CN106189449A - A kind of peelable derust and rust-proof paint of metal - Google Patents

A kind of peelable derust and rust-proof paint of metal Download PDF

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Publication number
CN106189449A
CN106189449A CN201610585907.8A CN201610585907A CN106189449A CN 106189449 A CN106189449 A CN 106189449A CN 201610585907 A CN201610585907 A CN 201610585907A CN 106189449 A CN106189449 A CN 106189449A
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parts
rust
metal
peelable
paint
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朱小龙
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/20Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for coatings strippable as coherent films, e.g. temporary coatings strippable as coherent films
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of peelable derust and rust-proof paint of metal, raw material is: styrene, dimethylbenzene, Xin Nashui, Vinylidene Chloride, dibutyl phthalate, organobentonite, calcium stearate, Oleum Ricini, Ammonium persulfate. and acetone;For metal rust preventing, surface strength height, viscosity 50 70s, fineness 35 55 μm, pliability 0.4 0.8mm, metal is had good adhesive force, adhesive force 12 grades;Antiseptic property is good, impact 50 90cm, impact strength 500 540N/cm, and resistance to salt water 6 10d is non-foaming, do not fall off, and humidity resistance is good;Hardness 0.4 0.8, coating drying property is good, surface drying 0.5 2.5h, does solid work 6 10h, covering power 95 115g/cm2

Description

A kind of peelable derust and rust-proof paint of metal
Technical field
The present invention relates to metal field of material technology, particularly relate to a kind of peelable derust and rust-proof paint of metal.
Background technology
Antirust paint is a kind of chemistry protecting metal surfaces from air, sea water etc. or the coating of electrochemical corrosion.Main Physical property to be divided into and the big class of chemically antirust paint two.The former is by the suitable cooperation of pigment and paint vehicle, formed fine and close paint film with Stop the intrusion of corrosive substance, such as peelable rust cleaning, peelable rust cleaning, graphite antirust paint etc.;The latter presses down by the chemistry of rust resisting pigment Rust effect, such as styrene, zinc chromate anti-rust paint etc..Antirust for metals such as bridge, boats and ships, pipelines.Styrene antirust paint is one The paint that kind styrene and drying oil mix.Its permeability, wettability are good, and paint film is soft, attachment is strong, but is dried relatively Slowly.Great additionally, due to styrene ratio, easily precipitate, and stored for a long time can be thickening, brushability is the most poor.
The antirust paint substantially oiliness used and aqueous two kinds.Oily antirust varniss makes the greasy difficulty of removing of material surface, It is rarely employed.Oily antirust varniss is easy to use, cheap, but because of containing the noxious substance such as nitrite, chromate, to operation Personnel's harm is relatively big, and country has limited use, and these type of properties of product are single, it is impossible to meets the antirust of magnetic alloy material and wants Ask.Epoxy anti-rust paint is used for polyamide as firming agent, and bisphenol-A letter Na Shui is adhesive, and film is good to substrate adhesion, executes Work is functional, and paint film flexibility is good, water-fast, oil resistant chemicals-resistant is good.Add different rust resisting pigments, difference can be configured to Antirust paint, mostly be priming paint.
It is main component that water-based metal antirust paint selects metal strength chelating agen inositol six letter to receive water ester, with other several water Property additive compound forms.Inositol six letter receive water ester be from cereal crops extract Nantural non-toxic Organic chemical products, when it make When using for magnetic material antirust agent, can chelate rapidly with metal on surface, form one layer of fine and close unimolecule complex protection Film, can effectively suppress corrosion of metal.Material surface after this product treatment keeps primary colors, it is not necessary to washing can enter application Deng next procedure.Conventional epoxy anti-rust paint has the peelable derust and rust-proof paint of epoxy, the peelable derust and rust-proof paint of epoxy, epoxy neighbour's benzene two Formic acid dibutyl ester antirust paint, the peelable derust and rust-proof paint of epoxy and epoxy zinc rich primer etc..
Rust resisting pigment is the important component part of antirust paint. physics rust resisting pigment is that an own chemical property of class is relatively stable Pigment, they are the physical properties by itself, and stable chemical performance, quality is hard, and granule is trickle, excellent fillibility, carries The consistency of high paint film, reduces the permeable of paint film thus plays antirust effect. and aoxidize peelable rust cleaning and just belong to this kind of material. and The rust-preventing characteristic of the peelable rust cleaning of metal is owing to peelable rust cleaning has sclay texture, forms paint film tight, also has stronger reflection The ability of ultraviolet, can improve paint film aging-resistant ability.The peelable rust cleaning of epoxy, the peelable rust cleaning of epoxy and epoxy O-phthalic It is the rust resisting pigment that epoxy anti-rust paint is conventional that dibutyl phthalate antirust paint aoxidizes peelable rust cleaning, if adding peelable rust cleaning, the most permissible Strengthen its rustless property, containing dibutyl phthalate and epoxy phthalic acid two fourth of the peelable derusting rust-proofing pigment of oxidation Ester antirust paint, antirust except for steel surface, also it is especially possible for the antirust of galvanized part.Should be noted that and be, due to neighbour Phthalic acid dibutyl ester is slightly soluble in water, although so the antirust paint rustless property containing dibutyl phthalate pigment is better than Comprise only the antirust paint of peelable rust cleaning, but it is not recommended for a long time for underwater sites, otherwise can produce the problems such as foaming.
The main component of antirust paint is rust resisting pigment and film forming matter.Generally name with the title of rust resisting pigment, such as: benzene Ethylene anticorrosive paint, peelable derusting rust-proofing paint etc..If divided with its rust inhibition, it is broadly divided into four big classes: thing Reason effect anticorrosive paint, chemical action anticorrosive paint, electrochemical action anticorrosive paint, comprehensive function anticorrosive paint.Styrene is prevented Rust paint composition: by compositions such as modified alkyd resin, rust resisting pigment, extender pigment, drier, organic solvents.Characteristic: adhesive force Good, rustless property is high, and resistance to water is strong, and natural drying is fast at normal temperatures.Some anticorrosive paints are based on trickle flakey material Want pigment.Conversion and prevention paint of rust is transformant solvent bottom paint, has the peelable rust cleaning of excellence, rustless property, can directly brush There is the metal surface of rust (thickness≤100 μm), simplify peelable rust cleaning operation, improve work efficiency, reduce cost.This paint exists Rustless metal surface also can use;Can support the use with multiple finish paint;Can construct under the conditions of-20 DEG C.
Peelable derusting rust-proofing coating be the most peelable a kind of rust cleaning, antirust but can be formed as paint macromolecule echo The premium quality product of structure.It changes the loaded down with trivial details operation process of conventional peelable derusting rust-proofing, the most only need simply to brush, Spray or immersion, can synchronously complete " corrosion protection of derusting;Due to unique formula design, there is the strongest penetrating power, can be rapidly Effectively disintegrate greasy dirt common on metal surface, and while corrosion being decomposed, convert it into one layer there is anti-corrosion performance Metal protective film, thus reach excellent peelable rust cleaning and rust-proof effect.
Summary of the invention
The present invention provides a kind of fast drying, the anti-corrosive properties peelable derust and rust-proof paint of good metal, solves existing metal material Material is dried the technical problems such as slow and antiseptic property is poor.
The present invention is by the following technical solutions: a kind of peelable derust and rust-proof paint of metal, mass fraction proportioning pressed by its raw material As follows: styrene 100 parts, dimethylbenzene 55-95 part, letter receives water 40-80 part, Vinylidene Chloride 4-8 part, dibutyl phthalate 25-45 part, organobentonite 1-5 part, calcium stearate 0.4-0.8 part, Oleum Ricini 10-30 part, Ammonium persulfate. 15-35 part, acetone 5-25 part.
As a preferred technical solution of the present invention: mass fraction pressed by the described metal raw material of peelable derust and rust-proof paint Proportioning is as follows: styrene 100 parts, dimethylbenzene 65-85 part, and water 50-70 part received by letter, Vinylidene Chloride 5-7 part, phthalic acid two fourth Ester 30-40 part, organobentonite 2-4 part, calcium stearate 0.5-0.7 part, Oleum Ricini 15-25 part, Ammonium persulfate. 20-30 part, third Ketone 10-20 part.
As a preferred technical solution of the present invention: mass fraction pressed by the described metal raw material of peelable derust and rust-proof paint Proportioning is as follows: styrene 100 parts, dimethylbenzene 65 parts, and 50 parts of water received by letter, Vinylidene Chloride 5 parts, dibutyl phthalate 30 parts, Organobentonite 2 parts, calcium stearate 0.5 part, Oleum Ricini 15 parts, Ammonium persulfate. 20 parts, 10 parts of acetone.
As a preferred technical solution of the present invention: mass fraction pressed by the described metal raw material of peelable derust and rust-proof paint Proportioning is as follows: styrene 100 parts, dimethylbenzene 85 parts, and 70 parts of water received by letter, Vinylidene Chloride 7 parts, dibutyl phthalate 40 parts, Organobentonite 4 parts, calcium stearate 0.7 part, Oleum Ricini 25 parts, Ammonium persulfate. 30 parts, 20 parts of acetone.
A kind of peelable derust and rust-proof paint of metal according to claim 1, it is characterised in that: described metal is with peelable It is as follows that mass fraction proportioning pressed by the raw material of derust and rust-proof paint: styrene 100 parts, dimethylbenzene 75 parts, and 60 parts of water received by letter, Vinylidene Chloride 6 parts, dibutyl phthalate 35 parts, organobentonite 3 parts, calcium stearate 0.6 part, Oleum Ricini 20 parts, Ammonium persulfate. 25 parts, 15 parts of acetone.
Beneficial effect
A kind of metal of the present invention uses above technical scheme compared with prior art with peelable derust and rust-proof paint, has Techniques below effect: 1, for metal rust preventing, surface strength height, viscosity 50-70s, fineness 35-55 μm, pliability 0.4- 0.8mm, has good adhesive force, adhesive force 1-2 level to metal;2, antiseptic property is good, impact 50-90cm, impact strength 500-540N/cm, resistance to salt water 6-10d is non-foaming, do not fall off, and humidity resistance is good;3, hardness 0.4-0.8, coating drying property is good, Surface drying 0.5-2.5h, does solid work 6-10h, covering power 95-115g/cm2, preparation method is simple, and raw material is simple and easy to get, can extensively give birth to Produce the not division of history into periods for current material.
Detailed description of the invention
Below in conjunction with example, the invention will be further described, and embodiment is only used for that the present invention will be described, not Constituting the restriction to right, other alternative means that it may occur to persons skilled in the art that, all in right of the present invention In claimed range.
Embodiment 1:
The first step: weigh styrene 100 parts, dimethylbenzene 55 parts according to mass fraction proportioning, letter receives 40 parts of water, Vinylidene Chloride 4 parts, dibutyl phthalate 25 parts, organobentonite 1 part, calcium stearate 0.4 part, Oleum Ricini 10 parts, Ammonium persulfate. 15 parts, 5 parts of acetone.
Second step: styrene, dimethylbenzene, Xin Nashui, Vinylidene Chloride and organobentonite are put in reactor, is heated to 120 DEG C, stir 40min with 260r/min speed.
3rd step: the liquid after stirring stands 80min, adds dibutyl phthalate, calcium stearate, Semen Ricini Oil, Ammonium persulfate. and acetone, put into grinder after 140 DEG C of mix homogeneously and grind 10h, pack after filtration.
High for metal rust preventing, surface strength, viscosity 50s, fineness 35 μm, pliability 0.4mm, metal is had good attached Put forth effort, adhesive force 2 grades;Antiseptic property is good, impact 50cm, impact strength 500N/cm, and resistance to salt water 6d is non-foaming, do not fall off, Humidity resistance is good;Hardness 0.4, coating drying property is good, and surface drying 2.5h does solid work 10h, covering power 95g/cm2
Embodiment 2:
The first step: weigh styrene 100 parts, dimethylbenzene 55-95 part according to mass fraction proportioning, letter receives water 40-80 part, mistake Vinyl chloride 4-8 part, dibutyl phthalate 25-45 part, organobentonite 1-5 part, calcium stearate 0.4-0.8 part, Oleum Ricini 10-30 part, Ammonium persulfate. 15-35 part, acetone 5-25 part.
Second step: styrene, dimethylbenzene, Xin Nashui, Vinylidene Chloride and organobentonite are put in reactor, is heated to 140 DEG C, stir 60min with 280r/min speed.
3rd step: the liquid after stirring stands 100min, adds dibutyl phthalate, calcium stearate, castor Oleum Sesami, Ammonium persulfate. and acetone, put into grinder after 180 DEG C of mix homogeneously and grind 14h, pack after filtration.
High for metal rust preventing, surface strength, viscosity 55s, fineness 40 μm, pliability 0.5mm, metal is had good attached Put forth effort, adhesive force 2 grades;Antiseptic property is good, impact 60cm, impact strength 510N/cm, and resistance to salt water 7d is non-foaming, do not fall off, Humidity resistance is good;Hardness 0.5, coating drying property is good, and surface drying 2h does solid work 9h, covering power 100g/cm2
Embodiment 3:
The first step: weigh styrene 100 parts, dimethylbenzene 65 parts according to mass fraction proportioning, letter receives 50 parts of water, Vinylidene Chloride 5 parts, dibutyl phthalate 30 parts, organobentonite 2 parts, calcium stearate 0.5 part, Oleum Ricini 15 parts, Ammonium persulfate. 20 parts, 10 parts of acetone.
Second step: styrene, dimethylbenzene, Xin Nashui, Vinylidene Chloride and organobentonite are put in reactor, is heated to 120 DEG C, stir 40min with 260r/min speed.
3rd step: the liquid after stirring stands 80min, adds dibutyl phthalate, calcium stearate, Semen Ricini Oil, Ammonium persulfate. and acetone, put into grinder after 140 DEG C of mix homogeneously and grind 10h, pack after filtration.
High for metal rust preventing, surface strength, viscosity 60s, fineness 45 μm, pliability 0.6mm, metal is had good attached Put forth effort, adhesive force 2 grades;Antiseptic property is good, impact 70cm, impact strength 520N/cm, and resistance to salt water 8d is non-foaming, do not fall off, Humidity resistance is good;Hardness 0.6, coating drying property is good, and surface drying 1.5h does solid work 8h, covering power 105g/cm2
Embodiment 4:
The first step: weigh styrene 100 parts, dimethylbenzene 85 parts according to mass fraction proportioning, letter receives 70 parts of water, Vinylidene Chloride 7 parts, dibutyl phthalate 40 parts, organobentonite 4 parts, calcium stearate 0.7 part, Oleum Ricini 25 parts, Ammonium persulfate. 30 parts, 20 parts of acetone.
Second step: styrene, dimethylbenzene, Xin Nashui, Vinylidene Chloride and organobentonite are put in reactor, is heated to 140 DEG C, stir 60min with 280r/min speed.
3rd step: the liquid after stirring stands 100min, adds dibutyl phthalate, calcium stearate, castor Oleum Sesami, Ammonium persulfate. and acetone, put into grinder after 180 DEG C of mix homogeneously and grind 14h, pack after filtration.
High for metal rust preventing, surface strength, viscosity 65s, fineness 50 μm, pliability 0.7mm, metal is had good attached Put forth effort, adhesion 1 grade;Antiseptic property is good, impact 80cm, impact strength 530N/cm, and resistance to salt water 9d is non-foaming, do not fall off, Humidity resistance is good;Hardness 0.7, coating drying property is good, and surface drying 2h does solid work 7h, covering power 110g/cm2
Embodiment 5:
The first step: weigh styrene 100 parts, dimethylbenzene 75 parts according to mass fraction proportioning, letter receives 60 parts of water, Vinylidene Chloride 6 parts, dibutyl phthalate 35 parts, organobentonite 3 parts, calcium stearate 0.6 part, Oleum Ricini 20 parts, Ammonium persulfate. 25 parts, 15 parts of acetone.
Second step: styrene, dimethylbenzene, Xin Nashui, Vinylidene Chloride and organobentonite are put in reactor, is heated to 130 DEG C, stir 50min with 270r/min speed.
3rd step: the liquid after stirring stands 90min, adds dibutyl phthalate, calcium stearate, Semen Ricini Oil, Ammonium persulfate. and acetone, put into grinder after 160 DEG C of mix homogeneously and grind 12h, pack after filtration.
High for metal rust preventing, surface strength, viscosity 70s, fineness 35 μm, pliability 0.8mm, metal is had good attached Put forth effort, adhesion 1 grade;Antiseptic property is good, impact 90cm, impact strength 540N/cm, and resistance to salt water 10d is non-foaming, do not take off Falling, humidity resistance is good;Hardness 0.8, coating drying property is good, and surface drying 0.5h does solid work 6h, covering power 115g/cm2

Claims (5)

1. the peelable derust and rust-proof paint of metal, it is characterised in that matter pressed by the described metal raw material of peelable derust and rust-proof paint Amount number proportioning is as follows: styrene 100 parts, dimethylbenzene 55-95 part, and water 40-80 part received by letter, Vinylidene Chloride 4-8 part, O-phthalic Dibutyl phthalate 25-45 part, organobentonite 1-5 part, calcium stearate 0.4-0.8 part, Oleum Ricini 10-30 part, Ammonium persulfate. 15-35 Part, acetone 5-25 part.
A kind of peelable derust and rust-proof paint of metal the most according to claim 1, it is characterised in that described metal is with divesting Press mass fraction proportioning as follows: styrene 100 parts for the raw material of rust antirust paint, dimethylbenzene 65-85 part, and water 50-70 part received by letter, mistake chlorine Ethylene 5-7 part, dibutyl phthalate 30-40 part, organobentonite 2-4 part, calcium stearate 0.5-0.7 part, Oleum Ricini 15- 25 parts, Ammonium persulfate. 20-30 part, acetone 10-20 part.
A kind of peelable derust and rust-proof paint of metal the most according to claim 1, it is characterised in that described metal is with divesting To press mass fraction proportioning as follows: styrene 100 parts for the raw material of rust antirust paint, dimethylbenzene 65 parts, and 50 parts of water received by letter, Vinylidene Chloride 5 Part, dibutyl phthalate 30 parts, organobentonite 2 parts, calcium stearate 0.5 part, Oleum Ricini 15 parts, Ammonium persulfate. 20 parts, 10 parts of acetone.
A kind of peelable derust and rust-proof paint of metal the most according to claim 2, it is characterised in that described metal is with divesting To press mass fraction proportioning as follows: styrene 100 parts for the raw material of rust antirust paint, dimethylbenzene 85 parts, and 70 parts of water received by letter, Vinylidene Chloride 7 Part, dibutyl phthalate 40 parts, organobentonite 4 parts, calcium stearate 0.7 part, Oleum Ricini 25 parts, Ammonium persulfate. 30 parts, 20 parts of acetone.
A kind of peelable derust and rust-proof paint of metal the most according to claim 1, it is characterised in that: described metal is with divesting To press mass fraction proportioning as follows: styrene 100 parts for the raw material of rust antirust paint, dimethylbenzene 75 parts, and 60 parts of water received by letter, Vinylidene Chloride 6 Part, dibutyl phthalate 35 parts, organobentonite 3 parts, calcium stearate 0.6 part, Oleum Ricini 20 parts, Ammonium persulfate. 25 parts, 15 parts of acetone.
CN201610585907.8A 2016-07-21 2016-07-21 A kind of peelable derust and rust-proof paint of metal Withdrawn CN106189449A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60181175A (en) * 1984-02-28 1985-09-14 Moritoshi Saito Strippable film-forming composition
CN101591490A (en) * 2008-05-28 2009-12-02 北京科技桥科贸有限公司 Strippable coatings

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60181175A (en) * 1984-02-28 1985-09-14 Moritoshi Saito Strippable film-forming composition
CN101591490A (en) * 2008-05-28 2009-12-02 北京科技桥科贸有限公司 Strippable coatings

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
周学良等: "《精细化工产品手册 涂料》", 31 May 2002, 化学工业出版社 *

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Application publication date: 20161207