extinction send out
Hot particle, this extinction heating particle can effectively absorb luminous energy, and be converted further into heat energy.
Additionally, the resin comprised according to this antifog compositions or the characteristic of sticker, user is the most permissible
This antifog compositions is configured to further this antifog plate (can also on the anti-fog surface of this substrate shape
Become this antifogging coating), the most i.e. can make this antifog plate by the effect of this extinction heating particle
The temperature of (or antifogging coating) rises, and makes aqueous vapor cannot be condensed in this antifog plate (or antifogging coating)
On, and then reach antifog effect.
Further, by this antifog compositions directly being prepared the various antifogging article of shaping, therefore,
Be not necessary to be prone to the antifoggant that comes off being intended on antifog article spraying, so reach to maintain antifog persistently
Effect of property.
Additionally, aforesaid antifog plate or be formed with the substrate of this antifogging coating more can be directly as example
As the Building Decoration Material such as window, eaves is used, or existing Building Decoration Material is carried out antifog
The processing of coating, (or adds through antifogging coating when sunlight is irradiated in the window being made up of this antifog plate
The window of work) time, window makes temperature rise, to avoid mist condensation because converting light energy into heat energy
Thereon, compared to the fog using electric heater to remove window surface, the employing present invention's is antifog for knot
Plate and be formed with the substrate of this antifogging coating as Building Decoration Material, can reach to save antifog institute
Effect of energy need to be expended.
Accompanying drawing explanation
Fig. 1: for the stereo appearance figure of the antifog plate of the present invention.
Fig. 2: for the cutaway view Amplified image of the antifog plate of the present invention.
Fig. 3: for polycarbonate plate E0 group photo figure after antifog test.
Fig. 4: for the present invention antifog plate E1 group photo figure after antifog test.
Detailed description of the invention
For above-mentioned and other purpose, feature and the advantage of the present invention can be become apparent, hereafter
Especially exemplified by presently preferred embodiments of the present invention, and coordinate institute's accompanying drawings, be described in detail below:
The antifog compositions of the present invention comprise be by weight percentage 0.001～10% extinction send out
Hot particle, this extinction heating particle can convert light energy into heat energy, make this antifog compositions have
Antifog effect.
In more detail, this extinction heating particle is tungstenic oxide nano-particles, tin indium oxide
(Antimony Tin Oxide is called for short for (Indium Tin Oxide is called for short ITO), antimony tin
Or lanthanum hexaboride (LaB ATO)6), or the group being made up of above-claimed cpd.Wherein, should
The size of extinction heating particle is 1nm～500nm, and this tungstenic oxide nano-particles
Can be tungsten oxide nanometer particle, tungsten bronze complex nanometer granule or the two combination.
In detail, the chemical formula of this tungsten oxide nanometer particle is WOx, wherein, 2.2 x 3；
The chemical formula of this tungsten bronze complex nanometer granule is AyWOz, wherein, A is the periodic table of elements
In major element, 0.01 y 1,2.2 z 3, it is preferred that A be lithium (Li), sodium (Na),
Potassium (K), rubidium (Rb), caesium (Cs), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba),
Aluminum (Al), gallium (Ga), carbon (C), silicon (Si), stannum (Sn), antimony (Sb), fluorine (F),
Chlorine (Cl), bromine (Br) or iodine (I), this tungsten bronze complex nanometer granule can be Cs0.33WO3、
K0.33WO3、K0.55WO3、Na0.5WO3Or Ba0.33WO3Nanoparticle.In first embodiment
In, this tungsten oxide nanometer particle is WO2.72Nanoparticle, this tungsten bronze complex nanometer granule
It is then Cs0.33WO3Nanoparticle.
Antifog compositions in first embodiment of the invention can additionally comprise and be by weight percentage
90～the resin of 99.999%, this resin can be polycarbonate (Polycarbonate is called for short PC),
Polymethyl methacrylate (Polymethylmethacrylate is called for short PMMA), glass fibre
Reinforced plastic (Fiber Reinforced Plastic, be called for short FRP) or polypropylene (Polypropylene,
It is called for short PP)；So, i.e. can be different according to contained resin kind and molecular weight thereof, can be formed
Transparent, translucent or opaque antifog plate, the antifog plate of different transmittances respectively has different purposes,
Wherein, present this transparent antifog plate to use as window or other perspective materials.
Refer to shown in Fig. 1～2, this is the schematic diagram of the antifog plate of the present invention, this antifog plate bag
Containing a resin plate 1 and several extinction heating particle 2, these several extinctions heating particle 2 disperses this tree
In ester plate 1, it is the resin of 90～99.999% by weight percentage that this antifog plate comprises, and with
Percentage by weight is calculated as the extinction heating particle 2 of 0.001～10%, and this antifog plate has a thickness d,
It is preferred that this thickness d is 10 μm～10mm, and this antifog plate can have with weight percent
Ratio is calculated as this extinction heating particle 2 of 0.005～10%, wherein, this thickness d of this antifog plate
And the ratio of this extinction heating particle 2 can work in coordination, to reach preferably except fog effect, lift
For example, when this thickness d is 10 μm, this antifog plate preferably contains 100000ppm (i.e.
Be 10% by weight percentage) extinction heating particle；When this thickness d is 1mm, should
Antifog plate preferably contains the extinction heating grain of 1000ppm (being 0.1% the most by weight percentage)
Son；When this thickness d is 2mm, this antifog plate preferably contains 500ppm (i.e. with weight hundred
Proportion by subtraction is calculated as 0.05%) extinction heating particle；When this thickness d is 10mm, this antifog plate
The preferably extinction heating particle containing 50ppm (being 0.005% the most by weight percentage).
This antifog plate can be shaped by the method such as forming process or die forming method of extrusion, depending on this resin
Kind, the purposes of this extinction heating particle and the mixing homogeneity of resin and this antifog plate adjusts
Whole, it is seldom to limit at this.For example: when this resin be thermoplasticity resin (such as: poly-
Carbonic ester, polypropylene or polymethyl methacrylate) time, first this extinction generated heat particle 2 and be somebody's turn to do
Resin feeds according to predetermined ratio at the charging of single screw extruder or double-screw compressor simultaneously, and
Extrude this antifog plate of various thickness；When the material of this resin plate be thermoset resin (such as: glass
Fibre strengthening plastic cement) time, the particle that generated heat by this extinction of special ratios makes an addition in unsaturated polyester (UP),
And mix homogeneously with cinnamic monomer, reheat and pour in mould, to form this thickness d specific
Antifog plate.It addition, when resin is respectively PC, PMMA, FRP and PP, shapes this and prevent
The processing temperature of mist plate preferably be respectively 250～290 DEG C, 180～220 DEG C, 80～120 DEG C and
190～230 DEG C.
Additionally, in the antifog compositions of second embodiment of the invention, except comprise as the aforementioned with
Percentage by weight be calculated as 0.001～10% this extinction heating particle outside, separately can comprise with weight
Amount percentages is the sticker of 90～99.999%；In details of the words, this sticker be a monomer or
Comprising the oligomer of this monomer, this monomer has choosing free siloxy, acrylic, carbamic acid
One functional group of the group that ester group is formed.
It is gluing that this sticker can be chosen as an oiliness acryl glue stick, an aqueous acryl
Agent, a Polyurethane glue stick or an organic liquid silica gel；For example, this oiliness acryl is gluing
Agent can be a thermoplasticity acryl glue stick (Changxing material industry limited company,
ETERAC 7106-X-58), (Changxing material industry share is limited for a thermosetting acryl adhesive
Company, ETERAC 7232-BR-58) or polyalcohols type acryl glue stick (Changxing material industry
Limited company, ETERAC 7305-3-XC-50) (this oiliness acryl glue stick relevant
Characteristic system can be as
http://www.eternal-group.com/Product/Detail？Shown in id=92&lang=tw)；This water
Property acryl glue stick can be an acrylic acid adhesive (Changxing material industry limited company,
ETERSOL 1137), a cinnamic acid adhesive (Changxing material industry limited company,
ETERSOL 6515T) or an acetate propylene acid adhesive (Changxing limited public affairs of material industry share
Department, ETERSOL 3503)；This Polyurethane glue stick can be the such as precious resin NP-35 in south or
Changxing material industry limited company ETERAC 7786 (spy about this Polyurethane glue stick
Property can be such as http://www.nanpao.com.cn/chi/product1.asp？D2=8 and
http://www.eternal-group.com/Product/Detail？Shown in id=88&lang=tw)；Should
Organic liquid silica gel can be an organic silicon adhesive (Gui Liguang limited company of Taiwan SHIN-ETSU HANTOTAI,
KR-282), monomethyl organic silicone adhesive (Gui Liguang limited company of Taiwan SHIN-ETSU HANTOTAI,
KR-500), an organosilicon alcohol acid adhesive (Gui Liguang limited company of Taiwan SHIN-ETSU HANTOTAI,
KR-5206) or one acid-organosilicon crylic acid adhesive (Gui Liguang limited company of Taiwan SHIN-ETSU HANTOTAI,
KR-9706) (the characteristic system about this organic liquid silica gel can be as
http://www.shinetsu.com.tw/html/pdt2.asp？Area=65&cat=212&sn=85 institute
Show).
Also, the antifog compositions of second embodiment of the invention can make an antifogging coating further,
Wet coating method such as can be utilized to coat the anti-fog surface of a substrate, continuous i.e. can be in via solidification
This anti-fog surface forms this antifogging coating.For example, the material of this substrate is selected from glass, poly-carbonic acid
Ester or polymethyl acrylate, and can anti-according to the material of this substrate or this second embodiment
The composition of mist compositions, selects to coat this base with knife coating, curtain coating, roll coating process or spraying process
The anti-fog surface of plate, separately can select with thermal curing method or ultraviolet light polymerization method to form this antifog painting
Layer, and the thickness of this antifogging coating can be preferably 100nm～10mm, to reach excellent preventing
Mist effect.
The substrate being formed with this antifogging coating can further be made an antifog door and window or appoint
What probably due to fog and affect structure (such as, the eyeglass of the lampshade of car light, glasses of light transmission
Deng), or, user can also be according to demand, using commercially available door and window as this substrate, Yu Qi
Form this antifogging coating on anti-fog surface, this antifog door and window can also be obtained.It should be noted that shape
Become to have the anti-fog surface of substrate of this antifogging coating can be preferably this substrate in order to contact Cryogenic air,
And it is relatively easy to the surface hazed；As a example by the door of chilled food showcase, this antifogging coating is preferable
This inner surface can be formed at；As a example by the window of building, this antifogging coating preferably may be used
To be formed at the outer surface of window with corresponding temperature Change；Additionally, user can also select in
Each surface of this substrate is respectively formed this antifogging coating, is not any limitation as in this.
It is the extinction of 0.001～10% by weight percentage that the antifog compositions of the present invention comprises
Heating particle, this extinction heating particle can effectively absorb luminous energy, and be converted further into heat energy.
Additionally, the resin comprised according to this antifog compositions or the characteristic of sticker, user is the most permissible
This antifog compositions is configured to further this antifog plate (can also on the anti-fog surface of this substrate shape
Become this antifogging coating), the most i.e. can make this antifog plate by the effect of this extinction heating particle
The temperature of (or antifogging coating) rises, and makes aqueous vapor cannot be condensed in this antifog plate (or antifogging coating)
On, and then reach antifog effect.
Further, by this antifog compositions directly being prepared the various antifogging article of shaping, therefore,
Be not necessary to be prone to the antifoggant that comes off being intended on antifog article spraying, so reach to maintain antifog persistently
Effect of property.
Additionally, aforesaid antifog plate or be formed with the substrate of this antifogging coating more can be directly as
The such as Building Decoration Material such as window, eaves is used, or is prevented by existing Building Decoration Material
The processing of mist coating, when sunlight is irradiated in the window being made up of this antifog plate (or through antifogging coating
The window of processing) time, window makes temperature rise, to avoid fog because converting light energy into heat energy
Condense thereon, compared to the fog using electric heater to remove window surface, use preventing of the present invention
Mist plate and be formed with the substrate of this antifogging coating as Building Decoration Material, can reach to save antifog
Required effect expending energy.
In order to confirm that this antifog plate made by the antifog compositions of the present invention has antifog really
Effectiveness, hereby carries out following test:
Temperature and anti misting capability test
This test converts different experiment parameters respectively, test each group with the temperature of matched group and antifog
Ability.Temperature test method is for be positioned over each group in room temperature environment, with distance 15 centimeters
The Halogen light of 500W irradiate 15 seconds (A0, A1 groups) or 30 seconds (B0～F0 and B1～
F1 group), and measure the Temperature numerical after each group of irradiation, anti misting capability with infrared temperature measurer
Test method is on the cup opening being covered in each group irradiated through Halogen light and containing 80 DEG C of hot water
Side, with perusal water smoke adhesion condition, group and the corresponding relation of experimental variation and test knot
Fruit is the most as shown in table 1 below, and Fig. 3 and Fig. 4 presents E0 group and E1 group the most respectively through anti-
Situation after mist test.Wherein, A0～D0 and A1～D1 group are solid slab structure, the
E0 and E1 group is cored slab structure.Wherein F0 is the clear glass of veneer of thickness 3mm, and F1 is
Coating 0.015mm thickness is 10% containing extinction exothermic material concentration by weight percentage
Single panel-shaped glass.
Table 1: group and the corresponding relation of experimental variation and result of the test
After the result tested by this is it will be evident that irradiate Halogen light one set time, it is added with
Antifog plate (A1, B1, C1, D1, E1 of the extinction heating particle of 20～100000ppm
And F1 group), relative to by made by resin tabular matched group (A0, B0, C0, D0,
E0 and F0 group), its temperature significantly improves.Visible relative to matched group, the antifog plate of the present invention
Heat energy can be efficiently converted into by irradiating the luminous energy that Halogen light is obtained, makes the temperature of this antifog plate
Degree is substantially increased, and prevents the aqueous vapor in air from meeting condensation knot thereon whereby.Further, by Fig. 3
And Fig. 4 understands, when being covered in above hot water compared to the matched group (E0 group) after irradiated,
Surface attachment has the obvious vaporific globule, antifog plate (E1 group) table of the irradiated present invention
Face has not observed that the globule produces, and thus can demonstrate,prove the antifog plate of the present invention and really can effectively prevent mist
Water is formed at this antifog plate surface.
In sum, the antifog compositions of the present invention comprises is 0.001～10% by weight percentage
Extinction heating particle, this extinction heating particle can effectively absorb luminous energy, and change further
Become heat energy.Additionally, the resin comprised according to this antifog compositions or the characteristic of sticker, use
This antifog compositions separately can be configured to this antifog plate by person further (can also preventing in this substrate
This antifogging coating is formed on cloudy surface), the most i.e. can make by the effect of this extinction heating particle
The temperature of this antifog plate (or antifogging coating) rises, make aqueous vapor cannot be condensed in this antifog plate (or
Antifogging coating) on, and then reach antifog effect.
Further, by this antifog compositions directly being prepared the various antifogging article of shaping, therefore,
Be not necessary to be prone to the antifoggant that comes off being intended on antifog article spraying, so reach to maintain antifog persistently
Effect of property.
Additionally, aforesaid antifog plate or be formed with the substrate of this antifogging coating more can be directly as example
As the Building Decoration Material such as window, eaves is used, or existing Building Decoration Material is carried out antifog
The processing of coating, (or adds through antifogging coating when sunlight is irradiated in the window being made up of this antifog plate
The window of work) time, window makes temperature rise, to avoid mist condensation because converting light energy into heat energy
Thereon, compared to the fog using electric heater to remove window surface, the employing present invention's is antifog for knot
Plate and be formed with the substrate of this antifogging coating as Building Decoration Material, can reach to save antifog institute
Effect of energy need to be expended.
These are only presently preferred embodiments of the present invention, be not able to this and limit the protection model that the present invention implements
Enclosing, the simple equivalence that the most all description with reference to the present invention are made changes and modifies, and still belongs to
Protection scope of the present invention.
Claims (37)
1. an antifog compositions, it is characterised in that comprise:
Be a resin of 90～99.999% by weight percentage, this resin be polycarbonate,
Polymethyl methacrylate, glass fibre reinforced plastic or polypropylene；And
It is an extinction heating particle of 0.001～10% by weight percentage, this extinction heating grain
Son is tungstenic oxide nano-particles, tin indium oxide, antimony tin or lanthanum hexaboride.
Antifog compositions the most as claimed in claim 1, it is characterised in that wherein, this tungstenic aoxidizes
A thing nanoparticle choosing freely tungsten oxide nanometer particle, and a tungsten bronze complex nanometer
The group that particle is formed.
Antifog compositions the most as claimed in claim 2, it is characterised in that wherein, this tungsten oxide is received
The chemical formula of rice corpuscles is WOx, wherein, 2.2 x 3.
Antifog compositions the most as claimed in claim 2, it is characterised in that wherein, this tungsten bronze is multiple
The chemical formula of compound nanoparticle is AyWOz, wherein, A is major element, 0.01 y
1,2.2 z 3.
Antifog compositions the most as claimed in claim 3, it is characterised in that wherein, this tungsten oxide is received
The chemical formula of rice corpuscles is WO2.72。
Antifog compositions the most as claimed in claim 4, it is characterised in that wherein, A be lithium, sodium,
Potassium, rubidium, caesium, magnesium, calcium, strontium, barium, aluminum, gallium, carbon, silicon, stannum, antimony, fluorine, chlorine,
Bromine or iodine.
Antifog compositions the most as claimed in claim 4, it is characterised in that wherein, this tungsten bronze is multiple
The chemical formula of compound nanoparticle is Cs0.33WO3。
Antifog compositions the most as claimed in claim 1, it is characterised in that wherein, this extinction generates heat
The particle diameter of particle is 1nm～500nm.
9. an antifog plate, it is characterised in that comprise: be 90～99.999% by weight percentage
One resin, this resin is polycarbonate, polymethyl methacrylate, glass fiber-reinforced
Plastic cement or polypropylene；And
It is an extinction heating particle of 0.001～10% by weight percentage, this extinction heating grain
Son is scattered in this resin, and this extinction heating particle is tungstenic oxide nano-particles, oxidation
Indium stannum, antimony tin or lanthanum hexaboride.
Antifog plate the most as claimed in claim 9, it is characterised in that wherein, the thickness of this antifog plate
It is 10 μm～10mm, and this antifog plate comprises by weight percentage 0.005～10%
This extinction heating particle.
The 11. antifog plates as described in claim 9 or 10, it is characterised in that wherein, this tungstenic aoxidizes
A thing nanoparticle choosing freely tungsten oxide nanometer particle, and a tungsten bronze complex nanometer
The group that particle is formed.
12. antifog plates as claimed in claim 11, it is characterised in that wherein, this tungsten oxide nanometer grain
The chemical formula of son is WOx, wherein, 2.2 x 3.
13. antifog plates as claimed in claim 11, it is characterised in that wherein, this tungsten bronze complex
The chemical formula of nanoparticle is AyWOz, wherein, A is major element, 0.01 y 1,
2.2≦z≦3。
14. antifog plates as claimed in claim 12, it is characterised in that wherein, this tungsten oxide nanometer grain
The chemical formula of son is WO2.72。
15. antifog plates as claimed in claim 13, it is characterised in that wherein, A be lithium (Li),
Sodium, potassium, rubidium, caesium, magnesium, calcium, strontium, barium, aluminum, gallium, carbon, silicon, stannum, antimony, fluorine,
Chlorine, bromine or iodine.
16. antifog plates as claimed in claim 13, it is characterised in that wherein, this tungsten bronze complex
The chemical formula of nanoparticle is Cs0.33WO3。
17. antifog plates as claimed in claim 9, it is characterised in that wherein, this extinction heating particle
Particle diameter be 1nm～500nm.
18. 1 kinds of antifog compositionss, it is characterised in that comprise:
Being a sticker of 90～99.999% by weight percentage, this sticker is a list
Body or comprise the oligomer of this monomer, this monomer have the free siloxy of choosing, acrylic,
One functional group of the group that carbamate groups is formed；And
It is an extinction heating particle of 0.001～10% by weight percentage, this extinction heating grain
Son is tungstenic oxide nano-particles, tin indium oxide, antimony tin or lanthanum hexaboride.
19. antifog compositionss as claimed in claim 18, it is characterised in that wherein, this sticker is
One oiliness acryl glue stick, an aqueous acryl glue stick, a Polyurethane are gluing
Agent or an organic liquid silica gel.
20. antifog compositionss as claimed in claim 19, it is characterised in that wherein, this oiliness pressure gram
Power adhesive be a thermoplasticity acryl glue stick, a thermosetting acryl adhesive or
One polyalcohols type acryl glue stick.
21. antifog compositionss as claimed in claim 19, it is characterised in that wherein, this aqueous pressure gram
Power adhesive is an acrylic acid adhesive, a cinnamic acid adhesive or an acetic acid third
Olefin(e) acid adhesive.
22. antifog compositionss as claimed in claim 19, it is characterised in that wherein, this organic liquid
Silica gel is an organic silicon adhesive, methylsiloxane ketone adhesive, an organosilicon
Alkyd adhesive or an acid-organosilicon crylic acid adhesive.
23. antifog compositionss as claimed in claim 18, it is characterised in that wherein, this tungstenic aoxidizes
A thing nanoparticle choosing freely tungsten oxide nanometer particle, and a tungsten bronze complex nanometer
The group that particle is formed.
24. antifog compositionss as claimed in claim 23, it is characterised in that wherein, this tungsten oxide is received
The chemical formula of rice corpuscles is WO2.72。
25. antifog compositionss as claimed in claim 23, it is characterised in that wherein, this tungsten bronze is multiple
The chemical formula of compound nanoparticle is AyWOz, wherein, A be lithium, sodium, potassium, rubidium, caesium,
Magnesium, calcium, strontium, barium, aluminum, gallium, carbon, silicon, stannum, antimony, fluorine, chlorine, bromine or iodine, and
0.01 y 1,2.2 z 3.
26. antifog compositionss as claimed in claim 25, it is characterised in that wherein, this tungsten bronze is multiple
The chemical formula of compound nanoparticle is Cs0.33WO3。
27. antifog compositionss as claimed in claim 18, it is characterised in that wherein, this extinction generates heat
The particle diameter of particle is 1nm～500nm.
28. 1 kinds of antifogging coatings, it is characterised in that comprise:
Being a sticker of 90～99.999% by weight percentage, this sticker is a list
Body or comprise the oligomer of this monomer, this monomer have the free siloxy of choosing, acrylic,
One functional group of the group that carbamate groups is formed；And
It is an extinction heating particle of 0.001～10% by weight percentage, this extinction heating grain
Son is tungstenic oxide nano-particles, tin indium oxide, antimony tin or lanthanum hexaboride；
Wherein, this extinction heating particle is scattered in this sticker, and via heat cure or ultraviolet light
Solidification is to be collectively forming an antifogging coating.
29. antifogging coatings as claimed in claim 28, it is characterised in that wherein, this antifogging coating
Thickness is 100nm～10mm.
30. antifogging coatings as claimed in claim 28, it is characterised in that wherein, this sticker is one
Individual oiliness acryl glue stick, aqueous acryl glue stick, a Polyurethane glue stick
Or an organic liquid silica gel.
31. antifogging coatings as claimed in claim 30, it is characterised in that wherein, this oiliness acryl
Adhesive is a thermoplasticity acryl glue stick, a thermosetting acryl adhesive or
Individual polyalcohols type acryl glue stick.
32. antifogging coatings as claimed in claim 30, it is characterised in that wherein, this aqueous acryl
Adhesive is an acrylic acid adhesive, a cinnamic acid adhesive or an acetate propylene
Acid adhesive.
33. antifogging coatings as claimed in claim 30, it is characterised in that wherein, this organic liquid silicon
Glue is an organic silicon adhesive, methylsiloxane ketone adhesive, an Organosilicon Alcohol in Organic
Acid adhesive or an acid-organosilicon crylic acid adhesive.
34. antifogging coatings as claimed in claim 28, it is characterised in that wherein, this contains tungsten oxide
A nanoparticle choosing freely tungsten oxide nanometer particle, and a tungsten bronze complex nanometer granule
The group that son is formed.
35. antifogging coatings as claimed in claim 34, it is characterised in that wherein, this tungsten oxide nanometer
The chemical formula of particle is WO2.72。
36. antifogging coatings as claimed in claim 34, it is characterised in that wherein, this tungsten bronze is combined
The chemical formula of thing nanoparticle is AyWOz, wherein, A be lithium, sodium, potassium, rubidium, caesium,
Magnesium, calcium, strontium, barium, aluminum, gallium, carbon, silicon, stannum, antimony, fluorine, chlorine, bromine or iodine, and
0.01 y 1,2.2 z 3.
37. antifogging coatings as claimed in claim 34, it is characterised in that wherein, this tungsten bronze is combined
The chemical formula of thing nanoparticle is Cs0.33WO3。
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| TW104137027 | 2015-11-10 | ||
| TW104137027A TWI576391B (en) | 2015-05-27 | 2015-11-10 | An USE OF A MIST-PROOF COMPOSITION FOR MIST-PROOF |
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| CN115466545A (en) * | 2022-09-26 | 2022-12-13 | 张磊 | Coating composition for intelligent lens and preparation method thereof |
| CN115505253A (en) * | 2022-10-18 | 2022-12-23 | 烟台佳隆纳米产业有限公司 | Heat absorption type antifogging lens and preparation process thereof |
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