CN106172401A - A kind of propargite that can eliminate uses the propargite preparation producing poisoning on Citrus - Google Patents
A kind of propargite that can eliminate uses the propargite preparation producing poisoning on Citrus Download PDFInfo
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- CN106172401A CN106172401A CN201610542345.9A CN201610542345A CN106172401A CN 106172401 A CN106172401 A CN 106172401A CN 201610542345 A CN201610542345 A CN 201610542345A CN 106172401 A CN106172401 A CN 106172401A
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- propargite
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- polyoxyethylene ether
- sodium
- citrus
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N3/00—Preservation of plants or parts thereof, e.g. inhibiting evaporation, improvement of the appearance of leaves or protection against physical influences such as UV radiation using chemical compositions; Grafting wax
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of propargite that can eliminate on Citrus, use the propargite preparation producing poisoning, the dosage form of this propargite preparation is emulsifiable powder, propargite can be eliminated on Citrus, use the poisoning of generation, described preparation contains the active component propargite of weight percentage 5% 40%, 5% 30% adsorbents, 5% 15% surfactants, 5% 40% anti-rising components, remaining for filler.The emulsifiable powder of propargite of the present invention, foliar spray can be carried out safely at a temperature of summer 20 37 DEG C, and tradition cream or the poisoning that easily causes of other dosage form will not be produced on blade face and fruit, substantially increase the safety that propargite uses in high temperature environments, thus provide the user the acaricide solution of more economically material benefit.
Description
Technical field
The invention belongs to pesticides application field, relate to propargite mite killing on Citrus and apply the technology of produced poisoning to solve
Scheme and preparation scheme.
Technical background
Propargite (Propargite), chemical name: 2-(4-tert-butyl benzene oxy) cyclohexyl acrylate-2-bright base sulfurous acid
Ester, is a kind of efficient, low toxicity, and broad spectrum activity organosulfur acaricide has stronger tagging and stomach poison function, can be widely used for preventing and treating
Cotton Gossypii, mandarin orange, Herba Marsileae Quadrifoliae fruits and vegetables, tea, the harmful demodicid mite of flowers and other crops, introduce China's preventing and treating demodicid mite class the nearlyest 20 years.Propargite has choosing
Selecting property, safer to Apis and natural enemy, residual effect is lasting, and toxicity is the lowest, endangers little to people and animals and natural environment, is integrated control
Preferable acaricide, the lasting period is 14～30 days.
Due to efficient, low toxicity, wide spectrum, cheap and use in the world and do not develop immunity to drugs for more than 30 year, thus alkynes demodicid mite
Spy is the most extensively received by the market as acaricide.
Propargite is all effective at any temperature, but effect is the most notable in hot weather, because temperature
During higher than 27 DEG C, propargite has tags and fumigates dual function.Especially using difficult anti-season in megathermal period demodicid mite class, contrast effect is more
Add notable.
Propargite is as acaricide common on market, and registration dosage form is cream and aqueous emulsion at present, but adjusts according to market
Looking into and feed back, both products use in summer and all also exist Citrus drug injury problem in various degree, and therefore this product is current
Use after autumn and winter season gathers only as Citrus clear garden medicament.
Finding according to the Chinese Academy of Agricultural Sciences's Citrus institute research, propargite not only has poisoning to Citrus spring tip tender leaf, and
Under summer high-temperature environment, if using excessive concentration or dosage excessive on fruit, fruit face can be made to produce yellow bar
Shape or irregular ring grain, affect fruit appearance.
Cream is a kind of common formulations of pesticide, is mainly made up of pesticide active ingredient, organic solvent and emulsifying agent, is one
Plant the settled solution of homogeneous stability, be watered the emulsion that can form milk shape.Cream possesses easily processing and easily stores, good drug efficacy etc.
Advantage.
Aqueous emulsion, the homogeneous emulsus formulations of pesticide of a kind of water baseization, enter water and can well be dispersed into uniform emulsion,
Mainly it is made up of pesticide active ingredient, emulsifying agent and water.
Emulsifiable powder, is also a kind of formulations of pesticide, mainly by pesticide active ingredient, adsorbent, emulsifying agent and filler group
Become, be a kind of homogeneous flowable powder formulation of outward appearance, in water can preferably emulsifying, dispersion, form metastable emulsus
Liquid.
Summary of the invention
It is an object of the invention to provide a kind of propargite preparation, propargite can be eliminated on Citrus, use the medicine of generation
Evil.
A kind of propargite that can eliminate uses the propargite preparation producing poisoning on Citrus, it is characterised in that this propargite
The dosage form of preparation is emulsifiable powder.
Further, described propargite preparation contains active component propargite 5%-40%, adsorbent 5%-30%, surface
Activating agent 5%-15%, anti-rising component 5%-40%, surplus is filler；Wherein, percentage ratio is weight percentage.
Described anti-rising component is selected from hexadecanol Emulsion, vinyl chloride docosanol, terpene resin, glyceride, 2-hydroxyl
Base-4-methoxy benzophenone, butylmethoxydibenzoylmethane, phenyl benzimidazole sulfonic acid or Uvinul T 150
In one or more.
Described adsorbent is kieselguhr, attapulgite, white carbon, fine particle calcium carbonate or Kaolin (2000 mesh).
Described surfactant includes serving as emulsifying agent, wetting agent, dispersant, synergist etc., can be nonionic
And anionic, it is also possible to be two or more compound uses.Described emulsifying agent selected from dodecylbenzene sodium sulfonate, 12
Alkyl benzene calcium sulfonate, castor oil polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, Fatty alcohol polyoxyethylene polyoxypropylene ether, benzene second
Alkene phenol polyethenoxy ether, styrenated phenol polyoxyethylene ether polyethenoxy ether or phosphate ester polyoxyethylene ether triethanolamine salt etc.；Institute
State dispersant to connect selected from naphthalene sulfonic acid condensate sodium salt, calcium lignosulfonate, sodium lignin sulfonate, polymeric polycarboxylic acid salt, Colophonium
Branch block copolymer or styrene acrylic copolymer sodium salt；Described wetting agent is selected from sodium lauryl sulphate, dibutyl naphthalene sulphur
Acid sodium or fatty alcohol-polyoxyethylene ether；Described synergist is selected from aliphatic amine polyoxyethylene ether, coconut oleoyl amine polyoxyethylene ether, tea
Saponin or fatty acid glyceride, above-mentioned surfactant accounts for the 5%-15% of propargite preparation compositions weight ratio.
Described filler is soluble inorganic salt or other inserts, preferably anhydrous sodium sulfate, sodium tripolyphosphate, carbon
Acid ammonium, ammonium sulfate, ammonium chloride, sodium benzoate, carbamide, the one or two kinds of thing mixed above in soluble starch.
In the above-mentioned emulsifiable powder that can eliminate propargite Citrus poisoning, except containing active component and function ingredients, suction
Attached dose, surfactant and carrier (filler) are outward, it may also be necessary to add solvent, stabilizer, stain etc..
Described solvent is solvent naphtha, N-Methyl pyrrolidone, decyl amide, one or both in sec-butyl acetate.
Described stabilizer is oleic acid, Polyethylene Glycol, epoxy soybean oil, sodium benzoate, epoxychloropropane etc..
Preparation can contain stain, such as azo dye or kiton colors.
In the present invention, the dosage form of propargite preparation is emulsifiable powder, has miticidal effect good, and low cost easily produces, right
The features such as Citrus safety is good.
The present invention uses the product such as 73% the most common propargite cream and 40% propargite aqueous emulsion, and summer is at honey
Fructus Citri tangerinae, red spider is prevented and treated by the Citrus such as Jiangxi is orange, under preferable preventive effect, finds that propargite can be burnt under 30-37 DEG C of high-temperature condition
Tender tip blade face and fruit, ultimately cause fruit black speck, affect fruit quality.
Comparing traditional propargite cream and aqueous emulsion, the present invention can be carried out at a temperature of summer 30-37 DEG C safely
Foliar spray, and tradition cream or the poisoning that easily causes of other dosage form will not be produced on blade face and fruit, it is greatly improved
The safety that propargite uses in high temperature environments, is a kind of ideal propargite Citrus poisoning technical solution.
The processing technique of the emulsifiable powder of invention formulation and equipment be disclose known.
Detailed description of the invention:
The present invention in order to illustrate, but is not limited to these examples with the following example that is embodied as.Percentage ratio in all formula
It is weight ratio.
The preparation of emulsifiable powder: A. first prepares propargite mother solution, will add emulsifying agent, antiperspirant in propargite crude oil
With other adjuvant component (if being solid under room temperature, add appropriate solvent heating for dissolving), it is stirring evenly and then adding into adsorbent,
Stirring mixing, is allowed to absorption uniformly, adds other surfactant and filler, after using turbine grinder coarse pulverization, enters
It is homogeneous that jet mill obtains outward appearance after pulverizing, emulsifiable scattered emulsifiable powder in water.
Embodiment 1:
Formula is: propargite 8%, calcium dodecyl benzene sulfonate 1.5%, styrenated phenol polyoxyethylene ether 1.5%, fatty alcohol
Polyoxyethylene ether 1%, white carbon 5%, calcium lignosulfonate 1.5%；ESCALOL 567 15%, ethyl hexyl
Base triazinone 25%, anhydrous sodium sulfate 10%, Polyethylene Glycol 5%, soluble starch supplies 100%.
Embodiment 2:
Formula is: propargite 15%, calcium dodecyl benzene sulfonate 2%, castor oil polyoxyethylene ether 2%, terpene resin
10%, solvent naphtha 5%, white carbon 8%, kieselguhr 5%, nekal 0.5%, tea saponin 1%, sodium lignin sulfonate
2%, polycarboxylate 1%；Uvinul T 150 10%, glyceride 5%, anhydrous sodium sulfate 10%；Soluble starch is supplied
100%.
Embodiment 3:
Formula is: propargite 20%, calcium dodecyl benzene sulfonate 2.5%, styrenated phenol polyoxyethylene ether polyethenoxy ether
0.5%, white carbon 12%, Kaolin (2000 mesh) 8%, nekal 0.5%, coconut oleoyl amine polyoxyethylene ether 1%,
Poly-sodium naphthalene sulfonate 1.5%, polycarboxylate 1%, hexadecanol Emulsion 8%, phenyl benzimidazole sulfonic acid 5%, 2-hydroxyl-4-methoxy
Base benzophenone 10%, anhydrous sodium sulfate 5%, ammonium sulfate 5%, sodium benzoate supplies 100%.
Embodiment 4:
Formula is: propargite 25%, phosphate ester polyoxyethylene ether triethanolamine salt 1.5%, and styrenated phenol polyoxyethylene gathers
Oxypropylene ether 1%, sodium lauryl sulphate 0.5%, white carbon 20%, kieselguhr 3%, polycarboxylate 2%, hexadecanol Emulsion
10%, Uvinul T 150 10%, ammonium sulfate 10%, anhydrous sodium sulfate supplies 100%.
Embodiment 5:
Formula is: propargite 30%, phosphate ester polyoxyethylene ether triethanolamine salt 2%, fatty alcohol-polyoxyethylene ether
1.5%, castor oil polyoxyethylene ether 2.5%, white carbon 25%, fine particle calcium carbonate 3%, sodium lignin sulfonate 4%, 2-hydroxyl-4-methoxy
Base benzophenone 5%；Butylmethoxydibenzoylmethane 5%, ammonium sulfate 4%, carbamide supplies 100%.
Embodiment 6:
Formula is: propargite 37%, epoxy soybean oil 1%, calcium dodecyl benzene sulfonate 2%, phosphate ester polyoxyethylene ether
Triethanolamine salt 2%, Fatty alcohol polyoxyethylene polyoxypropylene ether 2.5%, white carbon 28%, styrene acrylic copolymer sodium salt
3%；Uvinul T 150 8%, butylmethoxydibenzoylmethane 5%, sodium benzoate 5%, ammonium sulfate is supplied
100%.
With propargite preparation (emulsifiable powder of the present invention；Table all represents with C2) (use below with 73% propargite cream
C1 represents), 40% propargite aqueous emulsion (commercially available, to represent with C3 below), carry out red spider controlling experiment and propargite respectively
Safety testing to Citrus, concrete scheme and as follows to test data.
Test situation brief introduction: seeds are Fructus Citri tangerinae early-maturing variety and Jiangxi orange；Fructus Citri tangerinae kind was in spray in July 29 in 2015
Medicine, place is Hangzhou Xiaoshan army farm, when daily temperature 38 degree, 8 days temperature on average 37 degree after medicine；Jiangxi orange kind is in 2015
Year spray in July 10 medicine, place is that Mao Dian town, Gan County, Ganzhou City of Jiangxi Province pulk is near coal-mine, when daily temperature 37 degree, 8 days average air after medicine
Temperature 36 degree；
Table 1 testing program is arranged
| Medicament | Numbering | Extension rate |
| 73% propargite cream | C1 | 1500 times of preparation, 750 times, 500 times of dilutions |
| The 15% emulsifiable powder of propargite | C2 | 300 times of preparation, 150 times, 100 times of dilutions |
| 40% propargite aqueous emulsion | C3 | 833 times of preparation, 415 times, 277 times of dilutions |
| Clear water compares | CK | - |
Note: 3 samples, 1 clear water comparison, 3 concentration of each sample, each concentration 5 process, each process 20
Tree, clear water comparison 20 trees, totally 45 process, spray medicine 900 tree.
2: three kinds of products of table are to the red spider prevention effect on Hangzhou Xiaoshan Fructus Citri tangerinae and poisoning data
3: three kinds of products of table are to the red spider prevention effect on Jiangxi orange and poisoning data
| Mite killing medicament | Preventive effect | Burn rate in blade face | Fruit medicine speckle rate |
| C1-1500 times | 85% | 10% | 11% |
| C1-750 times | 90% | 21% | 19% |
| C1-500 times | 94% | 33% | 47% |
| C2-300 times | 85% | 0 | 0 |
| C2-150 times | 90% | 0 | 0 |
| C2-100 times | 92% | 0 | 0 |
| C3-833 times | 80% | 2% | 11% |
| C3-415 times | 87% | 8% | 19% |
| C3-277 times | 92% | 23% | 27% |
| Clear water comparison-CK | 0 | 0 | 0 |
Note: observe for after propargite drug effect and the damage results to blade face and fruit are spray medicine in above table 3 weeks, all
Data are meansigma methods.
From the point of view of above-mentioned experimental result, the emulsifiable powder of propargite of the present invention has preferable drug effect and safety,
Under summer high-temperature weather, the safety to common Citrus Cultivars such as Fructus Citri tangerinae and Jiangxi orange is the best, a kind of is worth of widely use
Efficiently, safety, economic mite killing medicament.
Claims (6)
1. one kind can eliminate propargite use on Citrus produce poisoning propargite preparation, it is characterised in that this propargite system
The dosage form of agent is emulsifiable powder.
Propargite preparation the most according to claim 1, it is characterised in that: described propargite preparation contains active component alkynes demodicid mite
Special 5%-40%, adsorbent 5%-30%, surfactant 5%-15%, anti-rising component 5%-40%, surplus is filler；Wherein, percentage
Ratio is weight percentage.
Propargite preparation the most according to claim 1, it is characterised in that: described anti-rising component is selected from hexadecanol breast
Agent, vinyl chloride docosanol, terpene resin, glyceride, ESCALOL 567, butyl methoxy dibenzoyl
One or more in methylmethane, phenyl benzimidazole sulfonic acid or Uvinul T 150.
Propargite preparation the most according to claim 1, it is characterised in that: described adsorbent is kieselguhr, attapulgite, white
White carbon black, fine particle calcium carbonate or Kaolin.
Propargite preparation the most according to claim 1, it is characterised in that: described surfactant includes emulsifying agent, moistening
Agent, dispersant or synergist；Described emulsifying agent is selected from dodecylbenzene sodium sulfonate, calcium dodecyl benzene sulfonate, Oleum Ricini polyoxy
Vinyl Ether, fatty alcohol-polyoxyethylene ether, Fatty alcohol polyoxyethylene polyoxypropylene ether, styrenated phenol polyoxyethylene ether, styrenated phenol
Polyoxyethylene ether polyethenoxy ether or phosphate ester polyoxyethylene ether triethanolamine salt；Described dispersant is selected from naphthalene sulfonic acid condensate
Sodium salt, calcium lignosulfonate, sodium lignin sulfonate, polymeric polycarboxylic acid salt, Colophonium graft block copolymer or styrene-acrylonitrile copolymer
Acid copolymer sodium salt；Described wetting agent is selected from sodium lauryl sulphate, nekal or fatty alcohol-polyoxyethylene ether；
Described synergist is selected from aliphatic amine polyoxyethylene ether, coconut oleoyl amine polyoxyethylene ether, tea saponin or fatty acid glyceride.
Propargite preparation the most according to claim 1, it is characterised in that: described filler is anhydrous sodium sulfate, tripolyphosphate
One or more in sodium, ammonium carbonate, ammonium sulfate, ammonium chloride, sodium benzoate, carbamide or soluble starch.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610542345.9A CN106172401B (en) | 2016-07-05 | 2016-07-05 | It is a kind of to eliminate propargite on citrus using the propargite preparation for generating phytotoxicity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610542345.9A CN106172401B (en) | 2016-07-05 | 2016-07-05 | It is a kind of to eliminate propargite on citrus using the propargite preparation for generating phytotoxicity |
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| CN106172401A true CN106172401A (en) | 2016-12-07 |
| CN106172401B CN106172401B (en) | 2019-07-16 |
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| CN201610542345.9A Active CN106172401B (en) | 2016-07-05 | 2016-07-05 | It is a kind of to eliminate propargite on citrus using the propargite preparation for generating phytotoxicity |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115769819A (en) * | 2022-11-16 | 2023-03-10 | 深圳诺普信农化股份有限公司 | Emulsifiable concentrate containing terpene resin and strobilurin fungicide as well as preparation method and application of emulsifiable concentrate |
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| CN101632361A (en) * | 2009-08-18 | 2010-01-27 | 江苏丰登农药有限公司 | Difenoconazole emulsible powder |
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2016
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| CN101518240A (en) * | 2008-02-28 | 2009-09-02 | 北京绿色农华植保科技有限责任公司 | Propargite-containing aqueous emulsion and preparation method thereof |
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Cited By (1)
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|---|---|---|---|---|
| CN115769819A (en) * | 2022-11-16 | 2023-03-10 | 深圳诺普信农化股份有限公司 | Emulsifiable concentrate containing terpene resin and strobilurin fungicide as well as preparation method and application of emulsifiable concentrate |
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| CN106172401B (en) | 2019-07-16 |
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Effective date of registration: 20221017 Address after: 343000 Tengfei Branch Road, Salt Chemical Industrial City, Xingan County, Ji'an City, Jiangxi Province Patentee after: Jiangxi Hetian Technology Co.,Ltd. Address before: 310018 plot m-18-5-4, Hangzhou Economic and Technological Development Zone, Zhejiang Province Patentee before: ZHEJIANG HETIAN CHEMICAL Co.,Ltd. Patentee before: LIANYUNGANG HETIAN CHEMICAL Co.,Ltd. |