CN107974313A - A kind of preparation method of octane number accelerating agent - Google Patents
A kind of preparation method of octane number accelerating agent Download PDFInfo
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- CN107974313A CN107974313A CN201710817974.2A CN201710817974A CN107974313A CN 107974313 A CN107974313 A CN 107974313A CN 201710817974 A CN201710817974 A CN 201710817974A CN 107974313 A CN107974313 A CN 107974313A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/103—Liquid carbonaceous fuels containing additives stabilisation of anti-knock agents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/08—Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/10—Use of additives to fuels or fires for particular purposes for improving the octane number
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/183—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom
- C10L1/1832—Organic compounds containing oxygen containing hydroxy groups; Salts thereof at least one hydroxy group bound to an aromatic carbon atom mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/223—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom
- C10L1/2235—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond having at least one amino group bound to an aromatic carbon atom hydroxy containing
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2270/00—Specifically adapted fuels
- C10L2270/02—Specifically adapted fuels for internal combustion engines
- C10L2270/023—Specifically adapted fuels for internal combustion engines for gasoline engines
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- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention discloses a kind of preparation method of octane number accelerating agent, include the following steps:By the combustion adjuvant of 1~30 parts by weight, the stabilizer of 0.01~3 parts by weight and 0.01~5 parts by weight except gum agents mix; under protective atmosphere; it is slowly added to the anti-knock agent of 50~85 parts by weight; stir to the transparent state of mixed liquor; the pH value of mixed liquor is adjusted to 6.5~7.5 by acid-base modifier; continue to stir, be down to room temperature naturally, up to the octane number accelerating agent.The preparation method technique of the present invention is simple, cost is low, stable processing technique, reproducible.The octane number accelerating agent being prepared by the present invention is pure organic octane number accelerating agent, pollution-free, completely ashless;Additive amount is few, and octane number enhancing rate is obvious;Crystallization and freezing is not easy, good with gasoline intersolubility, resistance to oxidation is not decomposed, safe.
Description
Technical field
The invention belongs to organic chemical industry field, more particularly to a kind of preparation method of octane number accelerating agent.
Background technology
In recent years, highlighting with home and abroad environment problem, countries in the world start the stringenter gasoline mark of strict implement
Standard, improves gasoline quality, solves the problem of environmental pollution that the use of fossil fuel is brought.In the used many metals of people and
In nonmetallic octane rating promoter, the using effect of metallic anti-knock agent is splendid and additive amount is small.But the shortcomings that it is maximum is discharge
Heavy metal, has high risks to environment so that it has dispute in use, and long-time service is also bound to cause Metal-accumulation, draws
Play spark plug failure, cause the defects of exhaust valve lost of life.For this reason, people put into great effort again studies pure organic compound
As octane rating promoter, such as methyl tertiary butyl ether(MTBE) (MTBE), it is with preferable anti-knock properties, but its oxygen content is higher,
Additive amount is larger (generally higher than 10%) in gasoline harmonic process, and octane number lifting is ineffective;It is easier to penetrate into ground at the same time
Lower water source, and water pollution is caused, therefore its use is subject to certain restrictions and restricts.
Therefore, pollution-free, stable processing technique, safe, the obvious octane of octane number enhancing rate how is prepared
Value accelerating agent is current wide concerned technical problem.
The content of the invention
The shortcomings that it is an object of the invention to overcome the prior art and deficiency, there is provided a kind of system of octane number accelerating agent
Preparation Method, using containing a kind of alkyl phenyl compound antiknock that can catch the living radical that gasoline produces in combustion
Agent, except gum agents, combustion adjuvant, stabilizer and acid-base modifier be raw material, and obtaining one kind by the preparation method of the present invention can
It is obviously improved the octane number accelerating agent of octane number.
The purpose of the present invention is achieved through the following technical solutions:
A kind of preparation method of octane number accelerating agent, includes the following steps:By the combustion adjuvant of 1~30 parts by weight,
The stabilizer of 0.01~3 parts by weight and 0.01~5 parts by weight are mixed except gum agents, under protective atmosphere, it is slowly added to 50~
The anti-knock agent of 85 parts by weight, is stirred to the transparent state of mixed liquor, by acid-base modifier adjust the pH value of mixed liquor to 6.5~
7.5, continue to stir, be down to room temperature naturally, up to the octane number accelerating agent.
The anti-knock agent for being slowly added to 50~85 parts by weight preferably carries out under conditions of 20 DEG C~50 DEG C.
The anti-knock agent be be under structure shown in formula I and room temperature liquid phenylalkyl compound in one kind or at least
Two kinds,
Wherein, R is the alkyl or alkoxy of C1~C20, and X is amino or hydroxyl.
The anti-knock agent is preferably with one kind or at least two in the phenylalkyl compound such as lower structure:
It is described except gum agents be preferably N,N-dimethylformamide, DMAC N,N' dimethyl acetamide, acetamide, formamide,
N- methyl caprolactams, N, N- dimethyl propylene alkenyls urea, 1,3- dimethyl-2-imidazolinones, 1-methyl-2-pyrrolidinone, N- hexamethylenes
Base pyrrolidones, 2-Pyrrolidone, 1- methylimidazoles or one kind in 2-methylimidazole or at least two with polyethylene glycol 200,
One kind or at least two composition in Liquid Macrogol, polyethylene glycol 400 or Macrogol 600.
The combustion adjuvant be preferably ethanol, isopropanol, butanol, isobutanol, the tert-butyl alcohol, amylalcohol, isoamyl alcohol, n-hexyl alcohol,
One kind in cyclohexanol, benzylalcohol, n-octyl alcohol, isooctanol, Decanol, lauryl alcohol or hexadecanol or at least two.
The stabilizer is preferably phenol, DBPC 2,6 ditertiary butyl p cresol, 2,6- xylenols, decanedioic acid double 1,2,
2,6,6- pentamethvls alcohol ester, bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate or succinic acid (4- hydroxyl -2,2,
6,6- tetramethyl -1- piperidine ethanols) one kind or at least two in ester.
The acid-base modifier be preferably diethyl toluamide, monoethanolamine, Propanolamine, butanolamine, acetic acid, butyric acid,
One kind in isobutyric acid, valeric acid, isovaleric acid, caproic acid, octanoic acid or isooctyl acid or at least two.
The amount of the acid-base modifier is preferably 0.1~5 parts by weight.
The protective atmosphere is preferably nitrogen.
The time of the stirring is preferably 10~30min.
The time for continuing stirring is preferably 10~20min.
The living radical that the octane number accelerating agent is produced in combustion by catching gasoline, by sudden
Go out free radical, to reduce the moment burn rate of gasoline, to improve the octane number of gasoline, so as to improve its capability of antidetonance.
The present invention is had the following advantages relative to the prior art and effect:
1st, such octane number accelerating agent preparation method simplicity, easily realization, pollution-free, stable processing technique, repeatability
Well, cost is low.
2nd, such octane number accelerating agent is pure organic octane number accelerating agent, complete ashless class accelerating agent, no
Easy crystallization and freezing, with gasoline intersolubility is good, resistance to oxidation is not decomposed, safe, octane number enhancing rate is obvious.
3rd, such octane number accelerating agent additive amount is small, and octane number improves positive effect;Meanwhile with accumulation superposition line
Property effect, its octane number enhancing rate with its additive amount (in 0.5~5% section) linearly increase.
4th, there is such octane number accelerating agent easy to use, oil saving and pollution reducing, reduction engine fuel oil system colloid to sink
Product, the effect for mitigating engine scuffing.
Embodiment
With reference to embodiment, the present invention is described in further detail, but the implementation of the present invention is not limited to this.
Embodiment 1
By 3 parts by weight of ethanol and 5 parts by weight butanol, double 1,2,2,6, the 6- pentamethvl alcohol esters of 0.1 parts by weight decanedioic acid,
1 parts by weight acetamide and 2 parts by weight polyethylene glycol 400s are added in the mixing kettle with stirring, under nitrogen protection, in room temperature (25
DEG C) under start to be slowly added to 85 parts by weight o-ethoxyphenols, continue stir 10min obtain transparent mixed liquor, detect its pH value, and
0.1 parts by weight diethyl toluamide is added under agitation, is adjusted mixed liquor pH value to 6.9, is continued to stir 10min, treat it
After being down to room temperature (25 DEG C), up to octane number accelerating agent finished product, its solidification point is about 5 DEG C, and 25 DEG C are not kept in dark place 15
It is non-discolouring.
By octane number accelerating agent made from the present embodiment, being added to base oil by the amount of 1% (w/w), (organon is pungent
Alkane value RON=89) in, the research octane number (RON) of obtained product oil is measured according to national standard GB/T5487-1995, institute
The RON=91.6 of product oil is obtained, adds 2.6 octane numbers;Its 2% amount is added in base oil (RON=89), gained
The RON=94.2 of product oil, adds 5.2 octane numbers.
Embodiment 2
By 10 parts of cyclohexanol of 6 parts by weight butanol and parts by weight, 1 parts by weight double (2,2,6,6- tetramethyl -4- piperidyls) last of the ten Heavenly stems
Two acid esters, 0.1 parts by weight formamide and 0.1 parts by weight polyethylene glycol 200 are added in the mixing kettle with stirring, are protected in nitrogen
Under, start to be slowly added to 68 parts by weight o-methoxyphenols and 12 parts by weight para aminophenyl ethyl ethers at 30 DEG C, continue to stir
20min obtains transparent mixed liquor, detects its pH value, and adds 0.2 parts by weight of ethanol amine under agitation, adjust mixed liquor pH value to
6.9, continue to stir 10min, treat that it is cooled to room temperature, up to octane number accelerating agent finished product, its solidification point is about 0 DEG C, and
25 DEG C be not kept in dark place 15 days it is non-discolouring.
Its 1% amount is added in base oil (RON=90), gained finished product is measured according to national standard GB/T5487-1995
The RON=92.2 of oil, adds 2.2 octane numbers;Its 2% amount is added in base oil (RON=90), gained product oil
RON=94.4, add 4.4 octane numbers.
Embodiment 3
By 30 parts by weight of isobutanol, 0.01 parts by weight 2,6- xylenols, 2 parts by weight 1,3- dimethyl -2- imidazolines
Ketone and 0.1 parts by weight Liquid Macrogol are added in the mixing kettle with stirring, under nitrogen protection, start slowly to add at 40 DEG C
Enter 60 parts by weight neighbour dodecyl phenols and 25 parts by weight paraphenetidines, continue stirring 20min and obtain transparent mixed liquor, detect
Its pH value, and 3 parts by weight butanolamines are added under agitation, mixed liquor pH value is adjusted to 7.0, is continued to stir 20min, is treated that it is down to
After room temperature, up to octane number accelerating agent finished product, its solidification point is about -6 DEG C, and 25 DEG C be not kept in dark place 15 days it is non-discolouring.
Its 1% amount is added in base oil (RON=90), the RON=of gained product oil is measured according to national standard GB/T5487-1995
92.8, add 2.8 octane numbers;Its 2% amount is added in base oil (RON=90), the RON=of gained product oil
95.5, add 5.5 octane numbers.
Embodiment 4
By 5 parts by weight of isopropyl alcohol and 10 parts by weight isooctanol, 0.3 parts by weight succinic acid (4- hydroxyls -2,2,6,6- tetramethyls
Base -1- piperidine ethanols) ester, 4 parts by weight N- cyclohexyl pyrrolidones and 0.05 parts by weight Macrogol 600 add mixing for band stirring
Close in kettle, under nitrogen protection, start to be slowly added to 85 parts by weight 3-Isopropylphenols at 50 DEG C, continue stirring 20min and obtain
Transparent mixed liquor, detects its pH value, and adds 5 parts by weight Propanolamines under agitation, adjusts mixed liquor pH value to 7.0, continues to stir
20min is mixed, treats that it is cooled to room temperature, up to octane number accelerating agent finished product, its solidification point is about 3 DEG C, and 25 DEG C of not lucifuges
Preserve 15 days it is non-discolouring.Its 1% amount is added in base oil (RON=90), institute is measured according to national standard GB/T5487-1995
The RON=91.9 of product oil is obtained, adds 1.9 octane numbers;Its 2% amount is added in base oil (RON=90), gained
The RON=93.8 of product oil, adds 3.8 octane numbers.
Embodiment 5
By 5 parts by weight of isopropyl alcohol and 22 parts by weight benzylalcohols, 1 parts by weight 2,6-di-tert-butyl p-cresol, 3 parts by weight N- methyl
Pyrrolidones and 0.1 parts by weight Liquid Macrogol are added in the mixing kettle that band stirs, under nitrogen protection, at 30 DEG C
75 parts by weight o-tert-butyl ether phenol are slowly added to, continues stirring 20min and obtains transparent mixed liquor, detect its pH value, and stirring
1.5 parts by weight diethyl toluamides of lower addition, adjust mixed liquor pH value to 6.9, continue to stir 20min, treat that it is down to room
Wen Hou, up to octane number accelerating agent finished product, its solidification point is about -8 DEG C, and 25 DEG C be not kept in dark place 15 days it is non-discolouring.Will
Its 1% amount is added in base oil (RON=90), and the RON=of gained product oil is measured according to national standard GB/T5487-1995
92.1, add 2.1 octane numbers;Its 2% amount is added in base oil (RON=90), the RON=of gained product oil
94.2, add 4.2 octane numbers.
Embodiment 6
By 8 parts by weight cyclohexanol and 20 parts by weight benzylalcohols, 2 parts by weight of phenol, 1 parts by weight N, N- dimethyl propylene alkenyl urea and
0.3 parts by weight polyethylene glycol 400 is added in the mixing kettle with stirring, under nitrogen protection, starts to be slowly added to 50 at room temperature
Parts by weight iso-octyl ether phenol and 20 parts by weight p-aminophenyl isopropyl ethers, continue stirring 10min and obtain transparent mixed liquor, detect
Its pH value, and 2 parts by weight diethyl toluamides are added under agitation, mixed liquor pH value is adjusted to 7.0, continues to stir
20min, treats that it is cooled to room temperature, and up to octane number accelerating agent finished product, its solidification point is about -1 DEG C, and 25 DEG C not lucifuge protect
Deposit 15 days it is non-discolouring.Its 1% amount is added in base oil (RON=90), gained is measured according to national standard GB/T5487-1995
The RON=92.9 of product oil, adds 2.9 octane numbers;Its 2% amount is added in base oil (RON=90), gained into
The RON=95.7 of product oil, adds 5.7 octane numbers.
Embodiment 7
By 5 parts by weight lauryl alcohols and 15 parts by weight isoamyl alcohol, 1 parts by weight of phenol, 0.1 parts by weight 1- methylimidazoles and 0.4
Parts by weight polyethylene glycol 200 is added in the mixing kettle with stirring, under nitrogen protection, starts to be slowly added to 75 weight at room temperature
Part p-aminophenyl isopropyl ether, continues stirring 10min and obtains transparent mixed liquor, detect its pH value, and add 0.1 weight under agitation
Part isooctyl acid is measured, mixed liquor pH value is adjusted to 7.0, continues to stir 10min, treat that it is cooled to room temperature, promote up to octane number
Into agent finished product, its solidification point is about -12 DEG C, and 25 DEG C be not kept in dark place 15 days it is non-discolouring.Its 1% amount is added to base oil
(RON=90) in, the RON=93.1 of gained product oil is measured according to national standard GB/T5487-1995, adds 3.1 octane numbers;
Its 2% amount is added in base oil (RON=90), the RON=96.2 of gained product oil, adds 6.2 octane numbers.
Embodiment 8
By 25 parts by weight isoamyl alcohol, 0.02 parts by weight decanedioic acid double 1,2,2,6,6- pentamethvl alcohol esters, 0.2 parts by weight
2-methylimidazole and 0.1 parts by weight Macrogol 600 are added in the mixing kettle with stirring, under nitrogen protection, are opened at room temperature
Beginning is slowly added to 78 parts by weight metacresols and 5 parts by weight para aminophenyl ethyl ethers, continues stirring 30min and obtains transparent mixed liquor, detects
Its pH value, and 0.1 parts by weight of ethanol amine is added under agitation, mixed liquor pH value is adjusted to 7.0, is continued to stir 10min, is treated its drop
To room temperature, up to octane number accelerating agent finished product, its solidification point is about -2 DEG C, and 25 DEG C be not kept in dark place 15 days it is constant
Color.Its 1% amount is added in base oil (RON=90), gained product oil is measured according to national standard GB/T5487-1995
RON=91.7, adds 1.7 octane numbers;Its 2% amount is added in base oil (RON=90), gained product oil
RON=93.4, adds 3.4 octane numbers.
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention and from above-described embodiment
Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (10)
1. a kind of preparation method of octane number accelerating agent, it is characterised in that include the following steps:
By the combustion adjuvant of 1~30 parts by weight, the stabilizer of 0.01~3 parts by weight and 0.01~5 parts by weight except gum agents mix,
Under protective atmosphere, the anti-knock agent of 50~85 parts by weight is slowly added to, stirs to the transparent state of mixed liquor, passes through acid-base accommodation
Agent adjusts the pH value of mixed liquor to 6.5~7.5, continues to stir, is down to room temperature naturally, promotes up to the octane number
Agent.
2. the preparation method of octane number accelerating agent according to claim 1, it is characterised in that:
The anti-knock agent for being slowly added to 50~85 parts by weight carries out under conditions of 20 DEG C~50 DEG C.
3. the preparation method of octane number accelerating agent according to claim 1, it is characterised in that:
The anti-knock agent be be under structure shown in formula I and room temperature liquid phenylalkyl compound in one kind or at least two
Kind,
Wherein, R is the alkyl or alkoxy of C1~C20, and X is amino or hydroxyl.
4. the preparation method of octane number accelerating agent according to claim 1, it is characterised in that the anti-knock agent is
One kind or at least two in phenylalkyl compound with such as lower structure:
5. the preparation method of octane number accelerating agent according to claim 1, it is characterised in that:
It is described except gum agents are N,N-dimethylformamide, DMAC N,N' dimethyl acetamide, acetamide, formamide, N- methyl oneself
Lactams, N, N- dimethyl propylene alkenyls urea, 1,3- dimethyl-2-imidazolinones, 1-methyl-2-pyrrolidinone, N- cyclohexyl pyrrolidines
Ketone, 2-Pyrrolidone, 1- methylimidazoles or one kind or at least two and polyethylene glycol 200, polyethylene glycol in 2-methylimidazole
300th, polyethylene glycol 400 or one kind or at least two composition in Macrogol 600.
6. the preparation method of octane number accelerating agent according to claim 1, it is characterised in that:
The combustion adjuvant is ethanol, isopropanol, butanol, isobutanol, the tert-butyl alcohol, amylalcohol, isoamyl alcohol, n-hexyl alcohol, cyclohexanol, benzyl
One kind in alcohol, n-octyl alcohol, isooctanol, Decanol, lauryl alcohol or hexadecanol or at least two.
7. the preparation method of octane number accelerating agent according to claim 1, it is characterised in that:
The stabilizer is phenol, the double 1,2,2,6,6- five of DBPC 2,6 ditertiary butyl p cresol, 2,6- xylenols, decanedioic acid
Methyl piperidine alcohol ester, bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate or succinic acid (4- hydroxyl -2,2,6,6- tetramethyls
Base -1- piperidine ethanols) one kind or at least two in ester.
8. the preparation method of octane number accelerating agent according to claim 1, it is characterised in that:
The acid-base modifier is diethyl toluamide, monoethanolamine, Propanolamine, butanolamine, acetic acid, butyric acid, isobutyric acid, penta
One kind in acid, isovaleric acid, caproic acid, octanoic acid or isooctyl acid or at least two.
9. the preparation method of octane number accelerating agent according to claim 1, it is characterised in that:
The amount of the acid-base modifier is 0.1~5 parts by weight.
10. the preparation method of octane number accelerating agent according to claim 1, it is characterised in that:
The protective atmosphere is nitrogen.
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Cited By (2)
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CN108998107A (en) * | 2018-06-20 | 2018-12-14 | 重庆市涪陵赵氏化工建材有限公司 | A kind of blend gasoline |
CN109468148A (en) * | 2018-12-25 | 2019-03-15 | 黄河三角洲京博化工研究院有限公司 | A kind of innoxious automobile fuel saving composition and preparation method thereof |
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