CN106178609A - A kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production - Google Patents
A kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production Download PDFInfo
- Publication number
- CN106178609A CN106178609A CN201610722262.8A CN201610722262A CN106178609A CN 106178609 A CN106178609 A CN 106178609A CN 201610722262 A CN201610722262 A CN 201610722262A CN 106178609 A CN106178609 A CN 106178609A
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- Prior art keywords
- organic
- silicon defoamer
- organic silicon
- oil
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
- B01D19/0409—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing Si-atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
- B01D19/0413—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing N-atoms
Abstract
The present invention provides a kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production, and it mainly comprises following component: silicone oil, organic solvent, organic additive.Described silicone oil is one or more in dimethicone, amido silicon oil, polyether modified silicon oil etc., and described organic solvent is one or more in kerosene, base oil, white oil etc., and described organic additive is fatty acid amide.The present invention added this organic silicon defoamer before Hydrogen Peroxide Production step hydrogenates, and prevented the generation of foam, and suds is strong, improved utilization rate of equipment and installations, reduced cost;And this organic silicon defoamer can extend and is applied to other oleaginous system.
Description
Technical field
The invention belongs to organosilicon material field, be specifically related to a kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production
Preparation method.
Background technology
At present, the technique more maturation producing hydrogen peroxide both at home and abroad is anthraquinone.Process for prepairng hydrogen peroxide by anthraquinone is main
Experience hydrogenation and two stages of oxidation.Hydrogenation stage: be dissolved in compounded organic solvent by alkyl-anthraquinone, in uniform temperature and pressure
Being passed through hydrogen under the conditions of power, hydrogenating alkyl anthraquinone generates hydrogen anthraquinone.Oxidation stage: the organic mixed solvent containing hydrogen anthraquinone is led to
Enter oxygen, the oxidized alkyl-anthraquinone that generates once again of hydrogen anthraquinone, generate hydrogen peroxide simultaneously.
Production process needs be passed through hydrogen and oxygen, in being passed through gas process, foam can be produced, occupy certain appearance
Long-pending, affect utilization rate of equipment and installations.Meanwhile, this working solution can not add aqueous or using water as the defoamer of solvent, because water meeting
On catalyst activity position, there is competitive Adsorption with anthraquinone, reduce the active constituent absorbability to anthraquinone, thus reduce catalysis
The activity of agent.At present, the defoamer for Hydrogen Peroxide Production does not the most also occur.
Summary of the invention
The present invention is directed to the problems referred to above, the technical problem to be solved in the present invention is to provide one and is applicable to Hydrogen Peroxide Production
The preparation method of organic silicon defoamer, defoamer was added before being passed through gas, suppression hydrogenation, oxidizing process is produced
Foam, prevent foam from occupying volume of equipment, improve utilization rate of equipment and installations.
The technical solution used in the present invention:
A kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production, described organic silicon defoamer includes following group by weight
Point:
Silicone oil 30 ~ 90 parts, organic solvent 10 ~ 70 parts, organic additive part 0.1 ~ 1.0 part.
Preferably, described organic silicon defoamer includes following components by weight:
Silicone oil 30 ~ 40 parts, organic solvent 59.5 ~ 69.5 parts, organic additive part 0.3 ~ 0.7 part.
Preferably, described organic silicon defoamer includes following components by weight:
Silicone oil 30 ~ 50 parts, organic solvent 10 ~ 40 parts, organic additive part 0.1 ~ 0.5 part.
Preferably, described organic silicon defoamer includes following components by weight:
Silicone oil 50 ~ 90 parts, organic solvent 40 ~ 70 parts, organic additive part 0.5 ~ 1.0 part.
Preferably, one or more during described silicone oil is dimethicone, amido silicon oil, polyether modified silicon oil.
Preferably, one or more during organic solvent is kerosene, base oil, white oil;
Preferably, organic additive is fatty acid amide.
Preferably, the consumption of the described organic silicon defoamer being applicable to Hydrogen Peroxide Production is 10-1000ppm.The present invention
Advantage as follows:
1,1) provide a kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production, added before being passed through gas, prevent foam
Producing, suds is strong, improves utilization rate of equipment and installations, reduces cost.2) organosilicon being applicable to Hydrogen Peroxide Production that the present invention provides disappears
Infusion, can extend and be applied to other oleaginous system.
2, the effective ingredient during silicone oil is this organic silicon defoamer, can be referred to as active ingredient.
3, organic solvent is as the term suggests playing the effect dissolving effective ingredient, and popular understanding will dilute, after dilution by silicone oil
Effective ingredient can preferably in hydrogen peroxide foam system disperse, improve antifoaming speed.
4, organic additive plays assosting effect, improves defoaming effect.
5, silicone oil of the present invention and the ratio of organic solvent, be related to the balance of effective ingredient and dispersibility.
Detailed description of the invention
Further illustrate the present invention below in conjunction with embodiment, but the scope of protection of present invention is not limited to implement
The scope of example statement.
Embodiment 1
A kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production, described organic silicon defoamer includes following group by weight
Point:
40 parts of silicone oil (methyl-silicone oil, amido silicon oil and polyether modified silicon oil, weight ratio is 80:8.5:11.5), 59.5 parts organic
Solvent (kerosene, base oil, white oil, weight ratio is 90:4:6), 0.5 part of fatty acid amide, the consumption of defoamer is 10ppm, point
Scattered property is relatively strong, and foam time is 40s, and the suds time is up to more than 30min.
Embodiment 2
A kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production, described organic silicon defoamer includes following group by weight
Point:
38 parts of silicone oil (methyl-silicone oil, amido silicon oil and polyether modified silicon oil, weight ratio is 90:0.5:9.5), 61.4 parts organic molten
Agent (kerosene, base oil, white oil, weight ratio is 85:6:9), 0.6 part of fatty acid amide, the consumption of defoamer is 40ppm, dispersion
Property relatively strong, foam time is 42s, and the suds time is up to more than 30min.
Embodiment 3
A kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production, described organic silicon defoamer includes following group by weight
Point:
35 parts of silicone oil (methyl-silicone oil, amido silicon oil and polyether modified silicon oil, weight ratio is 90:5.5:4.5), 64.3 parts organic molten
Agent (kerosene, base oil, white oil, weight ratio is 80:10:10), 0.7 part of fatty acid amide, the consumption of defoamer is 60ppm, point
Scattered property is relatively strong, and foam time is 50s, and the suds time is up to more than 30min.
Embodiment 4
A kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production, described organic silicon defoamer includes following group by weight
Point:
30 parts of silicone oil (methyl-silicone oil, amido silicon oil and polyether modified silicon oil, weight ratio is 90:0.5:9.5), 69.5 parts organic molten
Agent (kerosene, base oil, white oil, weight ratio is 90:4:6), 0.5 part of fatty acid amide, the consumption of defoamer is 100ppm, dispersion
Property relatively strong, foam time is 54s, and the suds time is up to more than 30min.
Embodiment 5
A kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production, described organic silicon defoamer includes following group by weight
Point:
40 parts of silicone oil (methyl-silicone oil, amido silicon oil are by weight the mixture for 99:1), 59.7 parts of organic solvent (organic solvents
For kerosene, base oil by weight the mixture for 90:10), 0.3 part of fatty acid amide, the consumption of defoamer is 200ppm, point
Scattered property is relatively strong, and foam time is 51s, and the suds time is up to more than 30min.
Embodiment 6
A kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production, described organic silicon defoamer includes following group by weight
Point:
35 parts of silicone oil (methyl-silicone oil), (organic solvent is that kerosene, base oil are by weight for 90:10's to 64.6 parts of organic solvents
Mixture), 0.4 part of fatty acid amide, the consumption of defoamer is 400ppm, and dispersibility is relatively strong, and foam time is 56s, during suds
Between up to more than 30min.
Embodiment 7
A kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production, described organic silicon defoamer includes following group by weight
Point:
30 parts of silicone oil (methyl-silicone oil), (organic solvent is that kerosene, base oil are by weight for 90:10's to 69.5 parts of organic solvents
Mixture), 0.5 part of fatty acid amide, the consumption of defoamer is 600ppm, and dispersibility is relatively strong, and foam time is 61s, during suds
Between up to more than 30min.
Embodiment 8
A kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production, described organic silicon defoamer includes following group by weight
Point:
40 parts of silicone oil (polyether modified silicon oil), (organic solvent is that kerosene, white oil are by weight for 90:10 to 59.7 parts of organic solvents
Mixture), 0.3 part of fatty acid amide, the consumption of defoamer is 800ppm, and dispersibility is relatively strong, and foam time is 54s, suds
Time is up to more than 40min.
Embodiment 9
A kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production, described organic silicon defoamer includes following group by weight
Point:
30 parts of silicone oil (polyether modified silicon oil), (organic solvent is that kerosene, white oil are by weight for 90:10 to 69.5 parts of organic solvents
Mixture), 0.5 part of fatty acid amide, the consumption of defoamer is 1000ppm, and dispersibility is relatively strong, and foam time is 44s, suds
Time is up to more than 65min.
The above embodiments are only the preferred technical solution of the present invention, and are not construed as the restriction for the present invention, this Shen
Embodiment in please and the feature in embodiment, can mutual combination in any in the case of not conflicting.The protection model of the present invention
Enclose the technical scheme should recorded with claim, including the equivalent side of technical characteristic in the technical scheme that claim is recorded
Case is protection domain.Equivalent the most in this range is improved, also within protection scope of the present invention.
Claims (7)
1. the organic silicon defoamer being applicable to Hydrogen Peroxide Production, it is characterised in that: described organic silicon defoamer includes by weight
The following components of amount part meter:
Silicone oil 30 ~ 90 parts, organic solvent 10 ~ 70 parts, organic additive part 0.1 ~ 1.0 part.
Organic silicon defoamer the most according to claim 1, it is characterised in that: described organic silicon defoamer includes by weight
The following components of meter:
Silicone oil 30 ~ 40 parts, organic solvent 59.5 ~ 69.5 parts, organic additive part 0.3 ~ 0.7 part.
Organic silicon defoamer the most according to claim 1, it is characterised in that: described organic silicon defoamer includes by weight
The following components of meter:
Silicone oil 30 ~ 50 parts, organic solvent 10 ~ 40 parts, organic additive part 0.1 ~ 0.5 part.
Organic silicon defoamer the most according to claim 1, it is characterised in that: described organic silicon defoamer includes by weight
The following components of meter:
Silicone oil 50 ~ 90 parts, organic solvent 40 ~ 70 parts, organic additive part 0.5 ~ 1.0 part.
Organic silicon defoamer the most according to claim 1, it is characterised in that: described silicone oil is dimethicone, amino silicone
One or more in oil, polyether modified silicon oil.
Organic silicon defoamer the most according to claim 1, it is characterised in that: organic solvent is in kerosene, base oil, white oil
One or more;
Organic silicon defoamer according to claim 1, it is characterised in that: organic additive is fatty acid amide.
7. according to a kind of organic silicon defoamer being applicable to Hydrogen Peroxide Production described in claim 1-7 any one, its feature
It is: the consumption of the described organic silicon defoamer being applicable to Hydrogen Peroxide Production is 10-1000ppm.
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Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010087196A1 (en) * | 2009-02-02 | 2010-08-05 | サンノプコ株式会社 | Defoaming agent |
CN101991975A (en) * | 2010-12-13 | 2011-03-30 | 南京四新科技应用研究所有限公司 | Mineral oil defoaming agent and preparation method thereof |
CN102350098A (en) * | 2011-07-16 | 2012-02-15 | 佛山市华联有机硅有限公司 | Preparation method for non-silicon antifoaming agent |
CN104069653A (en) * | 2013-03-29 | 2014-10-01 | 上海依科绿色工程有限公司 | Mineral oil defoamer and preparation method thereof |
CN104069654A (en) * | 2014-07-01 | 2014-10-01 | 西安道尔达化工有限公司 | Preparation method of high-viscosity organic silicon defoamer |
CN104436765A (en) * | 2014-12-06 | 2015-03-25 | 佛山市华联有机硅有限公司 | Preparation method of solid defoaming agent |
CN104520009A (en) * | 2012-06-30 | 2015-04-15 | 科莱恩金融(Bvi)有限公司 | Foam prevention in reserve flotation process for purifying calcium carbonate |
-
2016
- 2016-08-25 CN CN201610722262.8A patent/CN106178609A/en active Pending
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010087196A1 (en) * | 2009-02-02 | 2010-08-05 | サンノプコ株式会社 | Defoaming agent |
CN101991975A (en) * | 2010-12-13 | 2011-03-30 | 南京四新科技应用研究所有限公司 | Mineral oil defoaming agent and preparation method thereof |
CN102350098A (en) * | 2011-07-16 | 2012-02-15 | 佛山市华联有机硅有限公司 | Preparation method for non-silicon antifoaming agent |
CN104520009A (en) * | 2012-06-30 | 2015-04-15 | 科莱恩金融(Bvi)有限公司 | Foam prevention in reserve flotation process for purifying calcium carbonate |
CN104069653A (en) * | 2013-03-29 | 2014-10-01 | 上海依科绿色工程有限公司 | Mineral oil defoamer and preparation method thereof |
CN104069654A (en) * | 2014-07-01 | 2014-10-01 | 西安道尔达化工有限公司 | Preparation method of high-viscosity organic silicon defoamer |
CN104436765A (en) * | 2014-12-06 | 2015-03-25 | 佛山市华联有机硅有限公司 | Preparation method of solid defoaming agent |
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