CN106117803A - A kind of strip aluminum pigment splendid in injection product surface attachment - Google Patents
A kind of strip aluminum pigment splendid in injection product surface attachment Download PDFInfo
- Publication number
- CN106117803A CN106117803A CN201610594817.5A CN201610594817A CN106117803A CN 106117803 A CN106117803 A CN 106117803A CN 201610594817 A CN201610594817 A CN 201610594817A CN 106117803 A CN106117803 A CN 106117803A
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- China
- Prior art keywords
- product surface
- dehydrated alcohol
- aluminum pigment
- aluminium powder
- splendid
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The invention discloses a kind of strip aluminum pigment splendid in injection product surface attachment, be prepared by the raw materials in: flake aluminum 70 75, methacryloxypropyl trimethoxy silane 14 15, dehydrated alcohol are appropriate, trimethylolpropane trimethacrylate 28 30, acrylic acid 11 1.2, azodiisobutyronitrile 0.09 0.1, polyvinylpyrrolidone 1.75 1.9, silicic acid fat 3.5 4.5, polypropylene 17 20, rare-earth stabilizer 0.9 1.1, alginic acid triethanolamine salt 1.5 2, nanometer silicon carbide 34, tetraethyl orthosilicate 23, Tissuemat E 0.8 1.The product surface that the present invention makes is smooth, without current mark, the current mark defect produced during decreasing forming plastic pieces, improve the performance of plastic parts, and whole technical process be easy to Industry Control, safety is the most solvent-free.
Description
Technical field
The present invention relates to pigment technology field, particularly relate to a kind of strip aluminum face splendid in injection product surface attachment
Material.
Background technology
Aluminum pigment is also known as aluminum paste, aluminum argentum powder, flake aluminum, and it has smooth and very thin sclay texture, is application
One of most metallic effect pigments.Aluminum pigment possesses good antiseptic property, moreover it is possible to reflection visible ray, has argenteous gold
Belong to gloss, also changing, so aluminum pigment has good decorative effect along with the intensity of the light of the different reflections of angle simultaneously；
Aluminum pigment also can reflect infrared light and ultraviolet light, thus also have heat-insulating property and delay coating and rubber and ageing of plastics
Effect.Along with country and the raising of social concerns degree, low-carbon (LC) is the most no longer a concept with the topic of environmental protection, but converts
For out and out action.Along with material and the development of mould process, exempt to spray the new trend becoming modified plastics development, resin
Directly it is molded into part and can meet the effect that the manufacturers such as dumb light, high light or flaring pearlescent require.Eliminate and spray paint
Technique, just eliminates the injury to environment, and greatly reduces manufacturing cost.Household electrical appliances, automobile, electronic product industry working of plastics
Application complete, along with level of consumption and the raising of price, at household electrical appliances product profit drastically generally by workman is manual
While reduction, wage sharp rises, but the rising of recruitment cost has become enterprise and has been difficult to undertake the burden that must be born by again.
Preparation has pearl effect, the plastic material of metal-like is directly used in the machine-shaping of household electrical appliances plastics appearance member and can reduce environment
Pollute, improve product appearance class, reduce product cost, improve product competitiveness.So preparation is directly used in resin injection
Aluminum pigment is particularly important, and the application in plastic industry of the aluminum pigment is increasingly praised highly.
In patent " a kind of strip aluminum pigment and preparation method thereof " by conventional aluminium pigment is carried out filter pressing then with
High molecular polymer and auxiliary agent are extruded, and obtain the aluminum pigment of strip, and obtained aluminum pigment the most easily disperses, without powder
Dirt, versatility is good, can greatly reduce current mark during plastic shaping, solves aluminum pigment bad scattered difficult problem in resin, but
Resin and aluminum pigment and auxiliary agent are that during owing to extruding or being molded, temperature is all through high temperature melting twin screw again or Single screw extrusion
Higher, the easy variable color of aluminum pigment or oxidation under high temperature, so that surface of the work metallochrome is dimmed, this is accomplished by being improved by modification
The heat stability of aluminium powder, reduces the corrosivity of aluminum pigment.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of splendid in injection product surface attachment
Strip aluminum pigment.
The present invention is achieved by the following technical solutions:
A kind of strip aluminum pigment splendid in injection product surface attachment, is prepared by the raw materials in: flake aluminum 70-
75, methacryloxypropyl trimethoxy silane 14-15, dehydrated alcohol be appropriate, trimethylolpropane trimethacrylate 28-
30, acrylic acid 1-1-1.2, azodiisobutyronitrile 0.09-0.1, polyvinylpyrrolidone 1.75-1.9, silicic acid fat 3.5-4.5, poly-
Propylene 17-20, rare-earth stabilizer 0.9-1.1, alginic acid triethanolamine salt 1.5-2, nanometer silicon carbide 3-4, tetraethyl orthosilicate 2-
3, Tissuemat E 0.8-1.
Described a kind of strip aluminum pigment splendid in injection product surface attachment, is made up of step in detail below:
(1) by the dehydrated alcohol of molten for methacryloxypropyl trimethoxy silane 4-5 times amount, it is subsequently adding flaky aluminum
Powder, is heated to 55-60 DEG C, and after reacting 1-1.5 hour with absolute ethanol washing for several times, vacuum drying obtains coupling modifier aluminium powder；
(2) by coupling modifier aluminium powder adds the dehydrated alcohol of 2-3 times amount, put in reactor, add three hydroxyl first while stirring
Base propane triacrylate, acrylic acid and be dissolved in the polyvinylpyrrolidone of equivalent dehydrated alcohol, be heated under nitrogen protection
70-80 DEG C, then constant temperature dropping azodiisobutyronitrile, then rise to 85 DEG C and react 30-40 minute, question response is further continued for after terminating
Stir 50-60 minute, natural cooling, centrifugation, obtain filter cake, finally filter cake is put into rotary evaporator evaporates anhydrous
Ethanol, obtains being grafted aluminium powder；
(3) polypropylene is mixed with nanometer silicon carbide, Tissuemat E, send into the speed with 1000-1200 rev/min in high speed mixer
Degree mixing 1-2 minute, then discharging is in banbury, is heated to 140-150 DEG C, adds rare-earth stabilizer, alginic acid three ethanol
Amine salt, with speed banburying 8-10 minute of 100-120 rev/min, discharging, broken, obtain modified additive；
(4) modified additive that grafting aluminium powder step (2) obtained obtains with step (3) mixes, and continuously adds remaining and remains into
Point, put into extruded shape growth 3-5mm, the cylinder of a diameter of 1-2mm in double screw extruder, control extrusion temperature is 90-120
DEG C, finally it is vacuum dried 5-6 hour at 50-60 DEG C and get final product.
The invention have the advantage that the present invention first passes through methacryloxypropyl trimethoxy silane to flake aluminum
Carry out coupling so that flake aluminum surface conversion is lipophile, be allowed to preferably mix with oiliness monomer, in order at particle surface
Carry out home position polymerization reaction, be then polymerized by in-situ solution and trimethylolpropane trimethacrylate is coated on flake aluminum table
Face, clad is uniform and thin, serves the effect increasing interparticle repulsive forces, is equivalent to the effect of dispersant, improves aluminium powder
Dispersive property, simultaneously can intercept aluminium powder and directly contact with air, moisture, further increase the decay resistance of aluminium powder with
And the activity of holding aluminium powder, the aluminium powder heat stability after cladding is greatly improved simultaneously.
Detailed description of the invention
A kind of strip aluminum pigment splendid in injection product surface attachment, is made up of the raw material of following weight portion (kilogram):
Flake aluminum 70, methacryloxypropyl trimethoxy silane 14, dehydrated alcohol are appropriate, trimethylolpropane tris acrylic acid
Ester 28, acrylic acid 1, azodiisobutyronitrile 0.09, polyvinylpyrrolidone 1.75, silicic acid fat 3.5, polypropylene 17, rare earth-stabilized
Agent 0.9, alginic acid triethanolamine salt 1.5, nanometer silicon carbide 3, tetraethyl orthosilicate 2, Tissuemat E 0.8.
Described a kind of strip aluminum pigment splendid in injection product surface attachment, is made up of step in detail below:
(1) by the dehydrated alcohol of molten for methacryloxypropyl trimethoxy silane 4 times amount, it is subsequently adding flake aluminum,
Being heated to 55 DEG C, after reacting 1 hour with absolute ethanol washing for several times, vacuum drying obtains coupling modifier aluminium powder；
(2) by coupling modifier aluminium powder adds the dehydrated alcohol of 2 times amount, put in reactor, add trihydroxy methyl while stirring
Propane triacrylate, acrylic acid and be dissolved in the polyvinylpyrrolidone of equivalent dehydrated alcohol, be heated to 70 under nitrogen protection
DEG C, then constant temperature dropping azodiisobutyronitrile, then rise to 85 DEG C and react 30 minutes, question response is further continued for after terminating stirring 50 points
Clock, natural cooling, centrifugation, obtain filter cake, finally filter cake is put into and rotary evaporator evaporates dehydrated alcohol, connect
Branch aluminium powder；
(3) being mixed with nanometer silicon carbide, Tissuemat E by polypropylene, in feeding high speed mixer, the speed with 1000 revs/min is mixed
Closing 1 minute, then discharging is in banbury, is heated to 140 DEG C, adds rare-earth stabilizer, alginic acid triethanolamine salt, with 100
Rev/min speed banburying 8 minutes, discharging, broken, obtain modified additive；
(4) modified additive that grafting aluminium powder step (2) obtained obtains with step (3) mixes, and continuously adds remaining and remains into
Point, put into extruded shape growth 3mm, the cylinder of a diameter of 1mm in double screw extruder, controlling extrusion temperature is 120 DEG C, finally
It is vacuum dried 5 hours at 50 DEG C and get final product.
Through overtesting, product surface of the present invention is smooth, free from admixture, achromic point mottle, and heatproof is more than 250 DEG C, at plastics or
Dispersibility in rubber product is good, exempts from spraying moulding surfacing, without current mark, the easy demoulding with what it was made.
Claims (2)
1. one kind at the injection product surface splendid strip aluminum pigment of attachment, it is characterised in that by the raw material system of following weight portion
Become: flake aluminum 70-75, methacryloxypropyl trimethoxy silane 14-15, dehydrated alcohol are appropriate, trihydroxy methyl third
Alkane triacrylate 28-30, acrylic acid 1-1-1.2, azodiisobutyronitrile 0.09-0.1, polyvinylpyrrolidone 1.75-1.9,
Silicic acid fat 3.5-4.5, polypropylene 17-20, rare-earth stabilizer 0.9-1.1, alginic acid triethanolamine salt 1.5-2, nanometer silicon carbide
3-4, tetraethyl orthosilicate 2-3, Tissuemat E 0.8-1.
A kind of at the injection product surface splendid strip aluminum pigment of attachment, it is characterised in that by with
Lower concrete steps are made:
(1) by the dehydrated alcohol of molten for methacryloxypropyl trimethoxy silane 4-5 times amount, it is subsequently adding flaky aluminum
Powder, is heated to 55-60 DEG C, and after reacting 1-1.5 hour with absolute ethanol washing for several times, vacuum drying obtains coupling modifier aluminium powder；
(2) by coupling modifier aluminium powder adds the dehydrated alcohol of 2-3 times amount, put in reactor, add three hydroxyl first while stirring
Base propane triacrylate, acrylic acid and be dissolved in the polyvinylpyrrolidone of equivalent dehydrated alcohol, be heated under nitrogen protection
70-80 DEG C, then constant temperature dropping azodiisobutyronitrile, then rise to 85 DEG C and react 30-40 minute, question response is further continued for after terminating
Stir 50-60 minute, natural cooling, centrifugation, obtain filter cake, finally filter cake is put into rotary evaporator evaporates anhydrous
Ethanol, obtains being grafted aluminium powder；
(3) polypropylene is mixed with nanometer silicon carbide, Tissuemat E, send into the speed with 1000-1200 rev/min in high speed mixer
Degree mixing 1-2 minute, then discharging is in banbury, is heated to 140-150 DEG C, adds rare-earth stabilizer, alginic acid three ethanol
Amine salt, with speed banburying 8-10 minute of 100-120 rev/min, discharging, broken, obtain modified additive；
(4) modified additive that grafting aluminium powder step (2) obtained obtains with step (3) mixes, and continuously adds remaining and remains into
Point, put into extruded shape growth 3-5mm, the cylinder of a diameter of 1-2mm in double screw extruder, control extrusion temperature is 90-120
DEG C, finally it is vacuum dried 5-6 hour at 50-60 DEG C and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610594817.5A CN106117803A (en) | 2016-07-27 | 2016-07-27 | A kind of strip aluminum pigment splendid in injection product surface attachment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610594817.5A CN106117803A (en) | 2016-07-27 | 2016-07-27 | A kind of strip aluminum pigment splendid in injection product surface attachment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106117803A true CN106117803A (en) | 2016-11-16 |
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| CN201610594817.5A Pending CN106117803A (en) | 2016-07-27 | 2016-07-27 | A kind of strip aluminum pigment splendid in injection product surface attachment |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11884793B2 (en) | 2019-10-30 | 2024-01-30 | The Procter & Gamble Company | Molded article with metallic appearance |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102604445A (en) * | 2012-02-15 | 2012-07-25 | 合肥旭阳铝颜料有限公司 | Preparation method of aluminum pigment with high voltage breakdown resistance |
-
2016
- 2016-07-27 CN CN201610594817.5A patent/CN106117803A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102604445A (en) * | 2012-02-15 | 2012-07-25 | 合肥旭阳铝颜料有限公司 | Preparation method of aluminum pigment with high voltage breakdown resistance |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11884793B2 (en) | 2019-10-30 | 2024-01-30 | The Procter & Gamble Company | Molded article with metallic appearance |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161116 |
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| RJ01 | Rejection of invention patent application after publication |