CN106168689B - A kind of highlighted optical film producing method of high fog - Google Patents

A kind of highlighted optical film producing method of high fog Download PDF

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Publication number
CN106168689B
CN106168689B CN201610540684.3A CN201610540684A CN106168689B CN 106168689 B CN106168689 B CN 106168689B CN 201610540684 A CN201610540684 A CN 201610540684A CN 106168689 B CN106168689 B CN 106168689B
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optical film
light
producing method
coating
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CN106168689A (en
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李哲
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Shenzhen Changsong Technology Co ltd
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ZHEJIANG YUANTAI SPECIAL FILM CO Ltd
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/02Diffusing elements; Afocal elements
    • G02B5/0268Diffusing elements; Afocal elements characterized by the fabrication or manufacturing method
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/02Diffusing elements; Afocal elements
    • G02B5/0205Diffusing elements; Afocal elements characterised by the diffusing properties
    • G02B5/021Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures
    • G02B5/0226Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures having particles on the surface
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/02Diffusing elements; Afocal elements
    • G02B5/0273Diffusing elements; Afocal elements characterized by the use
    • G02B5/0278Diffusing elements; Afocal elements characterized by the use used in transmission

Abstract

A kind of highlighted optical film producing method of high fog, specific steps are as follows: (1) light diffusion coating is spread evenly across substrate front and forms upper Diffusion barrier layer, obtain semi-finished product after drying, aging, cooling;(2) back side that ultraviolet curing acrylic resin is spread evenly across semi-finished product is formed into film layer of adding lustre to, is got product after solidification.Step of the present invention is simple, strong operability, by the Optimal improvements for spreading formulation for coating material to light, the mutual coordinated of each component, optical film thickness and even density obtained have the characteristics that diffusingsurface is soft and is not easy to be scratched, and light diffusion function is excellent, optics luminance is high, mist degree and light transmittance are good, excellent in optical properties is able to satisfy requirement of the various sizes liquid crystal display to high luminance.

Description

A kind of highlighted optical film producing method of high fog
Technical field
The present invention relates to optical film manufacturing technology fields, highlight optical film producing method more particularly, to a kind of high fog.
Background technique
Important component of FPD (FPD, such as the LCD, PDP etc.) industry as information industry be even more in recent years It is rapidly developed.Flat-panel monitor be widely used in TV, computer monitor, laptop, mobile phone, digital camera, On the products such as MP3, MP4, MP5, vehicle-mounted DSC/DV, GPS navigator.But these flat-panel monitors itself do not shine, produced Picture light source be to be provided by backlight module therein, light source requirements uniformly, high brightness.Whether now using more LED backlight or traditional CCFL backlight, the light issued is point light source or linear light source, rather than face light Source.But passes through backlight module diffusion barrier, a uniform area source can be scattered in.When light passes through diffusion layer, lead to The optical phenomenas such as refraction, the reflection constantly occurred in the different medium of two kinds of refractive index are crossed, to obtain the knot of optics diffusion Fruit.The defects of existing optical diffusion there are optics luminance low, material is partially thick, diffusingsurface easily scratches, is unable to satisfy photoelectricity row Industry high demand.
For example, the Chinese patent of application publication number CN1570675A discloses a kind of manufacturing method of photoelectric diffusion barrier, Processing step are as follows: a. is by transparent or semitransparent substrate frame on coating machine platform;B. diffusion barrier ingredient is packed into the coating machine platform In;C. the diffusion barrier ingredient is coated on the substrate front to form the diffusion barrier light-emitting surface;D. the diffusion barrier is placed in perseverance Constant temperature and humidity frame is dried;E. the incidence surface for step a to d being repeated to form the diffusion barrier to the substrate reverse side.Using the hair Photoelectric diffusion barrier made from bright method is there are optics luminance is low, and mist degree and light transmittance are bad, and the quality of photoelectric diffusion barrier entirety is not The defects of high, while in process of production, diffusion barrier paint stability is poor, and the light diffusion particle spread in coating easily settles To influence the coating homogeneity of coating, product quality is influenced.
Summary of the invention
The present invention is to provide a kind of technique step to solve above-mentioned technical problem present in the optical film of the prior art Rapid simple, at low cost, the high fog of strong operability highlights optical film producing method, and optical film, which is made, has light diffusion function excellent The features such as good, optics luminance is high, mist degree and light transmittance are good.
To achieve the goals above, the invention adopts the following technical scheme:
A kind of high fog of the invention highlights optical film producing method, specific steps are as follows:
(1) light diffusion coating is spread evenly across substrate front and forms upper Diffusion barrier layer, obtain half after drying, aging, cooling Finished product, the light diffusion coating are made of the component of following parts by weight: 18 ~ 20 parts of methyl ethyl ketone, pentaerythritol acrylate 15 ~ 17 parts, 3 ~ 5 parts of butyl acrylate, 1 ~ 3 part of poly- diethanol, 5 ~ 10 parts of Vinalac 5920, dibutyltindilaurylmercaptide osmanthus It is 1 ~ 2 part of acid esters, 1 ~ 2 part of nano silica, 15 ~ 17 parts of butyl acetate, 3 ~ 4 parts of aliphatic polymeric isocyanate, polyether-modified poly- 0.2 ~ 0.5 part of dimethyl siloxane, 10 ~ 15 parts of polymethyl, 14 ~ 15 parts of polystyrene, 3 ~ 5 parts of light diffusion particle.This hair Bright the problems of the optical film for the prior art improves and optimizates light diffusion formulation for coating material, essentially consists in: increasing Pentaerythritol acrylate, butyl acrylate, poly- diethanol, dibutyltin dilaurate and nano silica, season are added Penta tetrol acrylate is colourless or light yellow liquid, can be compatible with other components perfection, has high crosslink density, rapid curing Characteristic, filming performance can be improved, while can make to spread optical film there is excellent flexibility and scratch-resistant, but season penta The addition of tetrol acrylate can improve the mobility of whole system, influence paintability, therefore joined two fourths in the present invention Base tin dilaurate, dibutyltin dilaurate can inhibit the mobility of whole system of the present invention, can solve that season penta is added Problem brought by tetrol acrylate, while dibutyltin dilaurate can also improve the photostability of upper diffusion optical film And the transparency, but the addition of dibutyltin dilaurate can make a large amount of bubble of light diffusion coating generation, the present invention passes through Nano silica is added to solve the problems, such as this, the light transmittance and index of refraction of silica are good, will not influence diffusion optical film Performance, and nano silica have foam-inhibiting effect, can reduce light diffusion coating in bubble, be conducive to improve diffusion optics The quality of film, in addition nano silica can improve the hardness of Diffusion barrier layer, improve scratch resistance performance;Butyl acrylate, which has, to be increased Light action can improve Diffusion barrier layer lustrous surface, improve the light transmittance of light, reduce light loss;Poly- diethanol can improve light expansion The stability and homogeneity for dissipating coating, effectively avoid coating from settling, and are conducive to improve coating performance.
(2) back side that ultraviolet curing acrylic resin is spread evenly across semi-finished product is formed into film layer of adding lustre to, after solidification i.e. Obtain finished product.It is obtained add lustre to film layer can composite protection film to play a protective role.
Preferably, it is 5 ~ 10 μm that light, which spreads coating coating thickness, in step (1).
Preferably, the smooth diffusion particle is polymethacrylates particle, granules of polystyrene, gathers in step (1) One of siloxane particles, polyacrylic acid granules are a variety of.
Preferably, the partial size of the smooth diffusion particle is 0.1 ~ 1 μm.
Preferably, the substrate is PET film in step (1).
Preferably, in step (1), the drying specific steps are as follows: be warming up to 100 ~ 120 DEG C, dry 40 ~ 60s.
Preferably, in step (1), the aging specific steps are as follows: 50 ~ 60 h of aging at 50 ~ 60 DEG C.
Preferably, ultraviolet curing acrylic resin coating thickness is 15 ~ 20 μm in step (2).
Therefore, the invention has the following beneficial effects: step of the present invention is simple, strong operability is applied by spreading to light The Optimal improvements of material formula, the mutual coordinated of each component, optical film thickness and even density obtained have diffusingsurface soft And it is not easy the features such as being scratched, and light diffusion function is excellent, optics luminance is high, mist degree and light transmittance are good, excellent in optical properties, energy Meet requirement of the various sizes liquid crystal display to high luminance.
Specific embodiment
Below by specific embodiment, the present invention will be further described.
Embodiment 1
A kind of highlighted optical film producing method of high fog, specific steps are as follows:
(1) light diffusion coating is spread evenly across the positive upper Diffusion barrier layer formed with a thickness of 7 μm of substrate (PET film), Be warming up to 110 DEG C of baking 50s, aging 55h at 55 DEG C, it is cooling after semi-finished product, light diffusion coating are made of the component of following weight: 19 kg of methyl ethyl ketone, 16 kg of pentaerythritol acrylate, butyl acrylate 4kg, poly- diethanol 2kg, polymethylacrylic acid N-butyl 7kg, 1.5 kg of dibutyltin dilaurate, 1.2 kg of nano silica, 16 kg of butyl acetate, aliphatic poly Isocyanates 3.5 kg, polyether-modified 0.4 kg of dimethyl silicone polymer, polymethyl 12 kg, polystyrene 14.5kg, grain Light diffusion particle (polymethacrylates particle) 4 kg that diameter is 0.2 μm;
(2) back side that ultraviolet curing acrylic resin (model ZHU-1668) is spread evenly across semi-finished product is formed into thickness For 17 μm of film layer of adding lustre to, got product after solidification.
Embodiment 2
A kind of highlighted optical film producing method of high fog, specific steps are as follows:
(1) light diffusion coating is spread evenly across the positive upper Diffusion barrier layer formed with a thickness of 10 μm of substrate (PET film), Be warming up to 120 DEG C of baking 60s, aging 60h at 60 DEG C, it is cooling after semi-finished product, light diffusion coating are made of the component of following weight: 20 kg of methyl ethyl ketone, 17 kg of pentaerythritol acrylate, butyl acrylate 5kg, poly- 3 kg of diethanol, polymethylacrylic acid 10 kg of N-butyl, 2 kg of dibutyltin dilaurate, 2 kg of nano silica, 17 kg of butyl acetate, aliphatic poly are different Cyanate 4 kg, polyether-modified 0.5 kg of dimethyl silicone polymer, 15 kg of polymethyl, 15 kg of polystyrene, partial size 1 μm 5 kg of light diffusion particle (polysiloxane particle);
(2) back side that ultraviolet curing acrylic resin (model ZHU-1668) is spread evenly across semi-finished product is formed into thickness For 20 μm of film layer of adding lustre to, got product after solidification.
Embodiment 3
A kind of highlighted optical film producing method of high fog, specific steps are as follows:
(1) light diffusion coating is spread evenly across the positive upper Diffusion barrier layer formed with a thickness of 5 μm of substrate (PET film), Be warming up to 100 DEG C of baking 40s, aging 50h at 50 DEG C, it is cooling after semi-finished product, light diffusion coating are made of the component of following weight: Methyl ethyl ketone 18kg, pentaerythritol acrylate 15kg, butyl acrylate 3kg, poly- 1 kg of diethanol, polymethylacrylic acid N-butyl 5kg, dibutyltin dilaurate 1kg, nano silica 1kg, butyl acetate 15kg, aliphatic polymeric isocyanate 3kg, polyether-modified dimethyl silicone polymer 0.2kg, polymethyl 10kg, polystyrene 14kg, the light that partial size is 0.1 μm expand Shot (granules of polystyrene and polyacrylic acid granules mass ratio 2:3) 3kg;
(2) back side that ultraviolet curing acrylic resin (model ZHU-1668) is spread evenly across semi-finished product is formed into thickness For 15 μm of film layer of adding lustre to, got product after solidification.
Step of the present invention is simple, strong operability, optical film thickness and even density obtained, has diffusingsurface softness simultaneously Be not easy the features such as being scratched, and light diffusion function is excellent, optics luminance is high, mist degree and light transmittance are good, the mist degree of finished product 90% with On, light transmittance is able to satisfy requirement of the various sizes liquid crystal display to high luminance in 80% or more, excellent in optical properties.
Above-mentioned embodiment is only a preferred solution of the present invention, not the present invention is made in any form Limitation, there are also other variations and modifications on the premise of not exceeding the technical scheme recorded in the claims.

Claims (5)

1. a kind of high fog highlights optical film producing method, which is characterized in that specific steps are as follows:
(1) light diffusion coating is spread evenly across substrate front and forms upper Diffusion barrier layer, obtain semi-finished product after drying, aging, cooling, The light diffusion coating is made of the component of following parts by weight: 18 ~ 20 parts of methyl ethyl ketone, pentaerythritol acrylate 15 ~ 17 Part, 3 ~ 5 parts of butyl acrylate, 1 ~ 3 part of poly- diethanol, 5 ~ 10 parts of Vinalac 5920, dibutyltin dilaurate 1 ~ 2 parts, 1 ~ 2 part of nano silica, 15 ~ 17 parts of butyl acetate, 3 ~ 4 parts of aliphatic polymeric isocyanate, polyether-modified poly dimethyl 0.2 ~ 0.5 part of siloxanes, 10 ~ 15 parts of polymethyl, 14 ~ 15 parts of polystyrene, 3 ~ 5 parts of light diffusion particle;The light diffusion Particle is one of polymethacrylates particle, granules of polystyrene, polysiloxane particle, polyacrylic acid granules or more Kind, the partial size of the smooth diffusion particle is 0.1 ~ 1 μm;It is 5 ~ 10 μm that light, which spreads coating coating thickness,;
(2) back side that ultraviolet curing acrylic resin is spread evenly across semi-finished product backsize: is formed into film layer of adding lustre to, solidification After get product.
2. a kind of high fog according to claim 1 highlights optical film producing method, which is characterized in that described in step (1) Substrate is PET film.
3. a kind of high fog according to claim 1 highlights optical film producing method, which is characterized in that described in step (1) Dry specific steps are as follows: be warming up to 100 ~ 120 DEG C, dry 40 ~ 60s.
4. a kind of high fog according to claim 1 highlights optical film producing method, which is characterized in that described in step (1) Aging specific steps are as follows: 50 ~ 60h of aging at 50 ~ 60 DEG C.
5. a kind of high fog according to claim 1 highlights optical film producing method, which is characterized in that ultraviolet in step (2) Light-cured acrylic resin coating thickness is 15 ~ 20 μm.
CN201610540684.3A 2016-07-11 2016-07-11 A kind of highlighted optical film producing method of high fog Active CN106168689B (en)

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CN107814968A (en) * 2017-11-07 2018-03-20 张永宏 Brightening piece
CN108387957A (en) * 2018-02-27 2018-08-10 宁波激智科技股份有限公司 A kind of high quantum dot diffusion barrier and its preparation method and application for covering high briliancy
CN108641323B (en) * 2018-04-05 2020-04-24 东莞市瑞年塑胶科技有限公司 Lampshade plastic film material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202383315U (en) * 2011-12-31 2012-08-15 宁波长阳科技有限公司 Optical diffusion film
CN102778712A (en) * 2012-08-02 2012-11-14 昆山乐凯锦富光电科技有限公司 Optical diffusion barrier
CN103412356A (en) * 2013-08-30 2013-11-27 浙江元泰特种膜有限公司 Optical diffusion film and preparation method of optical diffusion film
CN103592706A (en) * 2013-11-14 2014-02-19 宁波激智科技股份有限公司 Atomization film applied to large-size displayer and backlight module thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005255706A (en) * 2004-03-09 2005-09-22 Lintec Corp Hardenable pressure-sensitive adhesive composition, sheet for manufacturing optical disc and optical disc
JP6275935B2 (en) * 2010-09-17 2018-02-07 日東電工株式会社 Light diffusing element, polarizing plate with light diffusing element, and liquid crystal display using the same
CN104459842B (en) * 2014-10-30 2017-01-25 孟凡伟 Optical composite membrane and manufacturing method of optical composite membrane

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202383315U (en) * 2011-12-31 2012-08-15 宁波长阳科技有限公司 Optical diffusion film
CN102778712A (en) * 2012-08-02 2012-11-14 昆山乐凯锦富光电科技有限公司 Optical diffusion barrier
CN103412356A (en) * 2013-08-30 2013-11-27 浙江元泰特种膜有限公司 Optical diffusion film and preparation method of optical diffusion film
CN103592706A (en) * 2013-11-14 2014-02-19 宁波激智科技股份有限公司 Atomization film applied to large-size displayer and backlight module thereof

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