CN106188727A - A kind of environmental protection waterproof material and preparation method thereof - Google Patents
A kind of environmental protection waterproof material and preparation method thereof Download PDFInfo
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- CN106188727A CN106188727A CN201610540735.2A CN201610540735A CN106188727A CN 106188727 A CN106188727 A CN 106188727A CN 201610540735 A CN201610540735 A CN 201610540735A CN 106188727 A CN106188727 A CN 106188727A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L21/00—Compositions of unspecified rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a kind of environmental protection waterproof material, including the composition of following parts by weight: synthetic rubber 40 50 parts, dihydrate gypsum 10 20 parts, 8 12 parts of polypropylene sodium, expanded perlite 36 parts, elastomeric propylene 6 10 parts, 10 13 parts of mineral oil, 35 parts of kieselguhr, triethanolamine 25 parts, 9 12 parts of diethylene glycol monoethyl ether acetic acid fat, polyethylene glycol diamines 14 parts, gamma decalactone 26 parts, anti-2 decenal 6 10 parts, 3 hydroxyl 2 metering systems 48 parts, cautious lattice acid 10 15 parts.This waterproof material environmental protection, health, environmentally safe, water resistance is excellent simultaneously, has preferable application prospect, and waterproof material is thick at compacting 80mm, the 500cm globule, and 1000h is waterproof, do not absorb water, and surface hydrophobic rate reaches 85 90%.
Description
Technical field
The invention belongs to field of waterproof materials, be specifically related to a kind of environmental protection waterproof material and preparation method thereof.
Background technology
Along with the industry developments such as the quickening of Urbanization in China, city hide building and real estate are swift and violent, the various modern times
The building short time like the mushrooms after rain changed is flooded with each big city.But, owing to people are unordered to the exploitation of natural resources and
The unsustainable utilization of fossil energy, result also in environmental problem of today, and this result in heavy rain, hail etc. in recent years the most indirectly
Boisterous generation.Therefore, in each big modern architecture, building engineering field is increasing to the demand of waterproof material, right
Its quality requirements is more and more higher.The particularly expansion type development of real-estate market, dwelling construction, roof maintenance and building repair etc.
Also one of critically important factor of waterproof material industry requirement growth is become.At present, both at home and abroad in various waterproof materials, employing
Be macromolecule be the material of base material, mainly have ethylene propylene diene rubber (EPDM), polrvinyl chloride (PVC), chlorinated polyethylene (CPE),
Chlorinated polyethylene one rubber blend, rubber blend and reclaimed rubber polyethylene (PE) geomembrane etc..Thermoplastic polyolefin-like (letter
Claim TPO, lower same) waterproof material, it is a kind of new material prevailing at US and European in recent years, and gradually occupies importantly
Position.But, described TPO material there is also some deficiency, such as: hot strength is relatively low, is typically only 20Mpa；Especially it becomes
Dimensional stability after product is poor, close to and more than 1.5%, accordingly, it would be desirable to be modified, to meet relevant waterproof material aspect
Needs.And use ethylene propylene diene rubber (EPDM), chlorinated polyethylene one rubber blend, rubber blend and reclaimed rubber to make
Waterproof material all also exist the most aging, the course of processing generally needed to be added carbon black reinforcement, so environmental pollution is serious.
Summary of the invention
The problem easily causing environmental pollution for water resistance present in prior art time good, the invention provides one
Planting environmental protection waterproof material and preparation method thereof, this waterproof material can either meet ecological requirements, meets people raw to green
The demand lived, has good water resistance simultaneously.
Technical scheme: a kind of environmental protection waterproof material, including the composition of following parts by weight: synthetic rubber 40-50 part,
Dihydrate gypsum 10-20 part, polypropylene sodium 8-12 part, expanded perlite 3-6 part, elastomeric propylene 6-10 part, mineral oil 10-13 part,
Kieselguhr 3-5 part, triethanolamine 2-5 part, diethylene glycol monoethyl ether acetic acid fat 9-12 part, polyethylene glycol diamines 1-4 part, third last of the ten Heavenly stems
Lactone 2-6 part, trans-2-decenal 6-10 part, 3-hydroxy-2-methyl propylene 4-8 part, cautious lattice acid 10-15 part.
Preferably, described synthetic rubber 42-46 part, dihydrate gypsum 13-18 part, polypropylene sodium 9-11 part, expanded perlite
4-6 part, elastomeric propylene 7-9 part, mineral oil 11-12 part, kieselguhr 4-5 part, triethanolamine 2-4 part, diethylene glycol monoethyl ether second
Acid fat 10-12 part, polyethylene glycol diamines 1-3 part, gamma decalactone 3-5 part, trans-2-decenal 7-9 part, 3-hydroxy-2-methyl
Propylene 5-7 part, cautious lattice acid 12-14 part.
Preferably, described synthetic rubber 44 parts, dihydrate gypsum 16 parts, 10 parts of polypropylene sodium, expanded perlite 5 parts, elasticity
Propylene 8 parts, 11.5 parts of mineral oil, 4.5 parts of kieselguhr, triethanolamine 3 parts, 11 parts of diethylene glycol monoethyl ether acetic acid fat, poly-second two
Hydro diamine 2 parts, gamma decalactone 4 parts, trans-2-decenal 8 parts, 3-hydroxy-2-methyl propylene 6 parts, cautious lattice acid 13 parts.
The preparation method of a kind of environmental protection waterproof material, comprises the steps:
S1: by synthetic rubber 40-50 part, dihydrate gypsum 10-20 part, polypropylene sodium 8-12 part, expanded perlite 3-6 part, elasticity
Propylene 6-10 part, mineral oil 10-13 part, diethylene glycol monoethyl ether acetic acid fat 9-12 part and cautious lattice acid 10-15 part are in temperature 30-40
With the rotating speed mix homogeneously of 600-1000rpm/min at DEG C, obtain mixture A；
S2: kieselguhr 3-5 part, triethanolamine 2-5 part, gamma decalactone 2-6 part, 3-hydroxy-2-methyl propylene 4-8 part are added
In step S1 in mixture A, at temperature 80-100 DEG C, continue stirring, mix homogeneously, obtain mixture B；
S3: polyethylene glycol diamines 1-4 part is added dropwise to mixture B described in step S2, dropping limit, limit is stirred, in temperature 100-
10-20min is reacted at 120 DEG C；Add trans-2-decenal 6-10 part, continue stirring 30-40min, i.e. can get described green
Environment-friendly waterproof material.
Preferably, temperature described in step S1 is 35 DEG C, and rotating speed is 800rpm/min.
Preferably, temperature described in step S2 is 90 DEG C.
Preferably, temperature described in step S3 is 112 DEG C, reacts 15min, stirs 35min.
Beneficial effect: the preparation method of environmental protection waterproof material of the present invention, by by synthetic rubber, expanded pearlite
The works such as agitated, the heating of material such as rock, elastomeric propylene, mineral oil, kieselguhr, triethanolamine and diethylene glycol monoethyl ether acetic acid fat
Skill is fully reacted and is obtained environmental protection waterproof material.This waterproof material environmental protection, health, environmentally safe, simultaneously water resistance
Excellent, there is preferable application prospect, waterproof material is thick at compacting 80mm, the 500cm globule, and 1000h is waterproof, do not absorb water, table
Face hydrophobic rate reaches 85-90%.
Detailed description of the invention
Embodiment 1
S1: by synthetic rubber 40 parts, dihydrate gypsum 10 parts, 8 parts of polypropylene sodium, expanded perlite 3 parts, elastomeric propylene 6 parts, mineral
The sour 10 parts of rotating speeds at temperature 30 DEG C with 600rpm/min of oil 10 parts, 9 parts of diethylene glycol monoethyl ether acetic acid fat and cautious lattice mix
Uniformly, mixture A is obtained；
S2: 3 parts of kieselguhr, triethanolamine 2 parts, gamma decalactone 2 parts, 3-hydroxy-2-methyl propylene 4 parts are added in step S1
In mixture A, at temperature 80 DEG C, continue stirring, mix homogeneously, obtain mixture B；
S3: polyethylene glycol diamines 1 part is added dropwise to mixture B described in step S2, dropping limit, limit is stirred, at temperature 100 DEG C
Reaction 10min；Add trans-2-decenal 6 parts, continue stirring 30min, i.e. can get described environmental protection waterproof material.
This waterproof material environmental protection, pollution-free, the 500cm globule thick at compacting 80mm, 1000h is waterproof, do not absorb water, surface
Hydrophobic rate reaches 85%.
Comparative example 1
S1: by synthetic rubber 40 parts, dihydrate gypsum 10 parts, 8 parts of polypropylene sodium, 10 parts of mineral oil and diethylene glycol monoethyl ether acetic acid
9 parts of fat with the rotating speed mix homogeneously of 600rpm/min, obtains mixture A at temperature 30 DEG C；
S2: added by 3-hydroxy-2-methyl propylene 4 parts in step S1 in mixture A, continues stirring, mixing at temperature 80 DEG C
Uniformly, mixture B is obtained；
S3: polyethylene glycol diamines 1 part is added dropwise to mixture B described in step S2, dropping limit, limit is stirred, at temperature 100 DEG C
Reaction 10min, i.e. can get waterproof material.
This waterproof material is thick at compacting 80mm, the 500cm globule, and 1000h occurs permeable, water suction phenomenon.
Embodiment 2
S1: by synthetic rubber 50 parts, dihydrate gypsum 20 parts, 12 parts of polypropylene sodium, expanded perlite 6 parts, elastomeric propylene 10 parts, ore deposit
Thing oil 13 parts, 12 parts of diethylene glycol monoethyl ether acetic acid fat and cautious lattice acid 15 parts at temperature 40 DEG C with the rotating speed of 1000rpm/min
Mix homogeneously, obtains mixture A；
S2: 5 parts of kieselguhr, triethanolamine 5 parts, gamma decalactone 6 parts, 3-hydroxy-2-methyl propylene 8 parts are added in step S1
In mixture A, at temperature 100 DEG C, continue stirring, mix homogeneously, obtain mixture B；
S3: polyethylene glycol diamines 4 parts is added dropwise to mixture B described in step S2, dropping limit, limit is stirred, at temperature 120 DEG C
Reaction 20min；Add trans-2-decenal 10 parts, continue stirring 40min, i.e. can get described environmental protection waterproof material.
This waterproof material environmental protection, pollution-free, the 500cm globule thick at compacting 80mm, 1000h is waterproof, do not absorb water, surface
Hydrophobic rate reaches 88%.
Comparative example 2
S1: by synthetic rubber 50 parts, dihydrate gypsum 20 parts, 12 parts of polypropylene sodium, 13 parts of mineral oil and diethylene glycol monoethyl ether second
12 parts of fat of acid with the rotating speed mix homogeneously of 1000rpm/min, obtains mixture A at temperature 40 DEG C；
S2: added by 3-hydroxy-2-methyl propylene 8 parts in step S1 in mixture A, continues stirring, mixing at temperature 100 DEG C
Uniformly, mixture B is obtained；
S3: polyethylene glycol diamines 4 parts is added dropwise to mixture B described in step S2, dropping limit, limit is stirred, at temperature 120 DEG C
Reaction 20min, i.e. can get waterproof material.
This waterproof material is thick at compacting 80mm, the 500cm globule, and 1000h occurs permeable, water suction phenomenon.
Embodiment 3
S1: by synthetic rubber 42 parts, dihydrate gypsum 13 parts, 9 parts of polypropylene sodium, expanded perlite 6 parts, elastomeric propylene 7 parts, mineral
The sour 12 parts of rotating speeds at temperature 30 DEG C with 800rpm/min of oil 11 parts, 10 parts of diethylene glycol monoethyl ether acetic acid fat and cautious lattice mix
Uniformly, mixture A is obtained；
S2: 4 parts of kieselguhr, triethanolamine 2 parts, gamma decalactone 3 parts, 3-hydroxy-2-methyl propylene 5 parts are added in step S1
In mixture A, at temperature 80 DEG C, continue stirring, mix homogeneously, obtain mixture B；
S3: polyethylene glycol diamines 1 part is added dropwise to mixture B described in step S2, dropping limit, limit is stirred, at temperature 110 DEG C
Reaction 15min；Add trans-2-decenal 7 parts, continue stirring 35min, i.e. can get described environmental protection waterproof material.
This waterproof material environmental protection, pollution-free, the 500cm globule thick at compacting 80mm, 1000h is waterproof, do not absorb water, surface
Hydrophobic rate reaches 87.6%.
Embodiment 4
S1: by synthetic rubber 46 parts, dihydrate gypsum 18 parts, 11 parts of polypropylene sodium, expanded perlite 4 parts, elastomeric propylene 9 parts, ore deposit
The sour 14 parts of rotating speeds at temperature 40 DEG C with 900rpm/min of thing oil 12 parts, 12 parts of diethylene glycol monoethyl ether acetic acid fat and cautious lattice mix
Close uniformly, obtain mixture A；
S2: 5 parts of kieselguhr, triethanolamine 4 parts, gamma decalactone 5 parts, 3-hydroxy-2-methyl propylene 7 parts are added in step S1
In mixture A, at temperature 100 DEG C, continue stirring, mix homogeneously, obtain mixture B；
S3: polyethylene glycol diamines 3 parts is added dropwise to mixture B described in step S2, dropping limit, limit is stirred, at temperature 120 DEG C
Reaction 10min；Add trans-2-decenal 9 parts, continue stirring 40min, i.e. can get described environmental protection waterproof material.
This waterproof material environmental protection, pollution-free, the 500cm globule thick at compacting 80mm, 1000h is waterproof, do not absorb water, surface
Hydrophobic rate reaches 88.1%.
Embodiment 5
S1: by synthetic rubber 44 parts, dihydrate gypsum 16 parts, 10 parts of polypropylene sodium, expanded perlite 5 parts, elastomeric propylene 8 parts, ore deposit
Thing oil 11.5 parts, 11 parts of diethylene glycol monoethyl ether acetic acid fat and cautious lattice acid 13 parts at temperature 35 DEG C with the rotating speed of 800rpm/min
Mix homogeneously, obtains mixture A；
S2: 4.5 parts of kieselguhr, triethanolamine 3 parts, gamma decalactone 4 parts, 3-hydroxy-2-methyl propylene 6 parts are added step S1
In middle mixture A, at temperature 90 DEG C, continue stirring, mix homogeneously, obtain mixture B；
S3: polyethylene glycol diamines 2 parts is added dropwise to mixture B described in step S2, dropping limit, limit is stirred, at temperature 112 DEG C
Reaction 15min；Add trans-2-decenal 8 parts, continue stirring 35min, i.e. can get described environmental protection waterproof material.
This waterproof material environmental protection, pollution-free, the 500cm globule thick at compacting 80mm, 1000h is waterproof, do not absorb water, surface
Hydrophobic rate reaches 90%.
Claims (7)
1. an environmental protection waterproof material, it is characterised in that include the composition of following parts by weight: synthetic rubber 40-50 part,
Dihydrate gypsum 10-20 part, polypropylene sodium 8-12 part, expanded perlite 3-6 part, elastomeric propylene 6-10 part, mineral oil 10-13 part,
Kieselguhr 3-5 part, triethanolamine 2-5 part, diethylene glycol monoethyl ether acetic acid fat 9-12 part, polyethylene glycol diamines 1-4 part, third last of the ten Heavenly stems
Lactone 2-6 part, trans-2-decenal 6-10 part, 3-hydroxy-2-methyl propylene 4-8 part, cautious lattice acid 10-15 part.
A kind of environmental protection waterproof material the most according to claim 1, it is characterised in that described synthetic rubber 42-46 part,
Dihydrate gypsum 13-18 part, polypropylene sodium 9-11 part, expanded perlite 4-6 part, elastomeric propylene 7-9 part, mineral oil 11-12 part, silicon
Diatomaceous earth 4-5 part, triethanolamine 2-4 part, diethylene glycol monoethyl ether acetic acid fat 10-12 part, polyethylene glycol diamines 1-3 part, third last of the ten Heavenly stems
Lactone 3-5 part, trans-2-decenal 7-9 part, 3-hydroxy-2-methyl propylene 5-7 part, cautious lattice acid 12-14 part.
A kind of environmental protection waterproof material the most according to claim 2, it is characterised in that described synthetic rubber 44 parts, two
Water stone cream 16 parts, 10 parts of polypropylene sodium, expanded perlite 5 parts, elastomeric propylene 8 parts, 11.5 parts of mineral oil, 4.5 parts of kieselguhr, three
Ethanolamine 3 parts, 11 parts of diethylene glycol monoethyl ether acetic acid fat, polyethylene glycol diamines 2 parts, gamma decalactone 4 parts, trans-2-decenal 8
Part, 3-hydroxy-2-methyl propylene 6 parts, cautious lattice acid 13 parts.
4. the preparation method of an environmental protection waterproof material, it is characterised in that comprise the steps:
S1: by synthetic rubber 40-50 part, dihydrate gypsum 10-20 part, polypropylene sodium 8-12 part, expanded perlite 3-6 part, elasticity
Propylene 6-10 part, mineral oil 10-13 part, diethylene glycol monoethyl ether acetic acid fat 9-12 part and cautious lattice acid 10-15 part are in temperature 30-40
With the rotating speed mix homogeneously of 600-1000rpm/min at DEG C, obtain mixture A；
S2: kieselguhr 3-5 part, triethanolamine 2-5 part, gamma decalactone 2-6 part, 3-hydroxy-2-methyl propylene 4-8 part are added
In step S1 in mixture A, at temperature 80-100 DEG C, continue stirring, mix homogeneously, obtain mixture B；
S3: polyethylene glycol diamines 1-4 part is added dropwise to mixture B described in step S2, dropping limit, limit is stirred, in temperature 100-
10-20min is reacted at 120 DEG C；Add trans-2-decenal 6-10 part, continue stirring 30-40min, i.e. can get described green
Environment-friendly waterproof material.
The preparation method of a kind of environmental protection waterproof material the most according to claim 4, it is characterised in that institute in step S1
Stating temperature is 35 DEG C, and rotating speed is 800rpm/min.
The preparation method of a kind of environmental protection waterproof material the most according to claim 4, it is characterised in that institute in step S2
Stating temperature is 90 DEG C.
The preparation method of a kind of environmental protection waterproof material the most according to claim 4, it is characterised in that institute in step S3
Stating temperature is 112 DEG C, reacts 15min, stirs 35min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610540735.2A CN106188727A (en) | 2016-07-12 | 2016-07-12 | A kind of environmental protection waterproof material and preparation method thereof |
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| CN201610540735.2A CN106188727A (en) | 2016-07-12 | 2016-07-12 | A kind of environmental protection waterproof material and preparation method thereof |
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| CN201610540735.2A Pending CN106188727A (en) | 2016-07-12 | 2016-07-12 | A kind of environmental protection waterproof material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2841130A1 (en) * | 2021-05-28 | 2021-07-07 | Univ Madrid Politecnica | LIGHTWEIGHT CONSTRUCTION MATERIAL FOR PREFABRICATED PRODUCTS (Machine-translation by Google Translate, not legally binding) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103649006A (en) * | 2011-07-01 | 2014-03-19 | 瓦克化学股份公司 | Gypsum-containing construction material compounds |
| CN104073047A (en) * | 2014-07-21 | 2014-10-01 | 湖州三利漆业有限公司 | Exterior wall putty |
| CN104277339A (en) * | 2014-10-27 | 2015-01-14 | 安徽锐视光电技术有限公司 | Water-resistant and anti-aging synthetic rubber for color sorters and preparation method thereof |
-
2016
- 2016-07-12 CN CN201610540735.2A patent/CN106188727A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103649006A (en) * | 2011-07-01 | 2014-03-19 | 瓦克化学股份公司 | Gypsum-containing construction material compounds |
| CN104073047A (en) * | 2014-07-21 | 2014-10-01 | 湖州三利漆业有限公司 | Exterior wall putty |
| CN104277339A (en) * | 2014-10-27 | 2015-01-14 | 安徽锐视光电技术有限公司 | Water-resistant and anti-aging synthetic rubber for color sorters and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2841130A1 (en) * | 2021-05-28 | 2021-07-07 | Univ Madrid Politecnica | LIGHTWEIGHT CONSTRUCTION MATERIAL FOR PREFABRICATED PRODUCTS (Machine-translation by Google Translate, not legally binding) |
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