CN106188388B - A kind of heat/electrical response performance gel photo chromic glass material - Google Patents
A kind of heat/electrical response performance gel photo chromic glass material Download PDFInfo
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- CN106188388B CN106188388B CN201610553349.7A CN201610553349A CN106188388B CN 106188388 B CN106188388 B CN 106188388B CN 201610553349 A CN201610553349 A CN 201610553349A CN 106188388 B CN106188388 B CN 106188388B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/10—Aqueous solvent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F226/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
- C08F226/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
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Abstract
The present invention relates to a kind of Pyroelectric response hydrogel photo chromic glass material based on Ionic Liquid Modified, it is by by thermal response monomer, ionic liquid, crosslinking agent, initiator and catalyst is soluble in water is polymerize to obtain；The thermal response monomer is the mixture of one or more compositions in N N-isopropylacrylamides, N N-tert-butyl acrylamides and N caprolactams, and the chemical structural formula of the ionic liquid isOr, R in formula1、R2And R3Independently of one another carbon atom number is 1 ~ 8 alkyl, X–For Cl–、Br–、I–、NO3 –、SO4 2–、PO4 3–Or OH–；The crosslinking agent is bi-vinyl viologen derivative.Heat, electrical response performance hydrogel photo chromic glass material can be formed in this way, to increase the response changed to environmental condition；Improve the temperature-controllable to Electrochromic device, stability and service life.
Description
Technical field
The present invention relates to a kind of gel photo chromic glass materials, and in particular to a kind of heat/electrical response performance gel photo chromic glass material
Material.
Background technology
Photo chromic glass material has the function of good reversible adjusting optical property, and it is suitable, energy saving intelligently to reach daylighting
The purpose of environmental protection, using more and more extensive in architectural glazings.Wherein, thermochromism and electrochromic material application study
It is relatively broad.Water-soluble environmentally protective off-color material is excellent because of its low with manufacturing cost, easy to operate, energy conservation and environmental protection etc.
Point undoubtedly studies the beneficial trial of environment-protecting intelligent window.Therefore it is good environmental-friendly to have multi-functional and operational stability
The research of type off-color material is concerned by people.
And existing photo chromic glass material, it is often confined to only be changed optical property by a kind of change of environment, simultaneously
Water-soluble off-color material is easy leakage, volatile, the problems such as influencing its operational stability and service life.Therefore exploitation multiple environment is rung
It is answering and be not easy the aqueous photo chromic glass material revealed, undoubtedly have a vast market foreground.
Invention content
A kind of heat/electrical response performance gel photo chromic glass material is provided the invention aims to overcome the deficiencies in the prior art
Material.
In order to achieve the above objectives, the technical solution adopted by the present invention is：A kind of heat/electrical response performance gel photo chromic glass material
Material, it is by by thermal response monomer, ionic liquid, crosslinking agent, initiator and catalyst is soluble in water is polymerize to obtain；
The thermal response monomer is in n-isopropyl acrylamide, N tert butyl acrylamide and N- caprolactams
One or more compositions mixture,
The chemical structural formula of the ionic liquid is、、、
、、、Or, R in formula1、R2、R3、R4、R5、R6、R7、R8、R9、
R10、R11And R12Independently of one another carbon atom number is 1 ~ 16 alkyl, X–For Cl–、Br–、I–、NO3 –、SO4 2–、PO4 3–、OH–Or
TFSI–；The crosslinking agent is bi-vinyl viologen derivative.
Optimally, the initiator is the mixed of one or more of ammonium persulfate, potassium peroxydisulfate and hydrogen peroxide composition
Close the mixture of one or more of object or water-soluble azo initiator composition.
Optimally, the catalyst is one or more in tetra class compound.
Optimally, the crosslinking agent is selected from
、、、、、、WithIn
One or more of compositions mixtures, Z in formula1、Z2、Z3、Z4、Z5、Z6、Z7And Z8Independently of one another carbon atom number is 1 ~ 12
Alkyl, Y–For Cl–、Br–、I–、NO3 –、SO4 2–、PO4 3–、OH–Or TFSI–。
Optimally, the molar ratio of the thermo-responsive monomer and the crosslinking agent is 100 ~ 50：1, the ionic liquid with
The mass ratio of water is 1：4~4：1.
Further, the mass ratio of the thermo-responsive monomer and the ionic liquid is 1：2~2：1.
Since above-mentioned technical proposal is used, the present invention has following advantages compared with prior art：The present invention is based on ions
Heat/electrical response performance gel photo chromic glass material of liquid modification, by poly- with Ionic Liquid Modified thermal response monomer and crosslinking agent
Polymer made of conjunction can form heat, electrical response performance gel photo chromic glass material, change to environmental condition to increase in this way
The response of change；Improve the temperature-controllable to Electrochromic device, stability and service life.
Description of the drawings
Attached drawing 1 is the LCST test charts that off-color material transmitance varies with temperature in embodiment 1-4；
Attached drawing 2 is off-color material cyclic voltammetric CV test charts in embodiment 1-4；
Attached drawing 3 is the LCST test charts that off-color material transmitance varies with temperature in embodiment 5-8；
Attached drawing 4 is off-color material cyclic voltammetric CV test charts in embodiment 5-8.
Specific implementation mode
A kind of heat/electrical response performance gel photo chromic glass material of the present invention, it is by by thermal response monomer, ionic liquid, friendship
Connection agent, initiator and catalyst is soluble in water is polymerize to obtain；The thermal response monomer is n-isopropyl acrylamide, uncle N-
The mixing of one or more compositions in the amide compound containing alkenyl such as butylacrylamide and N- caprolactams
Object,
The chemical structural formula of the ionic liquid is；；；
；；；Or, R in formula1、R2、R3、R4、R5、R6、R7、R8、R9、
R10、R11And R12Independently of one another carbon atom number is 1 ~ 16 alkyl, X–For Cl–、Br–、I–、NO3 –、SO4 2–、PO4 3–、OH–Or
TFSI–；The crosslinking agent is bi-vinyl viologen derivative.
The initiator is the mixture of one or more of ammonium persulfate, potassium peroxydisulfate and hydrogen peroxide composition, or
Person is the mixture of one or more of water-soluble azo initiator composition.The catalyst is selected from tetra class chemical combination
It is one or more in object, such as tetramethyl diethylamine, tetramethyl dibutyl amine, tetraethyl dibutyl amine.
The crosslinking agent is
、、、、、、WithIn
One or more of compositions mixtures, Z in formula1、Z2、Z3、Z4、Z5、Z6、Z7And Z8Independently of one another carbon atom number is 1 ~ 12
Alkyl, Y–For Cl–、Br–、I–、NO3 –、SO4 2–、PO4 3–、OH–Or TFSI–（Double trifluoromethanesulfonimide radical ions）.Its system
Preparation Method includes the following steps：（a）By 4,4'- bipyridyls and allyl bromide, bromoallylene, methallyl bromide, acryloyl chloride, metering system
Acyl chlorides, vinyl benzyl chloride, methyl ethylene benzyl chloride, to vinylbenzoyl chloride or to vinyl such as vinyl methyl chlorobenzoyl chlorides
Class compound is placed in acetonitrile solution reacts 5 ~ 10 hours under conditions of 40 ~ 65 DEG C, and stratification removes acetonitrile（4,4'- joins pyrrole
The molar ratio of pyridine and vinylic chemical compound is 1：2~1：3）；（b）By step（a）Product washed repeatedly with ether.
The molar ratio of the thermo-responsive monomer and the crosslinking agent is 100 ~ 50：1, the quality of the ionic liquid and water
Than being 1：4~4：1.Final thermal response monomer, crosslinking agent, initiator, catalyst, ionic liquid and water ratio be preferably 0.1g ~
0.20g：0.002~0.009g：0.002~0.009g：0.004~0.018g：0.2~0.8ml（Or 0.10 ~ 0.81g）：0.2~5ml.
The present invention also provides a kind of a kind of above-mentioned preparation method and application of heat/electrical response performance gel photo chromic glass material,
Specially：（1）The thermo-responsive monomer, crosslinking agent, initiator and catalyst are added to the mixed solvent of ionic liquid and water
In either will state thermo-responsive monomer, ionic liquid monomer, crosslinking agent, initiator and catalyst and be added to the water, it is equal to be formed
Even mixed solution；（2）The mixed solution is placed in the container of sealing, is carried out freely in inert gas atmosphere, 20 ~ 30 DEG C
Base polymerisation 20 ~ 50 minutes gel, be uniformly applied between two panels ito glass and be packaged.
Below in conjunction with attached drawing embodiment, invention is further explained.
Embodiment 1
The present embodiment provides a kind of heat/electrical response performance gel photo chromic glass material, its preparation method includes the following steps：
（a）By 0.25gN- N-isopropylacrylamides（2.2mmol）, 0.002g 4,4'- diallyl bipyridyls
（0.002mmol）, 0.002g ammonium persulfates（APS）With 0.004g tetramethylethylenediamines（TEMED）, it is dissolved in 0.8mL 1- methyl-
The in the mixed solvent of 3- butyl imidazoles bromide and 0.2mL water composition, concussion stirring become transparent and homogeneous solution；
（b）By step（a）Obtained transparent and homogeneous solution, is transferred in the peace times bottle of 3mL, is bubbled after ten minutes with nitrogen
It is placed at polyase 13 0 minute at 20 DEG C, resulting polymers gel is taken out from peace times bottle；
（c）Gel gel1-1 is uniformly applied between two panels ito glass and is packaged.
Pass through UV-vis（Ultraviolet-visible absorption spectroscopy）Test, CV (cyclic voltammetric) tests, the photo chromic glass material is in height
Milky is presented when 22 DEG C, is pellucidity less than 22 DEG C；Purple state is presented in 1.6V or so, voltage of decorporating can restore
Colorless state.Its LCST（Minimum consolute temperature）It it is 22 DEG C, reduction potential is in ± 1.6V（Transmitance varies with temperature and CV curves
It is as shown in Figure 1 and Figure 2 respectively）.
Embodiment 2
The present embodiment provides a kind of heat/electrical response performance gel photo chromic glass material, its preparation method includes the following steps：
（a）By 0.25gN- N-isopropylacrylamides（2.2mmol）, 0.002g 4,4'- diallyl bipyridyls
（0.002mmol）, 0.002g ammonium persulfates（APS）With 0.004g tetramethylethylenediamines（TEMED）, it is dissolved in 0.6mL 1- methyl-
In 3- butyl imidazoles bromide and 0.4mL water mixed solvents, concussion stirring becomes transparent and homogeneous solution；
（b）By step（a）Obtained transparent and homogeneous solution, is transferred in the peace times bottle of 3mL, and polyase 13 0 divides at 20 DEG C
Clock；Resulting polymers are taken out from peace times bottle.
（c）Gel gel1-2 is uniformly applied between two panels ito glass and is packaged.
Pass through UV-vis（Ultraviolet-visible absorption spectroscopy）Test, CV (cyclic voltammetric) tests, the photo chromic glass material is in height
In 25oMilky is presented when C, is pellucidity less than 25 DEG C；Purple state is presented in 1.6V or so, voltage of decorporating can restore
Colorless state.Its LCST is 25 DEG C, and reduction potential is in ± 1.6V（Transmitance varies with temperature as shown in Figure 1, Figure 2 with CV curves difference
It is shown）.
Embodiment 3
The present embodiment provides a kind of heat/electrical response performance gel photo chromic glass material, its preparation method includes the following steps：
（a）By 0.25gN- N-isopropylacrylamides（2.2mmol）, 0.002g 4,4'- diallyl bipyridyls
（0.002mmol）, 0.002g ammonium persulfates（APS）, 0.004g tetramethylethylenediamines（TEMED）, it is dissolved in 0.4mL 1- methyl -3-
In butyl imidazole bromide/0.6mL water mixed solvents, concussion stirring becomes transparent and homogeneous solution；
（b）By step（a）Obtained transparent and homogeneous solution, is transferred in the peace times bottle of 3mL, and polyase 13 0 divides at 20 DEG C
Clock；Resulting polymers gel is taken out from peace times bottle.
（c）Gel gel1-3 is uniformly applied between two panels ito glass and is packaged.
Pass through UV-vis（Ultraviolet-visible absorption spectroscopy）Test, CV (cyclic voltammetric) tests, the photo chromic glass material is in height
Milky is presented when 27 DEG C, is pellucidity less than 27 DEG C；Purple state is presented in 1.6V or so, voltage of decorporating can restore
Colorless state.Its LCST is 27 DEG C, and reduction potential is in ± 1.6V（Transmitance varies with temperature as shown in Figure 1, Figure 2 with CV curves difference
It is shown）.
Embodiment 4
The present embodiment provides a kind of heat/electrical response performance gel photo chromic glass material, its preparation method includes the following steps：
（a）By 0.25gN- N-isopropylacrylamides（2.2mmol）, 0.002g 4,4'- diallyl bipyridyls
（0.002mmol）, 0.002g ammonium persulfates（APS）, 0.004g tetramethylethylenediamines（TEMED）, it is dissolved in 0.2mL 1- methyl -3-
In butyl imidazole bromide/0.8mL water mixed solvents, concussion stirring becomes transparent and homogeneous solution；
（b）By step（a）Obtained transparent and homogeneous solution, is transferred in the peace times bottle of 3mL, and polyase 13 0 divides at 20 DEG C
Clock；Resulting polymers are taken out from peace times bottle.
（c）Gel gel1-4 is uniformly applied between two panels ito glass and is packaged.
Pass through UV-vis（Ultraviolet-visible absorption spectroscopy）Test, CV (cyclic voltammetric) tests, the photo chromic glass material is in height
Milky is presented when 30 DEG C, is pellucidity less than 30 DEG C；Purple state is presented in 1.6V or so, voltage of decorporating can restore
Colorless state.Its LCST is 30 DEG C, and reduction potential is in ± 1.6V（Transmitance varies with temperature as shown in Figure 1, Figure 2 with CV curves difference
It is shown）.
Embodiment 5
The present embodiment provides a kind of heat/electrical response performance gel photo chromic glass materials, it includes the following steps：
a）By 0.20gN- N-isopropylacrylamides（1.77mmol）, 0.1022g vinyl imidazoles（0.4mmol）、
0.003g 4,4'- diallyl bipyridyls（0.008mmol）, 0.003g ammonium persulfates（APS）With 0.006g tetramethyls second two
Amine（TEMED）, it is dissolved in 1.8mL water, concussion stirring becomes transparent and homogeneous solution；
（b）By step（a）Obtained transparent and homogeneous solution, is transferred in the peace times bottle of 3mL, and polyase 13 0 divides at 20 DEG C
Clock；Resulting polymers are taken out from peace times bottle.
（c）So that the gel gel2-1 is uniformly applied between two panels ito glass, and encapsulates.
Pass through UV-vis（Ultraviolet-visible absorption spectroscopy）Test, CV (cyclic voltammetric) tests, the photo chromic glass material is in height
Milky is presented when 35 DEG C, is pellucidity less than 35 DEG C；Purple state is presented in 1.6V or so, voltage of decorporating can restore
Colorless state.Its LCST is 35 DEG C, and reduction potential is in ± 1.6V（Transmitance is varied with temperature with CV curves respectively such as Fig. 3, Fig. 4
It is shown）.
Embodiment 6
The present embodiment provides a kind of heat/electrical response performance gel photo chromic glass materials, it includes the following steps：
a）By 0.20gN- N-isopropylacrylamides（1.77mmol）, 0.2726g vinyl imidazoles（1.18mmol）、
0.005g 4,4'- diallyl bipyridyls（0.01mmol）, 0.005g ammonium persulfates（APS）, 0.010g tetramethylethylenediamines
（TEMED）, it is dissolved in 2.8mL water, concussion stirring becomes transparent and homogeneous solution；
（b）By step（a）Obtained transparent and homogeneous solution, is transferred in the peace times bottle of 5mL, polyase 13 0 minute at 20 DEG C；
Resulting polymers are taken out from peace times bottle.
（c）So that the gel gel2-2 is uniformly applied between two panels ito glass, and encapsulates.
Pass through UV-vis（Ultraviolet-visible absorption spectroscopy）Test, CV (cyclic voltammetric) tests, the photo chromic glass material is in height
Milky is presented when 38 DEG C, is pellucidity less than 38 DEG C；Purple state is presented in 1.6V or so, voltage of decorporating can restore
Colorless state.Its LCST is 38 DEG C, and reduction potential is in ± 1.6V（Transmitance is varied with temperature with CV curves respectively such as Fig. 3, Fig. 4
It is shown）.
Embodiment 7
The present embodiment provides a kind of heat/electrical response performance gel photo chromic glass materials, it includes the following steps：
a）By 0.20gN- N-isopropylacrylamides（1.77mmol）, 0.61g vinyl imidazoles（2.64mmol）、
0.008g 4,4'- diallyl bipyridyls（0.02mmol）, 0.008g ammonium persulfates（APS）, 0.016g tetramethylethylenediamines
（TEMED）, it is dissolved in 4.9mL water, concussion stirring becomes transparent and homogeneous solution；
（b）By step（a）Obtained transparent and homogeneous solution, is transferred in the peace times bottle of 5mL, polyase 13 0 minute at 20 DEG C；
Resulting polymers are taken out from peace times bottle.
（c）So that the gel gel2-3 is uniformly applied between two panels ito glass, and encapsulates.
Pass through UV-vis（Ultraviolet-visible absorption spectroscopy）Test, CV (cyclic voltammetric) tests, the photo chromic glass material is in height
Milky is presented when 42 DEG C, is pellucidity less than 42 DEG C；Purple state is presented in 1.6V or so, voltage of decorporating can restore
Colorless state.Its LCST is 42 DEG C, and reduction potential is in ± 1.6V（Transmitance is varied with temperature with CV curves respectively such as Fig. 3, Fig. 4
It is shown）.
Embodiment 8
The present embodiment provides a kind of heat/electrical response performance gel photo chromic glass materials, it includes the following steps：
a）By 0.10gN- N-isopropylacrylamides（0.88mmol）, 0.8117g vinyl imidazoles（3.51mmol）、
0.009g 4,4'- diallyl bipyridyls（0.02mmol）, 0.009g ammonium persulfates（APS）, 0.018g tetramethylethylenediamines
（TEMED）, it is dissolved in 5.0mL water, concussion stirring becomes transparent and homogeneous solution；
（b）By step（a）Obtained transparent and homogeneous solution, is transferred in the peace times bottle of 5mL, polyase 13 0 minute at 20 DEG C；
Resulting polymers are taken out from peace times bottle.
（c）So that the gel gel2-4 is uniformly applied between two panels ito glass, and encapsulates.
Pass through UV-vis（Ultraviolet-visible absorption spectroscopy）Test, CV (cyclic voltammetric) tests, the photo chromic glass material is in height
Milky is presented when 46 DEG C, is pellucidity less than 46 DEG C；Purple state is presented in 1.6V or so, voltage of decorporating can restore
Colorless state.Its LCST is 46 DEG C, and reduction potential is in ± 1.6V（Transmitance is varied with temperature with CV curves respectively such as Fig. 3, Fig. 4
It is shown）.
Embodiment 9
The present embodiment provides a kind of heat/electrical response performance gel photo chromic glass material, preparation process and raw material and embodiment 1
In it is almost the same, unlike the structural formula of ionic liquid be：, crosslinking agent is。
Embodiment 10
The present embodiment provides a kind of heat/electrical response performance gel photo chromic glass material, preparation process and raw material and embodiment 1
In it is almost the same, unlike the structural formula of ionic liquid be：, crosslinking agent is。
Embodiment 11
The present embodiment provides a kind of heat/electrical response performance gel photo chromic glass material, preparation process and raw material and embodiment 1
In it is almost the same, unlike the structural formula of ionic liquid be：, crosslinking agent is。
Comparative example 1
The present embodiment provides a kind of glass material, preparation method with it is almost the same in embodiment 1, unlike：It is former
1- methyl -3- butyl imidazole bromides are not added in material.The LCST of finally obtained glass material（Minimum consolute temperature）It is 32 DEG C
It remains unchanged, intelligent according to actual needs can not adjust phase transition temperature LCST, i.e. its thermo-responsive behavior is single；Simultaneously should
Gel is almost non-conductive, does not have electrical response performance.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art
Scholar cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention, all according to the present invention
Equivalent change or modification made by Spirit Essence, should be covered by the protection scope of the present invention.
Claims (6)
1. a kind of heat/electrical response performance gel photo chromic glass material, it is characterised in that：It by by thermal response monomer, ionic liquid,
Crosslinking agent, initiator and catalyst is soluble in water is polymerize to obtain；
The thermal response monomer is one in n-isopropyl acrylamide, N tert butyl acrylamide and N- caprolactams
The mixture of kind or a variety of compositions,
The chemical structural formula of the ionic liquid is、、、 、、、Or, R in formula1、R2、R3、R4、R5、R6、R7、R8、R9、R10、
R11And R12Independently of one another carbon atom number is 1 ~ 16 alkyl, X–For Cl–、Br–、I–、NO3 –、SO4 2–、PO4 3–、OH–Or
TFSI–；The crosslinking agent is bi-vinyl viologen derivative.
2. the heat according to claim 1 based on Ionic Liquid Modified/electrical response performance gel photo chromic glass material, feature
It is：The initiator is the mixture of one or more of ammonium persulfate, potassium peroxydisulfate and hydrogen peroxide composition, either
The mixture of one or more of water-soluble azo initiator composition.
3. a kind of heat according to claim 1/electrical response performance gel photo chromic glass material, it is characterised in that：The catalysis
Agent is one or more in tetra class compound.
4. a kind of heat according to claim 1/electrical response performance gel photo chromic glass material, it is characterised in that：The crosslinking
Agent is selected from
、、、、、、WithIn one
Kind or several compositions mixture, Z in formula1、Z2、Z3、Z4、Z5、Z6、Z7And Z8Independently of one another carbon atom number is 1 ~ 12 alkane
Base, Y–For Cl–、Br–、I–、NO3 –、SO4 2–、PO4 3–、OH–Or TFSI–。
5. a kind of heat according to claim 1/electrical response performance gel photo chromic glass material, it is characterised in that：The heat is rung
The molar ratio of answering property monomer and the crosslinking agent is 100 ~ 50：1, the mass ratio of the ionic liquid and water is 1：4~4：1.
6. a kind of heat according to claim 5/electrical response performance gel photo chromic glass material, it is characterised in that：The heat is rung
The mass ratio of answering property monomer and the ionic liquid is 1：2~2：1.
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