CN1800694A - Hydrogen storage device - Google Patents

Hydrogen storage device Download PDF

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Publication number
CN1800694A
CN1800694A CN 200410094188 CN200410094188A CN1800694A CN 1800694 A CN1800694 A CN 1800694A CN 200410094188 CN200410094188 CN 200410094188 CN 200410094188 A CN200410094188 A CN 200410094188A CN 1800694 A CN1800694 A CN 1800694A
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hydrogen
hydrogen storage
storage device
filter
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CN 200410094188
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Chinese (zh)
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CN100549492C (en )
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施志刚
黄先进
法汉·白普丁
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汉氢科技股份有限公司
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/32Hydrogen storage
    • Y02E60/321Storage of liquefied, solidified, or compressed hydrogen in containers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P90/00Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
    • Y02P90/45Hydrogen technologies in production processes

Abstract

The invention relates to a hydrogen storage device, which comprises a hydrogen storage pot, at least one first separator, and at least one second separator, while the hydrogen storage pot has a long axle; the first separator can divide the hydrogen storage pot into at least one space; at least one second separator can divide the space into several sub-spaces to contain the hydrogen-storage alloy; the second separator contains several nest rooms each of which has a inner wall in comb structure; the second separator has a square comb or fan comb structure; the inner wall of each nest room is vertical to the long axle of hydrogen storage pot to reach better heat transmission efficiency when feeding the hydrogen gas into hydrogen storage device. Since the alloy has uniform stress inside the pot, the structure is stable with improved safety.

Description

储氢装置 Hydrogen storage device

技术领域 FIELD

本发明涉及一种储氢装置(Hydrogen storage apparatus),特别是涉及一种用以储存一储氢合金(Hydrogen storage alloy)的储氢装置,使得氢气于该储氢装置进出时,热传效率更佳,且因合金在罐体内部应力均匀,结构稳定不易变形,以提高安全性。 When the present invention relates to a hydrogen storage device (Hydrogen storage apparatus), in particular hydrogen storage means for storing a hydrogen-absorbing alloy (Hydrogen storage alloy) relates to a for such hydrogen storage of hydrogen in and out of the apparatus more efficient heat transfer good, and because the stress uniformly inside the tank alloy, stable structures can be deformed, in order to improve security.

背景技术 Background technique

在过去,将氢气视为一种燃料来使用,已广泛的被注意。 In the past, the use of hydrogen as a fuel, has been widely noticed. 当世界上的石油存量正被快速耗尽的同时,氢气的供应却是无尽的。 When both oil stocks in the world are being quickly depleted, the supply of hydrogen is endless. 再者,氢气属于一成本较低的燃料,虽然目前氢气还是比石油要来得昂贵。 Furthermore, a low-cost hydrogen fuel belongs, although hydrogen is to be more expensive than oil. 氢气于所有燃料中,具有最高的能量密度,且因为氢气燃烧所产生的副产物为水,因此本质上来说并不具任何污染性。 Hydrogen in all of the fuel having the highest energy density, and because by-products generated by combustion of hydrogen is water, thus essentially does not have any contaminating.

虽然以氢气作为燃料具有非常广泛的潜在应用价值,不过在氢气的利用上却有一主要的缺点,即缺乏令人满意的储氢媒体。 Although hydrogen has a very wide range of potential applications as a fuel, but there is a major drawback in the use of hydrogen, namely the lack of a satisfactory hydrogen storage media. 公知技术将氢气于高压下储存于一压力罐体,或于一极低温的状态下,以液态氢的形式储存。 Well-known techniques at high pressure hydrogen gas stored in a pressure tank, or at an extremely low temperature state, stored in the form of liquid hydrogen. 以压缩气体方式来储存氢气,需要使用庞大的罐体,因而增加搬运上的困难度。 Way to store compressed gas in hydrogen requires a large tank, thus increasing the difficulty of handling. 另外,由于氢气具有低密度的性质,储存于罐体中的氢气容量将会受到限制。 Further, since hydrogen has a low density properties, the capacity of the hydrogen stored in the tank will be limited. 再者,由于氢气极度易燃,当用作汽车燃料时,若以液态方式储存,对安全性来说会产生极大的问题。 Furthermore, since hydrogen is extremely flammable when used as motor fuel, if the liquid way of storing, for it will have a great security problem. 此外,制造液态氢的成本非常昂贵。 Further, the manufacturing cost of the liquid hydrogen is very expensive.

公知技术亦或利用某些金属和合金以反复的储存及释放氢气,由于某些金属和合金具有高度的储氢效率,因此被视为极佳的储氢材料。 Yihuo known techniques and use of certain metal alloys of storing and releasing hydrogen repeated, some metals and alloys have high hydrogen storage efficiency, it is seen as an excellent hydrogen storage material. 非常多的金属合金皆被视为适合将氢气储存于其原子或晶体结构中。 Very many metal alloys are considered to be suitable for hydrogen atom or a crystal structure in stored therein. 尽管上述的储存方法极为方便且安全,但在储氢效率上,仍有进一步提高的空间。 Although the above method of storage is very convenient and safe, but in the hydrogen storage efficiency, there is still room for improvement. 例如,热传能力可以提高或抑制氢气于储氢系统中的金属合金的进出交换效率。 For example, heat transfer ability can be improved or suppressed in the hydrogen storage efficiency of the system and out of the exchange of the metal alloy hydrogen. 如一般的反应,要从一金属氢化物的晶体结构中将氢气释放,需要输入一些能量,通常是输入热量。 The general reaction, the crystal structure of the hydrogen will release from a metal hydride, requires some energy input, usually heat input. 而要将氢气置入一金属合金的晶体结构中时,便会释放出能量,通常释放的也是热量。 To the hydrogen implantation while a metal alloy crystal structure, will release energy, heat is generally released.

储氢合金于氢化的过程中所释放的热量必须被移除,若热量没有被有效的移除,将会使得氢化过程变慢,甚至终止,这对于快速吸氢而言,是一个极为严重的问题。 To heat the hydrogen storage alloy during hydrogenated released must be removed, if the heat is not effectively removed, so that the hydrogenation process will slow down or termination, for this fast absorbing, it is an extremely serious problem. 于快速吸氢的过程中,储氢合金会快速的被氢化,并且产生大量的热量。 In the process of rapid hydrogen absorption, the hydrogen-absorbing alloy is rapidly hydrogenated, and a large amount of heat. 此外,当储氢合金使用一段时间的后,储氢合金会有微粉化的现象发生。 Further, when the hydrogen storage alloy used for a period of time, the hydrogen-absorbing alloy will micronized phenomenon. 微粉化的储氢合金会渐渐积聚在储氢罐体的底部。 Micronized hydrogen-absorbing alloy will gradually accumulate in the bottom of the hydrogen storage tank. 当储氢罐进行充氢程序时,由于罐体底部的合金会因吸氢而产生约20%的膨胀率,进而导致罐体内上、下部因受力不均,而易使罐体变形,以致破损。 When the hydrogen storage tank for hydrogen charging procedure, the bottom of the can body alloy will produce about 20% overrun due to hydrogen absorption due, leading to the tank body, the lower portion due to uneven force, easily deformed can body, such that damaged. 例如,于美国专利第6,666,034号所披露的氢储运装置即有上述的缺点。 For example, the hydrogen storage device in U.S. Patent No. 6,666,034 that is disclosed in the above-described disadvantages.

于美国专利第6,626,323号所披露的储氢装置中,其装置结构亦无法有效的散热及防止微粉化合金的位移。 Hydrogen storage device in U.S. Patent No. 6,626,323 disclosed, the device structure which will not be able to prevent and effectively heat the alloy micronized displacement. 而于美国专利第6,709,497号所披露的储氢结构,由于尚需导热管(Heat exchangertube)来散热,整体热传效果较为不高,设计较为复杂,且成本亦相对较高。 And in U.S. Patent No. 6,709,497 disclosed a hydrogen storage structure, due to the heat transfer tubes still need (Heat exchangertube) to dissipate heat, the overall effect is more heat transfer is not high, the design is more complex, and the cost is also relatively high.

因此本发明的主要目的在于提供一种具有较佳热传效率及安全性的储氢装置,以解决上述问题。 Therefore the primary object of the present invention is to provide a better heat transfer efficiency and safety of hydrogen-absorbing means, in order to solve the above problems.

发明内容 SUMMARY

本发明的一目的在于提供一种用以储存一储氢合金(Hydrogen storagealloy)的储氢装置,使得氢气于该储氢装置进出时,热传效率更佳。 An object of the present invention is to provide a hydrogen storage device for storing the hydrogen absorbing alloy (Hydrogen storagealloy), so that the hydrogen gas into and out of the hydrogen storage device, the heat transfer efficiency is better.

本发明的另一目的在于提供一种用以储存一储氢合金(Hydrogen storagealloy)的储氢装置,用以当储氢合金于吸放氢过程中而微粉化时,降低储氢合金的位移量,以防止储氢罐的变形。 Another object of the present invention is to provide a hydrogen storage device for storing the hydrogen absorbing alloy (Hydrogen storagealloy), and when the hydrogen storage alloy used in the hydrogen absorption process and micronized, the hydrogen storage alloy to reduce the amount of displacement to prevent deformation of the hydrogen tank.

根据本发明的一较佳具体实施例的储氢装置,其包含有一储氢罐(Hydrogen storage canister)、至少一第一分隔物(Partition)以及至少一第二分隔物。 Particularly preferred embodiment of a hydrogen storage device according to the present embodiment of the invention, which includes a hydrogen tank (Hydrogen storage canister), at least one first spacer (the Partition) and at least one second spacer. 储氢罐定义一长轴(Longitudinal axis)。 Hydrogen tank defines a longitudinal axis (Longitudinal axis). 至少一第一分隔物用以将储氢罐分隔为至少一隔间(Compartment)。 At least a first spacer to be divided into at least a hydrogen tank compartment (Compartment). 至少一第二分隔物用以将至少一隔间分隔为数个次隔间,且储氢合金置放于该数个次隔间中。 At least a second separator for the at least one secondary compartment separated into several compartments, and the hydrogen storage alloy is placed to the plurality of secondary compartment. 至少一第二分隔物包含数个巢室(Cell),所述巢室皆具有一内壁(Cell wall)并且排列成一蜂巢式结构(Honeycomb configuration),每一巢室的内壁与储氢罐定义的长轴相垂直。 At least one second spacer comprises a plurality of nested chambers (Cell), all of the cells having an inner wall (Cell wall) and arranged in a honeycomb structure (Honeycomb configuration), the inner wall of the hydrogen tank chamber defined in each nest perpendicular to the major axis. 储氢装置进一步包含至少一第二滤片,用以包覆至少一第二分隔物的外表面。 Hydrogen storage device further comprises at least one second filter plate for covering the outer surface of the at least one second spacer.

所述的储氢装置,其中该储氢罐包含至少一控制阀(Control valve),该至少一控制阀用以控制氢气于该储氢罐的进出。 The hydrogen storage apparatus wherein the hydrogen tank includes at least a control valve (Control valve), the at least one control valve for controlling the hydrogen gas in the hydrogen tank out.

所述的储氢装置,其中该储氢罐另包含至少一第一滤片(Filter)以及至少一压环(Ring),每一该至少一压环用以将相对应的该第一滤片固定于相对应的该控制阀的底部,且该至少一第一滤片仅允许氢气通过。 The hydrogen storage apparatus wherein the hydrogen tank further comprises at least a first filter (the Filter) and at least one pressure ring (Ring), each of the at least one pressure ring of the first filter for the corresponding corresponding fixed to the bottom of the control valve, and the at least one first filter only allowing hydrogen to pass.

所述的储氢装置,其中该至少一第一滤片的孔隙(Porosity)小于1.0微米。 The hydrogen storage device, wherein the at least one aperture of the first filter (Porosity) less than 1.0 micron.

所述的储氢装置,其中该至少一第一分隔物为一滤片。 The hydrogen storage device, wherein the at least one first separator is a filter.

所述的储氢装置,其中该至少一第二分隔物具有可挠性,使得所述次隔间的大小为可调整的。 The hydrogen storage device, wherein the at least one second spacer having a flexibility, such that the size of the secondary compartment is adjustable.

所述的储氢装置,其中该至少一第二分隔物具有一方型蜂巢式结构(Rectangle-shaped honeycomb configuration)。 The hydrogen storage device, wherein the at least one of a second spacer having a honeycomb-type structure of formula (Rectangle-shaped honeycomb configuration).

所述的储氢装置,其中该至少一第二分隔物具有一扇型蜂巢式结构(Fan-shaped honeycomb configuration)。 The hydrogen storage device, wherein the at least one second spacer having a honeycomb-type structure (Fan-shaped honeycomb configuration).

所述的储氢装置,其中该储氢装置进一步包含一滤心(Filter center),该滤心通过该至少一第一分隔物以及该至少一第二分隔物的中心,用以过滤氢气。 The hydrogen storage apparatus, wherein the apparatus further comprises a hydrogen storage Filter (Filter center), the heart was filtered through the at least one first spacer and the center of at least a second separator for filtering hydrogen.

因此,通过本发明的储氢装置,不仅充分改善了氢气于储氢装置进出时的热传效率,并且确保微粉化的储氢合金于每一巢室中,以防止储氢罐因微粉化的储氢合金位移量太大,使得储氢罐内的应力不均而使罐体变形。 Thus, the hydrogen storage device of the present invention, not only a sufficiently improved heat transfer effectiveness of the hydrogen in the hydrogen storage device when out and ensure the hydrogen storage alloy is micronized to each nest chamber to prevent the hydrogen tank due to the micronized hydrogen-absorbing alloy displacement amount is too large, so that the stress of the hydrogen storage tank is uneven deformation tank. 此外,本发明的储氢装置适用于直式或横式的应用。 Further, the hydrogen storage device of the present invention is applied to a straight or horizontal applications.

关于本发明的优点与精神可以通过以下的发明详述及所附图式得到进一步的了解。 The advantage and spirit of the appended drawings the present invention may be further understood by the following detailed description of the invention and.

附图说明 BRIEF DESCRIPTION

图1为本发明的一具体实施例的储氢装置外部视图。 External view of an embodiment of the present invention. FIG. 1 a hydrogen storage apparatus.

图2为图1所示的储氢装置的分解图。 2 is an exploded view of a hydrogen storage device 1 shown.

图3为图2所示的第二分隔物的三种不同疏密度的展开图。 3 three different coarseness of the second spacer shown in FIG. 2 expanded FIG.

图4A为图2所示的第二分隔物的俯视图。 FIG 4A is a plan view of a second separator shown in FIG 2.

图4B为图2所示的第二分隔物的侧视图。 FIG 4B is a side view of a second separator shown in FIG 2.

图5为本发明的另一具体实施例的储氢装置分解图。 The hydrogen storage device of FIG. 5 an exploded view of another specific embodiment of the present invention.

图6为本发明的另一具体实施例的储氢装置分解图。 Hydrogen storage device of FIG exploded view of another specific embodiment 6 of the present invention.

图7为本发明的另一具体实施例的储氢装置外部视图。 Hydrogen storage device of the external view of the embodiment of FIG. 7 another embodiment of the present invention are described.

图8为本发明的另一具体实施例的储氢装置外部视图。 An external view of another hydrogen storage device according to the present invention are described in FIG. 8 embodiment.

图9为图8所示的储氢装置的分解图。 9 is an exploded view of a hydrogen storage device shown in FIG.

图10A为图9所示的第二分隔物的附视图。 FIG 10A is attached view of the second separator 9 is shown in FIG.

图10B为图9所示的第二分隔物的侧视图。 FIG 10B is a side view of a second separator 9 as shown in FIG.

图11为本发明的另一具体实施例的储氢装置分解图。 Hydrogen storage device of FIG exploded view of another embodiment 11 of the present invention are described.

图12为本发明的另一具体实施例的储氢装置分解图。 Hydrogen storage device of FIG exploded view of another embodiment 12 of the present invention are described.

其中,附图标记说明如下:10、24、30、40、50、64、70: 储氢装置12、52: 储氢罐13、33、53、73: 第一分隔物14、34、54、74: 第二分隔物16、16a、56、56a: 控制阀18、18a、58、58a: 第一滤片20、20a、60、60a: 压环22: 尾盖 32: 滤心46: 第二滤片 62: 上盖Y: 长轴具体实施方式请参阅图1至图3,图1为本发明的一具体实施例的储氢装置10外部视图。 Wherein reference numerals as follows: 10,24,30,40,50,64,70: hydrogen storage device 12, 52: hydrogen tank 13,33,53,73: a first divider 14,34,54, 74: second divider 16,16a, 56,56a: control valves 18,18a, 58,58a: a first filter 20,20a, 60,60a: pressure ring 22: End cap 32: filter 46: second filter 62: cover Y: DETAILED DESCRIPTION major axis 10 an exterior view of a hydrogen storage device of the embodiment Referring to FIG. 1 to FIG. 3, FIG. 1 of the present invention. 图2为图1所示的储氢装置10的分解图。 2 is an exploded view of a hydrogen storage device 10 shown in FIG. 图3为图2所示的第二分隔物14的三种不同疏密度的展开图。 FIG 3 is a second separator shown in FIG. 2 three different coarseness of FIG. 14 expanded. 储氢装置10用以储存一储氢合金(Hydrogen storage alloy)(图中未示)。 Hydrogen storage device 10 for storing a hydrogen-absorbing alloy (Hydrogen storage alloy) (not shown). 如图2所示,储氢装置10包含一储氢罐(Hydrogen storage canister)12、至少一第一分隔物(Partition)13、至少一第二分隔物14、一控制阀(Control valve)16、一第一滤片(Filter)18、一压环(Ring)20以及一尾盖(Bottom cover)22。 As shown, the hydrogen storage device 10 comprises a hydrogen tank 2 (Hydrogen storage canister) 12, at least a first partition (Partition) 13, at least a second spacer 14, a control valve (Control valve) 16, a first filter (filter) 18, a pressure ring (ring) 20, and a cover (Bottom cover) 22. 储氢罐12定义一长轴(Longitudinal axis)Y。 Hydrogen storage tank 12 defines a longitudinal axis (Longitudinal axis) Y. 于此实施例中,储氢装置10包含二个第一分隔物13以及一个第二分隔物14。 In this embodiment, the hydrogen storage device 10 comprises two first partition 13 and a second partition 14. 第一分隔物13为一滤片,且用以将储氢罐12分隔为至少一隔间(Compartment)。 The first partition 13 is a filter, and the hydrogen tank 12 to the partition of at least one compartment (Compartment). 第一分隔物13还可过滤氢气,亦即仅允许氢气通过,并且可以避免储氢合金粉末跑出。 The first hydrogen separator 13 may also be filtered, i.e., only allowing hydrogen to pass through and ran hydrogen absorbing alloy powder can be avoided.

控制阀16用以控制氢气于储氢罐12的进出。 The control valve 16 to control the flow of hydrogen gas in the hydrogen tank 12. 压环20用以将第一滤片18固定于控制阀16的底部,且第一滤片18仅允许氢气通过,使得储氢装置10于吸/放氢时,可以避免储氢合金粉末跑出。 Pressure ring 20 to the first filter 18 is fixed to the bottom of the control valve 16, and the first filter 18 allows only hydrogen through the hydrogen storage device 10 in that hydrogen absorption / desorption, hydrogen absorbing alloy powder can be avoided Ran . 第一滤片18的孔隙(Porosity)设计为小于1.0微米,效果较佳。 Porosity (Porosity) The first filter 18 is designed to be less than 1.0 micron, was better. 尾盖22用以罩住储氢罐12的底部,以防止氢气及储氢合金泄漏,如图1所示。 End cap 22 for covering the bottom of the hydrogen tank 12 to prevent leakage of hydrogen gas and a hydrogen storage alloy, as shown in FIG.

第二分隔物14用以将至少一隔间分隔为数个次隔间,储氢合金置放于所述次隔间中。 The second partition 14 for partitioning the at least one compartment into several sub-compartments, the hydrogen storage alloy is placed in the secondary compartment. 第二分隔物14包含数个巢室(Cell),每一巢室皆具有一内壁(Cell wall)并且排列成一蜂巢式结构(Honeycomb configuration),每一巢室的内壁皆与长轴Y相垂直。 The second separator 14 includes a plurality of nested chambers (Cell), are each nest chamber having an inner wall (Cell wall) and arranged in a honeycomb structure (Honeycomb configuration), the nest inner wall of each chamber are perpendicular to the long axis Y . 储氢合金置放于第二分隔物14的每一巢室中,以减少微粉化的储氢合金积聚于储氢罐12底部。 The hydrogen storage alloy is placed in each nest chamber in a second separator 14, to reduce the hydrogen storage alloy is micronized hydrogen tank 12 accumulates in the bottom. 此外,第二分隔物14具有可挠性,使得所述次隔间的大小为可调整的。 Further, the second spacer 14 has flexibility, so that the size of the secondary compartment is adjustable. 借此,可依据不同的需求,而改变所述次隔间的疏密度,以进一步增进热传导效率,如图3所示。 Whereby, can be based on different needs, changes coarseness of the secondary compartment, in order to further enhance the efficiency of heat conduction, as shown in FIG.

请参阅图4A以及图4B,图4A为图2所示的第二分隔物14的俯视图。 Please refer to FIG. 4A and FIG. 4B, a top view of a second separator 4A as shown in FIG. 14. 图4B为图2所示的第二分隔物14的侧视图。 FIG. 4B a side view of a second separator 214 shown in FIG. 由于第二分隔物14中每一巢室的内壁皆与长轴Y相垂直,使得第二分隔物14与储氢罐12的内壁相接触的面积增加,进而增进热传导效率,如图4B所示。 Since the nest inner wall of each chamber 14 of the second spacer are perpendicular to the major axis Y, such that the second partition 14 to increase the area of ​​contact with the inner wall of the hydrogen storage tank 12, and further enhance heat transfer efficiency, shown in Figure 4B . 第二分隔物14的上下表面具有一扇型蜂巢式结构(Fan-shaped honeycomb configuration),如图4A所示。 Upper and lower surface of the second separator 14 having a honeycomb-type structure (Fan-shaped honeycomb configuration), shown in Figure 4A. 此外,储氢装置10进一步包含至少一第二滤片(图中未示),第二滤片用以包覆第二分隔物14的外表面,确保微粉化的储氢合金于每一巢室中,以防止储氢罐因微粉化的储氢合金位移量太大,使得储氢罐内的应力不均而使罐体变形。 In addition, hydrogen storage device 10 further comprises at least a second filter (not shown), a second filter used to cover the outer surface of the second separator 14, to ensure that the hydrogen storage alloy is micronized to each nest chamber in order to prevent the hydrogen tank due to the hydrogen-absorbing alloy powder of the amount of displacement is too large, the uneven stress of the hydrogen storage tank so that the tank modification. 由于储氢合金皆被限制于第二分隔物14的每一巢室中,本发明的储氢装置10适用于直式或横式的应用。 Since the hydrogen absorbing alloy are nested in each chamber to be limited to a second separator 14, the hydrogen storage device 10 of the present invention is applicable to straight or horizontal applications.

请参阅图5,图5为本发明的另一具体实施例的储氢装置24分解图。 Refer to FIG. 5, FIG. 5 another embodiment of the present invention, the specific embodiment of the hydrogen storage device 24 exploded FIG. 储氢装置24与储氧装置10主要不同之处在于,储氢装置24将储氢装置10的尾盖22替换为一控制阀16a、一第一滤片18a以及一压环20a。 Hydrogen storage device 24 is different from the main storage device 10 comprising oxygen, hydrogen storage device 24 hydrogen storage device 22 replace the end cap 10 is a control valve 16a, a filter 18a and a first pressure ring 20a. 控制阀16a、第一滤片18a以及压环20a的功能及原理与控制阀16、第一滤片18以及压环20相同。 A control valve 16a, the first filter 18a and the principles and functions of the control valve 20a of the pressure ring 16, identical to the first filter 18 and the pressure ring 20. 当储氢装置24的氢气填充完成时,可同时将控制阀16以及控制阀16a打开,并且以高纯度氢气吹洗储氢罐12内部。 When the hydrogen storage device 24, the hydrogen filling is completed, while the control valve 16 and control valve 16a is opened, and the high purity hydrogen to purge the interior of the hydrogen tank 12. 借此,储氢罐12内不被储氢合金吸收的不纯物将可被吹出,以更加提高氢气的纯度达99.9999%以上。 Accordingly, the hydrogen tank 12 is not absorbed by the hydrogen storage alloy will be blown out impurities, to further improve the hydrogen purity of 99.9999% or more. 图5中的储氢装置24的功能与图2中的储氢装置10相同,在此不再赘述。 The same hydrogen storage device 2 of FIG. 5 functions of the hydrogen storage device 10, 24, are not repeated here.

请参阅图6,图6为本发明的另一具体实施例的储氢装置30分解图。 Refer to FIG. 6, hydrogen storage device 30 is an exploded view of another embodiment of the present invention. FIG. 6 specific embodiments. 储氢装置30与储氢装置10主要不同之处在于储氢装置30包含一滤心(Filtercenter)32、二个第一分隔物33以及三个第二分隔物34。 Hydrogen storage device 30 and the main hydrogen storage device 10 except that the hydrogen storage device 30 comprises a filter core (Filtercenter) 32, a first spacer 33 and two three second partition 34. 滤心32通过每一第一分隔物33以及每一第二分隔物34的中心,用以过滤氢气,并使得储存于下层储氢合金的氢气可以快速放出。 Filter 32 passing through the center of the first spacer 33 and each of the second separator 34, for filtering hydrogen, such hydrogen storage and in the lower hydrogen-absorbing alloy can be quickly discharged. 此外,由于储氢装置30的第二分隔物34的尺寸较储氢装置10的第二分隔物14来得小,使得第二分隔物34较容易成形,且储氢合金的位移量也较小。 Further, since the second partition size of the second hydrogen storage device 34 of the spacer 30 compared with 14 hydrogen storage device 10 is more small, so that the second shaped spacer 34 easier, and the displacement amount of the hydrogen-absorbing alloy is small. 图6中的储氢装置30的功能与图2中的储氢装置10相同,在此不再赘述。 The same hydrogen storage device 2 of FIG functions hydrogen storage device 30 in FIG. 610, it is not repeated here.

请参阅图7,图7为本发明的另一具体实施例的储氢装置40分解图。 Please refer to FIG. 7, FIG. 7 another embodiment of the present invention, the specific embodiment of the hydrogen storage device 40 exploded FIG. 储氢装置40与储氢装置30主要不同之处在于储氢装置40于每一第二分隔物34中,另包含一第二分隔物34。 Hydrogen storage device 40 and the hydrogen storage device 30 main difference is that the hydrogen storage device 40 to each of the second separator 34, further comprising a second separator 34. 于每一第二分隔物34外,皆包覆一第二滤片46。 Each of the second outer spacer 34, are coated with a second filter 46. 相较于储氢装置30,储氢装置40将第二分隔物分为内外两层,可进一步减少储氢合金的位移量。 Compared to the hydrogen storage device 30, a second hydrogen storage device 40 is divided into inner and outer separator layers, can further reduce the amount of displacement of the hydrogen-absorbing alloy. 此外,当储氢罐的尺寸较大时,将第二分隔物分为内外两层的设计较容易制造成形。 Further, when the hydrogen storage tank large in size, the inner and outer layers into the second separator design easier to fabricate molded. 图7中的储氢装置40的功能与图2、6中的储氢装置10、30相同,在此不再赘述。 FIG function in FIG. 7 2,6 hydrogen storage device 40 in the same hydrogen storage device 10, 30, are not repeated here.

请参阅图8至图9,图8为本发明的另一具体实施例的储氢装置50外部视图。 Please refer to FIG. 8 to FIG. 9, the external view of a hydrogen storage device 50 according to another embodiment of the present invention are described in FIG. 8 embodiment. 图9为图8所示的储氢装置50的分解图。 9 is an exploded view of a hydrogen storage device 50 shown in Fig. 储氢装置50用以储存一储氢合金(Hydrogen storage alloy)(图中未示)。 Hydrogen storage means 50 for storing a hydrogen-absorbing alloy (Hydrogen storage alloy) (not shown). 如图9所示,储氢装置50包含一储氢罐(Hydrogen storage canister)52、至少一第一分隔物(Partition)53、至少一第二分隔物54、一控制阀(Control valve)56、一第一滤片(Filter)58、一压环(Ring)60以及一上盖(Top cover)62。 9, hydrogen storage device 50 comprises a hydrogen tank (Hydrogen storage canister) 52, at least a first partition (Partition) 53, at least a second spacer 54, a control valve (Control valve) 56, a first filter (filter) 58, a pressure ring (ring) 60, and a cover (Top cover) 62. 储氢罐52定义一长轴(Longitudinalaxis)Y。 Hydrogen storage tank 52 defines a longitudinal axis (Longitudinalaxis) Y. 于此实施例中,储氢装置50包含二个第一分隔物53以及一个第二分隔物54。 In this embodiment, the hydrogen storage device 50 comprises two first spacer 53 and a second partition 54. 第一分隔物53为一滤片,且用以将储氢罐52分隔为至少一隔间(Compartment)。 The first separator is a filter 53, and to the hydrogen storage tank 52 is partitioned into at least one compartment (Compartment). 第一分隔物53还可过滤氢气,亦即仅允许氢气通过,并且可以避免储氢合金粉末跑出。 The first hydrogen separator 53 may also be filtered, i.e., only allowing hydrogen to pass through and ran hydrogen absorbing alloy powder can be avoided. 此外,第一分隔物53用以包覆第二分隔物54的外表面,确保微粉化的储氢合金于每一巢室中,以防止储氢罐因微粉化的储氢合金位移量太大,使得储氢罐内的应力不均而使罐体变形。 Further, the first partition 53 to second partition covering the outer surface 54 to ensure that the hydrogen storage alloy is micronized to each nest chamber to prevent the hydrogen tank due to the displacement amount of the hydrogen-absorbing alloy powder is too large , so that the stress of the hydrogen storage tank is uneven deformation tank.

控制阀56用以控制氢气于储氢罐52的进出。 For controlling the control valve 56 and out of the hydrogen in the hydrogen tank 52. 压环60用以将第一滤片58固定于控制阀56的内开口处,且第一滤片58仅允许氢气通过,使得储氢装置50于吸/放氢时,可以避免储氢合金粉末跑出。 When the first pressure ring 60 to the filter 58 is fixed to the opening of the control valve 56, and the first filter 58 allows only hydrogen through the hydrogen storage device 50 is such that in hydrogen absorption / desorption, hydrogen absorbing alloy powder can be avoided ran out. 第一滤片58的孔隙设计为小于1.0微米,效果较佳。 Design of the first aperture filter 58 is less than 1.0 micron, was better. 上盖62用以罩住储氢罐52的顶部,以防止氢气及储氢合金泄漏,如图8所示。 An upper cover 62 for covering the top of the hydrogen tank 52 to prevent leakage of hydrogen gas and a hydrogen storage alloy, as shown in FIG.

第二分隔物54用以将至少一隔间分隔为数个次隔间,储氢合金置放于所述次隔间中。 The second separator 54 to the at least one secondary compartment separated into several compartments, the hydrogen storage alloy is placed in the secondary compartment. 第二分隔物54包含数个巢室(Cell),每一巢室皆具有一内壁(Cell wall)并且排列成一蜂巢式结构(Honeycomb configuration),每一巢室的内壁皆与长轴Y相垂直。 The second separator 54 comprises a plurality of nested chambers (Cell), are each nest chamber having an inner wall (Cell wall) and arranged in a honeycomb structure (Honeycomb configuration), the nest inner wall of each chamber are perpendicular to the long axis Y . 储氢合金置放于第二分隔物54的每一巢室中,以减少微粉化的储氢合金积聚于储氢罐52底部。 Second hydrogen storage alloy is placed in each nest separator chamber 54 in order to reduce the hydrogen storage alloy is micronized hydrogen tank 52 accumulates in the bottom. 此外,第二分隔物54具有可挠性,使得所述次隔间的大小为可调整的。 Further, the second spacer 54 has flexibility, so that the size of the secondary compartment is adjustable. 借此,可依据不同的需求,而改变所述次隔间的疏密度,以进一步增进热传导效率。 Whereby, can be based on different needs, changes coarseness of the secondary compartment, in order to further enhance heat transfer efficiency.

请参阅图10A以及图10B,图10A为图9所示的第二分隔物54的俯视图。 See Figure 10A and 10B, and a top of the second separator 10A as shown in FIGS. 9 and 54. 图10B为图9所示的第二分隔物54的侧视图。 FIG. 10B a side view of a second separator 954 shown in FIG. 由于第二分隔物54中每一巢室的内壁皆与长轴Y相垂直,使得第二分隔物54与储氢罐52的上下壁相接触的面积增加,进而增进热传导效率,如图10A所示。 Since the partition wall of the second chamber 54 of each nest and are perpendicular to the major axis Y, so that the area of ​​the second separator 54 in contact with the upper and lower walls of the hydrogen tank 52 increases, and thus enhance heat transfer efficiency, as shown in FIG. 10A. shows. 第二分隔物54的侧表面具有一方型蜂巢式结构(Rectangle-shaped honeycomb configuration),如图10B所示。 The second side surface 54 of the spacer having one of a honeycomb-type structure of formula (Rectangle-shaped honeycomb configuration), shown in Figure 10B. 由于储氢合金皆被限制于第二分隔物54的每一巢室中,本发明的储氢装置50乃适用于直式或横式的应用。 Since the hydrogen absorbing alloy are both limited to the second separator chamber 54 of each nest, the hydrogen storage device 50 of the present invention is to apply to straight or horizontal applications.

请参阅图11,图11为本发明的另一具体实施例的储氢装置64分解图。 Referring to FIG 11, FIG 11 another embodiment of the present invention are described embodiment of the hydrogen storage device 64 exploded FIG. 储氢装置64与储氢装置50主要不同之处在于,储氢装置64另包含一控制阀56a、一第一滤片58a以及一压环60a。 64 and the hydrogen storage device 50 mainly differs in that the hydrogen storage means, hydrogen storage device 64 further comprises a control valve 56a, a filter 58a and a first pressure ring 60a. 控制阀56a、第一滤片58a以及压环60a的功能及原理与控制阀56、第一滤片58以及压环60相同。 A control valve 56a, the first filter 58a and the pressure ring and the principle functions of the control valve 56 60a are the same as first filter 58 and pressure ring 60. 当储氢装置64的氢气填充完成时,可同时将控制阀56以及控制阀56a打开,并且以高纯度氢气吹洗储氢罐52内部。 When the hydrogen storage device 64 hydrogen filling is completed, while the control valve 56 and control valve 56a is opened, and the high purity hydrogen to purge the interior of the hydrogen tank 52. 借此,储氢罐52内不被储氢合金吸收的不纯物将可被吹出,以更加提高氢气的纯度达99.9999%以上。 Accordingly, the hydrogen-absorbing alloy is not absorbed will be blown out impurities within the hydrogen storage tank 52, in order to further increase the purity of 99.9999% or hydrogen. 图11中的储氢装置64的功能与图9中的储氢装置50相同,在此不再赘述。 The same hydrogen storage apparatus 964 functions in FIG. 11 and FIG hydrogen storage device 50, not described herein again.

请参阅图12,图12为本发明的另一具体实施例的储氢装置70分解图。 Referring to FIG 12, FIG 12 another embodiment of the present invention are described embodiment of the hydrogen storage device 70 exploded FIG. 储氢装置70与储氢装置50主要不同之处在于储氢装置70包含三个第一分隔物73以及二个第二分隔物74。 Hydrogen storage device 70 and the main hydrogen storage device 50 except that the hydrogen storage device 70 comprises a first partition 73 and three two second separator 74. 相较于储氢装置50,储氧装置70将第二分隔物分为两层,可进一步减少储氢合金的位移量。 Compared to the hydrogen storage device 50, the oxygen storage device 70 into a second separator layers, can further reduce the amount of displacement of the hydrogen-absorbing alloy. 图12中的储氢装置70的功能与图9中的储氢装置50相同,在此不再赘述。 The same hydrogen storage apparatus 970 functions in FIG. 12 and FIG hydrogen storage device 50, not described herein again.

相较于公知技术,本发明的储氢装置不仅充分改善了氢气于储氢装置进出时的热传效率,并且确保微粉化的储氢合金于每一巢室中,以防止储氢罐因微粉化的储氢合金位移量太大,使得储氢罐内的应力不均而使罐体变形。 Compared to the known art, the hydrogen storage device of the present invention is not sufficiently improve the heat transfer efficiency in the hydrogen out of the hydrogen storage device, and to ensure that the hydrogen storage alloy is micronized to each nest chamber to prevent the hydrogen tank due micronized the displacement amount of hydrogen-absorbing alloy is too large, so that the stress of the hydrogen storage tank is uneven deformation tank. 本发明的储氢装置并且通过二控制阀的设计,进一步提高氢气的纯度。 Hydrogen storage device of the present invention and by a second control valve design, to further improve the purity hydrogen. 此外,本发明的储氢装置适用于直式或横式的应用。 Further, the hydrogen storage device of the present invention is applied to a straight or horizontal applications.

通过以上较佳具体实施例的详述,希望能更加清楚描述本发明的特征与精神,而并非以上述所披露的较佳具体实施例来对本发明的范畴加以限制。 Detailed Description of the preferred embodiment of the above particular embodiment, hoping to more clearly describe the characteristics and spirit of the invention, rather than to particular preferred embodiments disclosed above to be limiting the scope of the present invention. 相反地,其目的是希望能涵盖各种改变及具相等性的安排于本发明所欲申请的专利范围的范畴内。 Conversely, its purpose is to be able to cover various modifications within the scope of the patent and with equal scope of the present invention arranged in the desired application.

Claims (10)

  1. 1.一种用以储存一储氢合金的储氢装置,该储氢装置包含:一储氢罐,该储氢罐定义一长轴;至少一第一分隔物,该至少一第一分隔物用以将该储氢罐分隔为至少一隔间;以及至少一第二分隔物,该至少一第二分隔物用以将该至少一隔间分隔为数个次隔间,该储氢合金置放于该数个次隔间中;其中,该至少一第二分隔物包含数个巢室,所述巢室皆具有一内壁并且排列成一蜂巢式结构,每一所述巢室的内壁与该长轴相垂直。 A hydrogen storage means for storing a hydrogen-absorbing alloy This hydrogen-absorbing means comprises: a hydrogen tank, a hydrogen tank which defines a longitudinal axis; at least one first spacer, the at least one first spacer the hydrogen storage tank to the partition of at least one compartment; and at least a second partition, the at least one second partition for the at least one secondary compartment separated into several compartments, the hydrogen storage alloy is placed the number of times in the compartment; wherein the at least one second spacer comprises a plurality of nested chambers, all of the cells having an inner wall and are arranged in a honeycomb structure, an inner wall of each of the cells and the long perpendicular to the axis.
  2. 2.如权利要求1所述的储氢装置,其中该储氢罐包含至少一控制阀,该至少一控制阀用以控制氢气于该储氢罐的进出。 2. The hydrogen storage apparatus according to claim 1, wherein the at least one hydrogen storage tank comprises a control valve, the at least one control valve for controlling the hydrogen gas in and out of the hydrogen tank.
  3. 3.如权利要求2所述的储氢装置,其中该储氢罐另包含至少一第一滤片以及至少一压环,每一该至少一压环用以将相对应的该第一滤片固定于相对应的该控制阀的底部,且该至少一第一滤片仅允许氢气通过。 3. The hydrogen storage apparatus according to claim 2, wherein the hydrogen storage tank further comprising at least a first filter and at least one pressure ring, each of the at least one pressure ring of the first filter for the corresponding corresponding fixed to the bottom of the control valve, and the at least one first filter only allowing hydrogen to pass.
  4. 4.如权利要求3所述的储氢装置,其中该至少一第一滤片的孔隙小于1.0微米。 4. The hydrogen storage apparatus according to claim 3, wherein the at least a first aperture is less than 1.0 micron filter.
  5. 5.如权利要求1所述的储氢装置,其中该至少一第一分隔物为一滤片。 5. The hydrogen storage apparatus according to claim 1, wherein the at least one first separator is a filter.
  6. 6.如权利要求1所述的储氢装置,其中该至少一第二分隔物具有可挠性,使得所述次隔间的大小可调整。 The hydrogen storage device as claimed in claim 1, wherein the at least one second spacer having a flexibility, such that the size of the secondary compartment is adjustable.
  7. 7.如权利要求1所述的储氢装置,其中该至少一第二分隔物具有一方型蜂巢式结构。 7. The hydrogen storage apparatus according to claim 1, wherein the at least one of a second spacer having a honeycomb-type structure.
  8. 8.如权利要求1所述的储氢装置,其中该至少一第二分隔物具有一扇型蜂巢式结构。 8. The hydrogen storage apparatus according to claim 1, wherein the at least one second spacer having a honeycomb-type structure.
  9. 9.如权利要求8所述的储氢装置,其中该储氢装置进一步包含一滤心,该滤心通过该至少一第一分隔物以及该至少一第二分隔物的中心,用以过滤氢气。 9. The hydrogen storage apparatus according to claim 8, wherein the hydrogen storage device further comprises a filter core, the core was filtered through the at least one first spacer and the center of at least a second separator for filtering hydrogen .
  10. 10.如权利要求9所述的储氢装置,其中该储氢装置进一步包含至少一第二滤片,该至少一第二滤片用以包覆该至少一第二分隔物的外表面。 10. The hydrogen storage apparatus according to claim 9, wherein the hydrogen storage device further comprises at least one second filter, at least one second filter plate for covering the outer surface of the at least one second spacer.
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Cited By (2)

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CN102942159A (en) * 2012-11-26 2013-02-27 北京浩运金能科技有限公司 Composite hydrogen storage system
CN106185805A (en) * 2016-08-27 2016-12-07 温州集智科技有限公司 Solar energy-biomass energy-hydrogen energy combinative electric power generation device

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CN102942159A (en) * 2012-11-26 2013-02-27 北京浩运金能科技有限公司 Composite hydrogen storage system
CN102942159B (en) * 2012-11-26 2015-11-18 北京浩运金能科技有限公司 A composite hydrogen storage system
CN106185805A (en) * 2016-08-27 2016-12-07 温州集智科技有限公司 Solar energy-biomass energy-hydrogen energy combinative electric power generation device
CN106185805B (en) * 2016-08-27 2018-04-20 温州集智科技有限公司 A solar power generation apparatus combined biomass hydrogen

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