CN106186682A - A kind of glass for building purposes material and preparation method thereof - Google Patents
A kind of glass for building purposes material and preparation method thereof Download PDFInfo
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- CN106186682A CN106186682A CN201610530747.7A CN201610530747A CN106186682A CN 106186682 A CN106186682 A CN 106186682A CN 201610530747 A CN201610530747 A CN 201610530747A CN 106186682 A CN106186682 A CN 106186682A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B19/00—Other methods of shaping glass
- C03B19/02—Other methods of shaping glass by casting molten glass, e.g. injection moulding
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
- C03B25/00—Annealing glass products
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- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Manufacturing & Machinery (AREA)
- Glass Compositions (AREA)
- Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
Abstract
The invention discloses a kind of glass for building purposes material and preparation method thereof, including zirconium dioxide 35 55 parts, Disulfatozirconic acid. 20 25 parts, silicon dioxide 40 50 parts, cobalt sulfide 15 25 parts, titanium dioxide 8 15 parts, chitin fiber 6 10 parts, boron oxide 5 10 parts, 24 parts of aluminosilicate magnesium, rutile 48 parts, hydrogen oxide nickel oxide 39 parts, aluminium sesquioxide 48 parts.The present invention uses zirconium dioxide, Disulfatozirconic acid., silicon dioxide, cobalt sulfide, titanium dioxide, chitin fiber, boron oxide, aluminosilicate magnesium, rutile, hydrogen oxide nickel oxide, aluminium sesquioxide, ferric oxide nanometer particle and calcium oxide to carry out the proportioning combination of science, the pyroceram prepared has good resistance to elevated temperatures, the transparency, hardness.
Description
Technical field
The present invention relates to technical field of glass materials, be specifically related to a kind of glass for building purposes material and preparation method thereof.
Background technology
Glass can be divided into oxide glass and nonoxide glass by its main component, and it is mainly composed of SiO2, SiO2
It is widely used in glass, casting, pottery and refractory material, smelting duriron, flux for metallurgy, metallurgy, building, chemical industry, plastics, rubber
The industrial circle such as glue, abrasive material.
Along with the development of industry, improving constantly of science and technology, glass has been not only simple glass, but tool
There is multiple property, the glass of various performance requirement can be met.
Pyroceram is also referred to as high temp glass, is that glass can reach under the conditions of certain temperature, medium and pressure rating
To or bear corresponding temperature resistance to relevant pressure grade and the special glass of Applicable media, usually use high-purity siliceous ore deposit
Material, refines through high temperature and forms, and it the most still can hold the original permeability of glass and transparency.
High temp glass has the features such as transparency high, high temperature resistant, Heat stability is good, stable chemical performance, is that industry is automatic
Change the key element that production line is indispensable..
Summary of the invention
For solving the problems referred to above, the invention provides a kind of glass for building purposes material and preparation method thereof.
For achieving the above object, the technical scheme that the present invention takes is:
A kind of glass for building purposes material and preparation method thereof, makes including by the component of following weight portion: zirconium dioxide 35-55
Part, Disulfatozirconic acid. 20-25 part, silicon dioxide 40-50 part, cobalt sulfide 15-25 part, titanium dioxide 8-15 part, chitin fiber 6-10
Part, boron oxide 5-10 part, aluminosilicate magnesium 2-4 part, rutile 4-8 part, hydrogen oxide nickel oxide 3-9 part, aluminium sesquioxide 4-8 part.
Further, described component also includes ferric oxide nanometer particle 1-1.5 part.
Further, described component also includes calcium oxide 1.5-2.5 part.
Further, the preparation method of a kind of glass for building purposes material, comprise the steps:
S1, weigh zirconium dioxide 35-55 part, Disulfatozirconic acid. 20-25 part, silicon dioxide 40-50 part, cobalt sulfide 15-25 part, titanium dioxide
Titanium 8-15 part, chitin fiber 6-10 part, boron oxide 5-10 part, aluminosilicate magnesium 2-4 part, rutile 4-8 part, hydrogen oxide nickel oxide
3-9 part, aluminium sesquioxide 4-8 part, ferric oxide nanometer particle 1-1.5 part and calcium oxide 1.5-2.5 part join in blender,
It is uniformly mixed with 100-300r/min stir speed (S.S.)；
S2, the material after step S1 mix homogeneously is joined in corundum crucible, first heating 800-900 DEG C, rise again after stopping 2h
High-temperature, to 1350-1500 DEG C, is incubated 6-10 hour；
In S3, step S2, molding on preheated mould poured into by vitreous humour；
S4, by glass after the molding of step S3, first return goods to being incubated 1.5h when 800～1000 DEG C from temperature, secondary stage annealing is extremely
It is incubated 2h when 350 DEG C, is cooled to room temperature, is prepared into glass material.
Further, a kind of glass for building purposes material, make including by the component of following weight portion: zirconium dioxide 36-50
Part, Disulfatozirconic acid. 21-24 part, silicon dioxide 45-58 part, cobalt sulfide 18-20 part, titanium dioxide 9-14 part, chitin fiber 7-9
Part, boron oxide 6-9 part, aluminosilicate magnesium 3-4 part, rutile 5-7 part, hydrogen oxide nickel oxide 4-8 part, aluminium sesquioxide 5-7 part, oxygen
Change iron nano-particle 1.1-1.4 part and calcium oxide 1.6-2.0 part.
Further, a kind of glass for building purposes material, make including by the component of following weight portion: zirconium dioxide 39 parts,
Disulfatozirconic acid. 23 parts, silicon dioxide 48 parts, cobalt sulfide 19 parts, titanium dioxide 11 parts, chitin fiber 8 parts, boron oxide 6 parts, sial
4 parts of magnesium of acid, rutile 6 parts, hydrogen oxide nickel oxide 5 parts, aluminium sesquioxide 6 parts, ferric oxide nanometer particle 1.3 parts and calcium oxide
1.8 part.
The present invention use zirconium dioxide, Disulfatozirconic acid., silicon dioxide, cobalt sulfide, titanium dioxide, chitin fiber, boron oxide,
Aluminosilicate magnesium, rutile, hydrogen oxide nickel oxide, aluminium sesquioxide, ferric oxide nanometer particle and calcium oxide carry out the proportioning of science
Combination, the pyroceram prepared has good resistance to elevated temperatures, the transparency, hardness.
The glass material of the present invention place at 500 DEG C after 22h to 65h glass without softening, metaboly, have good
Good thermostability；Its preparation method is simple, it is easy to industrialized production.
The high strength glass material of the present invention does not adds the harmful elements such as As, Sb, have low thermal expansion, high temperature resistant,
The technical characteristics such as high intensity, high rigidity, high chemical stability.
The preparation method of the present invention is simple, and the processing temperature overcoming the zirconium dioxide glass of routine in preparation process is high
Problem, energy-conserving and environment-protective, be suitable to industrialized production.
Detailed description of the invention
In order to make objects and advantages of the present invention clearer, below in conjunction with embodiment, the present invention is carried out the most in detail
Explanation.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
The present invention includes being made up of the component of following weight portion: zirconium dioxide 35-55 part, Disulfatozirconic acid. 20-25 part, titanium dioxide
Silicon 40-50 part, cobalt sulfide 15-25 part, titanium dioxide 8-15 part, chitin fiber 6-10 part, boron oxide 5-10 part, aluminosilicate magnesium
2-4 part, rutile 4-8 part, hydrogen oxide nickel oxide 3-9 part, aluminium sesquioxide 4-8 part.
Described component also includes ferric oxide nanometer particle 1-1.5 part.
Described component also includes calcium oxide 1.5-2.5 part.
The preparation method of a kind of glass for building purposes material, comprises the steps:
S1, weigh zirconium dioxide 35-55 part, Disulfatozirconic acid. 20-25 part, silicon dioxide 40-50 part, cobalt sulfide 15-25 part, titanium dioxide
Titanium 8-15 part, chitin fiber 6-10 part, boron oxide 5-10 part, aluminosilicate magnesium 2-4 part, rutile 4-8 part, hydrogen oxide nickel oxide
3-9 part, aluminium sesquioxide 4-8 part, ferric oxide nanometer particle 1-1.5 part and calcium oxide 1.5-2.5 part join in blender,
It is uniformly mixed with 100-300r/min stir speed (S.S.)；
S2, the material after step S1 mix homogeneously is joined in corundum crucible, first heating 800-900 DEG C, rise again after stopping 2h
High-temperature, to 1350-1500 DEG C, is incubated 6-10 hour；
In S3, step S2, molding on preheated mould poured into by vitreous humour；
S4, by glass after the molding of step S3, first return goods to being incubated 1.5h when 800～1000 DEG C from temperature, secondary stage annealing is extremely
It is incubated 2h when 350 DEG C, is cooled to room temperature, is prepared into glass material.
A kind of glass for building purposes material, makes including by the component of following weight portion: zirconium dioxide 36-50 part, Disulfatozirconic acid.
21-24 part, silicon dioxide 45-58 part, cobalt sulfide 18-20 part, titanium dioxide 9-14 part, chitin fiber 7-9 part, boron oxide 6-
9 parts, aluminosilicate magnesium 3-4 part, rutile 5-7 part, hydrogen oxide nickel oxide 4-8 part, aluminium sesquioxide 5-7 part, ferric oxide nano
Grain 1.1-1.4 part and calcium oxide 1.6-2.0 part.
Further, a kind of glass for building purposes material, make including by the component of following weight portion: zirconium dioxide 39 parts,
Disulfatozirconic acid. 23 parts, silicon dioxide 48 parts, cobalt sulfide 19 parts, titanium dioxide 11 parts, chitin fiber 8 parts, boron oxide 6 parts, sial
4 parts of magnesium of acid, rutile 6 parts, hydrogen oxide nickel oxide 5 parts, aluminium sesquioxide 6 parts, ferric oxide nanometer particle 1.3 parts and calcium oxide
1.8 part.
Embodiment 1:
S1, weigh zirconium dioxide 39 parts, Disulfatozirconic acid. 23 parts, silicon dioxide 48 parts, cobalt sulfide 19 parts, titanium dioxide according to weight portion
11 parts, chitin fiber 8 parts, boron oxide 6 parts, 4 parts of aluminosilicate magnesium, rutile 6 parts, hydrogen oxide nickel oxide 5 parts, aluminium sesquioxide
6 parts, ferric oxide nanometer particle 1.4 parts and calcium oxide 1.7 parts join in blender, mixed with the stirring of 200r/min stir speed (S.S.)
Close uniformly；
S2, the material after step S1 mix homogeneously is joined in corundum crucible, first heating 800 DEG C, after stopping 2h, rise high temperature again
Degree, to 1350 DEG C, is incubated 6 hours；
In S3, step S2, molding on preheated mould poured into by vitreous humour；
S4, by glass after the molding of step S3, first return goods to being incubated 1.5h when 800 DEG C, during secondary stage annealing to 350 DEG C from temperature
Insulation 2h, is cooled to room temperature, is prepared into glass material.
Embodiment 2:
S1, weigh zirconium dioxide 55 parts, Disulfatozirconic acid. 25 parts, silicon dioxide 50 parts, cobalt sulfide 25 parts, titanium dioxide according to weight portion
15 parts, chitin fiber 10 parts, boron oxide 10 parts, 4 parts of aluminosilicate magnesium, rutile 8 parts, hydrogen oxide nickel oxide 9 parts, three oxidation two
8 parts of aluminum, ferric oxide nanometer particle 1.5 parts and calcium oxide 1.5 parts join in blender, mixed with the stirring of 300r/min stir speed (S.S.)
Close uniformly；
S2, the material after step S1 mix homogeneously is joined in corundum crucible, first heating 900 DEG C, after stopping 2h, rise high temperature again
Degree, to 1350 DEG C, is incubated 6 hours；
In S3, step S2, molding on preheated mould poured into by vitreous humour；
S4, by glass after the molding of step S3, first return goods to being incubated 1.5h, secondary stage annealing to 350 DEG C when 1000 DEG C from temperature
Shi Baowen 2h, is cooled to room temperature, is prepared into glass material.
Embodiment 3:
S1, weigh zirconium dioxide 35 parts, Disulfatozirconic acid. 20 parts, silicon dioxide 40 parts, cobalt sulfide 15 parts, titanium dioxide according to weight portion
8 parts, chitin fiber 6 parts, boron oxide 5 parts, 2 parts of aluminosilicate magnesium, rutile 4 parts, hydrogen oxide nickel oxide 3 parts, aluminium sesquioxide 4
Part, ferric oxide nanometer particle 1.2 parts and calcium oxide 1.9 parts join in blender, with the stirring mixing of 200r/min stir speed (S.S.)
Uniformly；
S2, the material after step S1 mix homogeneously is joined in corundum crucible, first heating 850 DEG C, after stopping 2h, rise high temperature again
Degree, to 1400 DEG C, is incubated 8 hours；
In S3, step S2, molding on preheated mould poured into by vitreous humour；
S4, by glass after the molding of step S3, first return goods to being incubated 1.5h when 900 DEG C, during secondary stage annealing to 350 DEG C from temperature
Insulation 2h, is cooled to room temperature, is prepared into glass material.
The present invention use zirconium dioxide, Disulfatozirconic acid., silicon dioxide, cobalt sulfide, titanium dioxide, chitin fiber, boron oxide,
Aluminosilicate magnesium, rutile, hydrogen oxide nickel oxide, aluminium sesquioxide, ferric oxide nanometer particle and calcium oxide carry out the proportioning of science
Combination, the pyroceram prepared has good resistance to elevated temperatures, the transparency, hardness.
The glass material of the present invention place at 500 DEG C after 22h to 65h glass without softening, metaboly, have good
Good thermostability；Its preparation method is simple, it is easy to industrialized production.
The high strength glass material of the present invention does not adds the harmful elements such as As, Sb, have low thermal expansion, high temperature resistant,
The technical characteristics such as high intensity, high rigidity, high chemical stability.
The preparation method of the present invention is simple, and the processing temperature overcoming the zirconium dioxide glass of routine in preparation process is high
Problem, energy-conserving and environment-protective, be suitable to industrialized production.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For Yuan, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should
It is considered as protection scope of the present invention.
Claims (6)
1. a glass for building purposes material, it is characterised in that include being made up of the component of following weight portion: zirconium dioxide 35-55
Part, Disulfatozirconic acid. 20-25 part, silicon dioxide 40-50 part, cobalt sulfide 15-25 part, titanium dioxide 8-15 part, chitin fiber 6-10
Part, boron oxide 5-10 part, aluminosilicate magnesium 2-4 part, rutile 4-8 part, hydrogen oxide nickel oxide 3-9 part, aluminium sesquioxide 4-8 part.
A kind of glass for building purposes material the most according to claim 1, it is characterised in that described component also includes that ferrum oxide is received
Rice grain 1-1.5 part.
A kind of glass for building purposes material the most according to claim 1, it is characterised in that described component also includes calcium oxide
1.5-2.5 part.
The preparation method of a kind of glass for building purposes material the most according to claim 1, it is characterised in that include walking as follows
Rapid:
S1, weigh zirconium dioxide 35-55 part, Disulfatozirconic acid. 20-25 part, silicon dioxide 40-50 part, cobalt sulfide 15-25 part, titanium dioxide
Titanium 8-15 part, chitin fiber 6-10 part, boron oxide 5-10 part, aluminosilicate magnesium 2-4 part, rutile 4-8 part, hydrogen oxide nickel oxide
3-9 part, aluminium sesquioxide 4-8 part, ferric oxide nanometer particle 1-1.5 part and calcium oxide 1.5-2.5 part join in blender,
It is uniformly mixed with 100-300r/min stir speed (S.S.)；
S2, the material after step S1 mix homogeneously is joined in corundum crucible, first heating 800-900 DEG C, rise again after stopping 2h
High-temperature, to 1350-1500 DEG C, is incubated 6-10 hour；
In S3, step S2, molding on preheated mould poured into by vitreous humour；
S4, by glass after the molding of step S3, first return goods to being incubated 1.5h when 800～1000 DEG C from temperature, secondary stage annealing is extremely
It is incubated 2h when 350 DEG C, is cooled to room temperature, is prepared into glass material.
A kind of glass for building purposes material the most according to claim 1, it is characterised in that include by the component of following weight portion
Make: zirconium dioxide 36-50 part, Disulfatozirconic acid. 21-24 part, silicon dioxide 45-58 part, cobalt sulfide 18-20 part, titanium dioxide 9-14
Part, chitin fiber 7-9 part, boron oxide 6-9 part, aluminosilicate magnesium 3-4 part, rutile 5-7 part, hydrogen oxide nickel oxide 4-8 part, three
Al 2 O 5-7 part, ferric oxide nanometer particle 1.1-1.4 part and calcium oxide 1.6-2.0 part.
A kind of glass for building purposes material the most according to claim 1, it is characterised in that include by the component of following weight portion
Make: zirconium dioxide 39 parts, Disulfatozirconic acid. 23 parts, silicon dioxide 48 parts, cobalt sulfide 19 parts, titanium dioxide 11 parts, chitin fiber 8
Part, boron oxide 6 parts, 4 parts of aluminosilicate magnesium, rutile 6 parts, hydrogen oxide nickel oxide 5 parts, aluminium sesquioxide 6 parts, ferric oxide nano
Grain 1.3 parts and calcium oxide 1.8 parts.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610530747.7A CN106186682A (en) | 2016-07-07 | 2016-07-07 | A kind of glass for building purposes material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610530747.7A CN106186682A (en) | 2016-07-07 | 2016-07-07 | A kind of glass for building purposes material and preparation method thereof |
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| CN106186682A true CN106186682A (en) | 2016-12-07 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107777878A (en) * | 2017-12-12 | 2018-03-09 | 吕玲 | A kind of novel high-strength glass and preparation method thereof |
| CN109279784A (en) * | 2018-09-18 | 2019-01-29 | 江苏锐阳照明电器设备有限公司 | A kind of high strength glass material |
| CN113845303A (en) * | 2021-10-25 | 2021-12-28 | 湖南兴龙环境艺术工程有限公司 | Wear-resistant toughened glass plate and manufacturing process thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104926144A (en) * | 2015-06-03 | 2015-09-23 | 苏州靖羽新材料有限公司 | High-temperature-resistant glass material and preparation method thereof |
| CN105693088A (en) * | 2016-03-04 | 2016-06-22 | 苏州圣谱拉新材料科技有限公司 | Explosion-proof glass material and preparation method thereof |
-
2016
- 2016-07-07 CN CN201610530747.7A patent/CN106186682A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104926144A (en) * | 2015-06-03 | 2015-09-23 | 苏州靖羽新材料有限公司 | High-temperature-resistant glass material and preparation method thereof |
| CN105693088A (en) * | 2016-03-04 | 2016-06-22 | 苏州圣谱拉新材料科技有限公司 | Explosion-proof glass material and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107777878A (en) * | 2017-12-12 | 2018-03-09 | 吕玲 | A kind of novel high-strength glass and preparation method thereof |
| CN109279784A (en) * | 2018-09-18 | 2019-01-29 | 江苏锐阳照明电器设备有限公司 | A kind of high strength glass material |
| CN113845303A (en) * | 2021-10-25 | 2021-12-28 | 湖南兴龙环境艺术工程有限公司 | Wear-resistant toughened glass plate and manufacturing process thereof |
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Application publication date: 20161207 |