CN106187051A - Nano titanium dioxide inorganic coating and preparation method thereof - Google Patents
Nano titanium dioxide inorganic coating and preparation method thereof Download PDFInfo
- Publication number
- CN106187051A CN106187051A CN201610544783.9A CN201610544783A CN106187051A CN 106187051 A CN106187051 A CN 106187051A CN 201610544783 A CN201610544783 A CN 201610544783A CN 106187051 A CN106187051 A CN 106187051A
- Authority
- CN
- China
- Prior art keywords
- nano titanium
- preparation
- titanium oxide
- titanium dioxide
- inorganic coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011248 coating agent Substances 0.000 title claims abstract description 43
- 238000000576 coating method Methods 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 28
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 title abstract description 10
- 239000002002 slurry Substances 0.000 claims abstract description 17
- 239000000945 filler Substances 0.000 claims abstract description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 72
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 40
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 22
- 239000010936 titanium Substances 0.000 claims description 17
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 16
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 12
- 229910052710 silicon Inorganic materials 0.000 claims description 12
- 239000010703 silicon Substances 0.000 claims description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 10
- 239000004408 titanium dioxide Substances 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- -1 alkyl silicon Chemical compound 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 6
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002518 antifoaming agent Substances 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000002131 composite material Substances 0.000 claims description 6
- 235000013312 flour Nutrition 0.000 claims description 6
- 238000000227 grinding Methods 0.000 claims description 6
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 claims description 6
- 229910052912 lithium silicate Inorganic materials 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 229910052700 potassium Inorganic materials 0.000 claims description 6
- 239000011591 potassium Substances 0.000 claims description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 6
- 239000000454 talc Substances 0.000 claims description 6
- 229910052623 talc Inorganic materials 0.000 claims description 6
- 235000012222 talc Nutrition 0.000 claims description 6
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 6
- 229910052882 wollastonite Inorganic materials 0.000 claims description 6
- 239000010456 wollastonite Substances 0.000 claims description 6
- JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical compound O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 claims description 5
- 229910021529 ammonia Inorganic materials 0.000 claims description 5
- 239000002994 raw material Substances 0.000 claims description 5
- DBTGFWMBFZBBEF-UHFFFAOYSA-N 2,4-dimethylpentane-2,4-diol Chemical compound CC(C)(O)CC(C)(C)O DBTGFWMBFZBBEF-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000001023 inorganic pigment Substances 0.000 claims description 3
- 238000003801 milling Methods 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000004576 sand Substances 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 6
- 238000001035 drying Methods 0.000 abstract description 3
- 238000001354 calcination Methods 0.000 abstract description 2
- 230000000593 degrading effect Effects 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 239000002253 acid Substances 0.000 description 4
- 239000008187 granular material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000010525 oxidative degradation reaction Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
The invention discloses a preparation method of nano titanium dioxide inorganic paint, which comprises the first step of preparing slurry containing nano titanium dioxide; the second step is the preparation of the filler; the third step is the preparation of the nano titanium dioxide inorganic coating. The invention also discloses a nano titanium dioxide inorganic coating. The nano titanium dioxide contained in the invention is thinner than the commonly purchased nano titanium dioxide, the function of degrading harmful gas is stronger, the process procedures of drying, calcining and crushing in the process of preparing the nano titanium dioxide are saved, and the cost of producing the nano titanium dioxide coating is reduced.
Description
Technical field
The present invention relates to a kind of inorganic coating adding nano titanium oxide and preparation method thereof, belong to building coating and prepare
Field.This coating is used for interior wall, has strong photocatalyst oxidative degradation ability to the harmful gas in indoor environment.For building
Build exterior wall, there is good self-cleaning property.
Background technology
Raising along with people's living standard.Need wall covering is given its performance of more environmental protection.To interior wall coating
For, in addition to general decoration performance, it is also desirable to interior wall coating can prestige that effectively many ornament materials discharge in decomposition chamber
The harmful gas of side of body health.For External Wall coating, in addition to protecting body of wall, it is also desirable to exterior coating has self-cleaning merit
Can, thus reduce the maintenance cost of building.Nano-titania particle is under energy is more than its semiconductor energy gap photon irradiation
Can produce hole, it has strong oxidative degradation ability for the pollutant in environment, is the excellent function material purifying ring mirror
Material.In recent years, coating use nano titanium oxide paid attention to widely.But, for current technology level, obtain
Obtain nanometer titanium dioxide titanium products the most expensive.Because nano titanium oxide is formed the most in the liquid phase, it is dried
During, granule can be reunited, and the reunion controlling granule becomes the key preparing nano titanium oxide success or failure.In order to control
Grain is reunited, and in addition to needs select effective dispersant, also must utilize special drying means, as being vacuum dried, with anhydrous
Ethanol seasoning.The use of these drying process measures all can be greatly improved the production cost of nano titanium oxide.Pin of the present invention
Inorganic coating is used in the slurry the characteristic of nano titanium oxide, it is proposed that the preparation side of brand-new nanometer titania coating
Case.
Summary of the invention
The present invention is to solve the problem that the nano titanium oxide granule being dried, in calcination is easily reunited, thus raw
Output low cost, be suitable in inorganic coating use nano titanium oxide.To the nano titanium oxide used in coating, propose
A kind of brand-new preparation method.
The nano titanium oxide inorganic coating that the present invention provides, it is by the preparation of raw material of following weight percents content
Become:
KP1 3-10%, lithium silicate 1-5%, Ludox 15-40%, butyl glycol ether 0 2-1%,
PTPP (potassium tripolyphosphate) 0 5-1 5%, silicon polyether-modified composite anti-foaming agent 0 3-1 5%,
Alkyl silicon levelling agent [model BCD-512] 0 2-1 2%, aluminium-magnesium silicate 0 3-1%, hydroxyethyl cellulose 0 3-1%, different
Thiazolinone 0 05-0 15%, silica flour 5-15%, calcined kaolin 2-12%, barium sulfate 1-10%,
Wollastonite 5-15%, Talcum 2-10%, titanium dioxide 0 15-15%, inorganic pigment 0-10%,
Nano titanium oxide 0 5-1 5%, deionized water 15-30%.
Invention additionally discloses a kind of nano titanium oxide inorganic preparation method for coating, step is as follows:
Step 1: containing the preparation of nano titania slurry
Hydrothermal reaction kettle adds deionized water, is stirred continuously down and adds Ti (S04)2In this hydrothermal reaction kettle, and by Ti
(S04)2The concentration of solution is configured to 02 ~ 08 mol/L；Add ammonia regulation pH value to 01 ~ 05；
After sealing described reactor, reactor being heated to 150 ° of C ~ 220 ° C, after reaching hydrothermal temperature, hydro-thermal is anti-
6 ~ 18 hours should be proceeded to；After described hydro-thermal reaction terminates, stop heating, described hydrothermal reaction kettle is cooled to room temperature, then adds
Enter Ba (0H)2, obtain the slurry containing nano titanium oxide；
Ti (the S0 wherein put into4)2、Ba(0H)2And the ratio row between the nano titanium oxide three produced in described slurry
For:
Ti(S04)2 : Ba (0H)2: nano titanium oxide=120: 85 6: 40.
Step 2: the preparation of filler
Arrange by the recipe ratio of inorganic coating and weigh: silica flour, calcined kaolin, barium sulfate, wollastonite, Talcum, titanium dioxide, nothing
Machine pigment, deionized water and PTPP (potassium tripolyphosphate) also join in ball milling, ball milling 10 hours, and 200 mesh sieves crossed by slurry, enter sand milling
Machine extra-fine grinding, is ground to fineness of materials D500 5-2 micron, it is thus achieved that filler；
Step 3: the preparation of inorganic coating
Arrange by the recipe ratio of inorganic coating and weigh: KP1, lithium silicate, Ludox, butyl glycol ether, silicon are polyether-modified
Composite anti-foaming agent, alkyl silicon levelling agent, aluminium-magnesium silicate, hydroxyethyl cellulose, isothiazolone and described containing nanometer titanium dioxide
The slurry of titanium also joins homogenizer, is subsequently adding the described filler after grinding, first high-speed stirred 1-3 hour, then low speed
Stir 1-3 hour, i.e. complete the preparation of inorganic coating.
The preparation method of the present invention uses Ti (SO4)2As raw material, control pH value, under hydrothermal conditions, shape by ammonia
Become nano titanium oxide.This nano titanium oxide is present in acid solution after being formed, and its acid is with SO3 =With Ba (OH)2In carrying out
With, in the solution in addition to nano titanium oxide, also form BaSO4, this composition is the utilizable a kind of filler of body of wall coating
Composition.Above-mentioned product is added directly in coating use, coating just obtains high performance nano titanium oxide.This
In the nano titanium oxide that obtains thinner than the general nano titanium oxide bought, degraded harmful gas with better function, save
The technical process being dried, being calcined, pulverize during preparing nano titanium oxide, reduces and produces nanometer titania coating
Cost.
Detailed description of the invention
The nano titanium oxide inorganic coating that the present invention proposes, it is by the preparation of raw material of following weight percents content
Become:
KP1 3-10%, lithium silicate 1-5%, Ludox 15-40%, butyl glycol ether 0 2-1%,
PTPP (potassium tripolyphosphate) 0 5-1 5%, silicon polyether-modified composite anti-foaming agent 0 3-1 5%,
Alkyl silicon levelling agent [model BCD-512] 0 2-1 2%, aluminium-magnesium silicate 0 3-1%, hydroxyethyl cellulose 0 3-1%,
Isothiazolone 0 05-0 15%, silica flour 5-15%, calcined kaolin 2-12%, barium sulfate 1-10%,
Wollastonite 5-15%, Talcum 2-10%, titanium dioxide 0 15-15%, inorganic pigment 0-10%,
Nano titanium oxide 0 5-1 5%, deionized water 15-30%.
According to different needs, the inorganic coating that the present invention proposes can also select to use according to following formula table.
When after the formula of selected nano titanium oxide inorganic coating, its preparation method, can carry out as follows:
Step 1: containing the preparation of nano titania slurry
In hydrothermal reaction kettle, add deionized water, be stirred continuously down the Ti (S0 adding 120 kg4)2In this hydro-thermal reaction
In still, and by Ti (S04)2The concentration of solution is configured to 02 ~ 08 mol/L；Add ammonia regulation pH value to 01 ~ 05；
After sealing described reactor, reactor being heated to 150 ° of C ~ 220 ° C, after reaching hydrothermal temperature, hydro-thermal is anti-
6 ~ 18 hours should be proceeded to；
After described hydro-thermal reaction terminates, stop heating, described hydrothermal reaction kettle is cooled to room temperature, adds the Ba of 85 6 kilograms
(0H)2, obtain the slurry containing 40 kilograms of nano titanium oxides；
As required, the Ti (S0 of input4)2、Ba(0H)2And between the nano titanium oxide three produced in described slurry
Ratio is classified as: Ti (S04)2: Ba (0H)2: nano titanium oxide=120: 85 6:40.
Step 2: the preparation of filler
Arrange by the recipe ratio of inorganic coating and weigh: silica flour, calcined kaolin, barium sulfate, wollastonite, Talcum, titanium dioxide, nothing
Machine pigment, deionized water and PTPP (potassium tripolyphosphate) also join in ball milling, ball milling 10 hours, and 200 mesh sieves crossed by slurry, enter sand milling
Machine extra-fine grinding, is ground to fineness of materials D500 5-2 micron, it is thus achieved that filler；
Step 3: the preparation of inorganic coating
Arrange by the recipe ratio of inorganic coating and weigh: KP1, lithium silicate, Ludox, butyl glycol ether, silicon are polyether-modified
Composite anti-foaming agent, alkyl silicon levelling agent [model BCD-512], aluminium-magnesium silicate, hydroxyethyl cellulose, isothiazolone and described
The slurry containing nano titanium oxide and join homogenizer, be subsequently adding the described filler after grinding, first high-speed stirred
1-3 hour, then stirring at low speed 1-3 hour, i.e. complete the preparation of inorganic coating.
The present invention uses Ti (SO4)2As raw material, control pH value by ammonia, under hydrothermal conditions, form nano-silica
Change titanium.This nano titanium oxide is present in acid solution after being formed, and its acid is with SO3 =With Ba (OH)2It is neutralized, in the solution
In addition to nano titanium oxide, also form BaSO4, this composition is the utilizable a kind of filler composition of body of wall coating.By above-mentioned
Product be added directly in coating use, coating just obtains high performance nano titanium oxide.Here obtain receives
Rice titanium dioxide is thinner than the general nano titanium oxide bought, degraded harmful gas with better function, eliminates preparation nanometer
The technical process be dried in titanium dioxide process, be calcined, pulverized, reduces the cost producing nanometer titania coating.
Claims (2)
1. a nano titanium oxide inorganic preparation method for coating, step is as follows:
Step 1: containing the preparation of nano titania slurry
Hydrothermal reaction kettle adds deionized water, is stirred continuously down and adds Ti (S04)2In this hydrothermal reaction kettle, and by Ti
(S04)2The concentration of solution is configured to 02 ~ 08 mol/L；Add ammonia regulation pH value to 01 ~ 05；
After sealing described reactor, reactor being heated to 150 ° of C ~ 220 ° C, after reaching hydrothermal temperature, hydro-thermal is anti-
6 ~ 18 hours should be proceeded to；
After described hydro-thermal reaction terminates, stop heating, described hydrothermal reaction kettle is cooled to room temperature, adds Ba (0H)2, obtain
Slurry containing nano titanium oxide；
Ti (the S0 wherein put into4)2、Ba(0H)2And the ratio row between the nano titanium oxide three produced in described slurry
For:
Ti(S04)2: Ba (0H)2: nano titanium oxide=120: 85 6:40；
Step 2: the preparation of filler
Arrange by the recipe ratio of inorganic coating and weigh: silica flour, calcined kaolin, barium sulfate, wollastonite, Talcum, titanium dioxide, nothing
Machine pigment, deionized water and PTPP (potassium tripolyphosphate) also join in ball milling, ball milling 10 hours, and 200 mesh sieves crossed by slurry, enter sand milling
Machine extra-fine grinding, is ground to fineness of materials D500 5-2 micron, it is thus achieved that filler；
Step 3: the preparation of inorganic coating
Arrange by the recipe ratio of inorganic coating and weigh: KP1, lithium silicate, Ludox, butyl glycol ether, silicon are polyether-modified
Composite anti-foaming agent, alkyl silicon levelling agent, aluminium-magnesium silicate, hydroxyethyl cellulose, isothiazolone and described containing nanometer titanium dioxide
The slurry of titanium also joins homogenizer, is subsequently adding the described filler after grinding, first high-speed stirred 1-3 hour, then low speed
Stir 1-3 hour, i.e. complete the preparation of inorganic coating.
2. nano titanium oxide inorganic coating as claimed in claim 1, it is by the preparation of raw material of following weight percents content
Form:
KP1 3-10%, lithium silicate 1-5%, Ludox 15-40%, butyl glycol ether 0 2-1%,
PTPP (potassium tripolyphosphate) 0 5-1 5%, silicon polyether-modified composite anti-foaming agent 0 3-1 5%, alkyl silicon levelling agent 0 2-1 2%,
Aluminium-magnesium silicate 0 3-1%, hydroxyethyl cellulose 0 3-1%, isothiazolone 0 05-0 15%, silica flour 5-15%,
Calcined kaolin 2-12%, barium sulfate 1-10%, wollastonite 5-15%, Talcum 2-10%, titanium dioxide 0 15-15%,
Inorganic pigment 0-10%, nano titanium oxide 0 5-1 5%, deionized water 15-30%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610544783.9A CN106187051B (en) | 2016-07-12 | 2016-07-12 | Nano titanium dioxide inorganic coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610544783.9A CN106187051B (en) | 2016-07-12 | 2016-07-12 | Nano titanium dioxide inorganic coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106187051A true CN106187051A (en) | 2016-12-07 |
| CN106187051B CN106187051B (en) | 2018-04-24 |
Family
ID=57476764
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610544783.9A Expired - Fee Related CN106187051B (en) | 2016-07-12 | 2016-07-12 | Nano titanium dioxide inorganic coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106187051B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107033710A (en) * | 2017-05-17 | 2017-08-11 | 合肥绿洁环保科技有限公司 | A kind of preparation method of breathable environment-protective fluorocarbon coating |
| CN108483897A (en) * | 2018-04-09 | 2018-09-04 | 徐冬 | A kind of preparation method of ceramic pigment nano-powder |
| CN113004727A (en) * | 2021-04-06 | 2021-06-22 | 上海淞叶新材料有限公司 | Transparent inorganic coating and preparation method thereof |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1357583A (en) * | 2001-12-26 | 2002-07-10 | 曾庆衿 | Heat resistant and wear resistant power-saving metallic paint |
| CN1415550A (en) * | 2002-12-12 | 2003-05-07 | 中山大学 | Method for preparing nano titanium dioxide in anatase type from fluid of hydrothermal crystallized titanium sulfate |
| CN1709987A (en) * | 2005-07-08 | 2005-12-21 | 清华大学 | Preparation of titanium dioxide nano water-based coating by alkali peptication process |
| JP2007090313A (en) * | 2005-09-26 | 2007-04-12 | Ichiro Moriya | Inexpensive high active photocatalyst excellent in photolysis of ethylene and its production method |
| CN101428853A (en) * | 2008-12-05 | 2009-05-13 | 江苏大学 | Method for producing pyromelane type nano-TiO2 powder with Ti(SO4)2 hydrothemal method |
| CN102533032A (en) * | 2010-12-10 | 2012-07-04 | 深圳市嘉达高科产业发展有限公司 | Automatic indoor humidity adjusting coating |
| CN105642262A (en) * | 2016-02-04 | 2016-06-08 | 梁书齐 | Two-dimensional-layered titanium-dioxide nanometer photocatalytic material and preparing method |
-
2016
- 2016-07-12 CN CN201610544783.9A patent/CN106187051B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1357583A (en) * | 2001-12-26 | 2002-07-10 | 曾庆衿 | Heat resistant and wear resistant power-saving metallic paint |
| CN1415550A (en) * | 2002-12-12 | 2003-05-07 | 中山大学 | Method for preparing nano titanium dioxide in anatase type from fluid of hydrothermal crystallized titanium sulfate |
| CN1709987A (en) * | 2005-07-08 | 2005-12-21 | 清华大学 | Preparation of titanium dioxide nano water-based coating by alkali peptication process |
| JP2007090313A (en) * | 2005-09-26 | 2007-04-12 | Ichiro Moriya | Inexpensive high active photocatalyst excellent in photolysis of ethylene and its production method |
| CN101428853A (en) * | 2008-12-05 | 2009-05-13 | 江苏大学 | Method for producing pyromelane type nano-TiO2 powder with Ti(SO4)2 hydrothemal method |
| CN102533032A (en) * | 2010-12-10 | 2012-07-04 | 深圳市嘉达高科产业发展有限公司 | Automatic indoor humidity adjusting coating |
| CN105642262A (en) * | 2016-02-04 | 2016-06-08 | 梁书齐 | Two-dimensional-layered titanium-dioxide nanometer photocatalytic material and preparing method |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107033710A (en) * | 2017-05-17 | 2017-08-11 | 合肥绿洁环保科技有限公司 | A kind of preparation method of breathable environment-protective fluorocarbon coating |
| CN108483897A (en) * | 2018-04-09 | 2018-09-04 | 徐冬 | A kind of preparation method of ceramic pigment nano-powder |
| CN108483897B (en) * | 2018-04-09 | 2020-08-25 | 佛山意达加精密陶瓷科技有限公司 | Preparation method of ceramic pigment nano powder |
| CN113004727A (en) * | 2021-04-06 | 2021-06-22 | 上海淞叶新材料有限公司 | Transparent inorganic coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106187051B (en) | 2018-04-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104772158B (en) | Preparation method of WO3/C3N4 mixed photocatalyst | |
| JP5209861B2 (en) | Titanium dioxide white pigment and method for producing the same | |
| CN105542516B (en) | One kind can reflect near infrared ray yellow uitramarine and preparation method thereof | |
| CN102863020B (en) | Preparation method of hollow titanium dioxide material | |
| CN106187051B (en) | Nano titanium dioxide inorganic coating and preparation method thereof | |
| CN104785349A (en) | Efficient preparation method for nano-scale solid powder | |
| CN105217676B (en) | Titania aerogel with nanometer sheet and nano-porous structure and preparation method thereof | |
| Li et al. | Synthesis of hollow TiO2@ SiO2 spheres via a recycling template method for solar heat protection coating | |
| CN107760063B (en) | Bismuth yellow hybrid pigment doped with 1:1 type silicate mineral and preparation method thereof | |
| CN102153318A (en) | Method for preparing photo-catalytic cement-based material and method for preparing photocatalyst | |
| Sadeghi-Niaraki et al. | Preparation of (Fe, Cr) 2O3@ TiO2 cool pigments for energy saving applications | |
| CN106554645A (en) | A kind of dry-type ecological interior wall coating based on conch meal | |
| CN106732724A (en) | A kind of N doping TiO2The preparation method of hollow nano-material | |
| CN107892334A (en) | The preparation method of nanometer alum acid iron | |
| CN106000390A (en) | Method for preparation of Bi2O3/BiTaO4 composite photocatalyst by molten salt technique | |
| CN101829590A (en) | Preparation method of easily-recovered nitrogen-doped core-shell ZnO/TiO2 visible light photocatalyst | |
| CN106629840B (en) | A kind of truncated cylinder shape octahedron Detitanium-ore-type TiO2Preparation method | |
| CN102070325A (en) | Far infrared ceramic material and preparation method thereof | |
| CN103691472A (en) | Preparation method of nitrogen-doped titanium dioxide mesoporous visible light photocatalyst | |
| CN104151871B (en) | A kind of porous surface modified nano-titanium dioxide and preparation method thereof | |
| CN107325586B (en) | A kind of method of soft mechanical force and chemical assisted Solid-state method titania type titanium yellow ceramic pigment | |
| CN104151868B (en) | Modified nano-titanium dioxide that a kind of photocatalysis effect strengthens and preparation method thereof | |
| CN103553124B (en) | Method for preparing blue titanium dioxide | |
| CN104772147B (en) | Photocatalyst responding to ultraviolet light and visible light and preparation method thereof | |
| CN104258894B (en) | There is visible light-responded metallic plate supported titanium2photocatalyst and preparation and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180424 Termination date: 20180712 |