CN106167902A - A kind of Surface hardened layer pricker is coated with material and preparation method thereof - Google Patents
A kind of Surface hardened layer pricker is coated with material and preparation method thereof Download PDFInfo
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- CN106167902A CN106167902A CN201610750385.2A CN201610750385A CN106167902A CN 106167902 A CN106167902 A CN 106167902A CN 201610750385 A CN201610750385 A CN 201610750385A CN 106167902 A CN106167902 A CN 106167902A
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- Prior art keywords
- pricker
- coated
- filler metal
- brazing filler
- metal alloy
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C24/00—Coating starting from inorganic powder
- C23C24/02—Coating starting from inorganic powder by application of pressure only
- C23C24/04—Impact or kinetic deposition of particles
Abstract
The invention discloses a kind of Surface hardened layer pricker and be coated with material, be coated with material bodies including pricker, pricker is coated with material bodies and is made up of brazing filler metal alloy internal layer and the hard alloy coating being sprayed on brazing filler metal alloy internal layer.The thickness of brazing filler metal alloy internal layer is 0.001~20mm, and the thickness of hard alloy coating is 0.001~20mm.Particulate material granularity in hard alloy coating is 15~45 μm.Hard alloy coating is one or more in carbide, nitride, boride, oxide.Brazing filler metal alloy internal layer is the one in fine copper, cuprio, money base, manganio, palladio, titanium based solder.During preparation, brazing filler metal alloy is smelting, extrude, rolling process is prepared as satisfactory banding/tabular brazing filler metal alloy internal layer, then satisfactory for the granularity processed cemented carbide powder is sprayed to brazing filler metal alloy internal layer surface by cold spray apparatus, form certain thickness hard alloy coating.Preparation method of the present invention and simple in construction, vacuum pricker is coated with effective.
Description
Technical field
The present invention relates to metal surface treatment technology, especially relate to a kind of Surface hardened layer pricker and be coated with material, the present invention is also
Relate to this pricker and be coated with the preparation method of material.
Background technology
Hard alloy has high rigidity, the advantage such as wear-resistant and corrosion-resistant, and some parts locally surface often requires that have
Higher wearability and corrosion resistance, if part is by overall hard alloy manufacture, the most relatively costly, and in body force
Learn the aspects such as performance and can not meet the most again requirement.By physical vaporous deposition (PVD), chemical vapour deposition technique (CVD), heat
The methods such as spraying process, welding method and pricker coating can improve the resistance to of piece surface at piece surface one layer of hard alloy of coating
Mill, the performance such as corrosion-resistant.Physical vapor sinks method and chemical vapour deposition technique can only obtain the thinnest coating, and price is higher, makes
Bigger by limitation;Thermally sprayed coating is the coating of a kind of mechanical snap, and coating is poor with the adhesion of matrix;The heating of surface overlaying
Temperature is higher, easily produces thermal stress and deformation, and surface forming performance is poor.The pricker coating of pricker coating and mother metal system metallurgical binding, knot
The mechanical bond closing strength ratio thermal spraying is much higher;Pricker be coated with than built-up welding time heating-up temperature low, thermal stress and mother metal performance
Change less;Pricker coating surface is smooth, and construction precision is high, i.e. can reach permissible accuracy through too small amount of processing.
Pricker is coated with material and is made up of two parts: a part is brazing filler metal alloy, and its fusion temperature is relatively low, is generally called low melting point group
Point;Another part is the hard alloy that fusing point is high, is generally called high melting point component.Traditional Surface hardened layer pricker is coated with material and typically will
The pulp-like pricker that powdered filler metal, hard alloy particle, bonding agent, Organic substance etc. are prepared as suspending is coated with material or lamellar pricker is coated with material
Material, is then coated with or is bonded at surface of the work, is then placed in vacuum drying oven completing whole pricker and is coated with process.Powdered filler metal oxygen content is relatively
Height, and pricker be coated with during Organic substance be easily generated carbon residual, thus produce various pore, the pricker such as be mingled with and be coated with defect.
Summary of the invention
The Surface hardened layer pricker that it is an object of the invention to provide that a kind of solder cleanliness factor is high, will not produce pricker and be coated with defect is coated with
Material, the present invention also provides for this pricker and is coated with the preparation method of material.
For achieving the above object, the present invention can take following technical proposals:
Surface hardened layer pricker of the present invention is coated with material, is coated with material bodies including pricker, and it is by brazing filler metal alloy that described pricker is coated with material bodies
Internal layer and the hard alloy coating composition being sprayed on described brazing filler metal alloy internal layer.
The thickness of described brazing filler metal alloy internal layer is 0.001~20mm, the thickness of described hard alloy coating be 0.001~
20mm.Particulate material granularity in hard alloy coating is 15~45 μm.
Described hard alloy coating includes one or more in carbide, nitride, boride, oxide.
Described brazing filler metal alloy internal layer is the one in fine copper, cuprio, money base, manganio, palladio, titanium based solder.
The preparation method that Surface hardened layer pricker of the present invention is coated with material is as follows:
First brazing filler metal alloy is smelting, extruding, rolling process are prepared as in the banding that is of the required size or tabular brazing filler metal alloy
Layer, then sprays to brazing filler metal alloy inner layer sheet by satisfactory for the granularity processed cemented carbide powder by cold spray apparatus
Face, forms certain thickness hard alloy coating.
It is an advantage of the current invention that simple in construction, vacuum pricker is coated with effective, concrete:
It is coated with material with the conventional suspension pulp-like vacuum pricker being prepared as by powdered filler metal, hard alloy particle, binding agent, Organic substance etc.
Material or lamellar vacuum pricker are coated with material and compare, and the pricker of the present invention is coated with material and is easy to deposit, transport and use;Brazing filler metal alloy is with hard simultaneously
Matter alloy ratio is consistent, and pricker can be coated with the stable, consistent of quality by effective guarantee pricker during being coated with;Owing to brazing filler metal alloy layer is than powdery pricker
Material cleanliness factor is high, pricker coating surface can be avoided to produce and be mingled with, and pricker is coated with in material without Organic substance, and pricker can realize without charcoal during being coated with
Residual, thus avoid pricker coating and produce pore, the defect such as be mingled with.
Accompanying drawing explanation
Fig. 1 is the cross-sectional structure schematic diagram of the present invention.
Detailed description of the invention
As it is shown in figure 1, Surface hardened layer pricker of the present invention is coated with material, being coated with material bodies including pricker, pricker is coated with material bodies and is
Be made up of brazing filler metal alloy internal layer 1 and the hard alloy coating 2 being sprayed on brazing filler metal alloy internal layer 1, in hard alloy coating 2
Pellet sizes is 15~45 μm.
During making, the thickness of brazing filler metal alloy internal layer 1 and hard alloy coating 2 can adjust in the range of 0.001~20mm:
It is mainly used in the coal cutting pick of the engineering such as coal mining and tunnel, tunnel, ground trench digging driving, makes to extend coal cutting pick
With the life-span, it usually needs be coated with hard alloy layer at coal cutting pick front-end surface pricker, to improve its hardness and wearability, extend coal cutting pick
Service life, now, brazing filler metal alloy internal layer 1 used and the thickness of hard alloy coating 2 are typically between 0.1~1mm.
Vinyon compressor granulating template surface is owing to constantly being swiped by four cutting knifes rotated, and working condition is disliked
Bad, it usually needs at template surface pricker hard coated layer matter alloy coat, now brazing filler metal alloy internal layer 1 used and hard alloy coating
The thickness of 2 is typically between 1~4mm.
Hard alloy coating steel plate is to specialize in the plate product that large area wear working condition uses, and is fine in toughness, plasticity
Ordinary low-carbon steel or surface of low-alloy steel pricker hard coated layer matter alloy, at this moment, brazing filler metal alloy internal layer 1 used and hard alloy
The thickness of coating 2 is typically between 1~20mm.
Further illustrate pricker of the present invention below by specific embodiment and be coated with preparation method and the using effect of material.
Embodiment 1
The operations such as brazing filler metal alloy is smelting, extrude, rolling are prepared as the BCu solder band that thickness is 0.2mm, hard alloy with 20~
The casting tungsten carbide powder of 30 mesh, Co powder are raw material, and agitated ball milling, mist projection granulating and vacuum-sintering prepare powdered block
WC12Co, is then 15~45 μm by crushing and screening, grading control dusty spray granularity.Xi'an Communications University is used independently to grind
The CS-2000 cold spraying system of system deposits hard alloy coating 0.5mm on BCu solder band, and matrix is Q235 carbon steel, uses
24 mesh palm fibre jade sand carry out blasting treatment, then this pricker is coated with material and matrix is put into vacuum drying oven and carried out pricker painting.Chi after pricker painting
Very little for 57mm × 25.5mm × 6mm.The product of embodiment 1 is carried out abrasive wear experiment, and abrasive grain wear test is at MLG-130A
Carry out on type dry type rubber wheel grain-abrasion testing machine.Test load is 20N, and abrasive material is No. 120 corundum sands, rubber wheel rotating speed
For 100r/min, sand flow amount is 100g/min, and wearing-in period is 15min, and the abrasion weight loss of coating represents, test result is
40mg.Use the BCu powder of ratio of the same race, 15~45 the traditional flake pricker of the preparation such as WC12Co powder of μm be coated with material at pricker of the same race
The test result being coated with in technique and abrasive grain wear test is 56mg, and result proves that the Surface hardened layer pricker of the present invention is coated with the resistance to of material
Mill property is coated with material apparently higher than traditional flake pricker.
Embodiment 2
The operations such as brazing filler metal alloy is smelting, extrude, rolling are prepared as the BCu86NiMn brazing filler metal alloy band that thickness is 0.2mm, hard
Alloy is with the casting tungsten carbide powder of 20~30 mesh, Co powder as raw material, and agitated ball milling, mist projection granulating and vacuum-sintering prepare powder
Block WC12Co, is then 15~45 μm by crushing and screening, grading control dusty spray granularity.Use Xi'an Communications University certainly
The CS-2000 cold spraying system of main development deposits hard alloy coating 0.5mm on BCu86NiMn solder band, and matrix is
Q235 carbon steel, uses 24 mesh palm fibre jade sand to carry out blasting treatment, then this pricker is coated with material and matrix is put into vacuum drying oven and carried out
Pricker is coated with.Size after pricker is coated with is 57mm × 25.5mm × 6mm.The product of embodiment 2 is carried out abrasive wear experiment, abrasive wear
Test is carried out on MLG-130A type dry type rubber wheel grain-abrasion testing machine.Test load is 20N, and abrasive material is that No. 120 palm fibres are firm
Beautiful sand, rubber wheel rotating speed is 100r/min, and sand flow amount is 100g/min, and wearing-in period is 15min, the abrasion weight loss of coating
Representing, test result is 36mg.Use the BCu86NiMn powder of ratio of the same race, 15~45 biographies of the preparation such as WC12Co powder of μm
It is 44mg that system lamellar pricker is coated with material test result in pricker of the same race is coated with technique and abrasive grain wear test, and result proves the present invention's
The wearability that Surface hardened layer is coated with material with pricker is coated with material apparently higher than traditional flake pricker.
Embodiment 3
The operations such as brazing filler metal alloy is smelting, extrude, rolling are prepared as the BAg85Mn brazing filler metal alloy band that thickness is 0.2mm, and hard closes
Gold is with the casting tungsten carbide powder of 20~30 mesh, Co powder as raw material, and agitated ball milling, mist projection granulating and vacuum-sintering prepare powder mass
Body WC12Co, is then 15~45 μm by crushing and screening, grading control dusty spray granularity.Use Xi'an Communications University autonomous
The CS-2000 cold spraying system developed deposits hard alloy coating 0.5mm on BAg85Mn solder band, and matrix is Q235 carbon
Steel, uses 24 mesh palm fibre jade sand to carry out blasting treatment, then this pricker is coated with material and matrix is put into vacuum drying oven and carried out pricker painting.Pricker
Size after painting is 57mm × 25.5mm × 6mm.The product of embodiment 3 is carried out abrasive wear experiment, and abrasive grain wear test exists
Carry out on MLG-130A type dry type rubber wheel grain-abrasion testing machine.Test load is 20N, and abrasive material is No. 120 corundum sands, rubber
Rubber tire rotating speed is 100r/min, and sand flow amount is 100g/min, and wearing-in period is 15min, and the abrasion weight loss of coating represents, surveys
Test result is 38mg.Use the BAg85Mn powder of ratio of the same race, 15~45 the traditional flake pricker of the preparation such as WC12Co powder of μm be coated with
Material test result in pricker of the same race is coated with technique and abrasive grain wear test is 49mg, and result proves that the Surface hardened layer of the present invention is used
Pricker is coated with the wearability of material and is coated with material apparently higher than traditional flake pricker.
Embodiment 4
The operations such as brazing filler metal alloy is smelting, extrude, rolling are prepared as the BCu97NiB brazing filler metal alloy band that thickness is 0.2mm, hard
Alloy is with the casting tungsten carbide powder of 20~30 mesh, Co powder as raw material, and agitated ball milling, mist projection granulating and vacuum-sintering prepare powder
Block WC12Co, is then 15~45 μm by crushing and screening, grading control dusty spray granularity.Use Xi'an Communications University certainly
The CS-2000 cold spraying system of main development deposits hard alloy coating 0.5mm on BCu97NiB solder band, and matrix is Q235
Carbon steel, uses 24 mesh palm fibre jade sand to carry out blasting treatment, then this pricker is coated with material and matrix is put into vacuum drying oven and carried out pricker painting.
Size after pricker is coated with is 57mm × 25.5mm × 6mm.The product of embodiment 4 is carried out abrasive wear experiment, abrasive grain wear test
MLG-130A type dry type rubber wheel grain-abrasion testing machine is carried out.Test load is 20N, and abrasive material is No. 120 corundum sands,
Rubber wheel rotating speed is 100r/min, and sand flow amount is 100g/min, and wearing-in period is 15min, and the abrasion weight loss of coating represents,
Test result is 39mg.Use the BCu97NiB powder of ratio of the same race, 15~45 traditional flake of the preparation such as WC12Co powder of μm
It is 45mg that pricker is coated with material test result in pricker of the same race is coated with technique and abrasive grain wear test, and result proves that the surface of the present invention is hard
The wearability that change is coated with material with pricker is coated with material apparently higher than traditional flake pricker.
Embodiment 5
The operations such as brazing filler metal alloy is smelting, extrude, rolling are prepared as the BCu81Ni brazing filler metal alloy band that thickness is 0.2mm, and hard closes
Gold is with the casting tungsten carbide powder of 20~30 mesh, Co powder as raw material, and agitated ball milling, mist projection granulating and vacuum-sintering prepare powder mass
Body WC12Co, is then 15~45 μm by crushing and screening, grading control dusty spray granularity.Use Xi'an Communications University autonomous
The CS-2000 cold spraying system developed deposits hard alloy coating 0.5mm on BCu81Ni solder band, and matrix is Q235 carbon
Steel, uses 24 mesh palm fibre jade sand to carry out blasting treatment, then this pricker is coated with material and matrix is put into vacuum drying oven and carried out pricker painting.Pricker
Size after painting is 57mm × 25.5mm × 6mm.The product of embodiment 5 is carried out abrasive wear experiment, and abrasive grain wear test exists
Carry out on MLG-130A type dry type rubber wheel grain-abrasion testing machine.Test load is 20N, and abrasive material is No. 120 corundum sands, rubber
Rubber tire rotating speed is 100r/min, and sand flow amount is 100g/min, and wearing-in period is 15min, and the abrasion weight loss of coating represents, surveys
Test result is 31mg.Use the BCu81Ni powder of ratio of the same race, 15~45 the traditional flake pricker of the preparation such as WC12Co powder of μm be coated with
Material test result in pricker of the same race is coated with technique and abrasive grain wear test is 42mg, and result proves that the Surface hardened layer of the present invention is used
Pricker is coated with the wearability of material and is coated with material apparently higher than traditional flake pricker.
Claims (6)
1. Surface hardened layer pricker is coated with a material, is coated with material bodies including pricker, it is characterised in that: it is by solder that described pricker is coated with material bodies
Alloy internal layer (1) and hard alloy coating (2) composition being sprayed on described brazing filler metal alloy internal layer (1).
Surface hardened layer pricker the most according to claim 1 is coated with material, it is characterised in that: described brazing filler metal alloy internal layer (1)
Thickness is 0.001~20mm, and the thickness of described hard alloy coating (2) is 0.001~20mm.
Surface hardened layer pricker the most according to claim 1 and 2 is coated with material, it is characterised in that: described hard alloy coating (2)
In particulate material granularity be 15~45 μm.
Surface hardened layer pricker the most according to claim 1 and 2 is coated with material, it is characterised in that: described hard alloy coating bag
Include one or more in carbide, nitride, boride, oxide.
Surface hardened layer pricker the most according to claim 1 and 2 is coated with material, it is characterised in that: described brazing filler metal alloy internal layer is
One in fine copper, cuprio, money base, manganio, palladio, titanium based solder.
6. described in claim 1, the preparation method of Surface hardened layer pricker painting material is as follows:
First brazing filler metal alloy is smelting, extruding, rolling process are prepared as in the banding that is of the required size or tabular brazing filler metal alloy
Layer, then sprays to brazing filler metal alloy inner layer sheet by satisfactory for the granularity processed cemented carbide powder by cold spray apparatus
Face, forms certain thickness hard alloy coating.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110315239A (en) * | 2019-07-05 | 2019-10-11 | 浙江省冶金研究院有限公司 | A kind of nickel alloy slurry and the ultra-thin band-like nickel-based solder by nickel alloy slurry preparation |
CN114082591A (en) * | 2022-01-10 | 2022-02-25 | 中机智能装备创新研究院(宁波)有限公司 | Diamond brazing tape preparation device and preparation method and brazing tape |
US20230031736A1 (en) * | 2019-12-19 | 2023-02-02 | Rogers Germany Gmbh | Solder material, method for producing a solder material of this type and use of a solder material of this type in order to connect a metal layer to a ceramic layer |
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CN205999483U (en) * | 2016-08-30 | 2017-03-08 | 郑州机械研究所 | A kind of Surface hardened layer pricker applies material |
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CN101524779A (en) * | 2008-03-05 | 2009-09-09 | 丹阳市友和工具有限责任公司 | Brazing technology for diamond |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN110315239A (en) * | 2019-07-05 | 2019-10-11 | 浙江省冶金研究院有限公司 | A kind of nickel alloy slurry and the ultra-thin band-like nickel-based solder by nickel alloy slurry preparation |
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CN114082591A (en) * | 2022-01-10 | 2022-02-25 | 中机智能装备创新研究院(宁波)有限公司 | Diamond brazing tape preparation device and preparation method and brazing tape |
CN114082591B (en) * | 2022-01-10 | 2022-05-03 | 中机智能装备创新研究院(宁波)有限公司 | Diamond brazing tape preparation device and preparation method and brazing tape |
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Application publication date: 20161130 |