CN106183284A - Safety anti-explosive fenestrated membrane - Google Patents
Safety anti-explosive fenestrated membrane Download PDFInfo
- Publication number
- CN106183284A CN106183284A CN201610756665.4A CN201610756665A CN106183284A CN 106183284 A CN106183284 A CN 106183284A CN 201610756665 A CN201610756665 A CN 201610756665A CN 106183284 A CN106183284 A CN 106183284A
- Authority
- CN
- China
- Prior art keywords
- sensitive adhesive
- adhesive layer
- polyester film
- explosive
- safe pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
- B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
- B32B37/1284—Application of adhesive
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B38/00—Ancillary operations in connection with laminating processes
- B32B38/16—Drying; Softening; Cleaning
- B32B38/164—Drying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/06—Interconnection of layers permitting easy separation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J201/00—Adhesives based on unspecified macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
- B32B2255/205—Metallic coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/28—Multiple coating on one surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/402—Coloured
- B32B2307/4026—Coloured within the layer by addition of a colorant, e.g. pigments, dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/554—Wear resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/584—Scratch resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/71—Resistive to light or to UV
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention relates to a kind of safety anti-explosive fenestrated membrane, have wearing layer (1), mould release membrance (4), between described wearing layer (1) and mould release membrance (4), also have safety anti-explosive layer, and each layer is complex as a whole；Described safety anti-explosive layer is made up of first polyester film (2 1) and first safe pressure-sensitive adhesive layer (3 1)；Or, described safety anti-explosive layer is made up of first polyester film (2 1), first safe pressure-sensitive adhesive layer (3 1), second polyurethane film (2 2) and second safe pressure-sensitive adhesive layer (3 2)；Or, described safety anti-explosive layer is made up of first polyester film (2 1), first safe pressure-sensitive adhesive layer (3 1), second polyurethane film (2 2), second safe pressure-sensitive adhesive layer (3 2), the 3rd polyester film (2 3) and the 3rd safe pressure-sensitive adhesive layer (3 3).The present invention has safety anti-explosive effect, during to reach glass accident fragmentation, prevents splashing glass from out hurting surrounding population.
Description
Technical field
Present invention relates particularly to a kind of safety anti-explosive fenestrated membrane, can be used for preparing double glazing, safety glass door and window, glass curtain
Walls etc. need the object of safety anti-explosive, are particularly suitable for being pasted onto the glass surface of the glass surface of building or automobile.
Background technology
Safety anti-explosive fenestrated membrane is a kind of a kind of function pad pasting that can fill and be attached to glass surface, for example, it is possible to dress is attached to build
Build thing glass surface, post the building glass of safety anti-explosive fenestrated membrane when originally cannot bear the invasion and attack of outside various strength and rupture,
Can under the adhesive effect of pad pasting, it is possible to fragment is sticked together, thus avoid because of fragment splash or dump human body or
Article damage.Therefore, safety anti-explosive fenestrated membrane is personal in protection and enjoys favor in various special article safety.Existing fenestrated membrane
In, have possess anti-ultraviolet function, have possess anti-fog function, have possess anti-blue light function, but above-mentioned fenestrated membrane exists
In safety anti-explosive performance poor, therefore, be badly in need of design one there is safety anti-explosive effect, to prevent from leading when accidental glass breakage
Cause the safety anti-explosive fenestrated membrane of glass dregs splashing injury surrounding population.
Summary of the invention
It is an object of the invention to: a kind of safety anti-explosive fenestrated membrane with safety anti-explosive effect is provided, unexpected to reach glass
During fragmentation, prevent splashing glass from out hurting the purpose of surrounding population.
The technical scheme realizing the object of the invention is: a kind of safety anti-explosive fenestrated membrane, has wearing layer, mould release membrance, its innovative point
It is between described wearing layer and mould release membrance, also have safety anti-explosive layer, and each layer is complex as a whole；
Described safety anti-explosive layer is made up of first polyester film and first safe pressure-sensitive adhesive layer, wherein, and first polyester film
Thickness is 23～188 μm, and the thickness of first safe pressure-sensitive adhesive layer is 6～25 μm；Wearing layer ultraviolet light polymerization is combined in first
On one surface of individual polyester film, first safe pressure-sensitive adhesive layer heat cure is combined in another surface of first polyester film
On, mould release membrance is compounded in the outer surface of first safe pressure-sensitive adhesive layer and constitutes safety anti-explosive fenestrated membrane；
Or, described safety anti-explosive layer is by first polyester film, first safe pressure-sensitive adhesive layer, second polyurethane film and second
Individual safe pressure-sensitive adhesive layer forms, and wherein, the thickness of first polyester film and second polyurethane film is 23～188 μm, and first
The thickness of individual safe pressure-sensitive adhesive layer and second safe pressure-sensitive adhesive layer is 6～25 μm；Wearing layer ultraviolet light polymerization is combined in
On one surface of one polyester film, first safe pressure-sensitive adhesive layer heat cure is combined in another surface of first polyester film
On, a surface recombination of second polyurethane film is at the outer surface of first safe pressure-sensitive adhesive layer, second safe pressure sensitive adhesive
Layer heat cure is combined on another surface of second polyurethane film, and mould release membrance is compounded in outside second safe pressure-sensitive adhesive layer
Surface constitutes safety anti-explosive fenestrated membrane；
Or, described safety anti-explosive layer by first polyester film, first safe pressure-sensitive adhesive layer, second polyurethane film, second
Individual safe pressure-sensitive adhesive layer, the 3rd polyester film and the 3rd safe pressure-sensitive adhesive layer composition, wherein, first polyester film, second
The thickness of polyurethane film and the 3rd polyester film is 23～188 μm, described first safe pressure-sensitive adhesive layer, second safety pressure
The thickness of quick glue-line and the 3rd safe pressure-sensitive adhesive layer is 6～25 μm；Wearing layer ultraviolet light polymerization is combined in first polyester
On one surface of film, first safe pressure-sensitive adhesive layer heat cure is combined on another surface of first polyester film, and second
One surface recombination of individual polyurethane film is in the outer surface of first safe pressure-sensitive adhesive layer, second safe pressure-sensitive adhesive layer heat cure
Being combined on another surface of second polyurethane film, a surface recombination of the 3rd polyester film is pressure-sensitive second safety
The outer surface of glue-line, the 3rd safe pressure-sensitive adhesive layer heat cure is combined in another surface of the 3rd polyester film, and mould release membrance is multiple
The outer surface being combined in the 3rd safe pressure-sensitive adhesive layer constitutes safety anti-explosive fenestrated membrane；
Form first safe pressure-sensitive adhesive layer, second safe pressure-sensitive adhesive layer, the mixed material phase of the 3rd safe pressure-sensitive adhesive layer
With, it is all by adhesive 30 ~ 70wt%, solvent 30 ~ 70wt%, ultraviolet absorber 0.1 ~ 5wt%, firming agent 0.1 ~ 5wt% group
Becoming, above-mentioned each component sum is 100wt%, and wherein, described ultraviolet absorber is in benzotriazole, benzophenone class, triazines
One or more.
In technique scheme, the mixed material forming wearing layer is by scraping-resistant agent 40 ~ 60wt%, solvent ethyl acetate
40 ~ 60wt% forms, and above-mentioned each component sum is 100wt%.
In technique scheme, first polyester film and the 3rd polyester film that form described safety anti-explosive layer are identical,
It is the most all transparent polyester film, or is all dyeing polyester film or is all primary colors polyester film, or be all ultraviolet-resistant polyester
Film, or be all aluminized polyester film, or be all magnetron sputtering polyester film.
In technique scheme, form first polyester film of described safety anti-explosive layer and the 3rd polyester film difference,
It is transparent polyester film, dyeing polyester film, primary colors polyester film, ultraviolet-resistant polyester film, aluminized polyester film, magnetron sputtering polyester film
Any one of.
In technique scheme, described second polyurethane film is transparent polyurethane film, the polyurethane film that dyes, primary colors gather
Any one of urethane film, ultraviolet-resistant polyurethane film, polyurethane film of aluminizing, magnetron sputtering polyurethane film.
In technique scheme, form first polyester film of described safety anti-explosive layer, second polyurethane film and
The thickness of three polyester films is identical, or entirely different, or any two of which is identical.
In technique scheme, form first safe pressure-sensitive adhesive layer of described safety anti-explosive layer, second safety pressure
The thickness of quick glue-line and the 3rd safe pressure-sensitive adhesive layer is identical or entirely different, or any two of which is identical.
In technique scheme, the thickness of described safety anti-explosive fenestrated membrane is 100～695 μm, wherein, the thickness of wearing layer
It is 2～6 μm；The thickness of mould release membrance is 23～50 μm.
The solution have the advantages that: safety anti-explosive fenestrated membrane of the present invention has composite construction, described wearing layer and mould release membrance
Between also have safety anti-explosive layer, and each layer is complex as a whole, and described safety anti-explosive layer is by first polyester film and first safety
Pressure-sensitive adhesive layer forms, or described safety anti-explosive layer is by first polyester film, first safe pressure-sensitive adhesive layer, second polyurethane
Film and second safe pressure-sensitive adhesive layer composition, or described safety anti-explosive layer is by first polyester film, first safe pressure sensitive adhesive
Layer, second polyurethane film, second safe pressure-sensitive adhesive layer, the 3rd polyester film and the 3rd safe pressure-sensitive adhesive layer composition, this
Sample, the present invention makes full use of safe pressure-sensitive adhesive layer and polyester film improves overall glass rigid, utilizes polyurethane film anti-impact simultaneously
Hit the feature of performance and good toughness, once post the glass of safety anti-explosive fenestrated membrane of the present invention by foreign impacts power, can be by
Impulsive force is decomposed at glass surface, and the ductility of polyester film and toughness can effectively offset and decompose impact, even if glass is sent out
Having given birth to broken, polyester film also can produce tensile force and the colloid with safe pressure-sensitive adhesive layer jointly acts on tractive and lives glass fragment, anti-
Only splash, effectively the protection person and property safety.And the knot power change of pressure-sensitive adhesive between different coating, polyester film is exclusive in addition
Lamination between the micrometric displacement that mutually slides, alleviate the impulsive force being applied to safety diaphragm through glass, form unique impact resistance,
Reinforcing glass intensity, the glass breaking that effective prevention is caused because of external force collision is hurted sb.'s feelings.Additionally, adjust safety of the present invention
The polyester film of explosion-proof layer and the thickness of safe pressure-sensitive adhesive layer so that it is the effect of safety anti-explosive will increase accordingly.The present invention has
Advantage be: 1, can effectively prevent external hard thing from glass surface is caused scuffing；2, ensure that glass is heated evenly, it is to avoid
Fragmentation；3, by external force collision time, it is possible to effectively stop penetrator；4, glass fragmentation faced or when coming off, it is possible to active adsorption fragment,
Avoid glass or fragment to drop, cause secondary injury.
Accompanying drawing explanation
Fig. 1 is the structural representation of the first safety anti-explosive fenestrated membrane of the present invention；
Fig. 2 is the structural representation of the second safety anti-explosive fenestrated membrane of the present invention；
Fig. 3 is the structural representation of the third safety anti-explosive fenestrated membrane of the present invention.
Detailed description of the invention
Below in conjunction with drawings and Examples, the present invention is further described in detail, but not limited.
Embodiment is raw materials used, unless otherwise indicated, is commercially available industrial goods, commercially available by commercial channel.
Embodiment 1
As it is shown in figure 1, a kind of safety anti-explosive fenestrated membrane, there are wearing layer 1, mould release membrance 4, also have between described wearing layer 1 and mould release membrance 4
Safety anti-explosive layer, and each layer is complex as a whole；
Described safety anti-explosive layer is made up of the safe pressure-sensitive adhesive layer 3-1 of first polyester film 2-1 and first, and wherein, first is gathered
The thickness of ester film 2-1 is 23～188 μm, and the thickness of first safe pressure-sensitive adhesive layer 3-1 is 6～25 μm；Wearing layer 1 UV-curing
Changing and be combined on a surface of first polyester film 2-1, first safe pressure-sensitive adhesive layer 3-1 heat cure is combined in first and gathers
On another surface of ester film 2-1, mould release membrance 4 is compounded in the outer surface of first safe pressure-sensitive adhesive layer 3-1 and constitutes safety anti-explosive
Fenestrated membrane.
Embodiment 2
As in figure 2 it is shown, the difference of embodiment 2 and embodiment 1 is: a kind of safety anti-explosive fenestrated membrane, there is wearing layer 1, release
Film 4, also has safety anti-explosive layer between described wearing layer 1 and mould release membrance 4, and each layer is complex as a whole；Described safety anti-explosive layer by
First polyester film 2-1, first safe pressure-sensitive adhesive layer 3-1, second polyurethane film 2-2 and second safe pressure-sensitive adhesive layer 3-
2 compositions, wherein, the thickness of first polyester film 2-1 and second polyurethane film 2-2 is 23～188 μm, first safety pressure
The thickness of quick glue-line 3-1 and second safe pressure-sensitive adhesive layer 3-2 is 6～25 μm；Wearing layer 1 ultraviolet light polymerization is combined in first
On one surface of individual polyester film 2-1, first safe pressure-sensitive adhesive layer 3-1 heat cure is combined in the another of first polyester film 2-1
On one surface, a surface recombination of second polyurethane film 2-2 at the outer surface of first safe pressure-sensitive adhesive layer 3-1,
Two safe pressure-sensitive adhesive layer 3-2 heat cures are combined on another surface of second polyurethane film 2-2, and mould release membrance 4 is compounded in
The outer surface of second safe pressure-sensitive adhesive layer 3-2 constitutes safety anti-explosive fenestrated membrane.
Embodiment 3
As it is shown on figure 3, the difference of embodiment 3 and embodiment 1 is: a kind of safety anti-explosive fenestrated membrane, there is wearing layer 1, release
Film 4, also has safety anti-explosive layer between described wearing layer 1 and mould release membrance 4, and each layer is complex as a whole；Described safety anti-explosive layer by
First polyester film 2-1, first safe pressure-sensitive adhesive layer 3-1, second polyurethane film 2-2, second safe pressure-sensitive adhesive layer 3-
2, the 3rd polyester film 2-3 and the 3rd safe pressure-sensitive adhesive layer 3-3 composition, wherein, first polyester film 2-1, second poly-ammonia
The thickness of ester film 2-2 and the 3rd polyester film 2-3 is 23～188 μm, described first safe pressure-sensitive adhesive layer 3-1, second
The thickness of safe pressure-sensitive adhesive layer 3-2 and the 3rd safe pressure-sensitive adhesive layer 3-3 is 6～25 μm；Wearing layer 1 ultraviolet light polymerization combines
On a surface of first polyester film 2-1, first safe pressure-sensitive adhesive layer 3-1 heat cure is combined in first polyester film 2-
On another surface of 1, a surface recombination of second polyurethane film 2-2 is in the appearance of first safe pressure-sensitive adhesive layer 3-1
Face, second safe pressure-sensitive adhesive layer 3-2 heat cure is combined on another surface of second polyurethane film 2-2, and the 3rd is gathered
One surface recombination of ester film 2-3 is in the outer surface of second safe pressure-sensitive adhesive layer 3-2, the 3rd safe pressure-sensitive adhesive layer 3-3 heat
Solidification is combined in another surface of the 3rd polyester film 2-3, and mould release membrance 4 is compounded in outside the 3rd safe pressure-sensitive adhesive layer 3-3
Surface constitutes safety anti-explosive fenestrated membrane.
In embodiment 1,2,3, formed first safe pressure-sensitive adhesive layer 3-1, second safe pressure-sensitive adhesive layer 3-2, the 3rd
The mixed material of safe pressure-sensitive adhesive layer 3-3 is identical, is all by adhesive 30 ~ 70wt%, solvent 30 ~ 70wt%, ultraviolet absorber
0.1 ~ 5wt%, firming agent 0.1 ~ 5wt% form, and above-mentioned each component sum is 100wt%, and wherein, described ultraviolet absorber is benzene
And one or more in triazole type, benzophenone class, triazines.
In embodiment 1,2,3, the mixed material forming wearing layer 1 is identical, is all by scraping-resistant agent 40 ~ 60wt%, solvent second
Acetoacetic ester 40 ~ 60wt% forms, and above-mentioned each component sum is 100wt%.
In embodiment 1,2,3, form first polyester film 2-1 of described safety anti-explosive layer and the 3rd polyester film 2-3 phase
With, it is the most all transparent polyester film, or is all dyeing polyester film or is all primary colors polyester film, or be all that ultraviolet-resistant gathers
Ester film, or be all aluminized polyester film, or be all magnetron sputtering polyester film.
In embodiment 1,2,3, form first polyester film 2-1 and the 3rd polyester film 2-3 of described safety anti-explosive layer not
With, be transparent polyester film, dyeing polyester film, primary colors polyester film, ultraviolet-resistant polyester film, aluminized polyester film, magnetron sputtering gather
Any one of ester film.
In embodiment 2,3, described second polyurethane film 2-2 is transparent polyurethane film, dyeing polyurethane film, the poly-ammonia of primary colors
Any one of ester film, ultraviolet-resistant polyurethane film, polyurethane film of aluminizing, magnetron sputtering polyurethane film.
In embodiment 1,2,3, form first polyester film 2-1 of described safety anti-explosive layer, second polyurethane film 2-2 and
The thickness of the 3rd polyester film 2-3 is identical or entirely different, or any two of which is identical.
In embodiment 1,2,3, form first safe pressure-sensitive adhesive layer 3-1 of described safety anti-explosive layer, second safety pressure
The thickness of quick glue-line 3-2 and the 3rd safe pressure-sensitive adhesive layer 3-3 is identical or entirely different, or any two of which
Identical.
In embodiment 1,2,3, the thickness of described safety anti-explosive fenestrated membrane is 100～695 μm, and wherein, the thickness of wearing layer 1 is
2～6 μm；The thickness of mould release membrance 4 is 23～50 μm.
As a example by embodiment 3, the detailed description of the invention of safety anti-explosive fenestrated membrane is prepared in description, operates as follows:
(A) raw material is prepared
1. base material is prepared
Prepare polyester film 2-1,2-3 and be respectively thickness 50 μm, the transparent polyester film of 100 μm；
Prepare the transparent polyurethane film that polyurethane film 2-2 is thickness 100 μm；
Prepare the mould release membrance 4 that thickness is 36 μm；
2. preparation forms the mixed material of wearing layer 1
Prepare scraping-resistant agent and solvent ethyl acetate for 1:1 in mass ratio, the two mix homogeneously is prepared the mixing forming wearing layer
Material, saves backup, and wherein, scraping-resistant agent is the urethane acrylate class coating produced along Chemical Co., Ltd. in Danyang
BW1001；Ethyl acetate is from Changzhou Asource Chemical Co., Ltd.；
3. preparation forms the mixed material of safe pressure-sensitive adhesive layer 3-1,3-2,3-3
By adhesive: solvent: ultraviolet absorber: the mass ratio of firming agent is that 20:20:0.3:0.3 prepares each component, in environment temperature
Degree is at 15～25 DEG C, saves backup after stirring；
Wherein, adhesive is 180-1197, and it is Shanghai National Starch factory product；Ultraviolet absorber is T-571, and it is Germany's bar
Si Fu joint-stock company product；Solvent is ethyl acetate, from Changzhou Asource Chemical Co., Ltd.；
(B) safety anti-explosive fenestrated membrane is prepared
On a surface of first transparent polyester film 2-1, after coating forms the mixed material of wearing layer 1, it is dried and light is solid
Changing and obtain wearing layer 1, its thickness is 3 μm, coated safety pressure-sensitive adhesive layer on another surface of first transparent polyester film 2-1
Mixed material after, be dried and heat cure obtain first safe pressure-sensitive adhesive layer 3-1, its thickness 18 μm, second transparent poly-ammonia
One surface recombination of ester film 2-2 is at the outer surface of first safe pressure-sensitive adhesive layer 3-1, the most again at second transparent polyurethane
On another surface of film 2-2 after the mixed material of coated safety pressure-sensitive adhesive layer, it is dried and heat cure obtains safe pressure-sensitive adhesive layer
3-2, its thickness 18 μm, in the surface recombination of the 3rd transparent polyester film 2-3 at the outer surface of safe pressure-sensitive adhesive layer 3-2,
After on another surface of the 3rd transparent polyester film 2-3, coating forms the mixed material of safe pressure-sensitive adhesive layer, it is dried and hot
Solidification obtains pressure-sensitive adhesive layer 3-3, and its thickness is 20 μm, then mould release membrance 4 is compounded in the outer surface of safe pressure-sensitive adhesive layer 3-3, from
And obtaining the safety anti-explosive fenestrated membrane that each layer is complex as a whole, its thickness is 345 μm (as shown in Figure 3).
(C) detection explosion-proof safety window film properties
With reference to CAS140-2007 glass safety film standard, the performance of the safety anti-explosive fenestrated membrane of above-mentioned preparation is detected, result
Showing, the safety anti-explosive fenestrated membrane product prepared as stated above meets its B grade standard, i.e. fenestrated membrane product and is affixed on 6mm glass surface
After, highly falling 5 times through the steel ball of 3kg weight at 3 meters and still will not be run through, safety anti-explosive is functional.
It is strong that the safety anti-explosive fenestrated membrane of the present invention has viscosity, good in optical property, it is possible to effectively prevent external hard thing to glass
The advantages such as scuffing are caused on surface, and the safety anti-explosive fenestrated membrane of the present invention ensure that glass is heated evenly, it is to avoid fragmentation, by external force
During shock, it is possible to effectively stop penetrator, glass fragmentation faced or when coming off, it is possible to active adsorption fragment, it is to avoid glass or fragment fall
Fall, cause secondary injury；And use very simple, as long as after according to concrete size cutting, after outermost mould release membrance 4 is peeled off
It is pasted onto glass surface.It is applicable to prepare double glazing, safety glass door and window, glass curtain wall etc. and needs the thing of safety anti-explosive
Body, is particularly suitable for being pasted onto the glass surface of the glass surface of building or automobile, has the effect of good safety anti-explosive.
Claims (8)
1. a safety anti-explosive fenestrated membrane, has wearing layer (1), mould release membrance (4), it is characterised in that described wearing layer (1) and mould release membrance
(4) also have safety anti-explosive layer between, and each layer is complex as a whole；
Described safety anti-explosive layer is made up of first polyester film (2-1) and first safe pressure-sensitive adhesive layer (3-1), wherein, and first
The thickness of individual polyester film (2-1) is 23～188 μm, and the thickness of first safe pressure-sensitive adhesive layer (3-1) is 6～25 μm；Wearing layer
(1) ultraviolet light polymerization is combined on a surface of first polyester film (2-1), the thermosetting of first safe pressure-sensitive adhesive layer (3-1)
Changing and be combined on another surface of first polyester film (2-1), mould release membrance (4) is compounded in first safe pressure-sensitive adhesive layer (3-
1) outer surface constitutes safety anti-explosive fenestrated membrane；
Or, described safety anti-explosive layer is by first polyester film (2-1), first safe pressure-sensitive adhesive layer (3-1), second poly-ammonia
Ester film (2-2) and second safe pressure-sensitive adhesive layer (3-2) composition, wherein, first polyester film (2-1) and second polyurethane film
(2-2) thickness is 23～188 μm, first safe pressure-sensitive adhesive layer (3-1) and the thickness of second safe pressure-sensitive adhesive layer (3-2)
Degree is 6～25 μm；Wearing layer (1) ultraviolet light polymerization is combined on a surface of first polyester film (2-1), first peace
Full pressure-sensitive adhesive layer (3-1) heat cure is combined on another surface of first polyester film (2-1), second polyurethane film (2-
2) a surface recombination is in the outer surface of first safe pressure-sensitive adhesive layer (3-1), the thermosetting of second safe pressure-sensitive adhesive layer (3-2)
Changing and be combined on another surface of second polyurethane film (2-2), mould release membrance (4) is compounded in second safe pressure-sensitive adhesive layer
(3-2) outer surface constitutes safety anti-explosive fenestrated membrane；
Or, described safety anti-explosive layer is by first polyester film (2-1), first safe pressure-sensitive adhesive layer (3-1), second poly-ammonia
Ester film (2-2), second safe pressure-sensitive adhesive layer (3-2), the 3rd polyester film (2-3) and the 3rd safe pressure-sensitive adhesive layer (3-3)
Composition, wherein, the thickness of first polyester film (2-1), second polyurethane film (2-2) and the 3rd polyester film (2-3) is
23～188 μm, described first safe pressure-sensitive adhesive layer (3-1), second safe pressure-sensitive adhesive layer (3-2) and the 3rd safety are pressure-sensitive
The thickness of glue-line (3-3) is 6～25 μm；Wearing layer (1) ultraviolet light polymerization is combined in a table of first polyester film (2-1)
On face, the heat cure of first safe pressure-sensitive adhesive layer (3-1) is combined on another surface of first polyester film (2-1), and second
One surface recombination of individual polyurethane film (2-2) is at the outer surface of first safe pressure-sensitive adhesive layer (3-1), and second safety is pressure-sensitive
Glue-line (3-2) heat cure is combined on another surface of second polyurethane film (2-2), the one of the 3rd polyester film (2-3)
Individual surface recombination combines in the outer surface of second safe pressure-sensitive adhesive layer (3-2), the 3rd safe pressure-sensitive adhesive layer (3-3) heat cure
On another surface of the 3rd polyester film (2-3), mould release membrance (4) is compounded in the appearance of the 3rd safe pressure-sensitive adhesive layer (3-3)
Face constitutes safety anti-explosive fenestrated membrane；
Form first safe pressure-sensitive adhesive layer (3-1), second safe pressure-sensitive adhesive layer (3-2), the 3rd safe pressure-sensitive adhesive layer (3-
3) mixed material is identical, is all by adhesive 30 ~ 70wt%, solvent 30 ~ 70wt%, ultraviolet absorber 0.1 ~ 5wt%, Gu
Agent 0.1 ~ 5wt% forms, and above-mentioned each component sum is 100wt%, and wherein, described ultraviolet absorber is benzotriazole, benzene first
One or more in ketone, triazines.
Safety anti-explosive fenestrated membrane the most according to claim 1, it is characterised in that formed wearing layer (1) mixed material be by
Scraping-resistant agent 40 ~ 60wt%, solvent ethyl acetate 40 ~ 60wt% form, and above-mentioned each component sum is 100wt%.
Safety anti-explosive fenestrated membrane the most according to claim 1, it is characterised in that first that forms described safety anti-explosive layer poly-
Ester film (2-1) is identical with the 3rd polyester film (2-3), is the most all transparent polyester film, or is all dyeing polyester film or is all
Primary colors polyester film, or be all ultraviolet-resistant polyester film, or be all aluminized polyester film, or be all magnetron sputtering polyester film.
Safety anti-explosive fenestrated membrane the most according to claim 1, it is characterised in that first that forms described safety anti-explosive layer poly-
Ester film (2-1) and the 3rd polyester film (2-3) are different, are transparent polyester film, dyeing polyester film, primary colors polyester film, ultraviolet resistance
Every any one of polyester film, aluminized polyester film, magnetron sputtering polyester film.
Safety anti-explosive fenestrated membrane the most according to claim 1, it is characterised in that described second polyurethane film (2-2) is
Bright polyurethane film, dyeing polyurethane film, primary colors polyurethane film, ultraviolet-resistant polyurethane film, polyurethane film of aluminizing, magnetron sputtering gather
Any one of urethane film.
Safety anti-explosive fenestrated membrane the most according to claim 1, it is characterised in that first that forms described safety anti-explosive layer poly-
Ester film (2-1), second polyurethane film (2-2) is identical or entirely different with the thickness of the 3rd polyester film (2-3),
Or any two of which is identical.
Safety anti-explosive fenestrated membrane the most according to claim 1, it is characterised in that form first peace of described safety anti-explosive layer
Full pressure-sensitive adhesive layer (3-1), second safe pressure-sensitive adhesive layer (3-2) and the complete phase of thickness of the 3rd safe pressure-sensitive adhesive layer (3-3)
With, entirely different, or any two of which is identical.
Safety anti-explosive fenestrated membrane the most according to claim 1, it is characterised in that the thickness of described safety anti-explosive fenestrated membrane is 100
～695 μm, wherein, the thickness of wearing layer (1) is 2～6 μm；The thickness of mould release membrance (4) is 23～50 μm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610756665.4A CN106183284A (en) | 2016-08-30 | 2016-08-30 | Safety anti-explosive fenestrated membrane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610756665.4A CN106183284A (en) | 2016-08-30 | 2016-08-30 | Safety anti-explosive fenestrated membrane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106183284A true CN106183284A (en) | 2016-12-07 |
Family
ID=58088461
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610756665.4A Pending CN106183284A (en) | 2016-08-30 | 2016-08-30 | Safety anti-explosive fenestrated membrane |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106183284A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108165186A (en) * | 2018-02-08 | 2018-06-15 | 江门市膜先生塑料实业有限公司 | A kind of easy clean explosion-proof composite membrane of Buddha's warrior attendant nanometer and preparation method thereof |
| CN109593486A (en) * | 2018-12-21 | 2019-04-09 | 苏州诚聚节能科技有限公司 | A kind of production complex method of glass-film |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1757508A (en) * | 2005-07-18 | 2006-04-12 | 项永忠 | Multi-layered, composite, thermal-isolation and explosion-proof glass film |
| CN102634292A (en) * | 2012-04-12 | 2012-08-15 | 苏州金海薄膜科技发展有限公司 | Explosion-proof glass film for isolating infrared ray and ultraviolet ray and preparation method thereof |
| CN203344390U (en) * | 2013-05-21 | 2013-12-18 | 常州博光薄膜科技有限公司 | Heat insulation film |
| CN104149453A (en) * | 2014-08-08 | 2014-11-19 | 常州山由帝杉防护材料制造有限公司 | Ultraviolet-blocking window film |
| CN205185460U (en) * | 2015-11-16 | 2016-04-27 | 皇冠（太仓）胶粘制品有限公司 | Rupture film |
| CN105885719A (en) * | 2016-05-17 | 2016-08-24 | 东莞市睿泰涂布科技有限公司 | TPU (thermoplastic polyurethane) explosion-proof membrane and preparation technique thereof |
-
2016
- 2016-08-30 CN CN201610756665.4A patent/CN106183284A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1757508A (en) * | 2005-07-18 | 2006-04-12 | 项永忠 | Multi-layered, composite, thermal-isolation and explosion-proof glass film |
| CN102634292A (en) * | 2012-04-12 | 2012-08-15 | 苏州金海薄膜科技发展有限公司 | Explosion-proof glass film for isolating infrared ray and ultraviolet ray and preparation method thereof |
| CN203344390U (en) * | 2013-05-21 | 2013-12-18 | 常州博光薄膜科技有限公司 | Heat insulation film |
| CN104149453A (en) * | 2014-08-08 | 2014-11-19 | 常州山由帝杉防护材料制造有限公司 | Ultraviolet-blocking window film |
| CN205185460U (en) * | 2015-11-16 | 2016-04-27 | 皇冠（太仓）胶粘制品有限公司 | Rupture film |
| CN105885719A (en) * | 2016-05-17 | 2016-08-24 | 东莞市睿泰涂布科技有限公司 | TPU (thermoplastic polyurethane) explosion-proof membrane and preparation technique thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108165186A (en) * | 2018-02-08 | 2018-06-15 | 江门市膜先生塑料实业有限公司 | A kind of easy clean explosion-proof composite membrane of Buddha's warrior attendant nanometer and preparation method thereof |
| CN109593486A (en) * | 2018-12-21 | 2019-04-09 | 苏州诚聚节能科技有限公司 | A kind of production complex method of glass-film |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106414642B (en) | Acrylic pressure-sensitive adhesive compositions with controlled molecular weight | |
| CN103443228B (en) | Fire-retardant band | |
| CN104149453B (en) | Intercept ultraviolet fenestrated membrane | |
| KR20140012736A (en) | Flame retarding adhesives | |
| CN106183284A (en) | Safety anti-explosive fenestrated membrane | |
| CN104175664B (en) | Intercept ultraviolet thermal-insulation window film | |
| KR101501863B1 (en) | Coating material, coating material layer, and laminated structure | |
| CN104149433B (en) | Intercept ultraviolet fenestrated membrane | |
| CN102975410A (en) | Grade-A fireproof aluminium alloy composite board | |
| CN202986257U (en) | Novel heat insulation ceramic window film | |
| BRPI0506667A (en) | fuselage | |
| CN206030688U (en) | Safe explosion -proof fenestrated membrane | |
| CN104062697A (en) | High-brightness colored reflective cloth | |
| KR101556015B1 (en) | Infrared rays-proof hard coating composition and Infrared rays-proof film by infrared rays-proof hard coating composition | |
| CN207916228U (en) | A kind of removable adhering film to glass | |
| WO2017217749A1 (en) | Binder composition for bonding polymer thermoplastic resin material, method for preparing said composition, and product bonded by said composition | |
| CN109593486A (en) | A kind of production complex method of glass-film | |
| CN113227288B (en) | Laminate having structure body including through-hole | |
| CN104149432B (en) | Intercept ultraviolet clear anti-fog fenestrated membrane | |
| KR20140045955A (en) | Easily dismantled adhesive agent composition and easily dismantled adhesive tape | |
| CN102776805A (en) | Anti-flaming wall paper | |
| CN105054445A (en) | Multifunctional biochemistry protection garment fabric | |
| CN110126392A (en) | A kind of A2 level composite material and preparation method thereof | |
| CN106281189B (en) | A kind of preparation method of hot melt fitting Special safety film | |
| CN205368221U (en) | Prevent blue light and antifog insulating protecting membrane |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161207 |