A kind of industrial dust purifies fire prevention hybrid system and method for work thereof
Technical field
The invention belongs to dedusting or fireproof anti-explosion device field, be specifically related to a kind of industrial dust and purify fire prevention hybrid system
And method of work.
Background technology
Dust refers to the solid particle swum in atmosphere.The source of industrial dust mainly has: the 1. machine of solid material
Tool is pulverized and is ground, the ore reduction process of such as ore dressing, refractory shop and various attrition process process;2. granular material
Mixing, sieve, pack and transport, the production of such as cement, flour etc. and transportation;3. the burning of material, such as coal combustion
The flue dust produced during burning;4. material produces when being heated the aerial oxidation of steam and condensation, such as ore sintering, metal
Smelt the zinc fume produced during waiting, can condense and be oxidized to solid.
The fire that dust in commercial production causes and blast are relatively common, as coal-dust explosion, metallic dust explode and spin
Knitting dust explosion etc., have sizable destructive power, shock wave and the destructiveness of heat wave that explosion time produces are extremely strong, to surrounding
Affect the biggest.Such as, on August 2nd, 2011, Fauna of Kunshan, Jiangsu city Zhong Rong metallic article company limited polishing departement occurs the most great
Aluminum dust explosion accident, causes great casualties, gives a lesson to the most painful.
The wide range of dust is general, and combustible dust mainly has a three major types: metallic dust, Mineral Dusts and Organic substance powder
Dirt.Dust explosion has sizable destructive power, it is generally required to three key elements, oxygen content is on maximum permissible value, and dust is dense
Degree is between upper and lower limit, and the energy of incendiary source exceedes minimum ignition energy.The dust suspended and oxygen mixing, reaching ignition energy
After amount, gas drastically expands, and produces huge blast pressure, dust of kicking up, and forms chain reaction.
The fire-proof and explosion-proof safety management of dust be one become more meticulous, the work of systematization, mobilism, set up specification dust prevent
Fire anti-explosion safety management system is particularly significant, should accomplish that sequencing, regulation and standardization, the work that can be so daily carry
For reliable reference and support.Except management, in addition it is also necessary to strong supervision, formulate detailed day-to-day supervision system, play supervision
Effect, make staff strictly by guidelines, it is to avoid security incident occur.Additionally, at the fire-proof and explosion-proof daily pipe of dust
During reason, safety to be put in the first place by staff, holds each link in producing, does from details, builds good
Working environment.
In actual production, there are the high-risk district of dust fire and blast, for these regions, it is necessary to strengthen safety
Management work, more refines the management of safe operation in region, does not stay blind spot, it is to avoid violation operation, reduces fire and blast occurs
Probability.Simultaneously need to arrange control point pointedly, monitoring, record, thus can improve safety in real time.Emphasis district
The management in territory comprises the link of several aspect, and such as equipment, production procedure, working specification, security protection etc., each work is the most necessary
Qualified, otherwise necessary Renovation, it is to avoid dangerous generation.Additionally, the safety management of key area also needs to implement operational detail,
In conjunction with necessary supervision link, it is ensured that quality.
Modern science and technology is fast-developing, uses state-of-the-art skill upgrading safety, the input of equipment as fire-proof and explosion-proof in dust,
The construction etc. of monitoring device, can improve reliability and safety, and some enterprise employs computer monitoring system the most both at home and abroad
System, utilizes advanced sensing device, the monitoring of Real-time and Dynamic, grasps first hand information, carry out security monitoring and protection.This
Outward, the input of increased capital is the most particularly significant, can be with Accelerating The Construction process.
Under prior art conditions, the increase of industrial dust purification fireproof equipment construction cost and operating cost will become
Inevitable, existing traditional handicraft, to there is technological process in processing method long, controls complexity, takes up an area big, the shortcomings such as processing cost is high.
Summary of the invention
In order to solve above-mentioned technical problem, the present invention provides a kind of industrial dust to purify fire prevention hybrid system and work side thereof
Method, including: industrial dust ventilation storehouse 1, initial filter grid 2, system processes storehouse 3, automatization's electric-control system 4;Described system processes storehouse 3
Sidewall is provided with industrial dust ventilation storehouse 1, described industrial dust ventilation storehouse 1 and inside, system process storehouse 3 and is mutually communicated, described industry
The internal initial filter grid 2 that is provided with in dust ventilation storehouse 1, described initial filter grid 2 and industrial dust ventilation storehouse 1 inwall are solid by draw-in groove mode
Fixed connection, described automatization electric-control system 4 is positioned at system and processes storehouse 3 top surface.
Further, described system processes storehouse 3 and includes: purifying the compound storehouse 3-1 of fire prevention, dust concentrates storehouse 3-2, fire prevention system
3-3, dust purification absorption baffle plate 3-4;The described compound storehouse 3-1 of fire prevention that purifies is made up of exotic material, purifies the compound storehouse of fire prevention
In hollow state inside 3-1;Described dust concentrates storehouse 3-2 to be positioned at purification fire prevention compound storehouse 3-1 lower surface, and dust concentrates storehouse 3-
2 are welded and fixed with purifying the compound storehouse 3-1 of fire prevention, and dust is concentrated and is mutually communicated inside storehouse 3-2 storehouse 3-1 compound with purification fire prevention, powder
Dirt concentrates storehouse 3-2 profile to be bucket-shaped structure, and dust concentrates storehouse 3-2 to be made up of exotic material;Described fire prevention system 3-3 is positioned at only
Chemoprevention fire is combined storehouse 3-1 interior side, and fire prevention system 3-3 is fixing with purification fire prevention compound storehouse 3-1 inwall to be connected;Described dust is clean
Change absorption baffle plate 3-4 and be positioned at fire prevention system 3-3 side, dust purification absorption baffle plate 3-4 and the 3-1 inwall weldering of purification fire prevention compound storehouse
Connecing fixing, dust purification absorption baffle plate 3-4 quantity is no less than 6 pieces, and dust purification absorption baffle plate 3-4 is set to α with horizontal plane angle,
Described α value is between 30 °~70 °, and dust purification absorption baffle plate 3-4 is made up of fibrous membrane or active material.
Further, described fire prevention system 3-3 includes: elastic self-recoverage telescoping mechanism 3-3-1, elastic self-recoverage telescopic machine
Structure fixed pin shaft 3-3-2, high temperature fuse 3-3-3, collapsible blade 3-3-4, collapsible blade fixed pin shaft 3-3-5;
It is fixed on purification by elastic self-recoverage telescoping mechanism fixed pin shaft 3-3-2 bottom described elastic self-recoverage telescoping mechanism 3-3-1
The compound 3-1 bottom surface, storehouse of fire prevention, elastic self-recoverage telescoping mechanism 3-3-1 is made up of spring or elastomeric material;Described high temperature fuse
3-3-3 is positioned at elastic position on the upper side, self-recoverage telescoping mechanism 3-3-1 stage casing, high temperature fuse 3-3-3 melting temperature at 250 DEG C~
450 DEG C, high temperature fuse 3-3-3 is connected with automatization electric-control system 4 polygon control survey;Described collapsible blade 3-3-4 one end
It is fixed on elastic self-recoverage telescoping mechanism 3-3-1 by collapsible blade fixed pin shaft 3-3-5, collapsible blade 3-3-
4 other ends are fixed on purification fire prevention compound storehouse 3-1 sidewall, collapsible blade by collapsible blade fixed pin shaft 3-3-5
3-3-4 compressive state is accordion, the collapsible blade rectangular tabular of 3-3-4 deployed condition, collapsible blade 3-3-4
Launch height storehouse 3-1 compound with purification fire prevention the most identical.
Further, described collapsible blade 3-3-4 is by macromolecular material pressing mold molding, collapsible blade 3-3-4
Constituent and manufacture process as follows:
One, collapsible blade 3-3-4 constituent:
Count by weight, poly-(styrene-methylacrylate-p-chloromethyl styrene) 67~157 parts, chloromethylation oligocene
Vinyl phosphonate-phosphoric acid hydrogen zirconium 87~157 parts, benzene sulfuryl isobutyl acetate 157~557 parts, E-2-methyl-2-butenoic acid-3,
7-dimethyl-6-octene ester 87~197 parts, (E, E)-2-methyl-2-butenoic acid-3,7-dimethyl-2,6-octadiene-1-alcohol ester
77~157 parts, (E)-4-(3,4-Dimethoxyphenyl)-4-oxygen-2-butylene acetoacetic ester 157~557 parts, concentration be 57ppm~
[[two (2-ethylhexyl) oxygen] bisthiosulfate base] di-n-butyl succinate 87 of 97ppm~157 parts, two (2-ethylhexyls) two
D2EHDTPA sulfuration oxygen molybdenum 77~157 parts, succinic acid two [2-(2-ethyl hexyl oxy) ethyl] ester sodium sulfonate 77~187 parts, hand over
Connection agent 97~167 parts, 2-[2-(diethylamino) ethyl]-ethyl 3-oxobutanoate 57~157 parts, 2-[(3-nitrobenzophenone)
Methylene]-ethyl 3-oxobutanoate 97~177 parts, sulfosuccinate C-[2-[2-(2-dodecyloxy) ethyoxyl] ethoxy
Base] ethyl ester disodium 57~87 parts, 3,4-Dichlorobenzene base carbamic acid-2-[3-butyl-4-(2,2-dicyanoethenyl)-3-first
Phenylamino] ethyl ester 57~157 parts;
Described cross-linking agent is 4,4-dimethyl-3-oxopentanoic acid methyl ester, 3-ketobutyric acid 2-(methyl (phenyl methyl) amino) second
Any one in ester, thiacetic acid .-S-(3-chloro-2-methyl-3-oxo) propyl ester;
Two, the manufacture process of collapsible blade 3-3-4, comprises the steps of
1st step: add ultra-pure water 557~1507 parts that electrical conductivity is 0.57 μ S/cm~0.77 μ S/cm in a kettle., start
Agitator in reactor, rotating speed is 97rpm~257rpm, starts heat pump, makes reactor temperature rise to 67 DEG C~87 DEG C;
It is sequentially added into poly-(styrene-methylacrylate-p-chloromethyl styrene), chloromethylation oligopolystyrene phosphonic acid-phosphoric acid hydrogen
Zirconium, benzene sulfuryl isobutyl acetate, stirring is to being completely dissolved, and regulation pH value is 5.7~7.7, and agitator speed is adjusted to 157rpm
~257rpm, temperature is 97 DEG C~167 DEG C, esterification 17~27 hours;
2nd step: take E-2-methyl-2-butenoic acid-3,7-dimethyl-6-octene ester, (E, E)-2-methyl-2-butenoic acid-3,7-
Dimethyl-2,6-octadiene-1-alcohol ester pulverizes, and powder diameter is 117~257 mesh;Add (E)-4-(3,4-dimethoxy benzene
Base)-4-oxygen-2-butylene acetoacetic ester mix homogeneously, it is laid in pallet, tiling thickness is 37mm~57mm, and employing dosage is
5.7kGy~8.7kGy, energy are the alpha ray irradiation 57 of 5.7MeV~17MeV~157 minutes, and the β ray of Isodose
Irradiation 77~167 minutes;
3rd step: the mixed-powder processed through the 2nd step is dissolved in [[two (2-ethylhexyl) oxygen] bisthiosulfate base] succinic acid two fourth
In ester, adding reactor, agitator speed is 87rpm~187rpm, and temperature is 97 DEG C~157 DEG C, starts vacuum pump and makes reaction
The vacuum of still reaches-0.87MPa~-0.57MPa, keeps this state response 17~37 hours;Pressure release is also passed through nitrogen, makes anti-
Answering pressure in still is 0.57MPa~0.77MPa, and insulation stands 17~37 hours;Agitator speed be promoted to 117rpm~
257rpm, simultaneous reactions still pressure release to 0MPa;It is sequentially added into two (2-ethylhexyl) Sulfurized Oxomolybdenum Dialkyldithiophosphate, succinic acid two
After [2-(2-ethyl hexyl oxy) ethyl] ester sodium sulfonate is completely dissolved, add cross-linking agent stirring mixing so that reactor solution
Hydrophile-lipophile balance value is 5.7~7.7, and insulation stands 17~37 hours;
4th step: when agitator speed is 157rpm~267rpm, is sequentially added into 2-[2-(diethylamino) ethyl]-3-oxygen
For ethyl n-butyrate., 2-[(3-nitrobenzophenone) methylene]-ethyl 3-oxobutanoate, sulfosuccinate C-[2-[2-(2-dodecane
Epoxide) ethyoxyl] ethyoxyl] ethyl ester disodium, 3,4-Dichlorobenzene base carbamic acid-2-[3-butyl-4-(2,2-dicyanoethylene
Base)-3-toluidino] ethyl ester, promote reactor pressure so that it is reaching 0.87MPa~1.67MPa, temperature is 157 DEG C~277
DEG C, polyreaction 17~27 hours;After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 27 DEG C~37 DEG C, discharging,
Enter molding press and can be prepared by collapsible blade 3-3-4.
The invention also discloses a kind of industrial dust and purify the method for work of fire prevention hybrid system, the method includes following several
Individual step:
1st step: enter industrial dust ventilation storehouse 1 containing industrial dust gas, by initial filter grid inside industrial dust ventilation storehouse 1
2 carry out prefiltration, after system is run 10~15 days, initial filter grid 2 is pulled down cleaning and changes;
2nd step: the gas after prefiltration enters and purifies in the compound storehouse 3-1 of fire prevention, and gas flows through dust purification absorption baffle plate 3-4,
A part of dust is adsorbed by dust purification absorption baffle plate 3-4, and a part of dust adsorbs baffle plate 3-4 inclined-plane to sinking with dust purification
It is down to dust concentrate in the 3-2 of storehouse;
3rd step: when system processes in the case of storehouse 3 internal temperature reaches between 250 DEG C~450 DEG C or be on fire, and automatization is automatically controlled
System 4 control system warning 60s~120s, high temperature fuse 3-3-3 fuse at high operating temperatures, elastic self-recoverage telescoping mechanism
3-3-1 does downwards reseting movement, and then Foldable compression blade 3-3-4 does downwards flattening motion, when elastic self-recoverage stretches
After mechanism 3-3-1 resets completely, collapsible blade 3-3-4 flattens completely, is isolated entirely from burning things which may cause a fire disaster by industrial dust.
Disclosed in patent of the present invention, a kind of industrial dust purifies fire prevention hybrid system and method for work thereof, has an advantage in that:
(1) this device purifies absorption baffle plate and uses angled manner layout, and industrial dust clean-up effect is more preferable;
(2) this apparatus structure is the compactest, and integrated level is high;
(3) this folding device compression blade uses macromolecular material to prepare, and fire protecting performance is high.
A kind of industrial dust of the present invention purifies fire prevention hybrid system and method for work novel and reasonable structure thereof, operation
Convenient and swift, dust removal efficiency is high, and fire protecting performance is good, it is adaptable to the purification fire prevention of different dusts processes.
Accompanying drawing explanation
Fig. 1 is that heretofore described a kind of industrial dust purifies fire prevention hybrid system schematic diagram.
Fig. 2 is that heretofore described system processes storehouse internal structure schematic diagram.
Fig. 3 is heretofore described fire prevention system structural representation.
Fig. 4 is collapsible blade material of the present invention and fire protecting performance enhancing rate graph of a relation.
In figure 1 above~Fig. 3, industrial dust ventilation storehouse 1, initial filter grid 2, system processes storehouse 3, purifies the compound storehouse 3-of fire prevention
1, dust concentrates storehouse 3-2, fire prevention system 3-3, elastic self-recoverage telescoping mechanism 3-3-1, elastic self-recoverage telescoping mechanism steady pin
Axle 3-3-2, high temperature fuse 3-3-3, collapsible blade 3-3-4, collapsible blade fixed pin shaft 3-3-5, dust purification
Absorption baffle plate 3-4, automatization's electric-control system 4.
Detailed description of the invention
A kind of industrial dust provided the present invention with embodiment below in conjunction with the accompanying drawings purifies fire prevention hybrid system and work thereof
It is further described as method.
As it is shown in figure 1, be that heretofore described a kind of industrial dust purifies fire prevention hybrid system schematic diagram.Figure is seen
Go out, including: industrial dust ventilation storehouse 1, initial filter grid 2, system processes storehouse 3, automatization's electric-control system 4;Described system processes storehouse 3
Sidewall is provided with industrial dust ventilation storehouse 1, described industrial dust ventilation storehouse 1 and inside, system process storehouse 3 and is mutually communicated, described industry
The internal initial filter grid 2 that is provided with in dust ventilation storehouse 1, described initial filter grid 2 and industrial dust ventilation storehouse 1 inwall are solid by draw-in groove mode
Fixed connection, described automatization electric-control system 4 is positioned at system and processes storehouse 3 top surface.
As in figure 2 it is shown, be that heretofore described system processes storehouse internal structure schematic diagram.As seen from Figure 2, described system
System processes storehouse 3 and includes: purify the compound storehouse 3-1 of fire prevention, and dust concentrates storehouse 3-2, fire prevention system 3-3, dust purification absorption baffle plate 3-
4;The described compound storehouse 3-1 of fire prevention that purifies is made up of exotic material, purifies inside the compound storehouse 3-1 of fire prevention in hollow state;Described
Dust concentrates storehouse 3-2 to be positioned at purification fire prevention compound storehouse 3-1 lower surface, and dust concentration storehouse 3-2 welds with purifying the compound storehouse 3-1 of fire prevention
Connecing fixing, dust is concentrated storehouse 3-2 and is mutually communicated inside the compound storehouse 3-1 that prevents fires with purifying, and dust concentrates storehouse 3-2 profile to be bucket-shaped knot
Structure, dust concentrates storehouse 3-2 to be made up of exotic material;Described fire prevention system 3-3 is positioned at the compound storehouse 3-1 of purification fire prevention internal
Side, fire prevention system 3-3 is fixing with purification fire prevention compound storehouse 3-1 inwall to be connected;Described dust purification absorption baffle plate 3-4 is positioned at fire prevention
System 3-3 side, dust purification absorption baffle plate 3-4 is welded and fixed with purifying fire prevention compound storehouse 3-1 inwall, dust purification absorption gear
Plate 3-4 quantity is no less than 6 pieces, and dust purification absorption baffle plate 3-4 and horizontal plane angle are set to α, described α value 30 °~70 ° it
Between, dust purification absorption baffle plate 3-4 is made up of fibrous membrane or active material.
As it is shown on figure 3, be heretofore described fire prevention system structural representation.Find out from Fig. 3, Fig. 2 or Fig. 1, institute
State fire prevention system 3-3 to include: elastic self-recoverage telescoping mechanism 3-3-1, elastic self-recoverage telescoping mechanism fixed pin shaft 3-3-2, high
Temperature fuse 3-3-3, collapsible blade 3-3-4, collapsible blade fixed pin shaft 3-3-5;Described elastic self-recoverage stretches
It is fixed on the compound 3-1 bottom surface, storehouse of purification fire prevention by elastic self-recoverage telescoping mechanism fixed pin shaft 3-3-2 bottom mechanism 3-3-1,
Elastic self-recoverage telescoping mechanism 3-3-1 is made up of spring or elastomeric material;Described high temperature fuse 3-3-3 is positioned at elastic self-recoverage
Position on the upper side, telescoping mechanism 3-3-1 stage casing, high temperature fuse 3-3-3 melting temperature at 250 DEG C~450 DEG C, high temperature fuse 3-
3-3 is connected with automatization electric-control system 4 polygon control survey;Described collapsible blade 3-3-4 one end is solid by collapsible blade
Rationed marketing axle 3-3-5 is fixed on elastic self-recoverage telescoping mechanism 3-3-1, and the collapsible blade 3-3-4 other end is pressed by folding
Leaf curl sheet fixed pin shaft 3-3-5 is fixed on purification fire prevention compound storehouse 3-1 sidewall, and collapsible blade 3-3-4 compressive state is pleat
Corrugation, the collapsible blade rectangular tabular of 3-3-4 deployed condition, collapsible blade 3-3-4 launches height to be prevented with purifying
Compound storehouse 3-1 is the most identical for fire.
A kind of industrial dust of the present invention purifies the work process of fire prevention hybrid system:
1st step: enter industrial dust ventilation storehouse 1 containing industrial dust gas, by initial filter grid inside industrial dust ventilation storehouse 1
2 carry out prefiltration, after system is run 10~15 days, initial filter grid 2 is pulled down cleaning and changes;
2nd step: the gas after prefiltration enters and purifies in the compound storehouse 3-1 of fire prevention, and gas flows through dust purification absorption baffle plate 3-4,
A part of dust is adsorbed by dust purification absorption baffle plate 3-4, and a part of dust adsorbs baffle plate 3-4 inclined-plane to sinking with dust purification
It is down to dust concentrate in the 3-2 of storehouse;
3rd step: when system processes in the case of storehouse 3 internal temperature reaches between 250 DEG C~450 DEG C or be on fire, and automatization is automatically controlled
System 4 control system warning 60s~120s, high temperature fuse 3-3-3 fuse at high operating temperatures, elastic self-recoverage telescoping mechanism
3-3-1 does downwards reseting movement, and then Foldable compression blade 3-3-4 does downwards flattening motion, when elastic self-recoverage stretches
After mechanism 3-3-1 resets completely, collapsible blade 3-3-4 flattens completely, is isolated entirely from burning things which may cause a fire disaster by industrial dust.
A kind of industrial dust of the present invention purifies fire prevention hybrid system and method for work novel and reasonable structure thereof, operation
Convenient and swift, dust removal efficiency is high, and fire protecting performance is good, it is adaptable to the purification fire prevention of different dusts processes.
The following is the embodiment of the manufacture process of collapsible blade 3-3-4 of the present invention, embodiment is to enter one
Step explanation present disclosure, but should not be construed as limitation of the present invention.Without departing substantially from present invention spirit and the situation of essence
Under, the amendment that the inventive method, step or condition are made and replacement, belong to the scope of the present invention.
If not specializing, the conventional means that technological means used in embodiment is well known to those skilled in the art.
Embodiment 1
Manufacture collapsible blade 3-3-4 of the present invention according to following steps, and count by weight:
1st step: add the ultra-pure water 557 parts that electrical conductivity is 0.57 μ S/cm in a kettle., start agitator in reactor, turn
Speed is 97rpm, starts heat pump, makes reactor temperature rise to 67 DEG C;It is sequentially added into poly-(styrene-methylacrylate-right
1-chloro-4-methyl-benzene) 67 parts, Chloromethyl zirconium oligo-polystyrenyl-phosphonate-phosphate 87 parts, benzene sulfuryl isobutyl acetate 157
Part, stirring is to being completely dissolved, and regulation pH value is 5.7, and agitator speed is adjusted to 157rpm, and temperature is 97 DEG C, esterification 17
Hour;
2nd step: take E-2-methyl-2-butenoic acid-3,7-dimethyl-6-octene ester 87 parts, (E, E)-2-methyl-2-butenoic acid-
3,7-dimethyl-2,6-octadiene-1-alcohol ester 77 parts pulverizes, and powder diameter is 117 mesh;Add (E)-4-(3,4-dimethoxy
Base phenyl)-4-oxygen-2-butylene acetoacetic ester 157 parts mix homogeneously, it is laid in pallet, tiling thickness is 37mm, and employing dosage is
5.7kGy, energy are the alpha ray irradiation 57 minutes of 5.7MeV, and the β x ray irradiation x of Isodose 77 minutes;
3rd step: the mixed-powder processed through the 2nd step is dissolved in [[two (2-ethylhexyl) oxygen] bisthiosulfate that concentration is 57ppm
Base] in di-n-butyl succinate 87 parts, add reactor, agitator speed is 87rpm, and temperature is 97 DEG C, starts vacuum pump and makes instead
The vacuum answering still reaches-0.87MPa, keeps this state response 17 hours;Pressure release is also passed through nitrogen, makes the reacting kettle inner pressure be
0.57MPa, insulation stands 17 hours;Agitator speed is promoted to 117rpm, simultaneous reactions still pressure release to 0MPa;It is sequentially added into two
(2-ethylhexyl) Sulfurized Oxomolybdenum Dialkyldithiophosphate 77 parts, succinic acid two [2-(2-ethyl hexyl oxy) ethyl] ester sodium sulfonate 77 parts
After being completely dissolved, add cross-linking agent 97 parts stirring mixing so that the hydrophile-lipophile balance value of reactor solution is 5.7, is incubated quiet
Put 17 hours;
4th step: when agitator speed is 157rpm, is sequentially added into 2-[2-(diethylamino) ethyl]-3-ketobutyric acid second
Ester 57 parts, 2-[(3-nitrobenzophenone) methylene]-ethyl 3-oxobutanoate 97 parts, sulfosuccinate C-[2-[2-(2-dodecane
Epoxide) ethyoxyl] ethyoxyl] ethyl ester disodium 57 parts, 3,4-Dichlorobenzene base carbamic acid-2-[3-butyl-4-(2,2-dicyano
Vinyl)-3-toluidino] ethyl ester 57 parts, promote reactor pressure so that it is reaching 0.87MPa, temperature is 157 DEG C, polymerization is anti-
Answer 17 hours;After having reacted, reacting kettle inner pressure is down to 0MPa, is cooled to 27 DEG C, discharging, enter molding press and can be prepared by folding
Folded compression blade 3-3-4;
Described cross-linking agent is 4,4-dimethyl-3-oxopentanoic acid methyl ester.
Embodiment 2
Manufacture collapsible blade 3-3-4 of the present invention according to following steps, and count by weight:
1st step: add the ultra-pure water 1507 parts that electrical conductivity is 0.77 μ S/cm in a kettle., start agitator in reactor, turn
Speed is 257rpm, starts heat pump, makes reactor temperature rise to 87 DEG C;Be sequentially added into poly-(styrene-methylacrylate-
P-chloromethyl styrene) 157 parts, Chloromethyl zirconium oligo-polystyrenyl-phosphonate-phosphate 157 parts, benzene sulfuryl isobutyl acetate
557 parts, stirring is to being completely dissolved, and regulation pH value is 7.7, and agitator speed is adjusted to 257rpm, and temperature is 167 DEG C, and esterification is anti-
Answer 27 hours;
2nd step: take E-2-methyl-2-butenoic acid-3,7-dimethyl-6-octene ester 197 parts, (E, E)-2-methyl-2-butenoic acid-
3,7-dimethyl-2,6-octadiene-1-alcohol ester 157 parts pulverizes, and powder diameter is 257 mesh;Add (E)-4-(3,4-dimethoxy
Base phenyl)-4-oxygen-2-butylene acetoacetic ester 557 parts mix homogeneously, it is laid in pallet, tiling thickness is 57mm, and employing dosage is
8.7kGy, energy are the alpha ray irradiation 157 minutes of 17MeV, and the β x ray irradiation x of Isodose 167 minutes;
3rd step: the mixed-powder processed through the 2nd step is dissolved in [[two (2-ethylhexyl) oxygen] bisthiosulfate that concentration is 97ppm
Base] in di-n-butyl succinate 157 parts, add reactor, agitator speed is 187rpm, and temperature is 157 DEG C, starts vacuum pump and makes
The vacuum of reactor reaches-0.57MPa, keeps this state response 37 hours;Pressure release is also passed through nitrogen, makes reacting kettle inner pressure
For 0.77MPa, insulation stands 37 hours;Agitator speed is promoted to 257rpm, simultaneous reactions still pressure release to 0MPa;It is sequentially added into
Two (2-ethylhexyl) Sulfurized Oxomolybdenum Dialkyldithiophosphate 157 parts, succinic acid two [2-(2-ethyl hexyl oxy) ethyl] ester sodium sulfonate
After 187 parts are completely dissolved, add cross-linking agent 167 parts stirring mixing so that the hydrophile-lipophile balance value of reactor solution is 7.7,
Insulation stands 37 hours;
4th step: when agitator speed is 267rpm, is sequentially added into 2-[2-(diethylamino) ethyl]-3-ketobutyric acid second
Ester 157 parts, 2-[(3-nitrobenzophenone) methylene]-ethyl 3-oxobutanoate 177 parts, sulfosuccinate C-[2-[2-(2-12
Alkoxyl) ethyoxyl] ethyoxyl] ethyl ester disodium 87 parts, 3,4-Dichlorobenzene base carbamic acid-2-[3-butyl-4-(2,2-dicyan
Base vinyl)-3-toluidino] ethyl ester 157 parts, promote reactor pressure so that it is reaching 1.67MPa, temperature is 277 DEG C, poly-
Close reaction 27 hours;Reacting kettle inner pressure being down to after having reacted 0MPa, is cooled to 37 DEG C, discharging, entering molding press can make
Obtain collapsible blade 3-3-4;
Described cross-linking agent is thiacetic acid .-S-(3-chloro-2-methyl-3-oxo) propyl ester.
Embodiment 3
Manufacture collapsible blade 3-3-4 of the present invention according to following steps, and count by weight:
1st step: add the ultra-pure water 907 parts that electrical conductivity is 0.67 μ S/cm in a kettle., start agitator in reactor, turn
Speed is 157rpm, starts heat pump, makes reactor temperature rise to 77 DEG C;Be sequentially added into poly-(styrene-methylacrylate-
P-chloromethyl styrene) 137 parts, Chloromethyl zirconium oligo-polystyrenyl-phosphonate-phosphate 117 parts, benzene sulfuryl isobutyl acetate
357 parts, stirring is to being completely dissolved, and regulation pH value is 6.7, and agitator speed is adjusted to 207rpm, and temperature is 117 DEG C, and esterification is anti-
Answer 19 hours;
2nd step: take E-2-methyl-2-butenoic acid-3,7-dimethyl-6-octene ester 147 parts, (E, E)-2-methyl-2-butenoic acid-
3,7-dimethyl-2,6-octadiene-1-alcohol ester 127 parts pulverizes, and powder diameter is 157 mesh;Add (E)-4-(3,4-dimethoxy
Base phenyl)-4-oxygen-2-butylene acetoacetic ester 457 parts mix homogeneously, it is laid in pallet, tiling thickness is 47mm, and employing dosage is
6.7kGy, energy are the alpha ray irradiation 127 minutes of 11MeV, and the β x ray irradiation x of Isodose 117 minutes;
3rd step: the mixed-powder processed through the 2nd step is dissolved in [[two (2-ethylhexyl) oxygen] bisthiosulfate that concentration is 77ppm
Base] in di-n-butyl succinate 117 parts, add reactor, agitator speed is 147rpm, and temperature is 117 DEG C, starts vacuum pump and makes
The vacuum of reactor reaches-0.67MPa, keeps this state response 27 hours;Pressure release is also passed through nitrogen, makes reacting kettle inner pressure
For 0.67MPa, insulation stands 27 hours;Agitator speed is promoted to 157rpm, simultaneous reactions still pressure release to 0MPa;It is sequentially added into
Two (2-ethylhexyl) Sulfurized Oxomolybdenum Dialkyldithiophosphate 117 parts, succinic acid two [2-(2-ethyl hexyl oxy) ethyl] ester sodium sulfonate
After 127 parts are completely dissolved, add cross-linking agent 127 parts stirring mixing so that the hydrophile-lipophile balance value of reactor solution is 6.7,
Insulation stands 27 hours;
4th step: when agitator speed is 207rpm, is sequentially added into 2-[2-(diethylamino) ethyl]-3-ketobutyric acid second
Ester 127 parts, 2-[(3-nitrobenzophenone) methylene]-ethyl 3-oxobutanoate 137 parts, sulfosuccinate C-[2-[2-(2-12
Alkoxyl) ethyoxyl] ethyoxyl] ethyl ester disodium 67 parts, 3,4-Dichlorobenzene base carbamic acid-2-[3-butyl-4-(2,2-dicyan
Base vinyl)-3-toluidino] ethyl ester 117 parts, promote reactor pressure so that it is reaching 1.27MPa, temperature is 187 DEG C, poly-
Close reaction 20 hours;Reacting kettle inner pressure being down to after having reacted 0MPa, is cooled to 30 DEG C, discharging, entering molding press can make
Obtain collapsible blade 3-3-4;
Described cross-linking agent is 3-ketobutyric acid 2-(methyl (phenyl methyl) amino) ethyl ester.
Reference examples
Reference examples is the collapsible blade service condition for the process of preventing fires of certain brand commercially available.
Embodiment 4
Collapsible blade described in collapsible blade 3-3-4 embodiment 1~3 prepared and reference examples is used for preventing fires
The service condition of process contrasts, and promotes with high temperature resistant enhancing rate, elastic enhancing rate, degree of drawing enhancing rate, service life
Rate is that technical specification is added up, and result is as shown in table 1:
Table 1 for the collapsible blade described in embodiment 1~3 and reference examples for the parameters of the service condition of process of preventing fires
Comparing result, as seen from Table 1, collapsible blade 3-3-4 of the present invention, enhancing rate that it is high temperature resistant, elastic enhancing rate,
Degree of drawing enhancing rate, service life enhancing rate are above the product that prior art produces.
Additionally, as shown in Figure 4, it is that collapsible blade 3-3-4 material of the present invention closes with fire protecting performance enhancing rate
System's figure.Finding out in figure, used by embodiment 1~3, collapsible blade 3-3-4 material is evenly distributed, and flameproof effect is good;Figure shows
Collapsible blade 3-3-4 of the present invention, its fire protecting performance enhancing rate is significantly better than existing product.