CN106189038A - A kind of compositional flame-retardant strengthens plastic cement aluminum pigment - Google Patents
A kind of compositional flame-retardant strengthens plastic cement aluminum pigment Download PDFInfo
- Publication number
- CN106189038A CN106189038A CN201610594916.3A CN201610594916A CN106189038A CN 106189038 A CN106189038 A CN 106189038A CN 201610594916 A CN201610594916 A CN 201610594916A CN 106189038 A CN106189038 A CN 106189038A
- Authority
- CN
- China
- Prior art keywords
- retardant
- tetramethylolmethane
- aluminum pigment
- dehydrated alcohol
- plastic cement
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/10—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F292/00—Macromolecular compounds obtained by polymerising monomers on to inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/62—Metallic pigments or fillers
- C09C1/64—Aluminium
- C09C1/644—Aluminium treated with organic compounds, e.g. polymers
- C09C1/646—Aluminium treated with organic compounds, e.g. polymers concomitant with mechanical comminution, shaping or abrasion of the particles
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/006—Combinations of treatments provided for in groups C09C3/04 - C09C3/12
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/04—Physical treatment, e.g. grinding, treatment with ultrasonic vibrations
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/10—Treatment with macromolecular organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
- C09C3/12—Treatment with organosilicon compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of compositional flame-retardant and strengthen plastic cement aluminum pigment, it is prepared by the raw materials in: flake aluminum 70 75, methacryloxypropyl trimethoxy silane 14 15, dehydrated alcohol is appropriate, trimethylolpropane trimethacrylate 28 30, acrylic acid 11 1.2, azodiisobutyronitrile 0.09 0.1, polyvinylpyrrolidone 1.75 1.9, fatty acid amide 3.5 4, polypropylene 18 20, double (ethyl acetoacetate) metatitanic acid diisopropyl ester 23, APP 56, tetramethylolmethane 2 2.4, tetraethyl orthosilicate 1 1.3, deionized water 56, TX 100.2 0.22, acetone in proper.Product of the present invention is good with the COMPONENTS COMPATIBILITY such as plastics, rubber, and dispersive property is good, fire prevention, environmental protection, and safety coefficient is high, and technique is simply easy to commercial production.
Description
Technical field
The present invention relates to pigment technology field, particularly relate to a kind of compositional flame-retardant and strengthen plastic cement aluminum pigment.
Background technology
Aluminum pigment is also known as aluminum paste, aluminum argentum powder, flake aluminum, and it has smooth and very thin sclay texture, is application
One of most metallic effect pigments.Aluminum pigment possesses good antiseptic property, moreover it is possible to reflection visible ray, has argenteous gold
Belong to gloss, also changing, so aluminum pigment has good decorative effect along with the intensity of the light of the different reflections of angle simultaneously;
Aluminum pigment also can reflect infrared light and ultraviolet light, thus also have heat-insulating property and delay coating and rubber and ageing of plastics
Effect.Along with country and the raising of social concerns degree, low-carbon (LC) is the most no longer a concept with the topic of environmental protection, but converts
For out and out action.Along with material and the development of mould process, exempt to spray the new trend becoming modified plastics development, resin
Directly it is molded into part and can meet the effect that the manufacturers such as dumb light, high light or flaring pearlescent require.Eliminate and spray paint
Technique, just eliminates the injury to environment, and greatly reduces manufacturing cost.Household electrical appliances, automobile, electronic product industry working of plastics
Application complete, along with level of consumption and the raising of price, at household electrical appliances product profit drastically generally by workman is manual
While reduction, wage sharp rises, but the rising of recruitment cost has become enterprise and has been difficult to undertake the burden that must be born by again.
Preparation has pearl effect, the plastic material of metal-like is directly used in the machine-shaping of household electrical appliances plastics appearance member and can reduce environment
Pollute, improve product appearance class, reduce product cost, improve product competitiveness.So preparation is directly used in resin injection
Aluminum pigment is particularly important, and the application in plastic industry of the aluminum pigment is increasingly praised highly.
In patent " a kind of strip aluminum pigment and preparation method thereof " by conventional aluminium pigment is carried out filter pressing then with
High molecular polymer and auxiliary agent are extruded, and obtain the aluminum pigment of strip, and obtained aluminum pigment the most easily disperses, without powder
Dirt, versatility is good, can greatly reduce current mark during plastic shaping, solves aluminum pigment bad scattered difficult problem in resin, but
Resin and aluminum pigment and auxiliary agent are that during owing to extruding or being molded, temperature is all through high temperature melting twin screw again or Single screw extrusion
Higher, the easy variable color of aluminum pigment or oxidation under high temperature, so that surface of the work metallochrome is dimmed, this is accomplished by being improved by modification
The heat stability of aluminium powder, reduces the corrosivity of aluminum pigment.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of compositional flame-retardant strengthens plastic cement aluminum face
Material.
The present invention is achieved by the following technical solutions:
A kind of compositional flame-retardant strengthens plastic cement aluminum pigment, is prepared by the raw materials in: flake aluminum 70-75, methyl-prop
Alkene acryloxypropylethoxysilane trimethoxy silane 14-15, dehydrated alcohol are appropriate, trimethylolpropane trimethacrylate 28-30, acrylic acid
1-1-1.2, azodiisobutyronitrile 0.09-0.1, polyvinylpyrrolidone 1.75-1.9, fatty acid amide 3.5-4, polypropylene 18-
20, double (ethyl acetoacetate) metatitanic acid diisopropyl ester 2-3, APP 5-6, tetramethylolmethane 2-2.4, tetraethyl orthosilicate 1-
1.3, deionized water 5-6, TX-100.2-0.22, acetone in proper.
Described a kind of compositional flame-retardant strengthens plastic cement aluminum pigment, is made up of step in detail below:
2, a kind of compositional flame-retardant strengthens plastic cement aluminum pigment according to claim 1, it is characterised in that by step in detail below
Make:
(1) by the dehydrated alcohol of molten for methacryloxypropyl trimethoxy silane 4-5 times amount, it is subsequently adding flaky aluminum
Powder, is heated to 55-60 DEG C, and after reacting 1-1.5 hour with absolute ethanol washing for several times, vacuum drying obtains coupling modifier aluminium powder;
(2) by coupling modifier aluminium powder adds the dehydrated alcohol of 2-3 times amount, put in reactor, add three hydroxyl first while stirring
Base propane triacrylate, acrylic acid and be dissolved in the polyvinylpyrrolidone of equivalent dehydrated alcohol, be heated under nitrogen protection
70-80 DEG C, then constant temperature dropping azodiisobutyronitrile, then rise to 85 DEG C and react 30-40 minute, question response is further continued for after terminating
Stir 50-60 minute, natural cooling, centrifugation, obtain filter cake, finally filter cake is put into rotary evaporator evaporates anhydrous
Ethanol, obtains being grafted aluminium powder;
(3) acetone of tetramethylolmethane with 2-3 times amount is mixed, add TX-10, tetraethyl orthosilicate, be sufficiently stirred for rear Under Ultrasonic Vibration
Swing 30-40 minute, be subsequently adding deionized water, be heated to being cooled to room temperature, mistake after 40-50 DEG C of water bath with thermostatic control is reacted 2-3 hour
Filter, with washing with acetone filter cake 2-3 time, finally vacuum drying at 60-70 DEG C, obtains Surface coating tetramethylolmethane stand-by;Will be poly-
Propylene is sent in banbury, adds Surface coating tetramethylolmethane, APP, is heated to 140-150 DEG C, with 100-120 rev/min
Speed banburying 5-6 minute, discharging, broken, obtain fire-retardant reinforcing aids;
(4) the fire-retardant reinforcing aids that grafting aluminium powder step (2) obtained obtains with step (3) mixes, and continuously adds its surplus
Remaining composition, puts into extruded shape growth 3-5mm, the cylinder of a diameter of 1-2mm in double screw extruder, controls extrusion temperature and is
90-120 DEG C, finally it is vacuum dried 5-6 hour at 50-60 DEG C and get final product.
The invention have the advantage that the present invention first passes through methacryloxypropyl trimethoxy silane to flake aluminum
Carry out coupling so that flake aluminum surface conversion is lipophile, be allowed to preferably mix with oiliness monomer, in order at particle surface
Carry out home position polymerization reaction, be then polymerized by in-situ solution and trimethylolpropane trimethacrylate is coated on flake aluminum table
Face, clad is uniform and thin, serves the effect increasing interparticle repulsive forces, is equivalent to the effect of dispersant, improves aluminium powder
Dispersive property, simultaneously can intercept aluminium powder and directly contact with air, moisture, further increase the decay resistance of aluminium powder with
And the activity of holding aluminium powder, the aluminium powder heat stability after cladding is greatly improved simultaneously.
The present invention carries out banburying, as auxiliary agent by compounding to the tetramethylolmethane of surface coating modification and APP with polypropylene
Adding in the preparation of aluminum pigment, synergism enables to flame-retardant composition and distributes uniformly in aluminum pigment, the energy when burning
The layer of charcoal that enough formation is more stable, flame retardant effect is notable, and product of the present invention is good with the COMPONENTS COMPATIBILITY such as plastics, rubber, dispersibility
Can be good, fire prevention, environmental protection, safety coefficient is high, and technique is simply easy to commercial production.
Detailed description of the invention
A kind of compositional flame-retardant strengthens plastic cement aluminum pigment, is made up of the raw material of following weight portion (kilogram): flake aluminum 70,
Methacryloxypropyl trimethoxy silane 14, dehydrated alcohol are appropriate, trimethylolpropane trimethacrylate 28, acrylic acid
1, azodiisobutyronitrile 0.09, polyvinylpyrrolidone 1.75, fatty acid amide 3.5, polypropylene 18, double (ethyl acetoacetates)
Metatitanic acid diisopropyl ester 2, APP 5, tetramethylolmethane 2, tetraethyl orthosilicate 1, deionized water 5, TX, acetone in proper.
Described a kind of compositional flame-retardant strengthens plastic cement aluminum pigment, is made up of step in detail below:
(1) by the dehydrated alcohol of molten for methacryloxypropyl trimethoxy silane 4 times amount, it is subsequently adding flake aluminum,
Being heated to 55 DEG C, after reacting 1 hour with absolute ethanol washing for several times, vacuum drying obtains coupling modifier aluminium powder;
(2) by coupling modifier aluminium powder adds the dehydrated alcohol of 2 times amount, put in reactor, add trihydroxy methyl while stirring
Propane triacrylate, acrylic acid and be dissolved in the polyvinylpyrrolidone of equivalent dehydrated alcohol, be heated to 70 under nitrogen protection
DEG C, then constant temperature dropping azodiisobutyronitrile, then rise to 85 DEG C and react 30 minutes, question response is further continued for after terminating stirring 50 points
Clock, natural cooling, centrifugation, obtain filter cake, finally filter cake is put into and rotary evaporator evaporates dehydrated alcohol, connect
Branch aluminium powder;
(3) acetone of tetramethylolmethane and 2 times amount is mixed, add TX, tetraethyl orthosilicate, be sufficiently stirred for rear sonic oscillation 30 points
Clock, is subsequently adding deionized water, is heated to being cooled to room temperature after 40 DEG C of waters bath with thermostatic control are reacted 2 hours, filters, filter with washing with acetone
Cake 2 times, is finally vacuum dried at 60 DEG C, obtains Surface coating tetramethylolmethane stand-by;Polypropylene is sent in banbury, add
Surface coating tetramethylolmethane, APP, be heated to 140 DEG C, with the speed banburying 5 minutes of 100 revs/min, and discharging, broken,
To fire-retardant reinforcing aids;
(4) the fire-retardant reinforcing aids that grafting aluminium powder step (2) obtained obtains with step (3) mixes, and continuously adds its surplus
Remaining composition, puts into extruded shape growth 3mm, the cylinder of a diameter of 1mm in double screw extruder, and controlling extrusion temperature is 120 DEG C,
Finally it is vacuum dried 5 hours at 50 DEG C and get final product.
Through overtesting, product surface of the present invention is smooth, free from admixture, achromic point mottle, and heatproof is more than 250 DEG C, at plastics or
Dispersibility in rubber product is good, exempts from spraying moulding surfacing, without current mark, the easy demoulding with what it was made.
Claims (2)
1. a compositional flame-retardant strengthens plastic cement aluminum pigment, it is characterised in that be prepared by the raw materials in: flake aluminum
70-75, methacryloxypropyl trimethoxy silane 14-15, dehydrated alcohol are appropriate, trimethylolpropane trimethacrylate
28-30, acrylic acid 1-1-1.2, azodiisobutyronitrile 0.09-0.1, polyvinylpyrrolidone 1.75-1.9, fatty acid amide
3.5-4, polypropylene 18-20, double (ethyl acetoacetate) metatitanic acid diisopropyl ester 2-3, APP 5-6, tetramethylolmethane 2-2.4,
Tetraethyl orthosilicate 1-1.3, deionized water 5-6, TX-100.2-0.22, acetone in proper.
The most according to claim 1, a kind of compositional flame-retardant strengthens plastic cement aluminum pigment, it is characterised in that by step in detail below
Make:
(1) by the dehydrated alcohol of molten for methacryloxypropyl trimethoxy silane 4-5 times amount, it is subsequently adding flaky aluminum
Powder, is heated to 55-60 DEG C, and after reacting 1-1.5 hour with absolute ethanol washing for several times, vacuum drying obtains coupling modifier aluminium powder;
(2) by coupling modifier aluminium powder adds the dehydrated alcohol of 2-3 times amount, put in reactor, add three hydroxyl first while stirring
Base propane triacrylate, acrylic acid and be dissolved in the polyvinylpyrrolidone of equivalent dehydrated alcohol, be heated under nitrogen protection
70-80 DEG C, then constant temperature dropping azodiisobutyronitrile, then rise to 85 DEG C and react 30-40 minute, question response is further continued for after terminating
Stir 50-60 minute, natural cooling, centrifugation, obtain filter cake, finally filter cake is put into rotary evaporator evaporates anhydrous
Ethanol, obtains being grafted aluminium powder;
(3) acetone of tetramethylolmethane with 2-3 times amount is mixed, add TX-10, tetraethyl orthosilicate, be sufficiently stirred for rear Under Ultrasonic Vibration
Swing 30-40 minute, be subsequently adding deionized water, be heated to being cooled to room temperature, mistake after 40-50 DEG C of water bath with thermostatic control is reacted 2-3 hour
Filter, with washing with acetone filter cake 2-3 time, finally vacuum drying at 60-70 DEG C, obtains Surface coating tetramethylolmethane stand-by;Will be poly-
Propylene is sent in banbury, adds Surface coating tetramethylolmethane, APP, is heated to 140-150 DEG C, with 100-120 rev/min
Speed banburying 5-6 minute, discharging, broken, obtain fire-retardant reinforcing aids;
(4) the fire-retardant reinforcing aids that grafting aluminium powder step (2) obtained obtains with step (3) mixes, and continuously adds its surplus
Remaining composition, puts into extruded shape growth 3-5mm, the cylinder of a diameter of 1-2mm in double screw extruder, controls extrusion temperature and is
90-120 DEG C, finally it is vacuum dried 5-6 hour at 50-60 DEG C and get final product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610594916.3A CN106189038A (en) | 2016-07-27 | 2016-07-27 | A kind of compositional flame-retardant strengthens plastic cement aluminum pigment |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610594916.3A CN106189038A (en) | 2016-07-27 | 2016-07-27 | A kind of compositional flame-retardant strengthens plastic cement aluminum pigment |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106189038A true CN106189038A (en) | 2016-12-07 |
Family
ID=57496087
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610594916.3A Pending CN106189038A (en) | 2016-07-27 | 2016-07-27 | A kind of compositional flame-retardant strengthens plastic cement aluminum pigment |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106189038A (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102604445A (en) * | 2012-02-15 | 2012-07-25 | 合肥旭阳铝颜料有限公司 | Preparation method of aluminum pigment with high voltage breakdown resistance |
-
2016
- 2016-07-27 CN CN201610594916.3A patent/CN106189038A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102604445A (en) * | 2012-02-15 | 2012-07-25 | 合肥旭阳铝颜料有限公司 | Preparation method of aluminum pigment with high voltage breakdown resistance |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN107987503B (en) | Spraying-free high-impact PC alloy material with metallic luster and preparation method thereof | |
CN104530565B (en) | Antibacterial spraying-free polypropylene composite material as well as preparation method and application thereof | |
CN110254014B (en) | Efficient antibacterial ABS plastic and preparation method thereof | |
CN105482351B (en) | ABS material with parian decorative effect and preparation method thereof | |
CN105968673A (en) | Marble-like-effect resin master batch, and preparation method and application thereof | |
CN108559175B (en) | Spraying-free polypropylene material with black and white marble textures and preparation method thereof | |
CN108314871A (en) | A kind of metallochrome coloring resin master batch and preparation method thereof | |
CN102746583B (en) | A kind of modified polypropylene material and preparation method thereof and application | |
CN108659346A (en) | A kind of no current mark eutectic lapping defect exempts from painted plastic and preparation method thereof | |
CN104804354B (en) | One kind is exempted to spray weather-proof metal-like ASA composite material and preparation method thereof | |
CN110157095A (en) | Exempt to spray fade effect modified polypropylene material and preparation method thereof | |
CN109423021A (en) | A kind of PC/ABS material and preparation method thereof for exempting to spray high glaze | |
CN110183781A (en) | One kind being suitable for fitting structure part fire-retardant PP material and preparation method thereof | |
CN103131078A (en) | Kitchen flame-retardant and scrapping-resistant polypropylene materials and preparation method of the same | |
CN106065118A (en) | A kind of modifying titanium dioxide improves the strip aluminium pigment of covering power | |
CN108623920A (en) | A kind of bumper polypropylene alloy and preparation method thereof for exempting from spraying pearl effect | |
CN113683876A (en) | Spraying-free high-flow high-impact flame-retardant PC material with metal texture and preparation method and application thereof | |
CN109503922A (en) | A kind of preparation method of pigment functional agglomerate and products thereof and application | |
CN106433067B (en) | A kind of formula and preparation method thereof of environment-friendly type PC/ABS alloy materials | |
CN106188625A (en) | A kind of plastic cement special strip colored aluminum pigment | |
CN105968683A (en) | Strip-shaped aluminum pigment with smooth surface and few flow marks | |
CN106188854A (en) | A kind of zeolite with carrying silver strengthens antibacterial enhancing plastic cement aluminum pigment | |
CN106189038A (en) | A kind of compositional flame-retardant strengthens plastic cement aluminum pigment | |
CN106117803A (en) | A kind of strip aluminum pigment splendid in injection product surface attachment | |
CN106188855A (en) | A kind of corrosion-resistant heat-staple strip aluminum pigment for plastics |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161207 |
|
RJ01 | Rejection of invention patent application after publication |