CN106189756A - A kind of water alcohol acid fluorescent paint - Google Patents
A kind of water alcohol acid fluorescent paint Download PDFInfo
- Publication number
- CN106189756A CN106189756A CN201610762780.2A CN201610762780A CN106189756A CN 106189756 A CN106189756 A CN 106189756A CN 201610762780 A CN201610762780 A CN 201610762780A CN 106189756 A CN106189756 A CN 106189756A
- Authority
- CN
- China
- Prior art keywords
- alcohol acid
- water alcohol
- fluorescent paint
- acid fluorescent
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/22—Luminous paints
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a kind of water alcohol acid fluorescent paint, this coating is prepared by the raw material including following parts by weight: aqueous alkide resin 30～45 parts, fluorescent material 25～40 parts, nertralizer 1～2 parts, dispersant 0～1 part, levelling agent 0～1 part, defoamer 0～1 part, thickening agent 2～5 parts, cosolvent 1～5 parts, solvent 10～30 parts.Water alcohol acid fluorescent paint of the present invention, uses fluorescent material as main luminescent material, coordinates the weatherability that aqueous alkide resin is good, available water alcohol acid fluorescent paint, and this product preparation process is simple, has the cost performance of excellence.
Description
Technical field
The invention belongs to technical field of coatings, especially relate to a kind of water alcohol acid fluorescent paint.
Background technology
Fluorescent paint is mainly used in building coating, outdoor man-made tourist site, billboard etc., is that one has extremely strong color sensation and dress
The coating of decorations property.Common fluorescent paint is all solvent based product, and VOC content is high, easily works the mischief environment, is unfavorable for joint
Can reduce discharging, and some cities of current China have been promulgated and ordered VOC within a certain time, therefore the use of solvent-borne type fluorescent paint the most more comes
The most receives restriction, water paint owing to containing extremely low VOC, the harm to environment and workmen is smaller, also because of
This receives wideling popularize of country.Aqueous alkide resin paint, has good weatherability and excellent cost performance, the suitableeest
Water alcohol acid fluorescent paint is prepared in conjunction.
Summary of the invention
For the deficiency of solvent-borne type fluorescent paint, present invention aim at providing a kind of water alcohol acid fluorescent paint, this product
Product fluorescent lifetime length, weatherability are well not pulverized easily, and the up time is long, have the cost performance of excellence.
The technical scheme is that and be achieved in that:
A kind of water alcohol acid fluorescent paint, is prepared by the raw material including following parts by weight:
Further, described aqueous alkide resin is Protec 3370.
Further, one or both the mixture during described nertralizer is multifunctional assistant AMP-95 or ammonia.
Further, described dispersant is BYK-190 or one or both mixture in AFCONA 4560.
Further, one or both the mixture during described levelling agent is AFCONA 3585 or AFCONA 3030.
Further, described defoamer is one or both the mixture of TEGO 901 or TEGO902.
Further, one or both the mixture during described thickening agent is Borchi 0620 or Borchi 0434.
Further, described solvent is deionized water, and described cosolvent is in isopropanol, ethylene glycol, N-Methyl pyrrolidone
One or more mixture.
Further, the parts by weight of described dispersant, levelling agent and defoamer are not the most 0.
Present invention also offers the preparation method of above-mentioned water alcohol acid fluorescent paint, the method comprises the steps:
(1) aqueous alkide resin is added in mobile basin, be sequentially added into nertralizer and partial solvent, stir at 30～50 DEG C
Mix to pH value be 8～10；
(2) under the stirring of rotating speed 800-1000rpm, cosolvent, dispersant, levelling agent, defoamer it are sequentially added into,
It is sufficiently stirred for 0.5h, is subsequently agitated under state adding fluorescent material and disperses, jitter time 1h, obtain being in harmonious proportion and starch；
(3) water alcohol acid fluorescence is i.e. obtained after adding thickening agent, residual solvent in the mediation slurry that described step (2) prepares
Coating.
Present invention also offers a kind of water alcohol acid fluorescent paint building coating, outdoor man-made tourist site, billboard should
With, this coating fluorescent lifetime is longer, and fluorescent effect is good, and coating weather resistance is exposed to open air well, for a long time and is not pulverized easily.
Beneficial effects of the present invention:
Relative to prior art, water alcohol acid fluorescent paint of the present invention has the advantage that
The water alcohol acid fluorescent paint that the present invention provides, uses fluorescent material as main luminescent material, coordinates aqueous alcoholic
The weatherability that acid resin is good, available water alcohol acid fluorescent paint, this product preparation process is simple, has the property of excellence
Valency ratio.
Detailed description of the invention
The present invention is described in detail below in conjunction with embodiment.
Embodiment 1
A kind of water alcohol acid fluorescent paint, is prepared by the raw material including following parts by weight:
The preparation method of described water alcohol acid fluorescent paint comprises the steps:
(1) 30 parts of aqueous alkide resin Protec 3370 are added in mobile basin, be sequentially added into 1 part of multifunctional assistant
AMP-95 and 15 parts of deionized waters, stir at 30 DEG C to pH value be 8.4；
(2) under the stirring that rotating speed is 800rpm, 5 parts of cosolvent isopropanols, 1 part of dispersant B YK-it are sequentially added into
190,3585,0.5 part of defoamer TEGO 901 of 0.5 part of levelling agent AFCONA, is sufficiently stirred for 0.5h, is subsequently agitated under state adding
Enter 25 parts of fluorescent material to disperse, jitter time 1h, obtain being in harmonious proportion and starch；
(3) in the mediation slurry that described step (2) prepares, 2 parts of thickening agent Borchi 0620,15 parts of deionizations of residue are added
Water alcohol acid fluorescent paint is i.e. obtained after water.
Embodiment 2
A kind of water alcohol acid fluorescent paint, is prepared by the raw material including following parts by weight:
The preparation method of described water alcohol acid fluorescent paint comprises the steps:
(1) 35 parts of aqueous alkide resin Protec 3370 are added in mobile basin, be sequentially added into 1 part of multifunctional assistant
AMP-95 and the mixture of ammonia and 15 parts of deionized waters, stir at 35 DEG C to pH value be 8.7；
(2) be sequentially added under the stirring that rotating speed is 900rpm 5 parts of cosolvent isopropanols and the mixture of ethylene glycol,
The mixture of 4560,0.5 part of levelling agent AFCONA of 1 part of dispersant A FCONA 3030 and AFCONA 3585,0.5 part of defoamer
TEGO 902, is sufficiently stirred for 0.5h, is subsequently agitated under state adding 30 parts of fluorescent material and disperses, and jitter time 1h is adjusted
And slurry；
(3) in the mediation slurry that described step (2) prepares, 2 parts of thickening agent Borchi 0434,10 parts of deionizations of residue are added
Water alcohol acid fluorescent paint is i.e. obtained after water.
Embodiment 3
A kind of water alcohol acid fluorescent paint, is prepared by the raw material including following parts by weight:
The preparation method of described water alcohol acid fluorescent paint comprises the steps:
(1) 40 parts of aqueous alkide resin Protec 3370 are added in mobile basin, be sequentially added into 1 part of multifunctional assistant
AMP-95 and 10 parts of deionized waters, stir at 40 DEG C to pH value be 9.1；
(2) under the stirring that rotating speed is 950rpm, it is sequentially added into 5 parts of cosolvent N-Methyl pyrrolidone, 1 part of dispersion
The mixture of agent BYK-190 and AFCONA 4560,3585,0.5 part of defoamer TEGO 901 and of 0.5 part of levelling agent AFCONA
The mixture of TEGO 902, is sufficiently stirred for 0.5h, is subsequently agitated under state adding 30 parts of fluorescent material and disperses, jitter time
1h, obtains being in harmonious proportion and starches；
(3) in the mediation slurry that described step (2) prepares, add 2 parts of thickening agent Borchi's 0620 and Borchi 0434
Water alcohol acid fluorescent paint is i.e. obtained after mixture, 10 parts of deionized waters of residue.
Embodiment 4
A kind of water alcohol acid fluorescent paint, is prepared by the raw material including following parts by weight:
The preparation method of described water alcohol acid fluorescent paint comprises the steps:
(1) 45 parts of aqueous alkide resin Protec 3370 are added in mobile basin, be sequentially added into 1 part of ammonia and 5 parts go from
Sub-water, stir at 50 DEG C to pH value be 9.3；
(2) under the stirring that rotating speed is 1000rpm, 5 parts of cosolvent isopropanols and the mixing of ethylene glycol it are sequentially added into
Thing, 1 part of dispersant B YK-190,3030,0.5 part of defoamer TEGO 902 of 0.5 part of levelling agent AFCONA, be sufficiently stirred for 0.5h,
It is subsequently agitated under state adding 35 parts of fluorescent material to disperse, jitter time 1h, obtains being in harmonious proportion and starch；
(3) in the mediation slurry that described step (2) prepares, 2 parts of thickening agent Borchi 0620,5 parts of deionizations of residue are added
Water alcohol acid fluorescent paint is i.e. obtained after water.
Embodiment 1-4 prepares water alcohol acid fluorescent paint each raw material weight number such as table 1
Table 1
| Raw material | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Aqueous alkide resin | 30 | 35 | 40 | 45 |
| Nertralizer | 1 | 1 | 1 | 1 |
| Dispersant | 1 | 1 | 1 | 1 |
| Solvent needed for step (1) | 15 | 15 | 10 | 5 |
| Fluorescent material | 25 | 30 | 30 | 35 |
| Cosolvent | 5 | 5 | 5 | 5 |
| Levelling agent | 0.5 | 0.5 | 0.5 | 0.5 |
| Defoamer | 0.5 | 0.5 | 0.5 | 0.5 |
| Thickening agent | 2 | 2 | 2 | 2 |
| Solvent needed for step (3) | 15 | 10 | 10 | 5 |
The performance test of water alcohol acid fluorescent paint prepared by embodiment 1-4 such as table 2
Table 2
Being described in detail the specific embodiment of the present invention above, but it is intended only as example, the present invention does not limit
Be formed on particular embodiments described above, to those skilled in the art, any equivalent modifications that the present invention is carried out and
Substitute the most all among scope of the invention.Therefore, the impartial conversion made without departing from the spirit and scope of the invention and
Amendment, all should contain within the scope of the invention.
Claims (10)
1. a water alcohol acid fluorescent paint, it is characterised in that: this coating is prepared by the raw material including following parts by weight:
A kind of water alcohol acid fluorescent paint the most according to claim 1, it is characterised in that: described nertralizer is multifunctional assistant
One or both mixture in agent AMP-95 or ammonia.
A kind of water alcohol acid fluorescent paint the most according to claim 1, it is characterised in that: described dispersant is BYK-190
Or the mixture of one or both in AFCONA 4560.
A kind of water alcohol acid fluorescent paint the most according to claim 1, it is characterised in that: described levelling agent is AFCONA
One or both mixture in 3585 or AFCONA 3030.
A kind of water alcohol acid fluorescent paint the most according to claim 1, it is characterised in that: described defoamer is TEGO 901
Or the mixture of one or both of TEGO902.
A kind of water alcohol acid fluorescent paint the most according to claim 1, it is characterised in that: described thickening agent is Borchi
One or both mixture in 0620 or Borchi 0434.
A kind of water alcohol acid fluorescent paint the most according to claim 1, it is characterised in that: described solvent is deionized water,
Described cosolvent is one or more the mixture in isopropanol, ethylene glycol, N-Methyl pyrrolidone.
A kind of water alcohol acid fluorescent paint the most according to claim 1, it is characterised in that: described dispersant, levelling agent and
The parts by weight of defoamer are not the most 0.
9. according to a kind of water alcohol acid fluorescent paint described in any one of claim 1-8, it is characterised in that: this water alcohol acid is glimmering
Optical coating is prepared by the method comprised the steps:
(1) aqueous alkide resin is added in mobile basin, be sequentially added into nertralizer and partial solvent, in 30～50 DEG C of stirrings to pH
Value is 8～10；
(2) under the stirring of rotating speed 800-1000rpm, cosolvent, dispersant, levelling agent, defoamer it are sequentially added into, fully
Stirring 0.5h, is subsequently agitated under state adding fluorescent material and disperses, and jitter time 1h obtains being in harmonious proportion and starches；
(3) i.e. obtain water alcohol acid fluorescence after adding thickening agent, residual solvent in the mediation slurry that described step (2) prepares to be coated with
Material.
10. a kind of water alcohol acid fluorescent paint described in any one of claim 1-9 is at building coating, outdoor man-made tourist site, wide
Accuse the application of board.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610762780.2A CN106189756A (en) | 2016-08-29 | 2016-08-29 | A kind of water alcohol acid fluorescent paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610762780.2A CN106189756A (en) | 2016-08-29 | 2016-08-29 | A kind of water alcohol acid fluorescent paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106189756A true CN106189756A (en) | 2016-12-07 |
Family
ID=58088933
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610762780.2A Pending CN106189756A (en) | 2016-08-29 | 2016-08-29 | A kind of water alcohol acid fluorescent paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106189756A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111349379A (en) * | 2018-12-20 | 2020-06-30 | 艾伦塔斯电气绝缘材料(珠海)有限公司 | Tri-proof paint with reactive fluorescence and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1322778A (en) * | 2001-05-30 | 2001-11-21 | 大连明辰振邦氟涂料股份有限公司 | Coating phosphor and its prepn and long-afterglow fluorescent aqueous paint containing the phosphor |
| CN103709298A (en) * | 2013-12-16 | 2014-04-09 | 丽王化工(南通)有限公司 | Non-formaldehyde fluorescent paint emulsion and preparation method thereof |
| CN105001769A (en) * | 2015-07-24 | 2015-10-28 | 龙岩学院 | Preparation method for long-afterglow water-borne alkyd resin coating |
| CN105273544A (en) * | 2015-11-18 | 2016-01-27 | 广州聚注专利研发有限公司 | Water-based fluorescent paint and preparation method thereof |
-
2016
- 2016-08-29 CN CN201610762780.2A patent/CN106189756A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1322778A (en) * | 2001-05-30 | 2001-11-21 | 大连明辰振邦氟涂料股份有限公司 | Coating phosphor and its prepn and long-afterglow fluorescent aqueous paint containing the phosphor |
| CN103709298A (en) * | 2013-12-16 | 2014-04-09 | 丽王化工(南通)有限公司 | Non-formaldehyde fluorescent paint emulsion and preparation method thereof |
| CN105001769A (en) * | 2015-07-24 | 2015-10-28 | 龙岩学院 | Preparation method for long-afterglow water-borne alkyd resin coating |
| CN105273544A (en) * | 2015-11-18 | 2016-01-27 | 广州聚注专利研发有限公司 | Water-based fluorescent paint and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111349379A (en) * | 2018-12-20 | 2020-06-30 | 艾伦塔斯电气绝缘材料(珠海)有限公司 | Tri-proof paint with reactive fluorescence and preparation method thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161207 |