CN106189022A - A kind of high heat conduction tenacity acrylic's ester rubber - Google Patents
A kind of high heat conduction tenacity acrylic's ester rubber Download PDFInfo
- Publication number
- CN106189022A CN106189022A CN201610580449.9A CN201610580449A CN106189022A CN 106189022 A CN106189022 A CN 106189022A CN 201610580449 A CN201610580449 A CN 201610580449A CN 106189022 A CN106189022 A CN 106189022A
- Authority
- CN
- China
- Prior art keywords
- weight portion
- heat conduction
- high heat
- rubber
- ester rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 63
- 150000002148 esters Chemical class 0.000 title claims abstract description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 34
- 239000012745 toughening agent Substances 0.000 claims abstract description 14
- 239000000049 pigment Substances 0.000 claims abstract description 12
- 239000000806 elastomer Substances 0.000 claims abstract description 11
- 239000007822 coupling agent Substances 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000004014 plasticizer Substances 0.000 claims abstract description 6
- 229920001225 polyester resin Polymers 0.000 claims description 26
- 239000004645 polyester resin Substances 0.000 claims description 26
- 239000000203 mixture Substances 0.000 claims description 14
- 229920002635 polyurethane Polymers 0.000 claims description 14
- 239000004814 polyurethane Substances 0.000 claims description 14
- 239000004005 microsphere Substances 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 229920001935 styrene-ethylene-butadiene-styrene Polymers 0.000 claims description 6
- 229910052709 silver Inorganic materials 0.000 claims description 5
- 239000004332 silver Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 229920002742 polystyrene-block-poly(ethylene/propylene) -block-polystyrene Polymers 0.000 claims description 4
- WNJSKZBEWNVKGU-UHFFFAOYSA-N 2,2-dimethoxyethylbenzene Chemical compound COC(OC)CC1=CC=CC=C1 WNJSKZBEWNVKGU-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 239000001055 blue pigment Substances 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims description 2
- 229920000768 polyamine Polymers 0.000 claims description 2
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 claims description 2
- 239000001054 red pigment Substances 0.000 claims description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 2
- YEIGUXGHHKAURB-UHFFFAOYSA-N viridine Natural products O=C1C2=C3CCC(=O)C3=CC=C2C2(C)C(O)C(OC)C(=O)C3=COC1=C23 YEIGUXGHHKAURB-UHFFFAOYSA-N 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 235000007164 Oryza sativa Nutrition 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 229920013822 aminosilicone Polymers 0.000 claims 1
- 235000012149 noodles Nutrition 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 235000009566 rice Nutrition 0.000 claims 1
- 238000012856 packing Methods 0.000 abstract description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 239000006185 dispersion Substances 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000005987 sulfurization reaction Methods 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 1
- 229920000800 acrylic rubber Polymers 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- -1 amino silicane Chemical compound 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 229960001124 trientine Drugs 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L87/00—Compositions of unspecified macromolecular compounds, obtained otherwise than by polymerisation reactions only involving unsaturated carbon-to-carbon bonds
- C08L87/005—Block or graft polymers not provided for in groups C08L1/00 - C08L85/04
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of high heat conduction tenacity acrylic's ester rubber, it has good heat conductivity, thermostability and elasticity, can meet high temperature, heavy burden machinery in be used as the demand of packing ring.Consisting of: be made up of combed acrylate rubber 100 weight portion, elastomer 20 40 weight portion, compatilizer 36 weight portion, plasticizer 28 weight portion, toughener 15 35 weight portion, coupling agent 35 weight portion, vulcanizing agent 13 weight portion, pigment 05 weight portion and compounded mix 36 80 weight portion.The onset mechanism of acrylate rubber of the present invention is novel, and product newly can be excellent, can meet existing actually used needs.
Description
Technical field
The present invention relates to a kind of acrylate rubber, be specifically related to one and there is high heat conduction, elastomeric acrylate rubber
Glue.
Background technology
Acrylate rubber refers to acrylate for main monomer through elastomer obtained by copolymerization, and its main chain is saturated carbon
Chain, side base is polar ester groups, and it has the performances such as excellent heat-resisting, ageing-resistant, oil resistant, resistance to ozone, uvioresistant, mechanical property
Being better than fluorubber and silicone rubber with processing characteristics, its heat-resisting, resistance to ag(e)ing and oil resistivity are better than nitrile rubber, and it is widely used in
In various high temperature, resistance to oil environment.
Acrylate rubber is when being used as loading structure packing ring under hot conditions, and, heat conductivity, elasticity heat-resisting to it have
Very high request, existing product is all difficult to life-time service, needs frequently to change.The present invention is directed to this problem carried out in detail
Research, finally give and there is excellent heat conducting, heat-resisting, elastic acrylate rubber, can high temperature, heavy burden machinery in use
Make packing ring, use the cycle long.
Summary of the invention
Goal of the invention: the present invention provides a kind of high heat conduction tenacity acrylic's ester rubber, it has good heat conductivity, resistance to
Hot and elastic, can meet high temperature, heavy burden machinery in be used as the demand of packing ring.
The present invention provide acrylate rubber by combed acrylate rubber 100 weight portion, elastomer 20-40 weight portion,
Compatilizer 3-6 weight portion, plasticizer 2-8 weight portion, toughener 15-35 weight portion, coupling agent 3-5 weight portion, vulcanizing agent 1-3 weight
Amount part, pigment 0-5 weight portion and compounded mix 36-80 weight portion composition.
Present invention uses combed acrylate rubber and polyurethane nano microsphere toughener.Acrylic rubber is as elasticity
Body, in the polymerized segment that its side chain graft is certain, forms comb structure, serves the buffering between main chain section, receive external force
Extruding, side chain section folds, buffers.
The combed acrylate rubber of described combed acrylate rubber more preferably lateral chain grafting polyester resin,
Polyester resin preferably comprises Merlon segment, and Merlon, as segment, which raises resistance to elevated temperatures and improves, but content is too
Promoting further of low resistance to elevated temperatures is inconspicuous, and content is the highest, can cause elastic reduction, therefore Merlon segment accounts for total polyester
Resin quality is most preferably 30-50%.
Using polyurethane nano microsphere toughener further, it is dispersed in acrylate rubber, and polyurethane nano microsphere rises
Having arrived good cushioning effect, external force peptizaiton is excellent, and effect is much better than other kinds of toughener.
Combed acrylate rubber and polyurethane nano microsphere with the use of, reached stress dispersion to greatest extent.
Toughener is preferably polyester resin grafted polyurethane Nano microsphere further, makes polyurethane nano microsphere gather with matrix side chain graft
The combed acrylate rubber of ester resin reaches high compatibility.
Described elastomer is SEBS, SBS, SIS or SEPS, and the use of elastomer further increases wilfulness, in order to realize
It is the most identical with matrix, adds suitably to peer.Consider the resistance to elevated temperatures of elastomer further, therefore most preferably
SEBS、SEPS。
Another important performance of the present invention is resistance to elevated temperatures, and it is quickly derived based on by heat, therefore described being combined is filled out
Material is CNT and spherical aluminium sesquioxide, and weight ratio is 3-5:1.CNT and spherical aluminium sesquioxide formed " point-
Line " connect, the coupling agent added in component makes contacting of filler and acrylate rubber, CNT and spherical aluminium sesquioxide
More stable, heat conductivity is more preferably.
As further preferably, CNT nano silver wire filling carbon nano-pipe.
Silver is as a kind of high-thermal conductive metal, and nano silver wire is filled in CNT, and heat is quickly formed at CNT
Space in pass to, affected less by outer acrylate rubber, it is possible to achieve heat quickly passes to, this is simple silver nanoparticle
Line, CNT are beyond one's reach.
Described vulcanizing agent is polyamine vulcanizing agent, preferably diethylenetriamine, triethylene tetramine, TEPA, 1,6-
Hexamethylene diamine.
Described coupling agent is amino silicane coupling agent, can be A-1100, A-1110,1-1120, A-1130, KBM-602,
South big-42, southern big-73.
Described pigment is Chinese white, red pigment, black pigment, blue pigment, viridine green, silver, gold
Pigment, gray paint and mixture thereof.Pigment carries out mixture according to actual color.
Technique effect: multicomponent is selected and combined by the present invention, be specially use combed acrylate rubber with
Polyurethane nano microsphere toughener coordinates, and plasticizer and elastomer are to use to improve elasticity so that it is be adapted to high answering
The dispersion of power, weighs effective；Use the proportioning of nano silver wire filling carbon nano-pipe and spherical aluminium sesquioxide special ratios, real
Show high heat conduction；Further preferably combed acrylate rubber and the polyester resin grafted polyurethane of lateral chain grafting polyester resin is received
Meter Wei Qiu improves again elasticity；The selection of SEBS and SEPS can also improve resistance to elevated temperatures.The combination of above-mentioned each component and use
Amount selection is to there is mutual synergism between specific selection, each component, improves heat conductivity, high temperature resistant and elastic, its
It is much better than the simple superposition of independent component.
Detailed description of the invention
Principle and feature to the present invention are described below, and example is only intended to explain the present invention, is not intended to
Limit the scope of the present invention.
Embodiment 1:
A kind of high heat conduction tenacity acrylic's ester rubber, consisting of the combed acrylate rubber of lateral chain grafting polyester resin
100 weight portions, elastomer SEBS 40 weight portion, compatilizer 6 weight portion, plasticizer 7 weight portion, toughener polyester resin are grafted
Polyurethane nano microsphere 25 weight portion, coupling agent 4 weight portion, vulcanizing agent 2 weight portion, pigment 2 weight portion and compounded mix 50 weight
Amount part, wherein in the combed acrylate rubber of lateral chain grafting polyester resin, Merlon segment accounts for total polyester resin quality 30%,
Compounded mix is nano silver wire filling carbon nano-pipe and spherical aluminium sesquioxide, and weight ratio is 4:1.
After each component mix homogeneously, can use after sulfuration.High heat conduction tenacity acrylic's ester rubber becomes through molding
Circular gasket.
Embodiment 2:
A kind of high heat conduction tenacity acrylic's ester rubber, consisting of the combed acrylate rubber of lateral chain grafting polyester resin
100 weight portions, elastomer SEBS 30 weight portion, compatilizer 5 weight portion, plasticizer 6 weight portion, toughener polyester resin are grafted
Polyurethane nano microsphere 30 weight portion, coupling agent 3 weight portion, vulcanizing agent 3 weight portion, pigment 1 weight portion and compounded mix 60 weight
Amount part, wherein in the combed acrylate rubber of lateral chain grafting polyester resin, Merlon segment accounts for total polyester resin quality 50%,
Compounded mix is nano silver wire filling carbon nano-pipe and spherical aluminium sesquioxide, and weight ratio is 4:1.
After each component mix homogeneously, can use after sulfuration.High heat conduction tenacity acrylic's ester rubber becomes through molding
Circular gasket.
Embodiment 3:
In embodiment 1, the combed acrylate rubber of lateral chain grafting polyester resin replaces with the side chain graft without Merlon segment
The combed acrylate rubber of polyester resin.
Embodiment 4:
In embodiment 1, toughener polyester resin grafted polyurethane Nano microsphere replaces with the polyurethane nano microsphere without grafting.
Embodiment 5:
In embodiment 1, nano silver wire filling carbon nano-pipe replaces with CNT.
Comparative example 1:
In embodiment 1, the combed acrylate rubber of lateral chain grafting polyester resin replaces with non-combed acrylate rubber.
Comparative example 2:
In embodiment 1, the combed acrylate rubber of lateral chain grafting polyester resin replaces with the combed third of lateral chain grafting polyester resin
Olefin(e) acid ester rubber, wherein in the combed acrylate rubber of lateral chain grafting polyester resin, Merlon segment accounts for total polyester resin matter
Amount 80%.
Comparative example 3:
In embodiment 1, toughener polyester resin grafted polyurethane Nano microsphere replaces with neoprene.
Comparative example 4:
In embodiment 1, nano silver wire filling carbon nano-pipe replaces with nano silver wire.
Comparative example 5:
Spherical aluminium sesquioxide in embodiment 1 replaces with needle-like aluminium sesquioxide.
Embodiment is as follows with comparative example component and performance test synopsis:
Contrasted by above-mentioned experimental data, it is found that the structure of acrylic resin, grafting material, toughener kind and structure, fill out
Material kind all creates decisive influence to final products, and there is impact each other, is to interact, non-single effect,
This combination and impact the most do not appear in the newspapers.
Claims (10)
1. one kind high heat conduction tenacity acrylic's ester rubber, it is characterised in that: described acrylate rubber is by combed acrylate
Rubber 100 weight portion, elastomer 20-40 weight portion, compatilizer 3-6 weight portion, plasticizer 2-8 weight portion, toughener 15-35 weight
Amount part, coupling agent 3-5 weight portion, vulcanizing agent 1-3 weight portion, pigment 0-5 weight portion and compounded mix 36-80 weight portion composition.
High heat conduction tenacity acrylic's ester rubber the most as claimed in claim 1, it is characterised in that: described combed acrylate rubber
It it is the combed acrylate rubber of lateral chain grafting polyester resin.
High heat conduction tenacity acrylic's ester rubber the most as claimed in claim 2, it is characterised in that: described polyester resin contains poly-carbon
Acid esters segment, Merlon segment accounts for total polyester resin quality 30-50%.
High heat conduction tenacity acrylic's ester rubber the most as claimed in claim 1, it is characterised in that: described elastomer be SEBS,
SBS, SIS or SEPS.
High heat conduction tenacity acrylic's ester rubber the most as claimed in claim 1, it is characterised in that: described compounded mix is that carbon is received
Mitron and spherical aluminium sesquioxide, weight ratio is 3-5:1.
High heat conduction tenacity acrylic's ester rubber the most as claimed in claim 1, it is characterised in that: described toughener is polyester tree
Fat grafted polyurethane Nano microsphere.
High heat conduction tenacity acrylic's ester rubber the most as claimed in claim 1, it is characterised in that: described vulcanizing agent is polyamine
Vulcanizing agent.
High heat conduction tenacity acrylic's ester rubber the most as claimed in claim 4, it is characterised in that: described CNT is that silver is received
Rice noodle filling carbon nano-pipe.
High heat conduction tenacity acrylic's ester rubber the most as claimed in claim 1, it is characterised in that: described coupling agent is amino silicone
Alkane coupling agent.
High heat conduction tenacity acrylic's ester rubber the most as claimed in claim 1, it is characterised in that: described pigment is white face
Material, red pigment, black pigment, blue pigment, viridine green, silver, golden pigment, gray paint and mixture thereof.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610580449.9A CN106189022B (en) | 2016-07-22 | 2016-07-22 | A kind of high heat conduction tenacity acrylic ester rubber |
| CN201810043234.2A CN108250644A (en) | 2016-07-22 | 2016-07-22 | A kind of high heat conduction tenacity acrylic ester rubber and its application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610580449.9A CN106189022B (en) | 2016-07-22 | 2016-07-22 | A kind of high heat conduction tenacity acrylic ester rubber |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810043234.2A Division CN108250644A (en) | 2016-07-22 | 2016-07-22 | A kind of high heat conduction tenacity acrylic ester rubber and its application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106189022A true CN106189022A (en) | 2016-12-07 |
| CN106189022B CN106189022B (en) | 2018-06-01 |
Family
ID=57491596
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610580449.9A Expired - Fee Related CN106189022B (en) | 2016-07-22 | 2016-07-22 | A kind of high heat conduction tenacity acrylic ester rubber |
| CN201810043234.2A Withdrawn CN108250644A (en) | 2016-07-22 | 2016-07-22 | A kind of high heat conduction tenacity acrylic ester rubber and its application |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810043234.2A Withdrawn CN108250644A (en) | 2016-07-22 | 2016-07-22 | A kind of high heat conduction tenacity acrylic ester rubber and its application |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN106189022B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107227027A (en) * | 2017-07-20 | 2017-10-03 | 广东创弘材料科技有限公司 | Thermoplastic composite elastomer and preparation method thereof, purposes |
| CN114163760A (en) * | 2020-09-10 | 2022-03-11 | 中国石油化工股份有限公司 | Acrylate rubber composition and application thereof |
| CN115703914A (en) * | 2021-08-06 | 2023-02-17 | 中国石油化工股份有限公司 | Acrylate rubber composition and application thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102465161B1 (en) * | 2019-11-06 | 2022-11-09 | 주식회사 아모그린텍 | Heat radiation sheet, method for manufacturing thereof, and electronic device comprising the same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01207346A (en) * | 1988-02-16 | 1989-08-21 | Asahi Chem Ind Co Ltd | Composition having rubber elasticity |
| CN1809612A (en) * | 2003-06-24 | 2006-07-26 | 澳大利亚聚合物股份有限公司 | Acrylic dispersing agents in nanocomposites |
| CN103224678A (en) * | 2013-03-29 | 2013-07-31 | 浙江固耐橡塑科技有限公司 | Acrylate rubber composite material |
| CN104725754A (en) * | 2013-12-23 | 2015-06-24 | 青岛新动力文化传媒有限公司 | Composite material used for producing O-shaped sealing rings |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103319829B (en) * | 2013-06-13 | 2015-06-03 | 深圳德邦界面材料有限公司 | Silicon-free heat-conducting gasket and preparation method thereof |
-
2016
- 2016-07-22 CN CN201610580449.9A patent/CN106189022B/en not_active Expired - Fee Related
- 2016-07-22 CN CN201810043234.2A patent/CN108250644A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01207346A (en) * | 1988-02-16 | 1989-08-21 | Asahi Chem Ind Co Ltd | Composition having rubber elasticity |
| CN1809612A (en) * | 2003-06-24 | 2006-07-26 | 澳大利亚聚合物股份有限公司 | Acrylic dispersing agents in nanocomposites |
| CN103224678A (en) * | 2013-03-29 | 2013-07-31 | 浙江固耐橡塑科技有限公司 | Acrylate rubber composite material |
| CN104725754A (en) * | 2013-12-23 | 2015-06-24 | 青岛新动力文化传媒有限公司 | Composite material used for producing O-shaped sealing rings |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107227027A (en) * | 2017-07-20 | 2017-10-03 | 广东创弘材料科技有限公司 | Thermoplastic composite elastomer and preparation method thereof, purposes |
| CN114163760A (en) * | 2020-09-10 | 2022-03-11 | 中国石油化工股份有限公司 | Acrylate rubber composition and application thereof |
| CN114163760B (en) * | 2020-09-10 | 2023-05-30 | 中国石油化工股份有限公司 | Acrylic rubber composition and application thereof |
| CN115703914A (en) * | 2021-08-06 | 2023-02-17 | 中国石油化工股份有限公司 | Acrylate rubber composition and application thereof |
| CN115703914B (en) * | 2021-08-06 | 2023-10-13 | 中国石油化工股份有限公司 | Acrylic rubber composition and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106189022B (en) | 2018-06-01 |
| CN108250644A (en) | 2018-07-06 |
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