CN106188794A - A kind of dust collecting high molecular nanometer Graphene load fibers bundle and production method thereof - Google Patents
A kind of dust collecting high molecular nanometer Graphene load fibers bundle and production method thereof Download PDFInfo
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- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
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Abstract
The invention discloses a kind of dust collecting high molecular nanometer Graphene load fibers bundle and preparation method thereof, it is made up of following raw material: gangue 20 25, nano aluminium oxide 24, mesh knot soil 10 15, sea mud 8 12, polyvinyl acetate 5 10, Oleum Verniciae fordii 46, molasses 36, sodium lauroyl sarcosine 12, abies balsam 35, asbestos wool 48, additive 68, water are appropriate.The fired brick of the present invention uses gangue to be that clay resource not only saved by main raw material(s), reduce production cost, also solve the process problem of gangue, it is to avoid its pollution to environment;It addition, fired brick of the present invention has intensity height, bearing capacity is strong, and density is little, and heat conductivity is low, meets the requirement of people, applied range, and market prospect is big.
Description
Technical field
The present invention relates to building material technical field, more specifically a kind of dust collecting high molecular nanometer Graphene loads
Fibre bundle and production method thereof.
Background technology
At present, use the mode of vitrified bond to prepare during major part brickmaking, but be as the increase of clay yield, clay
Resource is the deficientest, not only increases cost of winning, ecological environment also causes having a strong impact on simultaneously, therefore needs optimization badly and change
Enter existing brick-making method to change the status quo.
Use sodium hydroxide decomposing zircon sand, be China's main production of producing now basic zirconium chloride and zirconium dioxide.
China's basic zirconium chloride yearly productive capacity in 2007 has reached 150,000 t, occupies the first in the world.As functional material and structural material
The demand of zirconium dioxide is also continuously increased, and its production technology cost is relatively low, but shortcoming is that producing substantial amounts of garbage (often gives birth to
Produce 1t zirconium dioxide product and about discharge sig water 5m, acid white residue 1t).In recent years, along with production-scale expansion, produced
The process problem of the garbage produced in journey also becomes increasingly conspicuous.
The raising of national life level of expanding economy band, the trend that the purchase volume of private car the most linearly rises,
Automobile environment inside car becomes the problem that people become more concerned with.Polluter in private car mainly has Aerosol Pollution and volatility
Organic Pollution, investigation shows: total volatile organic compound concentration can raise and the increase of off-period and urgency along with temperature
Sharp increase adds.This is because be all bonded together by chemical adhesive between a lot of materials in automobile, temperature raises and close
The volatilization of harmful substance is accelerated in closed loop border next time.So, keep often ventilating and in automobile, putting into adsorbing material, such as activity
Charcoal or melt-blown material and the joint product of bulky grain activated carbon, adsorb harmful gas, purifies air in private car, but this
The product of sample often has certain life-span, needs often to change, in the case of there is no labelling or reminding, and the most easily quilt
Forget or neglect, it is impossible to the environment being effectively ensured in private car.For private car environment pollution situation, urgent need to develop
A kind of aerosol that can filter can eliminate again the dual durable filtering material of volatile organic matter.Composite filter material filters because of it
The advantages such as efficiency height, low, the length in service life of filtration resistance come into one's own all the more
Therefore, utilize the anti-haze of dust collecting high molecular nanometer to turn waste into wealth, protect the effective measures of environment, farmland saving, have good
Good social and economic benefits.
Summary of the invention
The invention aims to make up the deficiencies in the prior art, it is provided that a kind of intensity is high, heat conductivity is low, anti-ageing
Change, the anti-haze of dust collecting high molecular nanometer that density is little tie brick and production method thereof.
It is an object of the invention to be achieved through the following technical solutions:
A kind of dust collecting high molecular nanometer Graphene load fibers bundle, is made up of following raw material: cellulose acetate tow 25-
30, alginic acid 20-25, hydrochloric acid 5-10, gangue 30-35, ethylene-vinyl acetate copolymer 20-25, high density polyethylene 8-10,
Nanoparticle active agent 5-8, triacetyl glycerine 5-8, conductive mica powder 0.3-0.5, conductive nano graphite powder 0.2-0.4, many isocyanides
The trimer 0.8-1 of acid esters, polytetrafluoroethylene fibre 1-2, porous aluminium titanates 2-3, polylactic acid chitosan 15-20, nano-graphite
Alkene 10-15, modified nano-titanium dioxide 10-25, flyash 20-25, slaked lime 6-7, wollastonite 6-8, p-phthalic acid two
Ethyl ester 15-25, METHYL 3 AMINO CROTONATE 10-15, PHT4 15-20, polyvinyl resin 15-21, nano aluminium oxide 2-4,
Mesh knot soil 10-15, sea mud 8-12, polyvinyl acetate 5-10, Oleum Verniciae fordii 4-6, molasses 3-6, sodium lauroyl sarcosine 1-2, cold
China fir glue 3-5, asbestos wool 4-8, additive 6-8, water are appropriate;
The preparation method of described modified nano-titanium dioxide is: take complete substituted N-N-trimethyl chitosan TMC quaternary ammonium salt, lactic acid mixes
Close, and be uniformly completely dissolved, at access alginic acid to quaternary ammonium salt 80-90 DEG C of heated and stirred after adding the water of gross weight 4-6 times
Sodium, titanium dioxide granule stir at 90 DEG C, cooling, ultrasonic are drying to obtain;
Described nanoparticle active agent is that MgO, Al2O3, Si3N4, BN are mixed the compositions produced by the part by weight of 1:2:3:1
Described additive is made up of the raw material of following weight portion: a certain amount of magnesium aluminum-hydrotalcite is scattered in the deionization of de-CO2
After making serosity in water, the NaH2PO4 2H2O of excess being dissolved in water institute wiring solution-forming to be poured slowly in serosity, heated and stirred is also
Regulate PH to about 3.7 with acetic acid, react 3 hours under reflux temperature, after natural cooling, with the deionization washing of de-CO2
Wash product and filter until filtrate PH=7, being then dried to obtain;The preparation method of described nano-graphene is: added by concentrated sulphuric acid
Enter in graphite, stir 5-12 hour through-20 DEG C ~-10 DEG C low temperature, then after 0 DEG C ~ 5 DEG C stirrings 5-12 hour, add Gao Meng
Acid potassium carries out oxidation reaction and obtains graphite oxide solution;To obtain being directly added into CTAB in graphite oxide solution, CTAB is to oxidation
Graphite carries out flocculation and modified-reaction obtains modified graphite oxide solution;Modified graphite oxide solution is filtered, washs, at 50 DEG C
It is vacuum dried 24 hours, i.e. obtains nano-graphene.
The production method of a kind of dust collecting high molecular nanometer Graphene load fibers bundle, is prepared from by following steps:
(1) take alginic acid, mixed in hydrochloric acid, and the deionized water adding gross weight 6-10 times be heated to 100-120 DEG C and stir,
Adding cellulose acetate tow afterwards keeps this heating-up temperature to continue stirring 20-30min to uniform that Sargassum acidic group fiber liquid is standby;
By gangue, ethylene-vinyl acetate copolymer, high density polyethylene, nanoparticle active agent, triacetyl glycerine, conduction cloud
Female powder, conductive nano graphite powder, the trimer of polyisocyanates, polytetrafluoroethylene fibre, porous aluminium titanates, modified Nano two
Titanium oxide, flyash, slaked lime, wollastonite, diethyl terephthalate, METHYL 3 AMINO CROTONATE, PHT4,
Pulverize and grind after polyvinyl resin, nano aluminium oxide, asbestos wool, mesh knot soil, sea mud mixing, be subsequently adding molasses, Laurel
Acylsarcosine sodium, additive and appropriate water also stir, and obtain compound;
(2) will add compound in Sargassum acidic group fiber liquid, high temperature 90-100 DEG C stirs prepared base material;
(3) by abies balsam, Oleum Verniciae fordii, polyvinyl acetate mixing after 80-90 DEG C, 800-1000r/min stir 5-10min, then
The substrate surface that even application prepares in (2), 100-120 DEG C of insulation 2-4h;
By polylactic acid chitosan, nano-graphene mixing, the most quickly stirring 5-6h is to forming the saturating of stable homogeneous
Bright solution, by the loading base material of electron spray form high-temperature spray Graphene between layers;After cooling and get final product.
It is an advantage of the current invention that:
The activation of Sargassum acidic group fiber liquid increases the specific area of fiber solution, actively captures the haze granule in air, reaches antibacterial
Purpose except haze;The present invention joins with ethylene-vinyl acetate copolymer, high density polyethylene, nanoparticle active agent for major ingredient component raw material
Making reasonable science, the composition of interpolation not only can have its material protected of effective guarantee nonflammable, and the too high burning of temperature
Also will not produce harmful gas and there is the most high temperature resistant, fire prevention, fire-retardant advantage;Nano material modified synergic hinders
The combustion mechanical property of ethylene-vinyl acetate copolymer, fire resistance, heat resistance are preferable;By low temperature two benches legal system
The graphite oxide of standby high oxidation degree, and use CTAB to be modified processing to it, on the one hand improve graphene oxide in substrate
In dispersibility, on the other hand, it is long to there is finishing time in graphene oxide in last handling process, the problem that technique is loaded down with trivial details,
This also constrains graphene oxide and realizes application, uses CTAB to be added directly in graphite oxide solution, in modification
Meanwhile, CTAB has carried out flocculation treatment to graphite oxide solution, is substantially shorter the last handling process of graphite oxide, improves oxidation
Graphite preparation efficiency, therefore, uses CTAB that graphite oxide is carried out post processing, shortens graphite oxide post processing while modification
Technique, the reinforcing agent such as the rock wool floss of interpolation, porous aluminium titanates, zircon, cement cinder can improve resistant to thermal aging cracking performance,
Thus improve casting efficiency, reduce casting cost.The present invention is by selecting photocatalyst and degradable poly breast on material component
Filter fiber film prepared by acid chitosan, has the dual-use function of adsorbed gas colloidal sol and volatile organic matter, has degradable ring
The advantage protected, the chitosan of employing, can be with the antibacterial of adsorption site negative charge so that it is have sterilization merit because of molecular band positive charge
Energy;Structurally, it is prepared for the fibrous membrane layer of different-diameter and hole, in conjunction with nano-graphene between layers, improves
Hole and the specific surface area of composite adsorption film exist, and enhance effect.
Detailed description of the invention
Embodiment 1
A kind of dust collecting high molecular nanometer Graphene load fibers bundle, is made up of following weight raw material: cellulose acetate tow 25kg, sea
Alginic acid 20kg, hydrochloric acid 5kg, gangue 30kg, ethylene-vinyl acetate copolymer 20kg, high density polyethylene 8kg, nanoparticle active agent
5kg, triacetyl glycerine 5 kg, conductive mica powder 0.3kg, conductive nano graphite powder 0.2kg, the trimer of polyisocyanates
0.8kg, polytetrafluoroethylene fibre 1kg, porous aluminium titanates 2 kg, polylactic acid chitosan 15 kg, nano-graphene 10 kg, modified
Nano titanium oxide 10 kg, flyash 20 kg, slaked lime 6 kg, wollastonite 6 kg, diethyl terephthalate 15 kg,
METHYL 3 AMINO CROTONATE 10 kg, PHT4 15 kg, polyvinyl resin 15 kg, nano aluminium oxide 2 kg, mesh knot soil
10kg, sea mud 8kg, polyvinyl acetate 5kg, Oleum Verniciae fordii 4kg, molasses 3kg, sodium lauroyl sarcosine 1kg, abies balsam 3kg,
Asbestos wool 4kg, additive 6kg, water are appropriate;
The preparation method of described modified nano-titanium dioxide is: take complete substituted N-N-trimethyl chitosan TMC quaternary ammonium salt, lactic acid mixes
Close, and be uniformly completely dissolved, at access alginic acid to quaternary ammonium salt 80-90 DEG C of heated and stirred after adding the water of gross weight 4-6 times
Sodium, titanium dioxide granule stir at 90 DEG C, cooling, ultrasonic are drying to obtain;
Described nanoparticle active agent is that MgO, Al2O3, Si3N4, BN are mixed the compositions produced by the part by weight of 1:2:3:1
Described additive is made up of the raw material of following weight portion: a certain amount of magnesium aluminum-hydrotalcite is scattered in the deionization of de-CO2
After making serosity in water, the NaH2PO4 2H2O of excess being dissolved in water institute wiring solution-forming to be poured slowly in serosity, heated and stirred is also
Regulate PH to about 3.7 with acetic acid, react 3 hours under reflux temperature, after natural cooling, with the deionization washing of de-CO2
Wash product and filter until filtrate PH=7, being then dried to obtain;The preparation method of described nano-graphene is: added by concentrated sulphuric acid
Enter in graphite, stir 5-12 hour through-20 DEG C ~-10 DEG C low temperature, then after 0 DEG C ~ 5 DEG C stirrings 5-12 hour, add Gao Meng
Acid potassium carries out oxidation reaction and obtains graphite oxide solution;To obtain being directly added into CTAB in graphite oxide solution, CTAB is to oxidation
Graphite carries out flocculation and modified-reaction obtains modified graphite oxide solution;Modified graphite oxide solution is filtered, washs, at 50 DEG C
It is vacuum dried 24 hours, i.e. obtains nano-graphene.
The production method of a kind of dust collecting high molecular nanometer Graphene load fibers bundle, is prepared from by following steps:
(1) take alginic acid, mixed in hydrochloric acid, and the deionized water adding gross weight 6-10 times be heated to 100-120 DEG C and stir,
Adding cellulose acetate tow afterwards keeps this heating-up temperature to continue stirring 20-30min to uniform that Sargassum acidic group fiber liquid is standby;
By gangue, ethylene-vinyl acetate copolymer, high density polyethylene, nanoparticle active agent, triacetyl glycerine, conduction cloud
Female powder, conductive nano graphite powder, the trimer of polyisocyanates, polytetrafluoroethylene fibre, porous aluminium titanates, modified Nano two
Titanium oxide, flyash, slaked lime, wollastonite, diethyl terephthalate, METHYL 3 AMINO CROTONATE, PHT4,
Pulverize and grind after polyvinyl resin, nano aluminium oxide, asbestos wool, mesh knot soil, sea mud mixing, be subsequently adding molasses, Laurel
Acylsarcosine sodium, additive and appropriate water also stir, and obtain compound;
(2) will add compound in Sargassum acidic group fiber liquid, high temperature 90-100 DEG C stirs prepared base material;
(3) by abies balsam, Oleum Verniciae fordii, polyvinyl acetate mixing after 80-90 DEG C, 800-1000r/min stir 5-10min, then
The substrate surface that even application prepares in (2), 100-120 DEG C of insulation 2-4h;
By polylactic acid chitosan, nano-graphene mixing, the most quickly stirring 5-6h is to forming the saturating of stable homogeneous
Bright solution, by the loading base material of electron spray form high-temperature spray Graphene between layers;After cooling and get final product.
Embodiment 2
Cellulose acetate tow 30kg, alginic acid 25kg, hydrochloric acid 10kg, gangue 35kg, ethylene-vinyl acetate copolymer 25kg,
High density polyethylene 10kg, nanoparticle active agent 8kg, triacetyl glycerine 8 kg, conductive mica powder 0.5kg, conductive nano graphite powder
0.4kg, the trimer 1kg of polyisocyanates, fibrillated polytetrafluoroethylene 2kg, porous aluminium titanates 3 kg, polylactic acid chitosan 20
Kg, nano-graphene 15 kg modified nano-titanium dioxide 25 kg, flyash 25 kg, slaked lime 7 kg, wollastonite 8
Kg, diethyl terephthalate 25 kg, METHYL 3 AMINO CROTONATE 15 kg, PHT4 20 kg, polyvinyl resin 21
Kg, nano aluminium oxide 4 kg, mesh knot soil 12kg, sea mud 810kg, polyvinyl acetate 8kg, Oleum Verniciae fordii 5kg, molasses 4.5kg,
Sodium lauroyl sarcosine 1.5kg, abies balsam 4kg, asbestos wool 6kg, additive 7kg, water are appropriate;
The preparation method of described modified nano-titanium dioxide is: take complete substituted N-N-trimethyl chitosan TMC quaternary ammonium salt, lactic acid mixes
Close, and be uniformly completely dissolved, at access alginic acid to quaternary ammonium salt 80-90 DEG C of heated and stirred after adding the water of gross weight 4-6 times
Sodium, titanium dioxide granule stir at 90 DEG C, cooling, ultrasonic are drying to obtain;
Described nanoparticle active agent is that MgO, Al2O3, Si3N4, BN are mixed the compositions produced by the part by weight of 1:2:3:1
Described additive is made up of the raw material of following weight portion: a certain amount of magnesium aluminum-hydrotalcite is scattered in the deionization of de-CO2
After making serosity in water, the NaH2PO4 2H2O of excess being dissolved in water institute wiring solution-forming to be poured slowly in serosity, heated and stirred is also
Regulate PH to about 3.7 with acetic acid, react 3 hours under reflux temperature, after natural cooling, with the deionization washing of de-CO2
Wash product and filter until filtrate PH=7, being then dried to obtain;The preparation method of described nano-graphene is: added by concentrated sulphuric acid
Enter in graphite, stir 5-12 hour through-20 DEG C ~-10 DEG C low temperature, then after 0 DEG C ~ 5 DEG C stirrings 5-12 hour, add Gao Meng
Acid potassium carries out oxidation reaction and obtains graphite oxide solution;To obtain being directly added into CTAB in graphite oxide solution, CTAB is to oxidation
Graphite carries out flocculation and modified-reaction obtains modified graphite oxide solution;Modified graphite oxide solution is filtered, washs, at 50 DEG C
It is vacuum dried 24 hours, i.e. obtains nano-graphene.
The preparation method of dust collecting high molecular nanometer anti-haze knot brick is with embodiment 1.
Reasonable section is prepared for major ingredient component raw material with ethylene-vinyl acetate copolymer, high density polyethylene, nanoparticle active agent
Learning, the composition of interpolation not only can have its material protected of effective guarantee nonflammable, and the too high burning of temperature also will not be produced
Raw harmful gas has the most high temperature resistant, fire prevention, fire-retardant advantage;Nano material modified synergic flame-proof ethylene-
The mechanical property of vinyl acetate co-polymer, fire resistance, heat resistance are preferable;High oxidation is prepared by low temperature two-phase method
The graphite oxide of degree, and use CTAB to be modified processing to it, on the one hand improve graphene oxide dispersion in substrate
Property, on the other hand, it is long to there is finishing time in graphene oxide in last handling process, the problem that technique is loaded down with trivial details, and this also restricts
Graphene oxide realizes application, uses CTAB to be added directly in graphite oxide solution, while modification, and CTAB
Graphite oxide solution is carried out flocculation treatment, has been substantially shorter the last handling process of graphite oxide, improved graphite oxide and prepare
Efficiency, therefore, uses CTAB that graphite oxide is carried out post processing, shortens graphite oxide aftertreatment technology while modification;Add
The reinforcing agents such as the rock wool floss that adds, porous aluminium titanates, zircon, cement cinder can improve resistant to thermal aging cracking performance, thus carries
High casting efficiency, reduces casting cost.
The present invention prepares filter fiber film by selection photocatalyst and degradable poly chitosan lactate on material component,
There is the dual-use function of adsorbed gas colloidal sol and volatile organic matter, the advantage with Degradable environment protection, the chitosan of employing because of
For molecular band positive charge, can be with the antibacterial of adsorption site negative charge so that it is there is sterilizing function;Structurally, difference it is prepared for straight
The fibrous membrane layer of footpath and hole, in conjunction with nano-graphene between layers, improves hole and the specific surface of composite adsorption film
Amass, enhance effect.
The preparation method of dust collecting high molecular nanometer anti-haze knot brick is with embodiment 1.
Claims (2)
1. a dust collecting high molecular nanometer Graphene load fibers bundle, it is characterised in that: it is made up of following raw material: vinegar
Acid fibre bundle 25-30, alginic acid 20-25, hydrochloric acid 5-10, gangue 30-35, ethylene-vinyl acetate copolymer 20-25, height
Polyethylene 8-10, nanoparticle active agent 5-8, triacetyl glycerine 5-8, conductive mica powder 0.3-0.5, conductive nano graphite powder 0.2-
0.4, the trimer 0.8-1 of polyisocyanates, polytetrafluoroethylene fibre 1-2, porous aluminium titanates 2-3, polylactic acid chitosan 15-
20, nano-graphene 10-15, modified nano-titanium dioxide 10-25, flyash 20-25, slaked lime 6-7, wollastonite 6-8,
Diethyl terephthalate 15-25, METHYL 3 AMINO CROTONATE 10-15, PHT4 15-20, polyvinyl resin 15-21, receive
Rice aluminium oxide 2-4, mesh knot soil 10-15, sea mud 8-12, polyvinyl acetate 5-10, Oleum Verniciae fordii 4-6, molasses 3-6, lauroyl flesh
Propylhomoserin sodium 1-2, abies balsam 3-5, asbestos wool 4-8, additive 6-8, water are appropriate;
The preparation method of described modified nano-titanium dioxide is: take complete substituted N-N-trimethyl chitosan TMC quaternary ammonium salt, lactic acid mixes
Close, and be uniformly completely dissolved, at access alginic acid to quaternary ammonium salt 80-90 DEG C of heated and stirred after adding the water of gross weight 4-6 times
Sodium, titanium dioxide granule stir at 90 DEG C, cooling, ultrasonic are drying to obtain;
Described nanoparticle active agent is that MgO, Al2O3, Si3N4, BN are mixed the compositions produced by the part by weight of 1:2:3:1;Institute
Stating modified nano-titanium dioxide preparation method is: by adding 1-2 times of deionized water in NACF, soak in deionized water
Take out after 1-2h, take out standby after being dried 3-5h in an oven;Starched by metatitanic acid, carbamide mixes, and adds gross weight 3-5 times
After deionized water stirs, the NACF after addition process, at 90-96 DEG C, heated and stirred 2-4h obtains completely to reaction
Arrive;
Described additive is made up of the raw material of following weight portion: a certain amount of magnesium aluminum-hydrotalcite is scattered in the deionization of de-CO2
After making serosity in water, the NaH2PO4 2H2O of excess being dissolved in water institute wiring solution-forming to be poured slowly in serosity, heated and stirred is also
Regulate PH to about 3.7 with acetic acid, react 3 hours under reflux temperature, after natural cooling, with the deionization washing of de-CO2
Wash product and filter until filtrate PH=7, being then dried to obtain;The preparation method of described nano-graphene is: added by concentrated sulphuric acid
Enter in graphite, stir 5-12 hour through-20 DEG C ~-10 DEG C low temperature, then after 0 DEG C ~ 5 DEG C stirrings 5-12 hour, add Gao Meng
Acid potassium carries out oxidation reaction and obtains graphite oxide solution;To obtain being directly added into CTAB in graphite oxide solution, CTAB is to oxidation
Graphite carries out flocculation and modified-reaction obtains modified graphite oxide solution;Modified graphite oxide solution is filtered, washs, at 50 DEG C
It is vacuum dried 24 hours, i.e. obtains nano-graphene.
The production method of a kind of dust collecting high molecular nanometer Graphene load fibers bundle the most according to claim 1, it is special
Levy and be to be prepared from by following steps:
(1) take alginic acid, mixed in hydrochloric acid, and the deionized water adding gross weight 6-10 times be heated to 100-120 DEG C and stir,
Adding cellulose acetate tow afterwards keeps this heating-up temperature to continue stirring 20-30min to uniform that Sargassum acidic group fiber liquid is standby;
By gangue, ethylene-vinyl acetate copolymer, high density polyethylene, nanoparticle active agent, triacetyl glycerine, conduction cloud
Female powder, conductive nano graphite powder, the trimer of polyisocyanates, polytetrafluoroethylene fibre, porous aluminium titanates, modified Nano two
Titanium oxide, flyash, slaked lime, wollastonite, diethyl terephthalate, METHYL 3 AMINO CROTONATE, PHT4,
Pulverize and grind after polyvinyl resin, nano aluminium oxide, asbestos wool, mesh knot soil, sea mud mixing, be subsequently adding molasses, Laurel
Acylsarcosine sodium, additive and appropriate water also stir, and obtain compound;
(2) will add compound in Sargassum acidic group fiber liquid, high temperature 90-100 DEG C stirs prepared base material;
(3) by abies balsam, Oleum Verniciae fordii, polyvinyl acetate mixing after 80-90 DEG C, 800-1000r/min stir 5-10min, then
The substrate surface that even application prepares in (2), 100-120 DEG C of insulation 2-4h;
By polylactic acid chitosan, nano-graphene mixing, the most quickly stirring 5-6h is to forming the saturating of stable homogeneous
Bright solution, by the loading base material of electron spray form high-temperature spray Graphene between layers;After cooling and get final product.
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CN104588110A (en) * | 2014-12-23 | 2015-05-06 | 郑州轻工业学院 | Grapheme/chitosan/cuprous oxide composite material and preparation method and applications thereof |
CN104774372A (en) * | 2015-03-30 | 2015-07-15 | 安徽省高沟电缆有限公司 | High-performance flame-retardant cable material and preparation method thereof |
CN105130361A (en) * | 2015-07-15 | 2015-12-09 | 常州市武进金阳光电子有限公司 | Mildew-proof and corrosion-resistant composite nano calcium silicate brick and production method thereof |
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Application publication date: 20161207 |