CN106178028A - A kind of method utilizing plasma-activated aqueous solution to carry out equipment disinfection sterilization - Google Patents

A kind of method utilizing plasma-activated aqueous solution to carry out equipment disinfection sterilization Download PDF

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Publication number
CN106178028A
CN106178028A CN201610653668.5A CN201610653668A CN106178028A CN 106178028 A CN106178028 A CN 106178028A CN 201610653668 A CN201610653668 A CN 201610653668A CN 106178028 A CN106178028 A CN 106178028A
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CN
China
Prior art keywords
plasma
generating device
aqueous solution
water generating
air chamber
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610653668.5A
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Chinese (zh)
Inventor
刘东平
齐志华
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Dalian Minzu University
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Dalian Nationalities University
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Priority to CN201610653668.5A priority Critical patent/CN106178028A/en
Publication of CN106178028A publication Critical patent/CN106178028A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/16Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
    • A61L2/18Liquid substances or solutions comprising solids or dissolved gases
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2202/00Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
    • A61L2202/10Apparatus features
    • A61L2202/11Apparatus for generating biocidal substances, e.g. vaporisers, UV lamps
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/04Disinfection

Abstract

A kind of method utilizing plasma-activated aqueous solution to carry out equipment disinfection sterilization, plasma water generating device includes high-field electrode, ground electrode, medium tube, dielectric-slab, fixed mount, water tank and air chamber, and plasma water generating device is passed through working gas;The aqueous solution of water or normal saline or needs sterilization is put into plasma water generating device;After steady air current, plasma water generating device is energized, and 20~30min, obtain the activated solution rich in oil active particle;As needed sterilizing equipment decontaminating apparatus, equipment is put in plasma water generating device, rinse 5~10min by activated solution.The present invention compared with prior art has equipment without damaging, without chemical agent residue, for advantages such as non-secondary pollutions after water body sterilizing.

Description

A kind of method utilizing plasma-activated aqueous solution to carry out equipment disinfection sterilization
Present disclosure relates to the method for disinfection of a kind of solution.
Background technology improves constantly along with living standard, and people are more and more higher to the requirement of water quality, so processing at water In process system, a lot of water treatment facilities need to use sterilizing equipment decontaminating apparatus, ensure good water quality.It addition, some complicated medical treatment Equipment is owing to being not equipped with special disinfection tool so that it is sterilization is abnormal difficult, and uses disinfectant solution can produce abnormal flavour, the most residual Stay thus cause secondary pollution, even affect the healthy of people.Plasma is different from the thing of solid, liquids and gases Matter the 4th state, low temperature plasma can effectively kill the bacterial micro-organism etc. being present in air and in liquid, and Can also degrade the pollutant in contaminated water.So, utilizing plasma that equipment or water body are carried out sterilizing is very must Want.
Summary of the invention it is an object of the invention to provide one and utilizes plasma-activated aqueous solution to carry out equipment disinfection to kill The method of bacterium, this method for equipment without damage, without chemical agent residue, for non-secondary pollution after water body sterilizing.
The present invention is mainly the method for the sterilizing that carries out disinfection equipment and water body, and concrete technical scheme is as follows:
The method that the present invention proposes, step is as follows:
(1) plasma water generating device: this device mainly include high-field electrode, ground electrode, medium tube, dielectric-slab, Fixed mount, water tank and air chamber, be wherein all provided with at the upper and lower opening of air chamber in the space that dielectric-slab, air chamber and two dielectric-slabs are formed If several homogenizing plates with holes, the space of these homogenizing plates composition upper and lower opening, described air chamber has and communicates with inside it Air inlet pipe, the above-mentioned dielectric-slab being positioned at air chamber upper opening sets water tank, the bottom of water tank sets fixed mount, and this fixed mount is Being made up of upper cover, supporting plate and connecting tube, the top of supporting plate sets corresponding upper cover, under the upper surface of supporting plate and upper cover Setting tube seat between end face, the bottom of supporting plate sets one end and leads to the connecting tube of its upper surface, and the other end of connecting tube communicates with air chamber, Setting medium tube in tube seat between supporting plate and upper cover, have high-field electrode inside medium tube, air chamber is stretched out in high-field electrode and one end At lower openings, the high-voltage line of dielectric-slab connects, and sets ground electrode, on water tank on the inwall of described water tank and near apical position Also there is the water inlet pipe communicated with inside it;
(2) plasma water generating device is passed through working gas;
(3) aqueous solution of water or normal saline or needs sterilization is put into plasma water generating device;
(4) after steady air current, plasma water generating device is energized, and 20~30min, obtain rich in oil active particle Activated solution;
(5) as needed sterilizing equipment decontaminating apparatus, equipment is put in plasma water generating device, by activated solution rinse 5~ 10min。
As a preferred version of the present invention, described working gas is air or oxygen or nitrogen, preferably air.
As a preferred version of the present invention, the NaCl concentration in the aqueous solution of described needs sterilization or normal saline is 0.1%~6.9%.
As a preferred version of the present invention, the flow of described working gas is 0.5~1.5L/min.
As a preferred version of the present invention, the high-field electrode of described plasma water generating device uses electric conductivity good Good metal material, such as tungsten filament, platinum filament, spun gold etc..
As a preferred version of the present invention, the ground electrode of described plasma water generating device is Copper Foil, aluminium foil etc. Material.
As a preferred version of the present invention, the medium tube of described plasma water generating device, dielectric-slab, fixing Frame, water tank and air chamber are made by quartzy or pottery or politef.
In the plasma water generating device of the present invention, high-field electrode is connected with power supply by high-voltage line, and ground electrode passes through Wired earth, high-field electrode constitutes high voltage supply part after connecting with power supply, and high-field electrode provides suitable frequency and electric discharge electricity Pressure, is passed through working gas by the air inlet pipe of air chamber, is passed through water or normal saline by water inlet pipe or needs the water of sterilization Solution, atmos low-temperature plasma activated water is gradually lowered, when with air for reaction gas because of its PH during producing Forming some hydrogen peroxide, rich oxygen containing free radical can suppress bacterial growth inside equipment and water body effectively, makes simultaneously Equipment will not be constituted the danger destroyed during with, more water body will not be polluted.
The present invention compared with prior art has the advantage that
1, for equipment disinfection without damaging, without chemical agent residue, simple operation;
2, for non-secondary pollution after water body disinfection, have no side effect, it is ensured that the safety of sterilization;
3, disinfection effect is good, efficiency is high, and service life is long, applied range.
Description of drawings 1 is the three-dimensional simplified schematic diagram of plasma water generating device of the present invention.
Fig. 2 is that the master of plasma water generating device of the present invention regards section simplified schematic diagram.
Fig. 3 is the fixed mount solid simplified schematic diagram of plasma water generating device of the present invention.
Fig. 4 is sterilization (escherichia coli) the experiment effect figure of the present invention.
Detailed description of the invention the most just combines accompanying drawing and elaborates the present invention
A kind of method utilizing plasma-activated aqueous solution to carry out equipment disinfection sterilization, step is as follows:
(1) plasma water generating device, as shown in Figure 1, Figure 2 and shown in Fig. 3, cross section is the air chamber about 9 of triangle Opening part sets 3 homogenizing plates 7 with holes in being all provided with the space that dielectric-slab 6, air chamber and two dielectric-slabs are formed, these homogenizing plates form Cross section is triangular in shape and the space of upper and lower opening, and described air chamber has the air inlet pipe 8 communicated with inside it, above-mentioned is positioned at gas Setting cross section water tank triangular in shape 1 on dielectric-slab at the upper opening of room, the bottom of water tank sets fixed mount 3, this fixed mount be by Upper cover, supporting plate and connecting tube composition, the top of supporting plate 311 sets corresponding upper cover 312, the upper surface of supporting plate and upper cover Lower surface between set tube seat 313, the bottom of supporting plate sets one end and leads to the connecting tube 314 of its upper surface, the other end of connecting tube Communicate with air chamber, in the tube seat between supporting plate and upper cover, set medium tube 5, there is inside medium tube high-field electrode, high-field electrode with One end is stretched out the high-voltage line 10 of dielectric-slab at air chamber lower openings and is connected, and sets on the inwall of described water tank and near apical position Ground electrode 2, water tank also has the water inlet pipe 4 communicated with inside it;Described ground electrode is made up of Copper Foil, described high-field electrode Being made up of tungsten filament, described medium tube is made up of quartz material, and described water tank is made up of poly (methyl methacrylate) plate, and described dielectric-slab is by pottery Material is made, and described air chamber is made up of poly (methyl methacrylate) plate.
(2) being passed through air by the air inlet pipe of plasma water generating device, air mass flow is 1L/min;
(3) aqueous solution (NaCl concentration is 2%) needing sterilization is put into plasma water generating device by water inlet pipe;
(4) after steady air current, plasma water generating device energising 30min, obtain the activation rich in oil active particle Solution;
(5) equipment is put in the water tank of plasma water generating device, rinse 10min by activated solution.

Claims (7)

1. the method utilizing plasma-activated aqueous solution to carry out equipment disinfection sterilization, is characterized in that:
(1) plasma water generating device: this device mainly includes high-field electrode, ground electrode, medium tube, dielectric-slab, fixes Frame, water tank and air chamber, be wherein all provided with dielectric-slab at the upper and lower opening of air chamber, if setting in the space of air chamber and the formation of two dielectric-slabs A dry homogenizing plate with holes, the space of these homogenizing plates composition upper and lower opening, described air chamber has entering of communicating with inside it Trachea, the above-mentioned dielectric-slab being positioned at air chamber upper opening sets water tank, and the bottom of water tank sets fixed mount, and this fixed mount is by upper Lid, supporting plate and connecting tube composition, the top of supporting plate sets corresponding upper cover, the upper surface of supporting plate and the lower surface of upper cover Between set tube seat, the bottom of supporting plate sets one end and leads to the connecting tube of its upper surface, and the other end of connecting tube communicates with air chamber, supporting plate And setting medium tube in the tube seat between upper cover, have high-field electrode inside medium tube, air chamber bottom is stretched out in high-field electrode and one end The high-voltage line of opening part dielectric-slab connects, and sets ground electrode, water tank also has on the inwall of described water tank and near apical position There is the water inlet pipe communicated with inside it;
(2) plasma water generating device is passed through working gas;
(3) aqueous solution of water or normal saline or needs sterilization is put into plasma water generating device;
(4) after steady air current, plasma water generating device is energized, and 20~30min, obtain the activation rich in oil active particle Solution;
(5) as needed sterilizing equipment decontaminating apparatus, equipment is put in plasma water generating device, rinse 5~10min by activated solution.
The method utilizing plasma-activated aqueous solution to carry out equipment disinfection sterilization the most according to claim 1, its feature It is: described working gas is air.
The method utilizing plasma-activated aqueous solution to carry out equipment disinfection sterilization the most according to claim 1 and 2, it is special Levy and be: the NaCl concentration made in the described aqueous solution needing sterilization or normal saline is 0.1%~6.9%.
The method utilizing plasma-activated aqueous solution to carry out equipment disinfection sterilization the most according to claim 3, its feature It is: the flow of described working gas is 0.5~1.5L/min.
5. according to utilizing, described in claim 1 or 2 or 4, the method that plasma-activated aqueous solution carries out equipment disinfection sterilization, It is characterized in that: the high-field electrode of described plasma water generating device uses tungsten filament or platinum filament or spun gold.
The method utilizing plasma-activated aqueous solution to carry out equipment disinfection sterilization the most according to claim 5, its feature It is: the ground electrode of described plasma water generating device is Copper Foil or aluminium foil.
The method utilizing plasma-activated aqueous solution to carry out equipment disinfection sterilization the most according to claim 6, its feature Be: medium tube, dielectric-slab, fixed mount, water tank and the air chamber of described plasma water generating device by quartz or pottery or Politef is made.
CN201610653668.5A 2016-08-11 2016-08-11 A kind of method utilizing plasma-activated aqueous solution to carry out equipment disinfection sterilization Pending CN106178028A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107715141A (en) * 2017-09-29 2018-02-23 北京市农林科学院 A kind of method based on atmos low-temperature plasma activated solution inactivation of viruses
CN107750085A (en) * 2017-08-30 2018-03-02 大连民族大学 Atmos low-temperature microplasma activates water generating device
CN108383205A (en) * 2018-01-30 2018-08-10 大连民族大学 A kind of plasma-activated water preparation apparatus
CN108617069A (en) * 2018-05-03 2018-10-02 大连民族大学 A kind of embedded plasma-activated water preparation apparatus of electrode
CN108821392A (en) * 2018-06-21 2018-11-16 大连民族大学 A kind of plasma-activated water preparation apparatus
CN110550694A (en) * 2019-09-18 2019-12-10 大连民族大学 Water purification system adopting non-equilibrium plasma jet technology
CN111315224A (en) * 2017-11-07 2020-06-19 Gea 食品策划巴克尔公司 Food processing apparatus cleaned using plasma activated water
CN115413749A (en) * 2022-08-09 2022-12-02 大连民族大学 Atmospheric pressure cold plasma preparation method and application of efficient bacteriostatic active oil-water emulsion

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CN104591355A (en) * 2015-01-29 2015-05-06 广东佳德环保科技有限公司 Method for disinfecting and sterilizing water by virtue of streamer discharge plasmas

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107750085A (en) * 2017-08-30 2018-03-02 大连民族大学 Atmos low-temperature microplasma activates water generating device
CN107715141A (en) * 2017-09-29 2018-02-23 北京市农林科学院 A kind of method based on atmos low-temperature plasma activated solution inactivation of viruses
CN111315224A (en) * 2017-11-07 2020-06-19 Gea 食品策划巴克尔公司 Food processing apparatus cleaned using plasma activated water
CN108383205A (en) * 2018-01-30 2018-08-10 大连民族大学 A kind of plasma-activated water preparation apparatus
CN108617069A (en) * 2018-05-03 2018-10-02 大连民族大学 A kind of embedded plasma-activated water preparation apparatus of electrode
CN108821392A (en) * 2018-06-21 2018-11-16 大连民族大学 A kind of plasma-activated water preparation apparatus
CN108821392B (en) * 2018-06-21 2021-04-13 大连民族大学 Plasma activated water preparation device
CN110550694A (en) * 2019-09-18 2019-12-10 大连民族大学 Water purification system adopting non-equilibrium plasma jet technology
CN110550694B (en) * 2019-09-18 2022-03-15 大连民族大学 Water purification system adopting non-equilibrium plasma jet technology
CN115413749A (en) * 2022-08-09 2022-12-02 大连民族大学 Atmospheric pressure cold plasma preparation method and application of efficient bacteriostatic active oil-water emulsion
CN115413749B (en) * 2022-08-09 2024-01-05 大连民族大学 Preparation method and application of atmospheric pressure cold plasma of efficient antibacterial active oil-water emulsion

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