CN106189047A - A kind of high surface finish ABS material - Google Patents

A kind of high surface finish ABS material Download PDF

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Publication number
CN106189047A
CN106189047A CN201610598958.4A CN201610598958A CN106189047A CN 106189047 A CN106189047 A CN 106189047A CN 201610598958 A CN201610598958 A CN 201610598958A CN 106189047 A CN106189047 A CN 106189047A
Authority
CN
China
Prior art keywords
parts
high surface
surface finish
abs
toughener
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610598958.4A
Other languages
Chinese (zh)
Inventor
王兆中
都昌满
吴姗姗
熊亚南
郑旭
曹茂华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GETTEL GROUP (TONGCHENG) PLASTIC INDUSTRY Co Ltd
Original Assignee
GETTEL GROUP (TONGCHENG) PLASTIC INDUSTRY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GETTEL GROUP (TONGCHENG) PLASTIC INDUSTRY Co Ltd filed Critical GETTEL GROUP (TONGCHENG) PLASTIC INDUSTRY Co Ltd
Priority to CN201610598958.4A priority Critical patent/CN106189047A/en
Publication of CN106189047A publication Critical patent/CN106189047A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a kind of high surface finish ABS material, be made up of the raw material of following weight parts: ABS resin 85 90 parts, styrene acrylonitrile copolymer 5 10 parts, toughener 36 parts, 0.3 0.8 parts of antioxidant, UV absorbent 0 0.5 parts.The present invention is by adding styrene acrylonitrile copolymer and improving former fineness in ABS resin, and both schemes are carried out simultaneously so that product glossiness is brought up to 95 100 by 85 90;Styrene acrylonitrile copolymer can be the most compatible with ABS, has been simultaneously introduced toughener, it is ensured that the toughness of material, still disclosure satisfy that the requirement of impact resistance and tensile property;There is excellent anti-ultraviolet property simultaneously, extend the service life of material.

Description

A kind of high surface finish ABS material
Technical field
The present invention relates to technical field of polymer materials, specifically a kind of high surface finish ABS material.
Background technology
ABS is acrylonitrile, 1,3-butadiene, the graft copolymer of three kinds of monomers of styrene, have high intensity, good toughness, The feature that glossiness is high.For household electrical appliances, common ABS can meet the demand of product glossiness, but special for some Parts, such as the surface of high-grade household electrical appliances, it is desirable to reach mirror effect, then cannot meet.ABS is improved glossiness difficulty relatively big, mesh Before also there is no suitable method.
Summary of the invention
It is an object of the invention to provide a kind of high surface finish ABS material, to solve above-mentioned background technology proposes Problem.
For achieving the above object, the present invention provides following technical scheme:
A kind of high surface finish ABS material, is made up of the raw material of following weight parts:
ABS resin 85-90 part, SAN 5-10 part, toughener 3-6 part, antioxidant 0.3-0.8 part, UV absorbent 0-0.5 part.
Preferably, described UV absorbent is Ultraviolet Absorber UV-P.
Preferably, described toughener is butadiene type terpolymer.
Preferably, described antioxidant is 2, tri-grades of butyl-4-methylphenols of 6-.
Preferably, described a kind of high surface finish ABS material, it is made up of the raw material of following weight parts:
ABS resin 88 parts, SAN 6 parts, toughener 5.2 parts, 0.5 part of antioxidant, ultra-violet absorption Agent 0.3 part
Compared with prior art, the invention has the beneficial effects as follows:
The present invention is by adding SAN and improving former fineness in ABS resin, and these are two years old The scheme of kind is carried out simultaneously so that product glossiness is brought up to 95-100 by 85-90;SAN is permissible with ABS The most compatible, it is simultaneously introduced toughener, it is ensured that the toughness of material, still disclosure satisfy that impact resistance and tensile property Requirement;There is excellent anti-ultraviolet property simultaneously, extend the service life of material.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further illustrated.
Embodiment 1
One high surface finish ABS material of the present invention, is made up of the raw material of following weight parts:
ABS resin 85 parts, SAN 10 parts, toughener 4.6 parts, 0.3 part of antioxidant, ultraviolet is inhaled Receive agent UV-P 0.1 part.
Described toughener is butadiene type terpolymer.
Described antioxidant is 2, tri-grades of butyl-4-methylphenols of 6-, can delay or suppress the carrying out of polymer oxidizing process, Thus stop the aging of polymer and extend its service life.
UV absorbent can absorb ultraviolet (especially wavelength is 290-400nm) consumingly;Heat stability is good, even if Work in-process also will not change because of heat, and hot volatility is little;Chemical stability is good, unfavorable instead with material component generation in goods Should;Compatibility is good, may be uniformly dispersed in material, and no blooming does not oozes out;The photochemical stability of absorbent itself is good, no Decompose, invariant color;Colourless, nontoxic, odorless;Resistance to embathe;Inexpensive, be easy to get.
A kind of high surface finish ABS material of the present invention, in preparation process, selects the product mold of corresponding requirements, will Cavity-polishing grade brings up to essence and throws grade.
Embodiment 2
One high surface finish ABS material of the present invention, is made up of the raw material of following weight parts:
ABS resin 88 parts, SAN 6 parts, toughener 5.2 parts, 0.5 part of antioxidant, ultra-violet absorption Agent UV-P 0.3 part.
Described toughener is butadiene type terpolymer.
Described antioxidant is 2, tri-grades of butyl-4-methylphenols of 6-, can delay or suppress the carrying out of polymer oxidizing process, Thus stop the aging of polymer and extend its service life.
UV absorbent can absorb ultraviolet (especially wavelength is 290-400nm) consumingly;Heat stability is good, even if Work in-process also will not change because of heat, and hot volatility is little;Chemical stability is good, unfavorable instead with material component generation in goods Should;Compatibility is good, may be uniformly dispersed in material, and no blooming does not oozes out;The photochemical stability of absorbent itself is good, no Decompose, invariant color;Colourless, nontoxic, odorless;Resistance to embathe;Inexpensive, be easy to get.
A kind of high surface finish ABS material of the present invention, in preparation process, selects the product mold of corresponding requirements, will Cavity-polishing grade brings up to essence and throws grade.
Embodiment 3
One high surface finish ABS material of the present invention, is made up of the raw material of following weight parts:
ABS resin 90 parts, SAN 5 parts, toughener 3-5 part, 4.2 parts of antioxidant, ultra-violet absorption Agent UV-P 0.5 part.
Described toughener is butadiene type terpolymer.
Described antioxidant is 2, tri-grades of butyl-4-methylphenols of 6-, can delay or suppress the carrying out of polymer oxidizing process, Thus stop the aging of polymer and extend its service life.
UV absorbent can absorb ultraviolet (especially wavelength is 290-400nm) consumingly;Heat stability is good, even if Work in-process also will not change because of heat, and hot volatility is little;Chemical stability is good, unfavorable instead with material component generation in goods Should;Compatibility is good, may be uniformly dispersed in material, and no blooming does not oozes out;The photochemical stability of absorbent itself is good, no Decompose, invariant color;Colourless, nontoxic, odorless;Resistance to embathe;Inexpensive, be easy to get.
A kind of high surface finish ABS material of the present invention, in preparation process, selects the product mold of corresponding requirements, will Cavity-polishing grade brings up to essence and throws grade.

Claims (5)

1. a high surface finish ABS material, it is characterised in that be made up of the raw material of following weight parts:
ABS resin 85-90 part, SAN 5-10 part, toughener 3-6 part, antioxidant 0.3-0.8 part, ultraviolet Light absorbers 0-0.5 part.
A kind of high surface finish ABS material the most according to claim 1, it is characterised in that described UV absorbent For Ultraviolet Absorber UV-P.
A kind of high surface finish ABS material the most according to claim 1, it is characterised in that described toughener is fourth two Alkenes terpolymer.
A kind of high surface finish ABS material the most according to claim 1, it is characterised in that described antioxidant is 2,6- Three grades of butyl-4-methylphenols.
5. according to a kind of high surface finish ABS material described in any one of claim 1-4, it is characterised in that by following heavy The raw material of amount part is made:
ABS resin 88 parts, SAN 6 parts, toughener 5.2 parts, 0.5 part of antioxidant, UV absorbent 0.3 part.
CN201610598958.4A 2016-07-27 2016-07-27 A kind of high surface finish ABS material Pending CN106189047A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610598958.4A CN106189047A (en) 2016-07-27 2016-07-27 A kind of high surface finish ABS material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610598958.4A CN106189047A (en) 2016-07-27 2016-07-27 A kind of high surface finish ABS material

Publications (1)

Publication Number Publication Date
CN106189047A true CN106189047A (en) 2016-12-07

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610598958.4A Pending CN106189047A (en) 2016-07-27 2016-07-27 A kind of high surface finish ABS material

Country Status (1)

Country Link
CN (1) CN106189047A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109054279A (en) * 2018-06-19 2018-12-21 青岛海尔股份有限公司 A kind of preparation method of ABS plate, inner container of icebox and ABS plate
WO2022194814A1 (en) 2021-03-16 2022-09-22 Ineos Styrolution Group Gmbh Abs molding composition with improved surface quality for plating applications

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101851384A (en) * 2009-04-03 2010-10-06 上海锦湖日丽塑料有限公司 Fireproof anti-ultraviolet anti-static ABS material and preparation method thereof
CN101875753A (en) * 2009-10-29 2010-11-03 深圳市科聚新材料有限公司 ABS (Acrylonitrile Butadiene Styrene) modified material with high heat resistance, high gloss and flame retardance and preparation method thereof
CN101974197A (en) * 2010-10-20 2011-02-16 深圳市科聚新材料有限公司 Metal-imitated high-gloss ABS (Acrylonitrile Butadiene Styrene) alloy and preparation method thereof
CN102863731A (en) * 2012-08-14 2013-01-09 深圳市科聚新材料有限公司 Acrylonitrile-butadiene-styrene (ABS) composite plastic, and preparation method and application thereof
CN103044850A (en) * 2013-01-21 2013-04-17 山东大学 Black highlight acrylonitrile butadiene styrene (ABS) alloy and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101851384A (en) * 2009-04-03 2010-10-06 上海锦湖日丽塑料有限公司 Fireproof anti-ultraviolet anti-static ABS material and preparation method thereof
CN101875753A (en) * 2009-10-29 2010-11-03 深圳市科聚新材料有限公司 ABS (Acrylonitrile Butadiene Styrene) modified material with high heat resistance, high gloss and flame retardance and preparation method thereof
CN101974197A (en) * 2010-10-20 2011-02-16 深圳市科聚新材料有限公司 Metal-imitated high-gloss ABS (Acrylonitrile Butadiene Styrene) alloy and preparation method thereof
CN102863731A (en) * 2012-08-14 2013-01-09 深圳市科聚新材料有限公司 Acrylonitrile-butadiene-styrene (ABS) composite plastic, and preparation method and application thereof
CN103044850A (en) * 2013-01-21 2013-04-17 山东大学 Black highlight acrylonitrile butadiene styrene (ABS) alloy and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109054279A (en) * 2018-06-19 2018-12-21 青岛海尔股份有限公司 A kind of preparation method of ABS plate, inner container of icebox and ABS plate
WO2022194814A1 (en) 2021-03-16 2022-09-22 Ineos Styrolution Group Gmbh Abs molding composition with improved surface quality for plating applications

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Application publication date: 20161207

RJ01 Rejection of invention patent application after publication