CN106188748A - A kind of corrosion-resistant cold-resistant high temperature resistant waterproof film - Google Patents
A kind of corrosion-resistant cold-resistant high temperature resistant waterproof film Download PDFInfo
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- CN106188748A CN106188748A CN201610555588.6A CN201610555588A CN106188748A CN 106188748 A CN106188748 A CN 106188748A CN 201610555588 A CN201610555588 A CN 201610555588A CN 106188748 A CN106188748 A CN 106188748A
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
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- C08L2201/00—Properties
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- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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Abstract
The invention discloses a kind of corrosion-resistant cold-resistant high temperature resistant waterproof film, being made up by the mass ratio of 2:6 10 with LDPE of additive, wherein additive is made up of according to the raw material of mass percent following: ethylene-vinyl acetate/polyethylene octene elastomer 15 21%, ethylene vinyl acetate thing 35 41%, polyolefin elastomer 25 31%, linear low density polyethylene 8 12%, ultra-high molecular weight polyethylene 4 8% altogether.Film double-sided of the present invention spray is containing ultraviolet (UV) resistant agent and the ethylene-vinyl acetate/polyethylene octene elastomer of ethylene-vinyl acetate content 14%, tensile strength, elongation, resistant to shearing degree, bending break stiffness all have greatly improved, uvioresistant index is obviously improved, and convenient ultraviolet irradiates and uses under exposure environment the most regional, long-term.Add multiple additives raw material targetedly so that it is possess the features such as cold resistant, sunburst irradiation high temperature resistant, resistance to, UV resistant, ageing-resistant, saline-alkaline corrosion-resistant.
Description
Technical field
The present invention relates to a kind of plastic material technical field, a kind of corrosion-resistant cold-resistant high temperature resistant waterproof film.
Background technology
Use high density polyethylene (HDPE) (High Density Polyethylene, referred to as " HDPE ") in the market more
As waterproof layer, carrying out film use in traditional HDPE woven film, this surface film tarpaulin drenches lepthymenia, makes tarpaulin
Not there is water proofing property, only possess basic splash-proof ability.At present polyethylene tarpaulin inner substrate part be polyethylene filament via
Braider be longitude and latitude braiding form, inside and outside spray Low Density Polyethylene (LDPE) liquation, through calendering formed thin film, base
Material plays raising thin film pull resistance, and film then plays primary watertightness effect.This tarpaulin strengthens the use intensity of thin film, but
Water proofing property aspect, does not make further performance and improves.
This polyethylene tarpaulin is possible to prevent the process that dabbles of transience, but cannot meet the most waterproof, seepage control project and want
Ask, in reality produces, rarely have enterprise to use as waterproof layer, and often dust-proof block as job site is temporary,
Or play sunshade effect during a property time uses.
Traditional material substrate is HDPE, and production technology is braiding;Two sides film is LDPE, and production technology is spray, two
Person rolls together through equipment.But this is that kind of a material, production technology are the most entirely different after all, can cause film and the base material can not
Fully laminating, easily tears, is easily generated seepage, two kinds of material separation easy to foaming.
Summary of the invention
It is an object of the invention to provide a kind of corrosion-resistant cold-resistant high temperature resistant waterproof film, for this film ethylene tarpaulin institute
The water-proof function of shortcoming, is the oriented invention of unique environments situation being had for high altitude localities, and this thin film can be
The chemical environment such as the most saline and alkaline plays long-term antiseepage effect.High heat in summer for highlands has fabulous being suitable for winter severe cold
Property, can go through for many years and retention performance is constant.
For achieving the above object, the present invention provides following technical scheme:
A kind of corrosion-resistant cold-resistant high temperature resistant waterproof film, is made up by the mass ratio of 2:6-10 with LDPE of additive, Qi Zhongtian
Add agent to be made up of according to the raw material of mass percent following:
Ethene-vinyl acetate/polyethylene octene elastomer 15-21%
Ethylene vinyl acetate thing 35-41% altogether
Polyolefin elastomer 25-31%
Linear low density polyethylene 8-12%
Ultra-high molecular weight polyethylene 4-8%.
As the further scheme of the present invention: vinyl acetate content in ethene-vinyl acetate/polyethylene octene elastomer
It is 14%.
As the further scheme of the present invention: additive is 2:8 with the mass ratio of LDPE.
As the further scheme of the present invention: additive is made up of according to the raw material of mass percent following:
Ethene-vinyl acetate/polyethylene octene elastomer 18%
Ethylene vinyl acetate thing 38% altogether
Polyolefin elastomer 28%
Linear low density polyethylene 10%
Ultra-high molecular weight polyethylene 6%.
As the further scheme of the present invention: the preparation process of additive is: by ethene-vinyl acetate/polyethylene octene
Elastomer, ethylene vinyl acetate thing, polyolefin elastomer, linear low density polyethylene, ultra-high molecular weight polyethylene altogether is pressed altogether
After weighing according to the ratio of mass percent, it is injected into fuse machine, agitating heating under the hot melting temperature of 200 DEG C, all it is fused into
Liquid, after extrusion, reduces temperature through cooling device, takes mould to be pressed into tabular simultaneously, then is cut into graininess and i.e. obtains and add
Add agent.
In the present invention vinyl acetate content be 14% ethene-vinyl acetate/polyethylene octene elastomer make thin film have
There is excellent anti-ultraviolet property.Ethylene vinyl acetate thing altogether increases degree of adhesion and the hot strength of thin film.Polyolefin elastomer
Increase the pliability of thin film, do not cause fracture because of folding.Linear low density polyethylene extends thin film ageing resistance, antioxidation
Ability.Ultra-high molecular weight polyethylene increases thin film wear resistence, self lubricity, water-resistance.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention be directed to existing ldpe film and be oriented compositional refinements, use the material combination of different proportion, this skill
Art is by ldpe film carries out formulation optimization, by the material modified interpolation of proper proportion so that it is have extremely strong environment
Weatherability, has the water resistance of brilliance simultaneously, simultaneously improves production technology, make film substrate combine together with two-sided film,
The most easy to crack, will not under cold and hot frequent alternate environment, unlike material material natural separation and affect water resistance.Have extremely strong
Tensile strength, meet engineering waterproofing requirement.
Newly-increased anti-ultraviolet property in thin film of the present invention, this thin film upper and lower surface has all sprayed one layer containing ultraviolet (UV) resistant agent
And the ethene-vinyl acetate/polyethylene octene elastomer of ethene-vinyl acetate content 14%.
This ethylene containing ultraviolet (UV) resistant agent and ethene-vinyl acetate content 14% of film double-sided of the present invention spray-
Vinyl acetate/polyethylene octene elastomer, so the tensile strength of polyethylene film, elongation, resistant to shearing degree, bending are very
Degree all has greatly improved, and adds ultraviolet (UV) resistant agent, and the uvioresistant index of polyethylene film is obviously improved, time long
Between be exposed to the sun by burning sun and also not had problem, convenient ultraviolet irradiates and uses under exposure environment the most regional, long-term.Thoroughly
Solve outside the adhesion problem of HDPE and LDPE bi-material, summer high temperature feature extremely cold according to the winter of highlands, there is pin
Addition multiple additives raw material to property so that it is possess cold resistant, sunburst irradiation high temperature resistant, resistance to, UV resistant, resistance to always
The features such as change, saline-alkaline corrosion-resistant.
Accompanying drawing explanation
Fig. 1 is the process chart of additive of the present invention.
Detailed description of the invention
Below in conjunction with detailed description of the invention, technical scheme is described in more detail.
Embodiment 1
Referring to Fig. 1, the embodiment of the present invention exists, a kind of corrosion-resistant cold-resistant high temperature resistant waterproof film, additive press with LDPE
The mass ratio of 2:6 is made, and wherein additive is made up of according to the raw material of mass percent following:
Vinyl acetate content is the ethene-vinyl acetate/polyethylene octene elastomer 15% of 14%
Ethylene vinyl acetate thing 41% altogether
Polyolefin elastomer 25%
Linear low density polyethylene 12%
Ultra-high molecular weight polyethylene 7%.
By ethene-vinyl acetate/polyethylene octene elastomer that vinyl acetate content is 14%, ethylene vinyl acetate
Thing, polyolefin elastomer, linear low density polyethylene, ultra-high molecular weight polyethylene weigh according to the ratio of mass percent altogether
After, it is injected into fuse machine, agitating heating under the hot melting temperature of 200 DEG C, all it is fused into liquid, after extrusion, sets through supercooling
Make preparation for dropping low temperature, take mould to be pressed into tabular simultaneously, then be cut into graininess through cutter and i.e. obtain additive.Treat that product is natural
Cool down, dry, can pack, store for future use.In real work, add LDPE by the mass ratio that above-mentioned finished product is pressed 2:6
In, can have the waterproof membrane of the performances such as corrosion-resistant, cold-resistant, high temperature resistance, water proofing property.
Embodiment 2
Referring to Fig. 1, the embodiment of the present invention exists, a kind of corrosion-resistant cold-resistant high temperature resistant waterproof film, additive press with LDPE
The mass ratio of 2:10 is made, and wherein additive is made up of according to the raw material of mass percent following:
Vinyl acetate content is the ethene-vinyl acetate/polyethylene octene elastomer 21% of 14%
Ethylene vinyl acetate thing 35% altogether
Polyolefin elastomer 31%
Linear low density polyethylene 8%
Ultra-high molecular weight polyethylene 5%.
By ethene-vinyl acetate/polyethylene octene elastomer that vinyl acetate content is 14%, ethylene vinyl acetate
Thing, polyolefin elastomer, linear low density polyethylene, ultra-high molecular weight polyethylene weigh according to the ratio of mass percent altogether
After, it is injected into fuse machine, agitating heating under the hot melting temperature of 200 DEG C, all it is fused into liquid, after extrusion, sets through supercooling
Make preparation for dropping low temperature, take mould to be pressed into tabular simultaneously, then be cut into graininess through cutter and i.e. obtain additive.Treat that product is natural
Cool down, dry, can pack, store for future use.In real work, add LDPE by the mass ratio that above-mentioned finished product is pressed 2:10
In, can have the waterproof membrane of the performances such as corrosion-resistant, cold-resistant, high temperature resistance, water proofing property.
Embodiment 3
Referring to Fig. 1, the embodiment of the present invention exists, a kind of corrosion-resistant cold-resistant high temperature resistant waterproof film, additive press with LDPE
The mass ratio of 2:7 is made, and wherein additive is made up of according to the raw material of mass percent following:
Vinyl acetate content is the ethene-vinyl acetate/polyethylene octene elastomer 15% of 14%
Ethylene vinyl acetate thing 40% altogether
Polyolefin elastomer 25%
Linear low density polyethylene 12%
Ultra-high molecular weight polyethylene 8%.
By ethene-vinyl acetate/polyethylene octene elastomer that vinyl acetate content is 14%, ethylene vinyl acetate
Thing, polyolefin elastomer, linear low density polyethylene, ultra-high molecular weight polyethylene weigh according to the ratio of mass percent altogether
After, it is injected into fuse machine, agitating heating under the hot melting temperature of 200 DEG C, all it is fused into liquid, after extrusion, sets through supercooling
Make preparation for dropping low temperature, take mould to be pressed into tabular simultaneously, then be cut into graininess through cutter and i.e. obtain additive.Treat that product is natural
Cool down, dry, can pack, store for future use.In real work, add LDPE by the mass ratio that above-mentioned finished product is pressed 2:7
In, can have the waterproof membrane of the performances such as corrosion-resistant, cold-resistant, high temperature resistance, water proofing property.
Embodiment 4
Referring to Fig. 1, the embodiment of the present invention exists, a kind of corrosion-resistant cold-resistant high temperature resistant waterproof film, additive press with LDPE
The mass ratio of 2:9 is made, and wherein additive is made up of according to the raw material of mass percent following:
Vinyl acetate content is the ethene-vinyl acetate/polyethylene octene elastomer 21% of 14%
Ethylene vinyl acetate thing 36% altogether
Polyolefin elastomer 31%
Linear low density polyethylene 8%
Ultra-high molecular weight polyethylene 4%.
By ethene-vinyl acetate/polyethylene octene elastomer that vinyl acetate content is 14%, ethylene vinyl acetate
Thing, polyolefin elastomer, linear low density polyethylene, ultra-high molecular weight polyethylene weigh according to the ratio of mass percent altogether
After, it is injected into fuse machine, agitating heating under the hot melting temperature of 200 DEG C, all it is fused into liquid, after extrusion, sets through supercooling
Make preparation for dropping low temperature, take mould to be pressed into tabular simultaneously, then be cut into graininess through cutter and i.e. obtain additive.Treat that product is natural
Cool down, dry, can pack, store for future use.In real work, add LDPE by the mass ratio that above-mentioned finished product is pressed 2:9
In, can have the waterproof membrane of the performances such as corrosion-resistant, cold-resistant, high temperature resistance, water proofing property.
Embodiment 5
Referring to Fig. 1, the embodiment of the present invention exists, a kind of corrosion-resistant cold-resistant high temperature resistant waterproof film, additive press with LDPE
The mass ratio of 2:8 is made, and wherein additive is made up of according to the raw material of mass percent following:
Vinyl acetate content is the ethene-vinyl acetate/polyethylene octene elastomer 18% of 14%
Ethylene vinyl acetate thing 38% altogether
Polyolefin elastomer 28%
Linear low density polyethylene 10%
Ultra-high molecular weight polyethylene 6%.
By ethene-vinyl acetate/polyethylene octene elastomer that vinyl acetate content is 14%, ethylene vinyl acetate
Thing, polyolefin elastomer, linear low density polyethylene, ultra-high molecular weight polyethylene weigh according to the ratio of mass percent altogether
After, it is injected into fuse machine, agitating heating under the hot melting temperature of 200 DEG C, all it is fused into liquid, after extrusion, sets through supercooling
Make preparation for dropping low temperature, take mould to be pressed into tabular simultaneously, then be cut into graininess through cutter and i.e. obtain additive.Treat that product is natural
Cool down, dry, can pack, store for future use.In real work, add LDPE by the mass ratio that above-mentioned finished product is pressed 2:8
In, can have the waterproof membrane of the performances such as corrosion-resistant, cold-resistant, high temperature resistance, water proofing property.
The production of the present invention is still main at LDPE, but in LDPE, additive, each raw material in additive are added in design
Different ratio ratio and produce mode and make thin film have different new features.According to the formula of additive product, by 5 kinds of additive raw materials
Being proportionally added in fuse machine, order of addition, regardless of front and back, is stirred to tremble and is uniformly blended into.Additive is used in mixed way with LDPE, thus
Make masking raw material have multiple new features, especially significantly improve in terms of the density of novel thin film finished product, degree of adhesion, degree of drawing
Change, be used in mixed way good with LDPE of additive.Membrane-film preparation process is consistent with former LDPE film production process.
The present invention is on former film making process, only in raw materials for production, adds neoteric additive, it is not necessary to increase
Add new production equipment and investment of production.Thin film is provided with ability and ultraviolet resistance, and not exposed solarization by sunlight is affected and change characteristic;
Thin film is prone to bonding, and bonding firmness is high, is difficult to tear after bonding;Thin film is the most brittle, has after repeatedly folding and still will not
Fracture, recover the characteristic of original flatness;Thin film has ageing resistance, can meet seriality and use more than 3 years Production requirements
Characteristic;Thin film increases wearability, newly increases hydrophobicity, can withstand flowing water long period of soaking and use characteristic.
Above the better embodiment of the present invention is explained in detail, but the present invention is not limited to above-mentioned embodiment party
Formula, in the ken that one skilled in the relevant art is possessed, it is also possible on the premise of without departing from present inventive concept
Various changes can be made.
Claims (5)
1. a corrosion-resistant cold-resistant high temperature resistant waterproof film, is made up by the mass ratio of 2:6-10 with LDPE of additive, and its feature exists
In, wherein additive is made up of according to the raw material of mass percent following:
Ethene-vinyl acetate/polyethylene octene elastomer 15-21%
Ethylene vinyl acetate thing 35-41% altogether
Polyolefin elastomer 25-31%
Linear low density polyethylene 8-12%
Ultra-high molecular weight polyethylene 4-8%.
Corrosion-resistant cold-resistant high temperature resistant waterproof film the most according to claim 1, it is characterised in that ethene-vinyl acetate/poly-second
In alkene octene elastomer, vinyl acetate content is 14%.
Corrosion-resistant cold-resistant high temperature resistant waterproof film the most according to claim 1, it is characterised in that additive and the quality of LDPE
Ratio is 2:8.
Corrosion-resistant cold-resistant high temperature resistant waterproof film the most according to claim 1, it is characterised in that additive by following according to matter
The raw material composition of amount percentage ratio:
Ethene-vinyl acetate/polyethylene octene elastomer 18%
Ethylene vinyl acetate thing 38% altogether
Polyolefin elastomer 28%
Linear low density polyethylene 10%
Ultra-high molecular weight polyethylene 6%.
5. according to the corrosion-resistant cold-resistant high temperature resistant waterproof film described in claim 1 or 4, it is characterised in that the preparation of additive
Cheng Shi: by ethene-vinyl acetate/polyethylene octene elastomer, ethylene vinyl acetate altogether thing, polyolefin elastomer, linear
After Low Density Polyethylene, ultra-high molecular weight polyethylene weigh according to the ratio of mass percent, it is injected into fuse machine, at 200 DEG C
Hot melting temperature under agitating heating, be all fused into liquid, after extrusion, through cooling device reduce temperature, take mould simultaneously
It is pressed into tabular, then is cut into graininess and i.e. obtains additive.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114957844A (en) * | 2022-05-06 | 2022-08-30 | 北京东方雨虹防水技术股份有限公司 | Resin master batch for modified flexible thermoplastic polyolefin waterproof roll, preparation method of resin master batch and waterproof roll prepared by using resin master batch |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105713275A (en) * | 2015-12-23 | 2016-06-29 | 青岛赛特镭科高新技术发展有限公司 | High-adhesion, high-strength and anti-seepage woven composite PE (polyethylene) film |
-
2016
- 2016-07-14 CN CN201610555588.6A patent/CN106188748A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105713275A (en) * | 2015-12-23 | 2016-06-29 | 青岛赛特镭科高新技术发展有限公司 | High-adhesion, high-strength and anti-seepage woven composite PE (polyethylene) film |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114957844A (en) * | 2022-05-06 | 2022-08-30 | 北京东方雨虹防水技术股份有限公司 | Resin master batch for modified flexible thermoplastic polyolefin waterproof roll, preparation method of resin master batch and waterproof roll prepared by using resin master batch |
CN114957844B (en) * | 2022-05-06 | 2023-12-19 | 北京东方雨虹防水技术股份有限公司 | Resin master batch for modified flexible thermoplastic polyolefin waterproof coiled material, preparation method thereof and waterproof coiled material prepared by using resin master batch |
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Application publication date: 20161207 |