CN106186842A - A kind of novel environmental-friendly construction material - Google Patents
A kind of novel environmental-friendly construction material Download PDFInfo
- Publication number
- CN106186842A CN106186842A CN201610518779.5A CN201610518779A CN106186842A CN 106186842 A CN106186842 A CN 106186842A CN 201610518779 A CN201610518779 A CN 201610518779A CN 106186842 A CN106186842 A CN 106186842A
- Authority
- CN
- China
- Prior art keywords
- parts
- construction material
- friendly construction
- environmental
- novel environmental
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/28—Polysaccharides or derivatives thereof
- C04B26/285—Cellulose or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/20—Polyamides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of novel environmental-friendly construction material, following components raw material is comprised: kieselguhr 100~150 parts, sugarcane marrow 100~120 parts, metakaolin 50~60 parts according to ratio of weight and number, wood powder 10~12 parts, natural environmental-protective resin 5~15 parts, polyglyceryl methacrylate 0.5~2.5 parts, ammonium hydrogen phosphate 1~1.5 parts, modifying agent 3~5 parts, stabilizer 2~5 parts, dispersant 1~3 parts, thickening agent 2~5 parts and adhesive 2~3 parts.The raw materials used relatively environmental protection of environmental-friendly construction material of the present invention, harmful material or gas is the most outwards discharged when interior wall or exterior wall finishing, and, because the raw material used can be recycled mostly, will not become building waste in actual mechanical process, major part is recyclable carries out secondary utilization;Further low cost of the present invention, the simplest and the most direct, convenient.
Description
Technical field
The present invention relates to a kind of construction material, particularly to a kind of novel environmental-friendly construction material.
Background technology
Along with expanding economy, people are more and more higher to the requirement of quality of life, not only require building materials high-quality, have length
The construction material in life-span, and the feature of environmental protection of construction material is had higher requirement, the performance of building be there has also been higher wanting
Asking, along with the tail gas pollution that increases of automobile is consequently increased and the increasing of ultraviolet, pollution increases, and the environmental consciousness of people is more come
The strongest, and traditional building materials Performance comparision is single, requires weak to the feature of environmental protection of building materials.
Particular for the requirement of interior decoration, the air pollution that indoor decorating and refurnishing materials brings to indoor is produced the most therewith
Raw.Interior decoration market survey result shows, the house decorative material that there are poisonous gas accounts for 68%, containing volatile organic compound
Thing is up to kind more than 300, wherein maximum to the injury of human body with formaldehyde, toluene, ammonia and TVOC.These materials or material are to human body
Respiratory system, cardiovascular system and nervous system produce bigger harm.And the indoor decorating and refurnishing materials of environment-friendly type is few at present, tool
The building material price having environmental protection is expensive, finishing operation complexity, therefore, needs a kind of not only environmental protection, low cost badly but also is beneficial to construction
Construction material.
The information being disclosed in this background section is merely intended to increase the understanding of the general background to the present invention, and should not
When being considered to recognize or imply in any form this information structure prior art well known to persons skilled in the art.
Summary of the invention
It is an object of the invention to provide a kind of novel environmental-friendly construction material, thus overcome environmental protection Building wood in prior art
Expect shortcoming expensive, that cost is high, construction is complicated.
For achieving the above object, the technical scheme that the present invention provides is as follows:
A kind of novel environmental-friendly construction material, comprises following components raw material according to ratio of weight and number: kieselguhr 100~150 parts,
Sugarcane marrow 100~120 parts, metakaolin 50~60 parts, wood powder 10~12 parts, natural environmental-protective resin 5~15 parts, polyglyceryl methyl
Acrylate 0.5~2.5 parts, ammonium hydrogen phosphate 1~1.5 parts, modifying agent 3~5 parts, stabilizer 2~5 parts, dispersant 1~3 parts, increase
Thick dose 2~5 parts and adhesive 2~3 parts.
Wherein, described modifying agent comprises following components raw material according to ratio of weight and number: methoxy cinnamic acid ethyl methyl ester
10~20 parts, glycerol 5~7 parts, poly-hydroxy stearic acid 1~2 parts and ergotin 0.1~0.3 part.
Wherein, described stabilizer is lauryl alcohol, selenic ester polysaccharide, calcium stearate, potassium hydroxide, high glutinous carboxymethyl cellulose
One in element (HV-CMC), hydroxyethyl ether cellulose (HEC) or polyacrylamide (HPAM).
Wherein, described dispersant is polyethylene glycol 200 or PEG400.
Wherein, described thickening agent be hydroxypropyl methyl cellulose (HPMC), polyvinyl alcohol graft copolymerized calcium acrylate copolymer,
One in trimethylolpropane allyl ether, tetraethyl orthosilicate, beta-diketon complexation aluminum or styrene resin.
Wherein, described adhesive is the one in cellulose nitrate ester, polyester, polyamide or polyacrylate.
A kind of above-mentioned novel environmental-friendly construction material, its preparation method comprises following operating procedure:
(1) weigh required each component raw material: kieselguhr 100~150 parts, sugarcane marrow 100~120 parts, metakaolin 50~
60 parts, wood powder 10~12 parts, natural environmental-protective resin 5~15 parts, polyglyceryl methacrylate 0.5~2.5 parts, ammonium hydrogen phosphate
1~1.5 part, modifying agent 3~5 parts, stabilizer 2~5 parts, dispersant 1~3 parts, thickening agent 2~5 parts and adhesive 2~3 parts, so
After by other raw material mixing and stirring in addition to modifying agent;
(2) in step (1), mixing gained material adds modifying agent, stir, to obtain final product.
Wherein, above-mentioned prepare gained novel environmental-friendly construction material use time, can use after mixing homogeneously with water.Water mixes
After, must use in 2 hours completely.
Compared with prior art, there is advantages that
The raw materials used relatively environmental protection of environmental-friendly construction material of the present invention, the most outwards discharges human body when interior wall or exterior wall finishing
Harmful material or gas, and, because the raw material used can be recycled mostly, will not become in actual mechanical process and build
Building refuse, major part is recyclable carries out secondary utilization;Further low cost of the present invention, the simplest and the most direct, convenient.
Detailed description of the invention
It is described in detail below in conjunction with detailed description of the invention, it is to be understood that protection scope of the present invention is not by concrete
The restriction of embodiment.In embodiment, natural environmental-protective resin uses rosin resin.
Embodiment 1
A kind of above-mentioned novel environmental-friendly construction material, its preparation method operating procedure is as follows:
(1) required each component raw material is weighed according to ratio of weight and number: 100 parts of kieselguhr, 100 parts of sugarcane marrow, metakaolin
50 parts, wood powder 10 parts, rosin resin 5 parts, polyglyceryl methacrylate 0.5 part, ammonium hydrogen phosphate 1 part, modifying agent 3 parts, surely
Determine agent 2 parts, dispersant 1 part, thickening agent 2 parts and adhesive 2 parts, then by equal for other raw material mix and blends in addition to modifying agent
Even;Wherein, each component raw material of modifying agent: methoxy cinnamic acid ethyl methyl ester 10 parts, glycerol 5 parts, poly-hydroxy stearic acid 1 part and wheat
0.1 part of angle alkali;Stabilizer is lauryl alcohol;Dispersant is polyethylene glycol 200;Thickening agent is hydroxypropyl methyl cellulose (HPMC);
Adhesive is cellulose nitrate ester;
(2) in step (1), mixing gained material adds modifying agent, stir, to obtain final product.
When preparing the use of gained novel environmental-friendly construction material, can use after mixing homogeneously with water.After water mixing, 2 hours
In must use completely.
Embodiment 2
A kind of above-mentioned novel environmental-friendly construction material, its preparation method operating procedure is as follows:
(1) required each component raw material is weighed according to ratio of weight and number: 125 parts of kieselguhr, 110 parts of sugarcane marrow, metakaolin
55 parts, wood powder 11 parts, rosin resin 10 parts, lantana extract 7 parts, polyglyceryl methacrylate 1.5 parts, ammonium hydrogen phosphate
1.3 parts, modifying agent 4 parts, stabilizer 3.5 parts, dispersant 2 parts, thickening agent 3.5 parts, adhesive 2.5 parts, then will be except modifying agent
Other raw material mixing and stirring in addition;Wherein, each component raw material of modifying agent: methoxy cinnamic acid ethyl methyl ester 15 parts, sweet
Oil 6 parts, poly-hydroxy stearic acid 1.5 parts and ergotin 0.2 part;Stabilizer is calcium stearate;Dispersant is PEG400;Increase
Thick dose is trimethylolpropane allyl ether;Adhesive is polyamide;Wherein, lantana extract is the leaf taking lantana
Become 0.3~0.7:1 mass ratio mixing with ethanol, 85 DEG C of decompressions are distilled 0.5 hour and get final product;
(2) in step (1), mixing gained material adds modifying agent, stir, to obtain final product.
When preparing the use of gained novel environmental-friendly construction material, can use after mixing homogeneously with water.After water mixing, 2 hours
In must use completely.
Embodiment 3
A kind of above-mentioned novel environmental-friendly construction material, its preparation method operating procedure is as follows:
(1) required each component raw material is weighed according to ratio of weight and number: 150 parts of kieselguhr, 120 parts of sugarcane marrow, metakaolin
60 parts, wood powder 12 parts, rosin resin 15 parts, polyglyceryl methacrylate 2.5 parts, ammonium hydrogen phosphate 1.5 parts, modifying agent 5 parts,
Stabilizer 5 parts, dispersant 3 parts, thickening agent 5 parts, adhesive 3 parts, then by other raw material mix and blends in addition to modifying agent
Uniformly;Wherein, each component raw material of modifying agent: methoxy cinnamic acid ethyl methyl ester 20 parts, glycerol 7 parts, poly-hydroxy stearic acid 2 parts and
Ergotin 0.3 part;Stabilizer is potassium hydroxide;Dispersant is polyethylene glycol 200;Thickening agent is beta-diketon complexation aluminum;Adhesive
For polyester;
(2) in step (1), mixing gained material adds modifying agent, stir, to obtain final product.
When preparing the use of gained novel environmental-friendly construction material, can use after mixing homogeneously with water.After water mixing, 2 hours
In must use completely.
Comparative example 1
Regular convention formula construction material:
Following component raw material is weighed: 12 parts of kieselguhr, perlite 5 parts, epoxy resin 13 parts, ore deposit in units of parts by weight
Thing insulation material 9 parts, 4 parts of Gypsum Fibrosum, MTES 7 parts, Merlon 5 parts, magnesium oxide 3 parts, acrylate 8 parts,
Colophonium 17 parts, portland cement 42 parts, poly-milling is by 12 parts and 7 parts of phenolic resin, by above-mentioned each component raw material mixing and stirring,
Obtain construction material.
Detection
Above-described embodiment 1, embodiment 2 and comparative example 1 are prepared gained construction material, is applied in the sky of 1 cubic metre
Between on interior wall, smearing thickness is 5~10mm, detects that the formaldehyde in this space, benzene,toluene,xylene etc. are poisonous to be had the most respectively
The content of pest matter.
The detection of content of formaldehyde:
Utilize climate box method measure scribble 1 cubic metre of space of each construction material in discharge when reaching steady statue in air
Formaldehyde amount, draw such as data in table 1.
The detection of benzene,toluene,xylene:
Utilize the content of gas chromatography detection benzene,toluene,xylene, with Activated charcoal tube to scribbling the 1 of each construction material
Cubic meter space in air in gather benzene,toluene,xylene, sample introduction after carbon disulfide desorption, through chromatographic column separate, hydrogen flame from
Sonization detector detects the content of the benzene,toluene,xylene in this space, and data are as shown in table 1.
Table 1
By data in table 1 it can be seen that environmental-friendly construction material indoor environment PARA FORMALDEHYDE PRILLS(91,95) of the present invention, benzene,toluene,xylene are examined
Surveying, meet " Indoor Air Quality standards ", particularly in embodiment 2, the lantana extract of interpolation can effectively equalize formula
Middle poisonous and harmful substance in use discharges so that formula more environmental protection, gentleness, be suitable for, for construction material, Ge Xianghan
Amount detection numerical value is the most much smaller, uses safer, environmental protection.
The aforementioned description to the specific illustrative embodiment of the present invention illustrates that and the purpose of illustration.These describe
It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to above-mentioned teaching, can much change
And change.The purpose selected exemplary embodiment and describe is to explain that the certain principles of the present invention and reality thereof should
With so that those skilled in the art be capable of and utilize the present invention various different exemplary and
Various different selections and change.The scope of the present invention is intended to be limited by claims and equivalents thereof.
Claims (7)
1. a novel environmental-friendly construction material, it is characterised in that comprise following components raw material according to ratio of weight and number: kieselguhr
100~150 parts, sugarcane marrow 100~120 parts, metakaolin 50~60 parts, wood powder 10~12 parts, natural environmental-protective resin 5~15 parts,
Polyglyceryl methacrylate 0.5~2.5 parts, ammonium hydrogen phosphate 1~1.5 parts, modifying agent 3~5 parts, stabilizer 2~5 parts, point
Powder 1~3 parts, thickening agent 2~5 parts and adhesive 2~3 parts.
Novel environmental-friendly construction material the most according to claim 1, it is characterised in that described modifying agent is according to ratio of weight and number
Comprise following components raw material: methoxy cinnamic acid ethyl methyl ester 10~20 parts, glycerol 5~7 parts, poly-hydroxy stearic acid 1~2 parts and
Ergotin 0.1~0.3 part.
Novel environmental-friendly construction material the most according to claim 1, it is characterised in that: described stabilizer is lauryl alcohol, selenic acid
One in polysaccharide ester, calcium stearate, potassium hydroxide, high glutinous carboxymethyl cellulose, hydroxyethyl ether cellulose or polyacrylamide.
Novel environmental-friendly construction material the most according to claim 1, it is characterised in that: described dispersant is polyethylene glycol 200
Or PEG400.
Novel environmental-friendly construction material the most according to claim 1, it is characterised in that: described thickening agent is that hydroxypropyl methyl is fine
Tie up calcium acrylate copolymer plain, polyvinyl alcohol graft copolymerized, trimethylolpropane allyl ether, tetraethyl orthosilicate, beta-diketon complexation
One in aluminum or styrene resin.
Novel environmental-friendly construction material the most according to claim 1, it is characterised in that: described adhesive is celluloid
One in ester, polyester, polyamide or polyacrylate.
7. a right subgroup beats up the preparation method of the novel environmental-friendly construction material described in sulfur, it is characterised in that comprise following behaviour
Make step:
(1) required each component raw material is weighed according to ratio of weight and number: kieselguhr 100~150 parts, sugarcane marrow 100~120 parts, partially
Kaolin 50~60 parts, wood powder 10~12 parts, natural environmental-protective resin 5~15 parts, polyglyceryl methacrylate 0.5~2.5
Part, ammonium hydrogen phosphate 1~1.5 parts, modifying agent 3~5 parts, stabilizer 2~5 parts, dispersant 1~3 parts, thickening agent 2~5 parts and gluing
Agent 2~3 parts, then by other raw material mixing and stirring in addition to modifying agent;
(2) in step (1), mixing gained material adds modifying agent, stir, to obtain final product.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610518779.5A CN106186842A (en) | 2016-07-01 | 2016-07-01 | A kind of novel environmental-friendly construction material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610518779.5A CN106186842A (en) | 2016-07-01 | 2016-07-01 | A kind of novel environmental-friendly construction material |
Publications (1)
Publication Number | Publication Date |
---|---|
CN106186842A true CN106186842A (en) | 2016-12-07 |
Family
ID=57465438
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610518779.5A Pending CN106186842A (en) | 2016-07-01 | 2016-07-01 | A kind of novel environmental-friendly construction material |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106186842A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114560666A (en) * | 2022-04-11 | 2022-05-31 | 广东大禹工程技术有限公司 | Environment-friendly durable building material |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101538139A (en) * | 2009-04-16 | 2009-09-23 | 同济大学 | Dry-mixed mortar with waste stone dust in stone mining and processing plant as aggregate and filler |
CN101891430A (en) * | 2010-06-28 | 2010-11-24 | 上海衡峰氟碳材料有限公司 | Flexible cement component, flexible cement product and preparation method and use thereof |
CN102838330A (en) * | 2012-09-04 | 2012-12-26 | 同济大学 | Self-clean self-purification cement-based facing material and production method thereof |
CN104211439A (en) * | 2014-09-11 | 2014-12-17 | 岳阳东方雨虹防水技术有限责任公司 | Highly-environment-friendly and anti-settling type waterproof mortar |
CN104891894A (en) * | 2015-05-14 | 2015-09-09 | 吉林省嘉鹏集团有限公司 | Fast-setting high-strength hydraulic material and preparation method thereof |
CA2691670C (en) * | 2007-07-05 | 2016-10-11 | United States Gypsum Company | Lightweight cementitious compositions and building products and methods for making same |
-
2016
- 2016-07-01 CN CN201610518779.5A patent/CN106186842A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2691670C (en) * | 2007-07-05 | 2016-10-11 | United States Gypsum Company | Lightweight cementitious compositions and building products and methods for making same |
CN101538139A (en) * | 2009-04-16 | 2009-09-23 | 同济大学 | Dry-mixed mortar with waste stone dust in stone mining and processing plant as aggregate and filler |
CN101891430A (en) * | 2010-06-28 | 2010-11-24 | 上海衡峰氟碳材料有限公司 | Flexible cement component, flexible cement product and preparation method and use thereof |
CN102838330A (en) * | 2012-09-04 | 2012-12-26 | 同济大学 | Self-clean self-purification cement-based facing material and production method thereof |
CN104211439A (en) * | 2014-09-11 | 2014-12-17 | 岳阳东方雨虹防水技术有限责任公司 | Highly-environment-friendly and anti-settling type waterproof mortar |
CN104891894A (en) * | 2015-05-14 | 2015-09-09 | 吉林省嘉鹏集团有限公司 | Fast-setting high-strength hydraulic material and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
卢艳光: "《人造板及其制品质量监督检验实务》", 31 July 2017 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114560666A (en) * | 2022-04-11 | 2022-05-31 | 广东大禹工程技术有限公司 | Environment-friendly durable building material |
CN114560666B (en) * | 2022-04-11 | 2023-07-04 | 广东大禹工程技术有限公司 | Environment-friendly durable building material |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101974168B (en) | Multipurpose cooked rubber powder for architectural ornaments and preparation method thereof | |
WO2010104981A3 (en) | Deuterium isobaric tag reagents for quantitative analysis | |
CN102399350B (en) | Aqueous epoxy acrylate resin and preparation method thereof | |
CN107936767A (en) | A kind of bi-component water dispersible epoxy primer coating and preparation method thereof | |
CN107540486B (en) | Hydrogen storage type emulsified seismic charge and seismic bomb using same | |
CN106186842A (en) | A kind of novel environmental-friendly construction material | |
CN106187022A (en) | A kind of energy-conserving and environment-protective green construction material | |
CN109575878A (en) | One kind being based on dregs of beans adhesive tannin based cross-linker and its application | |
CN104356974A (en) | Environment-friendly building adhesive | |
CN108147692B (en) | Cement grinding aid and preparation method thereof | |
CN103450732A (en) | Natural vegetable glue putty | |
CN106145856A (en) | A kind of high-strength environmental-friendly construction material | |
CN106243815B (en) | It is a kind of that there is the additive for improving metope alignment material workability | |
CN106187023A (en) | A kind of novel energy-saving environment-friendly construction material | |
WO2008070945A3 (en) | Process for obtaining nitrocellulose, process for nitrating wood cellulose to obtain nitrocellulose, and nitrocellulose obtained from such process | |
CN101045711B (en) | Production method of hexamethoxy methyl melamine resin | |
CN103881055A (en) | Glycidyl ether modified water-borne epoxy resin and preparation method thereof | |
CN111607278B (en) | Application of putty powder and fermented tea powder as putty powder retarder | |
CN105482667B (en) | One kind is except formaldehyde solid powder paint and preparation method thereof | |
CN111849236A (en) | Environment-friendly anti-cracking antiviral flexible putty powder and preparation method thereof | |
CN110144039B (en) | Preparation method of multifunctional water-based epoxy resin curing agent | |
CN109880548B (en) | Environment-friendly building glue and preparation method thereof | |
CN103497704B (en) | A kind of chloroprene rubber adhesive agent and preparation method thereof | |
CN105086894A (en) | Biological wood adhesive and preparation method therefor | |
CN103304353B (en) | A kind of glue for fireworks and firecrackers paper lead-in wire and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161207 |