CN106185805A - A kind of solar biomass energy Hydrogen Energy combined power generation device - Google Patents
A kind of solar biomass energy Hydrogen Energy combined power generation device Download PDFInfo
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- CN106185805A CN106185805A CN201610737088.4A CN201610737088A CN106185805A CN 106185805 A CN106185805 A CN 106185805A CN 201610737088 A CN201610737088 A CN 201610737088A CN 106185805 A CN106185805 A CN 106185805A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P80/00—Climate change mitigation technologies for sector-wide applications
- Y02P80/20—Climate change mitigation technologies for sector-wide applications using renewable energy
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Abstract
The invention discloses a kind of solar biomass energy Hydrogen Energy combined power generation device.Including device of solar generating, biomass thermal chemistry device for producing hydrogen, gas washing device, gas drier, organic hydrogen storage device and fuel cell, device of solar generating converts solar energy into electrical energy, electric energy is partially into electrical network, it is partially into biomass thermal chemistry device for producing hydrogen and organic hydrogen storage device is converted into chemical energy and stores, when solar energy is under-supply or unstable, chemical energy is then converted to electric energy by organic hydrogen storage device and fuel cell again, enter electrical network, round-the-clock supply of electric power can be realized, make full use of the advantage of each energy, obtain utilization rate of equipment and installations high, generated energy is stable, the TRT that generating efficiency is high.
Description
Technical field
The present invention relates to electric energy field, a kind of solar biomass energy Hydrogen Energy cogeneration dress
Put.
Background technology
Along with the deterioration of environment and constantly raising up of Fossil fuel price, new energy is all developed encouraging energetically in countries in the world
Source, the adjustment of electric power energy structure is the most inevitable.With wind-power electricity generation and solar energy, the new forms of energy as representative undergo an unusual development fast
Speed, but these new forms of energy are typically all and occur with single forms of electricity generation, with some more obvious defects.Following energy
Target is a kind of continuable novel renewable energy of green high-efficient of exploitation, and the energy density of hydrogen is up to 120MJkg-1, sending out of hydrogen
Calorific value is even above Fossil fuel, for 142351kJ/kg, is 3 times of gasoline calorific capacity.We can from reproducible raw material such as
Water, biomass or biogas prepare hydrogen.Hydrogen both can be applied to internal combustion engine as gasoline
Power-equipment provides energy, can be applied to fuel cell as energy and material again.At present, hydrogen producing technology mainly has biological hydrogen production
And water electrolysis hydrogen production etc., wherein biomass have aboundresources, and reserves are huge and reproducible feature, are combined by pyrolysis
Cleavage method converts biomass into hydrogen-rich combustion gas, can be former by various agricultural refuses such as rice husk, corn stalk, rice straw or straws
Material wide accommodation, and raw material availability is high, in the hydrogen-rich gas-phase product obtained, hydrogen content is high.The storage of hydrogen and transport are always
The bottleneck of restriction hydrogen energy source development, mostly there is some deficiency in existing storing hydrogen technology, can't fully meet following Hydrogen Energy
Economic demand；High-pressure gaseous hydrogen storage efficiency is the lowest, and there is container explosion and hydrogen is easily let out during transporting and using
The unsafe factors such as leakage；Low temperature liquid hydrogen storage technology is owing to must be provided with corresponding chiller, and its quality hydrogen-storage density is just subject to
Arrive restriction, cause this hydrogen storage mode cost the highest；For hydride hydrogen-storing, most metal hydride or be
The most stable or the most unstable, after being hydrogenated with circulation several times, its lattice structure is more easily damaged.
Solar energy and biomass energy all have widely distributed, inexhaustible, with low cost, the feature of clean environment firendly, rationally
Developing them, the sustainable development realizing the energy is had important strategic importance, solar electrical energy generation utilizes sun conduct
Energy source, owing to the energy density of solar energy is low, this just determines the biggest light field of needs and floor space, and cost of investment is very
Height, change over time and round the clock, there is fluctuation and intermittence in photo-thermal supply, the supply of photo-thermal is discontinuous, unstable, by sky
Gas impact electricity frequency can not keep stablizing constant, and the efficiency of simple solar light-heat power-generation is low, cost is high, and power plant transports and stop daytime night,
Hourage is few, utilization rate of equipment and installations is low in generating, and device frequent start-stop, equipment suffers greater impact, affects service life, and generated energy is normal
Ordinary wave moves, and causes the biggest pressure to local electrical network.
Summary of the invention
The deficiency existed for prior art, it is an object of the invention to provide a kind of solar biomass energy Hydrogen Energy associating
TRT, combines complementary angle from various energy resources, develops a kind of new solar energy, biomass energy and Hydrogen Energy cogeneration system
The optimized integrated device of system, makes full use of the advantage of each energy, obtains utilization rate of equipment and installations high, and generated energy is stable, and generating efficiency is high
TRT.
For achieving the above object, the technical scheme is that a kind of solar biomass energy Hydrogen Energy is combined to send out
Electric installation, including device of solar generating, biomass thermal chemistry device for producing hydrogen, gas washing device, gas drier, organic
Hydrogen-storing device and fuel cell, described device of solar generating converts solar energy into electrical energy, and described device of solar generating divides
Do not electrically connect with biomass thermal chemistry device for producing hydrogen and organic hydrogen storage device；Described biomass thermal chemistry device for producing hydrogen includes pyrolysis
Device, separator, cracking reformer, filter and shift-converter, the outlet of described pyrolysis apparatus is connected with the entrance of separator, institute
The entrance of the outlet and cracking reformer of stating separator is connected, and the described outlet of cracking reformer is connected with the entrance of filter,
The outlet of described filter is connected with the entrance of shift-converter；Biomass are decomposed under high temperature in pyrolysis apparatus and are converted into gas
Phase product and carbon residue, carbon residue is separated from gas-phase product and removes by separator, and gas-phase product splits in cracking reformer
Solving reformation and obtain hydrogen-rich gas, hydrogen-rich gas carries out impurity desulfurization in the filter, during after remove impurity, gas enters shift-converter
Improve the hydrogen content of hydrogen-rich gas further；The outlet of described shift-converter is connected with the import of gas washing device, described
Biomass thermal chemistry device for producing hydrogen convert biomass into hydrogen-rich gas by heat chemistry hydrogen production process；From biomass thermal chemistry
Device for producing hydrogen hydrogen-rich gas out enters gas washing device and removes nitrogenous gas therein and after carbonaceous gas obtains remove impurity
Hydrogen-rich gas, the described outlet of gas washing device is connected with the entrance of gas drier, from gas washing device out
After remove impurity, hydrogen-rich gas enters gas drier and carries out except water, the outlet of described gas drier and organic hydrogen storage device
Entrance is connected, and after remove impurity enters organic hydrogen storage device except the hydrogen-rich gas after water, hydrogen is stored in organic hydrogen storage material
In, the described gas outlet of organic hydrogen storage device is connected with the air inlet of fuel cell, and hydrogen is deviate from from organic hydrogen storage material
Fuel as fuel cell.
As a further improvement on the present invention, described organic hydrogen storage device includes hydrogenation plant and dehydrogenation unit, described in add
Being provided with two heat filtering devices between hydrogen production device and described dehydrogenation unit, described heat filtering device includes upper inlet, downside
Outlet, left hand inlet port and right-side outlet, the left hand inlet port of the liquid outlet of described hydrogenation plant and first heat filtering device is connected,
The right-side outlet of described first heat filtering device is connected with the upper inlet of second heat filtering device, described second hot mistake
The underside outlet of filter device is connected with the inlet of dehydrogenation unit, the liquid outlet of described dehydrogenation unit and second heat filtering device
Left hand inlet port be connected, the upper inlet of right-side outlet the first heat filtering device of described second heat filtering device is connected, the
The underside outlet of one heat filtering device is connected with the inlet of hydrogenation plant.
As a further improvement on the present invention, described heat filtering device includes heat filter, conduction oil interlayer, ultrasonic generation
Device and supersonic vibration rod, described conduction oil interlayer is arranged on outside heat filter, and described ultrasonic generator is arranged on heat filter top
On, described supersonic vibration rod is connected with ultrasonic generator, and described supersonic vibration rod is inserted in through installing hole on heat filter roof
In heat filter, described heat filter is provided with the first liquid separatnig plate, the second liquid separatnig plate, baffler, base plate, filtration core and elasticity
Rubber blanket, described base plate is arranged on the upside of heat filter diapire, and described first liquid separatnig plate and the second liquid separatnig plate are provided with water conservancy diversion
Hole, interconnecting of described first liquid separatnig plate, the second liquid separatnig plate and baffler, described first liquid separatnig plate is arranged on heat filtering
Under device roof, remaining limit of described first liquid separatnig plate is fixed on heat filter sidewall, and described second liquid separatnig plate is arranged on hot mistake
Filter sidewall is inboard, and remaining limit of described second liquid separatnig plate is fixed on heat filter sidewall and base plate, described first liquid separatnig plate,
Heat filter is divided into the first dispersion space, the second dispersion space, filter space and discharge opeing by the second liquid separatnig plate, baffler and base plate
Space, described first dispersion space and upper inlet directly communicate, and described second dispersion space and left hand inlet port directly communicate, institute
Stating filter space and right-side outlet directly communicates, described drainage space and underside outlet directly communicate, described heat filter diapire
In horn-like, described resilient rubbber cushion is arranged on base plate, and described heat filter right side wall and diapire intersection are provided with breach,
Edge, described breach side is positioned on right side wall, and relative opposite side edge is positioned on diapire, and described breach is outside equipped with sealing lid,
The described cross section sealing lid is arcuation, and described sealing lid is connected on the wall of heat filter, and described filtration core includes some
Shape filter wire, described filter wire lower end is fixed on resilient rubbber cushion, and described filter wire upper end and the first liquid separatnig plate contact.
As a further improvement on the present invention, described conduction oil interlayer is outside equipped with asbestos heat-insulation layer.
As a further improvement on the present invention, it is arranged with outside the conveyance conduit between described hydrogenation plant and dehydrogenation unit and leads
Hot oil pipeline layer.
As a further improvement on the present invention, a diameter of 0.1-0.25mm of described pod apertures.
As a further improvement on the present invention, described filter wire opposed vertical direction tilts 5-20 degree, and each filter wire is not advised
Then tilt to different directions.
As a further improvement on the present invention, a diameter of 0.005-0.01mm of described filter wire.
The combined power generation device of the present invention, including device of solar generating, biomass thermal chemistry device for producing hydrogen, gas eluting
Device, gas drier, organic hydrogen storage device and fuel cell, device of solar generating converts solar energy into electrical energy, electricity
Electrical network can be partially into, be partially into biomass thermal chemistry device for producing hydrogen and organic hydrogen storage device is converted into chemical energy and stores
Coming, when solar energy is under-supply or unstable, chemical energy is then converted to electric energy, enters by organic hydrogen storage device and fuel cell again
Entering electrical network, make full use of the advantage of each energy, obtain utilization rate of equipment and installations high, generated energy is stable, the TRT that generating efficiency is high.
Accompanying drawing explanation
Fig. 1 is the structural representation of the present invention；
Fig. 2 is the structural representation of heat filtering device of the present invention；
Fig. 3 is the structural representation of heat filter of the present invention.
Detailed description of the invention
Below in conjunction with the embodiment given by accompanying drawing, the present invention is described in further detail.
With reference to shown in Fig. 1-3, a kind of solar biomass energy Hydrogen Energy combined power generation device of the present embodiment, including solar energy
TRT 1, biomass thermal chemistry device for producing hydrogen 2, gas washing device 3, gas drier 4, organic hydrogen storage device 5 and combustion
Material battery 6, device of solar generating 1 converts solar energy into electrical energy, device of solar generating 1 respectively with biomass thermal chemistry system
Hydrogen production device 2 and organic hydrogen storage device 5 electrically connect, and by day in the case of solar energy abundance, the electric energy part that solar energy converts is entered
Entering electrical network, part electric energy provides required energy for biomass heat chemistry device for producing hydrogen 2 and organic hydrogen storage device 5, utilizes organic storage
Hydrogen production device 5 converts electrical energy into chemical energy and stores, at night or solar energy is insufficient overcast and rainy, organic hydrogen storage device
5 and fuel cell 6 chemical energy is then converted to electric energy and enters electrical network, it is ensured that grid generation amount is stable；Biomass thermal chemistry hydrogen manufacturing
Device 2 includes pyrolysis apparatus 21, separator 22, cracking reformer 23, filter 24 and shift-converter 25, the outlet of pyrolysis apparatus 21
Being connected with the entrance of separator 22, the outlet of separator 22 is connected with the entrance of cracking reformer 23, going out of cracking reformer 23
Mouth is connected with the entrance of filter 24, and the outlet of filter 24 is connected with the entrance of shift-converter 25；Biomass are at pyrolysis apparatus
Decomposing under high temperature in 21 and be converted into gas-phase product and carbon residue, carbon residue is separated from gas-phase product and removes by separator 22,
Gas-phase product carries out cracking reformation in cracking reformer 23 and obtains hydrogen-rich gas, and hydrogen-rich gas carries out desulfurization in filter 24
Remove impurity, improves the hydrogen content of hydrogen-rich gas further during gas enters shift-converter 25 after remove impurity；Going out of shift-converter 25
Mouth is connected with the import of gas washing device 3, and biomass are turned by biomass thermal chemistry device for producing hydrogen 2 by heat chemistry hydrogen production process
Turn to hydrogen-rich gas；Enter gas washing device 3 from biomass thermal chemistry device for producing hydrogen 2 hydrogen-rich gas out and remove therein
Nitrogenous gas and carbonaceous gas obtain hydrogen-rich gas after remove impurity, the outlet of gas washing device 3 and the entrance of gas drier 4
Being connected, after gas washing device 3 remove impurity out, hydrogen-rich gas entrance gas drier 4 carries out except water, and gas drying fills
Putting the outlet of 4 to be connected with the entrance of organic hydrogen storage device 5, organic hydrogen storage device 5 also includes hydrogen gas compressor, fills from gas drying
Put 4 hydrogen out first to compress through hydrogen gas compressor, be hydrogenated with again after hydrogen pressure is raised, through remove impurity except the hydrogen rich gas after water
After body enters organic hydrogen storage device 5, hydrogen is stored in organic hydrogen storage material, the gas outlet of organic hydrogen storage device 5 and fuel
The air inlet of battery 6 is connected, and hydrogen is used as the fuel of fuel cell 6 from organic hydrogen storage material by abjection.
As a kind of detailed description of the invention improved, organic hydrogen storage device 5 includes hydrogenation plant 51 and dehydrogenation unit 52, adds
Being provided with two heat filtering devices 7 between hydrogen production device 51 and dehydrogenation unit 52, heat filtering device 7 includes that upper inlet, downside go out
Mouth, left hand inlet port and right-side outlet, the left hand inlet port of the liquid outlet of hydrogenation plant 51 and first heat filtering device 7 is connected, the
The right-side outlet of one heat filtering device 7 is connected with the upper inlet of second heat filtering device 7, second heat filtering device 7
Underside outlet be connected with the inlet of dehydrogenation unit 52, the liquid outlet of dehydrogenation unit 52 and a left side for second heat filtering device 7
Side entrance is connected, and the upper inlet of right-side outlet the first heat filtering device 7 of second heat filtering device 7 is connected, the first hot mistake
The underside outlet of filter device 7 is connected with the inlet of hydrogenation plant 51.
Can be entrainment of hydrogenation catalyst in organic hydrogen storage material after hydrogenation out from hydrogenation plant 51, as can not be timely
Filtering, the most easily block valve, if entering dehydrogenation unit 52 with organic hydrogen storage material after hydrogenation, dehydrogenation effect can be affected
Really, can be entrainment of dehydrogenation in organic hydrogen storage material out from dehydrogenation unit 52, as do not filtered in time, long this with
Toward easily blocking valve, if entering hydrogenation plant 51 with organic hydrogen storage material, can affect hydrogenation effect, this improvement makes organic storage
Hydrogen material hydrogenated after being hydrogenated with in hydrogenation plant 51 after organic hydrogen storage material, then hydrogenation after organic hydrogen storage material from hydrogenation
In device 51 out after through by left hand inlet port enter first heat filtering device 7, first heat filtering device 7 is by hydrogenation therein
Catalyst filters；After hydrogenation, organic hydrogen storage material obtains organic hydrogen storage material, the most organic storage in dehydrogenation unit 52 after dehydrogenation
Hydrogen material from dehydrogenation unit 52 out after through by left hand inlet port enter second heat filtering device 7, second heat filtering device 7
Dehydrogenation therein is filtered；The upside of the right-side outlet of first heat filtering device 7 and second heat filtering device 7 enters
Mouth is connected, and the underside outlet of second heat filtering device 7 is connected with the inlet of dehydrogenation unit 52, organic after filtered hydrogenation
Hydrogen storage material first flows through second heat filtering device 7, enters back into dehydrogenation unit 52, can be by under filter in second heat filtering device 7
Dehydrogenation pour in dehydrogenation unit 52；The upside of right-side outlet the first heat filtering device 7 of second heat filtering device 7
Entrance is connected, and the underside outlet of the first heat filtering device 7 is connected with the inlet of hydrogenation plant 51, filtered organic hydrogen storage material
Material first flows through first heat filtering device 7, enters back into hydrogenation plant 51, can be by the hydrogenation under filtering in first heat filtering device 7
Catalyst pours in hydrogenation plant 51.
As a kind of detailed description of the invention improved, heat filtering device 7 includes heat filter 8, conduction oil interlayer 9, ultrasonic
Generator 10 and supersonic vibration rod 11, conduction oil interlayer 9 is arranged on outside heat filter 8, and ultrasonic generator 10 is arranged on heat filtering
On device 8 top, supersonic vibration rod 11 is connected with ultrasonic generator 10, and supersonic vibration rod 11 is through installing hole on heat filter 8 roof
It is inserted in heat filter 8, heat filter 8 is provided with first liquid separatnig plate the 81, second liquid separatnig plate 82, baffler 83, base plate 84, mistake
Filter element 85 and resilient rubbber cushion 86, base plate 84 is arranged on the upside of heat filter 8 diapire, the first liquid separatnig plate 81 and the second liquid separatnig plate 82
On be provided with pod apertures 87, first liquid separatnig plate the 81, second liquid separatnig plate 82 and baffler 83 interconnect, the first liquid separatnig plate
81 are arranged under heat filter 8 roof, and remaining limit of the first liquid separatnig plate 81 is fixed on heat filter 8 sidewall, the second liquid separatnig plate
82 are arranged on heat filter 8 sidewall inboard, and remaining limit of the second liquid separatnig plate 82 is fixed on heat filter 8 sidewall and base plate 84,
Heat filter 8 is divided into the first dispersion space 12, second by first liquid separatnig plate the 81, second liquid separatnig plate 82, baffler 83 and base plate 84
Dispersion space 13, filter space 14 and drainage space 15, the first dispersion space 12 and upper inlet directly communicate, the second dispersion sky
Between 13 and left hand inlet port directly communicate, filter space 14 and right-side outlet directly communicate, and drainage space 15 and underside outlet are direct
Communicating, heat filter 8 diapire is horn-like, and resilient rubbber cushion 86 is arranged on base plate 84, heat filter 8 right side wall and diapire phase
Being provided with breach 88 at friendship, edge, breach 88 side is positioned on right side wall, and relative opposite side edge is positioned on diapire, outside breach 88
Being provided with sealing lid 89, the cross section sealing lid 89 is arcuation, seals lid 89 and is connected on the wall of heat filter 8, filtration core 85
Including some strip filter wire, filter wire lower end is fixed on resilient rubbber cushion 86, filter wire upper end and the first liquid separatnig plate 81 phase
Contact.
Because organic hydrogen storage material compares thickness mostly, arranging of conduction oil interlayer 9 can flow through heat filtering device 7
Liquid to be filtered temperature is higher, and mobility is preferable, it is simple to improve filter efficiency；Organic hydrogen storage material after hydrogenation in hydrogenation plant 51
In dehydrogenation unit 52 in transfer process, in hydrogenation plant 51, after hydrogenation, organic hydrogen storage material is extruded by air pressure, via conveying
Pipeline arrives the left hand inlet port of first heat filtering device 7, subsequently into the second dispersion space 13, via on the second liquid separatnig plate 82
Pod apertures 87 is disperseed, and subsequently into filter space 14, filters in filtration core 85, now first heat filtering device
In 7, ultrasonic generator 10 is closed, and hydrogenation catalyst is filtered by filtration core 85；After hydrogenation, organic hydrogen storage material is from first
Individual heat filtering device 7 right-side outlet enters the upper inlet of second heat filtering device 7 the most afterwards, subsequently into the first dispersion sky
Between 12, disperse via pod apertures 87 on the first liquid separatnig plate 81, subsequently into filter space 14, now second heat filtering dress
The ultrasonic generator 10 put in 7 starts, and drives supersonic vibration rod 11 vibrations, because filter wire only has lower end to be fixed on gum elastic
On pad 86, supersonic vibration rod 11 makes filter wire start vibrations, and after hydrogenation, organic hydrogen storage material is by dehydrogenation band in filter wire
Walk, and at breach 88, flow into dehydrogenation unit 52 together；When hydrogenation after organic hydrogen storage material in dehydrogenation unit 52 by store
After hydrogen release is released, just being sent and return to hydrogenation plant 51, in dehydrogenation unit 52, organic hydrogen storage material is to hydrogenation plant 51 transfer
During shifting, in dehydrogenation unit 52, organic hydrogen storage material is extruded by air pressure, arrives second heat filtering dress via conveyance conduit
Put the left hand inlet port of 7, subsequently into the second dispersion space 13, disperse, then via pod apertures 87 on the second liquid separatnig plate 82
Entering filter space 14, filter in filtration core 85, now in second heat filtering device 7, ultrasonic generator 10 is in pass
Closed state, dehydrogenation is filtered by filter wire；Organic hydrogen storage material is the most laggard from second heat filtering device 7 right-side outlet
Enter the upper inlet of first heat filtering device 7, subsequently into the first dispersion space 12, via pod apertures on the first liquid separatnig plate 81
87 disperse, and subsequently into filter space 14, now the ultrasonic generator 10 of first heat filtering device 7 starts, and drive super
Sonic vibration rod 11 vibrations, because filter wire only has lower end to be fixed on resilient rubbber cushion 86, supersonic vibration rod 11 makes filter wire open
Beginning to shake, hydrogenation catalyst in filter wire is taken away, and is flowed into hydrogenation plant 51 through breach 88 together by organic hydrogen storage material.
As a kind of detailed description of the invention improved, conduction oil interlayer 9 is outside equipped with asbestos heat-insulation layer.Heat is avoided to dissipate
Lose, save the energy.
As a kind of detailed description of the invention improved, the conveyance conduit between hydrogenation plant 51 and dehydrogenation unit 52 is outer sheathed
There is heat-conducting oil pipes channel layer.The design of this structure makes liquid energy and conduction oil in the heat conducting oil pipe 54 of outer layer in conveyance conduit 53
Fully carry out heat exchange, it is to avoid liquid becomes viscous in course of conveying.
As a kind of detailed description of the invention improved, a diameter of 0.1-0.25mm of pod apertures 87.Diameter can not make the most greatly liquid
Body plays good dispersion effect, and diameter is the least, it is possible to blocked by solid particle.
As a kind of detailed description of the invention improved, filter wire opposed vertical direction tilts 5-20 degree, and each filter wire is not advised
Then tilt to different directions.Ensure liquid from the side of filtration core 85 enter time image through drainage screen layer by layer, can preferably by
Solid particle filters, and flushing liquor sweeps away from top and still can wash away being stuck in solid particle filter wire well.
As a kind of detailed description of the invention improved, a diameter of 0.005-0.01mm of filter wire.Suitably filter wire is straight
Footpath ensure that filter wire has suitable elasticity, and the solid particle contributed between filter wire is washed down.
The above is only the preferred embodiment of the present invention, and protection scope of the present invention is not limited merely to above-mentioned enforcement
Example, all technical schemes belonged under thinking of the present invention belong to protection scope of the present invention.It should be pointed out that, for the art
Those of ordinary skill for, some improvements and modifications without departing from the principles of the present invention, these improvements and modifications are also
Should be regarded as protection scope of the present invention.
Claims (8)
1. a solar biomass energy Hydrogen Energy combined power generation device, it is characterised in that: include device of solar generating (1), life
Material heat chemistry device for producing hydrogen (2), gas washing device (3), gas drier (4), organic hydrogen storage device (5) and fuel electricity
Pond (6), described device of solar generating (1) is electrically connected with biomass thermal chemistry device for producing hydrogen (2) and organic hydrogen storage device (5) respectively
Connect；Described biomass thermal chemistry device for producing hydrogen (2) includes pyrolysis apparatus (21), separator (22), cracking reformer (23), filter
(24) and shift-converter (25), the outlet of described pyrolysis apparatus (21) is connected with the entrance of separator (22), described separator
(22) outlet is connected with the entrance of cracking reformer (23), the outlet of described cracking reformer (23) and entering of filter (24)
Mouth is connected, and the outlet of described filter (24) is connected with the entrance of shift-converter (25), going out of described shift-converter (25)
Mouth is connected with the import of gas washing device (3), the outlet of described gas washing device (3) and entering of gas drier (4)
Mouth is connected, and the outlet of described gas drier (4) is connected with the entrance of organic hydrogen storage device (5), described organic hydrogen storage device
(5) gas outlet is connected with the air inlet of fuel cell (6).
A kind of solar biomass energy Hydrogen Energy combined power generation device the most according to claim 1, it is characterised in that have described in:
Machine hydrogen-storing device (5) includes hydrogenation plant (51) and dehydrogenation unit (52), described hydrogenation plant (51) and described dehydrogenation unit
(52) being provided with two heat filtering devices (7) between, described heat filtering device (7) includes that upper inlet, underside outlet, left side enter
Mouth and right-side outlet, the liquid outlet of described hydrogenation plant (51) and the left hand inlet port of first heat filtering device (7) are connected, described
The right-side outlet of first heat filtering device (7) is connected with the upper inlet of second heat filtering device (7), described second heat
The underside outlet of defecator (7) is connected with the inlet of dehydrogenation unit (52), the liquid outlet of described dehydrogenation unit (52) and
The left hand inlet port of two heat filtering devices (7) is connected, right-side outlet the first heat filtering dress of described second heat filtering device (7)
The upper inlet putting (7) is connected, the underside outlet of described first heat filtering device (7) and the inlet phase of hydrogenation plant (51)
Even.
A kind of solar biomass energy Hydrogen Energy combined power generation device the most according to claim 2, it is characterised in that: described heat
Defecator (7) includes heat filter (8), conduction oil interlayer (9), ultrasonic generator (10) and supersonic vibration rod (11), described
Conduction oil interlayer (9) is arranged on heat filter (8) outward, and described ultrasonic generator (10) is arranged on heat filter (8) top, described
Supersonic vibration rod (11) is connected with ultrasonic generator (10), and described supersonic vibration rod (11) is pacified on heat filter (8) roof
Dress hole is inserted in heat filter (8), is provided with the first liquid separatnig plate (81), the second liquid separatnig plate (82), resistance in described heat filter (8)
Dividing plate (83), base plate (84), filtration core (85) and resilient rubbber cushion (86), described base plate (84) is arranged on heat filter (8) end
On the upside of wall, described first liquid separatnig plate (81) and the second liquid separatnig plate (82) are provided with pod apertures (87), described first liquid separatnig plate
(81), the second liquid separatnig plate (82) and baffler (83) while interconnecting, described first liquid separatnig plate (81) is arranged on heat filtering
Under device (8) roof, remaining limit of described first liquid separatnig plate (81) is fixed on heat filter (8) sidewall, described second liquid separatnig plate
(82) being arranged on heat filter (8) sidewall inboard, remaining limit of described second liquid separatnig plate (82) is fixed on heat filter (8) sidewall
With on base plate (84), described first liquid separatnig plate (81), the second liquid separatnig plate (82), baffler (83) and base plate (84) are by heat filter
(8) the first dispersion space (12), the second dispersion space (13), filter space (14) and drainage space (15) it are divided into, described first
Dispersion space (12) and upper inlet directly communicate, and described second dispersion space (13) and left hand inlet port directly communicate, described mistake
Filter space (14) and right-side outlet directly communicate, and described drainage space (15) and underside outlet directly communicate, described heat filter
(8) diapire is horn-like, and described resilient rubbber cushion (86) is arranged on base plate (84), described heat filter (8) right side wall and the end
Wall intersection is provided with breach (88), and described breach (88) edge, side is positioned on right side wall, and relative opposite side edge is positioned at the end
On wall, described breach (88) is outside equipped with sealing lid (89), and the described cross section sealing lid (89) is arcuation, described sealing lid (89)
Being connected on the wall of heat filter (8), described filtration core (85) includes that some strip filter wire, described filter wire lower end are fixed
On resilient rubbber cushion (86), described filter wire upper end and the first liquid separatnig plate (81) contact.
A kind of solar biomass energy Hydrogen Energy combined power generation device the most according to claim 3, it is characterised in that lead described in:
Deep fat interlayer (9) is outside equipped with asbestos heat-insulation layer.
A kind of solar biomass energy Hydrogen Energy combined power generation device the most according to claim 4, it is characterised in that add described in:
It is arranged with heat conducting oil pipe layer outside conveyance conduit between hydrogen production device (51) and dehydrogenation unit (52).
A kind of solar biomass energy Hydrogen Energy combined power generation device the most according to claim 5, it is characterised in that lead described in:
Discharge orifice (87) a diameter of 0.1-0.25mm.
7., according to a kind of solar biomass energy Hydrogen Energy combined power generation device described in any one of claim 3-6, its feature exists
In: described filter wire opposed vertical direction tilts 5-20 degree, and each filter wire tilts to different directions brokenly.
A kind of solar biomass energy Hydrogen Energy combined power generation device the most according to claim 7, it is characterised in that: described mistake
A diameter of 0.005-0.01mm of filter wire.
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| CN106185805B (en) | 2018-04-20 |
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