CN106148811A - A kind of automobile gas exhausting manifold branch high temperature resistant nodular cast iron part and preparation method thereof - Google Patents

A kind of automobile gas exhausting manifold branch high temperature resistant nodular cast iron part and preparation method thereof Download PDF

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Publication number
CN106148811A
CN106148811A CN201610681042.5A CN201610681042A CN106148811A CN 106148811 A CN106148811 A CN 106148811A CN 201610681042 A CN201610681042 A CN 201610681042A CN 106148811 A CN106148811 A CN 106148811A
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CN
China
Prior art keywords
ferrum liquid
high temperature
bag
gas exhausting
manifold branch
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Pending
Application number
CN201610681042.5A
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Chinese (zh)
Inventor
王春基
潘桂林
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JIANGYIN LIANHUA CASTING CO Ltd
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JIANGYIN LIANHUA CASTING CO Ltd
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Priority to CN201610681042.5A priority Critical patent/CN106148811A/en
Publication of CN106148811A publication Critical patent/CN106148811A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/10Cast-iron alloys containing aluminium or silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D5/00Heat treatments of cast-iron
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/08Making cast-iron alloys
    • C22C33/10Making cast-iron alloys including procedures for adding magnesium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/04Cast-iron alloys containing spheroidal graphite
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/06Cast-iron alloys containing chromium

Abstract

The invention discloses a kind of automobile gas exhausting manifold branch high temperature resistant nodular cast iron part and preparation method thereof, the percentage by weight of each chemical constituent of this nodular iron casting is: C 3.2 3.8%, Si 4.9 5.3%, Mo 1.3 1.8%, Mn 0.7 1.1%, Cr 0.5 0.8%, Al 0.2 0.4%, V 0.1 0.2%, Nb 0.3 0.6%, Co 0.2 0.5%, Pm 0.05 0.1%, P≤0.04%, S≤0.02%, and surplus is Fe.The present invention is by improving the content of Si, Mo, Mn, it is simultaneously introduced the alloying elements such as Al, Nb, Co, Pm, and by adjusting casting smelting technique, in conjunction with the rational spheroidizing process of science and Technology for Heating Processing, the nodular iron casting prepared is made at high temperature to have good mechanical performance and chemical stability, use temperature up to 900 1000 DEG C, fully meet the use requirement of automobile gas exhausting manifold branch.

Description

A kind of automobile gas exhausting manifold branch high temperature resistant nodular cast iron part and preparation method thereof
Technical field
The present invention relates to a kind of automobile gas exhausting manifold branch high temperature resistant nodular cast iron part and preparation method thereof, belong to spheroidal graphite cast-iron Technical field.
Background technology
The birth of automobile has had the history of a century, quickly grows, has the most become the most topmost vehicles With the important driving force spurred economic growth, also it is that people live indispensable important component part.Foundry goods is automobile product One of important composition of parts, cast product application on auto parts and components occupies critical role.The master of automotive castings Want feature be complex-shaped, wall thickness is relatively thin, dimensional accuracy is high, production lot is big, require that reliability is the most high.Automobile will to the greatest extent may be used Low can alleviate own wt, it is desirable to foundry goods should be light, also to have the highest intensity.The material of past many auto parts and components It is casting pig, the most mostly changes nodular iron casting into.
Automobile gas exhausting manifold branch is one of vitals of automobile exhaust system, and it is connected with automobile engine by flange, And the waste gas produced in electromotor is discharged outside car, its internal temperature is close to engine temperature, and outside contacts with natural environment, Its operating temperature is at 150-200 DEG C.In order to protect environment, auto-maker improves the burning of fuel by updating technology Rate and discharge the purifying rate of gas, result makes the temperature of discharge gas more and more higher, and the delivery temperature of part vehicle is even more than 800 DEG C.This resistance to elevated temperatures just requiring there is excellence for the nodular iron casting of automobile gas exhausting manifold branch.
Summary of the invention
It is an object of the invention to provide a kind of automobile gas exhausting manifold branch high temperature resistant nodular cast iron part and preparation method thereof.
For achieving the above object, the present invention adopts the following technical scheme that
A kind of automobile gas exhausting manifold branch high temperature resistant nodular cast iron part, the percentage by weight of its each chemical constituent is: C 3.2-3.8%, Si 4.9-5.3%、Mo 1.3-1.8%、Mn 0.7-1.1%、Cr 0.5-0.8%、Al 0.2-0.4%、V 0.1-0.2%、Nb 0.3-0.6%, Co 0.2-0.5%, Pm 0.05-0.1%, P≤0.04%, S≤0.02%, surplus is Fe.
The preparation method of a kind of automobile gas exhausting manifold branch high temperature resistant nodular cast iron part, comprises the following steps:
(1) weigh the furnace charges such as the pig iron, steel scrap, molybdenum filament, carborundum, ferromanganese, foundry returns to join in medium-frequency induction furnace and melt Refining, smelting temperature is 1460-1490 DEG C, and after furnace charge all melts, sample analysis also adjusts ferrum liquid composition, rises after reaching requirement Temperature, to 1520-1550 DEG C, is 200-300W at power, and rotating speed is magnetic agitation 10-under conditions of 1000-1500r/min 15min, stands 20-30min, comes out of the stove;
(2), before ferrum liquid is come out of the stove, first add in the base wells on bag dam, nodularization bag side and be equivalent to ferrum liquid quality 1.2-1.4% Rare earth ferrosilicomagnesium nodulizer, covers the silicon strontium inovulant being equivalent to ferrum liquid quality 0.5-0.8% on nodulizer, is then breeding Agent surface uniformly spreads that last layer is clean, be dried, rustless magnesium iron is considered to be worth doing and consolidated, when ferrum liquid is come out of the stove, by ferrum liquid by lid bag aperture Carrying out nodularization and inoculation in flowing into nodularization bag, temperature controls, at 1470-1510 DEG C, after treating spheroidizing reacion, to exist immediately Collection swelling perlite powder is spread on ferrum liquid surface, is 500-600W at power, and frequency is ultrasonic vibration 20-under conditions of 30-40kHz 30mim, and scratch clean the scum silica frost on ferrum liquid surface, stand 10-15min, then chill block analysis is produced in sampling, and detection nodularization is qualified After can pour into a mould;
(3) before cast, nodularization bag and bag being baked to 780-840 DEG C, pouring temperature controls at 1440-1460 DEG C, cast speed Degree controls at 0.4-0.6kg/s;
(4) foundry goods to moulding by casting carries out heat treatment: first with the ramp of 60-80 DEG C/h to 540-580 DEG C, be incubated 4- 6h, then with the ramp of 50-70 DEG C/h to 920-960 DEG C, it is incubated 2-4h;Then Cooling Quenching in 0-80 DEG C of cold oil is put into, Cooling 5-20s;Last microwave heating 3-4h under conditions of power is 300-400W, then under conditions of power is 700-800W Microwave heating 1-2h, air cooling of coming out of the stove.
Beneficial effects of the present invention:
The present invention, by improving the content of Si, Mo, Mn, is simultaneously introduced the alloying elements such as Al, Nb, Co, Pm, and is cast by adjustment Smelting technology, in conjunction with the rational spheroidizing process of science and Technology for Heating Processing, makes the nodular iron casting prepared at high temperature have good Good mechanical performance and chemical stability, use temperature up to 900-1000 DEG C, and the use fully meeting automobile gas exhausting manifold branch is wanted Ask.
Detailed description of the invention
A kind of automobile gas exhausting manifold branch high temperature resistant nodular cast iron part, the percentage by weight of its each chemical constituent is: C 3.2- 3.8%、Si 4.9-5.3%、Mo 1.3-1.8%、Mn 0.7-1.1%、Cr 0.5-0.8%、Al 0.2-0.4%、V 0.1-0.2%、 Nb 0.3-0.6%, Co 0.2-0.5%, Pm 0.05-0.1%, P≤0.04%, S≤0.02%, surplus is Fe.
The preparation method of a kind of automobile gas exhausting manifold branch high temperature resistant nodular cast iron part, comprises the following steps:
(1) weigh the furnace charges such as the pig iron, steel scrap, molybdenum filament, carborundum, ferromanganese, foundry returns to join in medium-frequency induction furnace and melt Refining, smelting temperature is 1480 DEG C, and after furnace charge all melts, sample analysis also adjusts ferrum liquid composition, is warming up to after reaching requirement 1530 DEG C, be 250W at power, and rotating speed is magnetic agitation 12min under conditions of 1200r/min, stands 25min, comes out of the stove;
(2), before ferrum liquid is come out of the stove, in the base wells on bag dam, nodularization bag side, the rare earth being equivalent to ferrum liquid quality 1.3% is first added Magnesium ferrosilicon nodulizer, covers the silicon strontium inovulant being equivalent to ferrum liquid quality 0.7% on nodulizer, then equal on inovulant surface Even spread that last layer is clean, be dried, rustless magnesium iron consider and consolidated, when ferrum liquid is come out of the stove, by ferrum liquid by the inflow nodularization of lid bag aperture Carrying out nodularization and inoculation in bag, temperature controls at 1490 DEG C, after treating spheroidizing reacion, spreads collection immediately on ferrum liquid surface swollen Swollen crushed crude pearlite, is 550W at power, and frequency is ultrasonic vibration 25mim under conditions of 35kHz, and scratches clean the floating of ferrum liquid surface Slag, stands 15min, and then chill block analysis is produced in sampling, can pour into a mould after detection nodularization is qualified;
(3) before cast, nodularization bag and bag being baked to 800 DEG C, pouring temperature controls at 1450 DEG C, and poring rate controls 0.5kg/s;
(4) foundry goods to moulding by casting carries out heat treatment: first with the ramp of 70 DEG C/h to 560 DEG C, be incubated 5h, then with 60 DEG C/ramp of h to 940 DEG C, be incubated 3h;Then put into Cooling Quenching in 25 DEG C of cold oil, cool down 10s;At power it is finally Microwave heating 4h under conditions of 350W, microwave heating 1.5h under conditions of power is 750W, air cooling of coming out of the stove.
Through inspection, its mechanical property is: tensile strength 724Mpa, yield strength 649Mpa, percentage elongation 13.3%, and 950 DEG C go out The cycle-index of existing crackle: 586 times.

Claims (2)

1. an automobile gas exhausting manifold branch high temperature resistant nodular cast iron part, it is characterised in that the percentage by weight of its each chemical constituent For: C 3.2-3.8%, Si 4.9-5.3%, Mo 1.3-1.8%, Mn 0.7-1.1%, Cr 0.5-0.8%, Al 0.2-0.4%, V 0.1-0.2%, Nb 0.3-0.6%, Co 0.2-0.5%, Pm 0.05-0.1%, P≤0.04%, S≤0.02%, surplus is Fe.
2. a preparation method for automobile gas exhausting manifold branch high temperature resistant nodular cast iron part as claimed in claim 1, its feature exists In comprising the following steps:
Weigh the furnace charges such as the pig iron, steel scrap, molybdenum filament, carborundum, ferromanganese, foundry returns to join medium-frequency induction furnace carries out melting, Smelting temperature is 1460-1490 DEG C, and after furnace charge all melts, sample analysis also adjusts ferrum liquid composition, heats up after reaching requirement To 1520-1550 DEG C, being 200-300W at power, rotating speed is magnetic agitation 10-15min under conditions of 1000-1500r/min, Stand 20-30min, come out of the stove;
Before ferrum liquid is come out of the stove, in the base wells on bag dam, nodularization bag side, first add the rare earth being equivalent to ferrum liquid quality 1.2-1.4% Magnesium ferrosilicon nodulizer, covers the silicon strontium inovulant being equivalent to ferrum liquid quality 0.5-0.8%, then at inovulant table on nodulizer Face uniformly spreads that last layer is clean, be dried, rustless magnesium iron consider and consolidated, when ferrum liquid is come out of the stove, by ferrum liquid by the inflow of lid bag aperture Carrying out nodularization and inoculation in nodularization bag, temperature controls at 1470-1510 DEG C, after treating spheroidizing reacion, immediately at ferrum liquid Collection swelling perlite powder is spread on surface, is 500-600W at power, and frequency is ultrasonic vibration 20-30mim under conditions of 30-40kHz, And scratch clean the scum silica frost on ferrum liquid surface, and stand 10-15min, then sampling produces chill block analysis, after detection nodularization is qualified Pour into a mould;
Before cast, nodularization bag and bag being baked to 780-840 DEG C, pouring temperature controls at 1440-1460 DEG C, poring rate control System is at 0.4-0.6kg/s;
(4) foundry goods to moulding by casting carries out heat treatment: first with the ramp of 60-80 DEG C/h to 540-580 DEG C, be incubated 4- 6h, then with the ramp of 50-70 DEG C/h to 920-960 DEG C, it is incubated 2-4h;Then Cooling Quenching in 0-80 DEG C of cold oil is put into, Cooling 5-20s;Last microwave heating 3-4h under conditions of power is 300-400W, then under conditions of power is 700-800W Microwave heating 1-2h, air cooling of coming out of the stove.
CN201610681042.5A 2016-08-18 2016-08-18 A kind of automobile gas exhausting manifold branch high temperature resistant nodular cast iron part and preparation method thereof Pending CN106148811A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107236896A (en) * 2017-06-30 2017-10-10 马鞍山市兴隆铸造有限公司 A kind of casting method of mortar pump pump body cast
CN107747067A (en) * 2017-10-23 2018-03-02 宁国市正兴耐磨材料有限公司 A kind of corrosion resistant low-chromium wear-resistant ball and its casting method
CN110777292A (en) * 2019-10-22 2020-02-11 山东力得汽车科技股份有限公司 Production method for performing tip passivation on flake graphite of flake graphite cast iron

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101851722A (en) * 2009-04-01 2010-10-06 西峡县西泵特种铸造有限公司 Formula of high silicon molybdenum ductile iron exhaust manifold and preparation method thereof
CN102888551A (en) * 2012-10-30 2013-01-23 齐齐哈尔市精铸良铸造有限责任公司 High-temperature-resistant antioxidant exhaust manifold nodular cast iron and preparation method thereof
CN103820700A (en) * 2014-01-30 2014-05-28 南车戚墅堰机车车辆工艺研究所有限公司 Heat-resisting spheroidal graphite cast iron and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101851722A (en) * 2009-04-01 2010-10-06 西峡县西泵特种铸造有限公司 Formula of high silicon molybdenum ductile iron exhaust manifold and preparation method thereof
CN102888551A (en) * 2012-10-30 2013-01-23 齐齐哈尔市精铸良铸造有限责任公司 High-temperature-resistant antioxidant exhaust manifold nodular cast iron and preparation method thereof
CN103820700A (en) * 2014-01-30 2014-05-28 南车戚墅堰机车车辆工艺研究所有限公司 Heat-resisting spheroidal graphite cast iron and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107236896A (en) * 2017-06-30 2017-10-10 马鞍山市兴隆铸造有限公司 A kind of casting method of mortar pump pump body cast
CN107747067A (en) * 2017-10-23 2018-03-02 宁国市正兴耐磨材料有限公司 A kind of corrosion resistant low-chromium wear-resistant ball and its casting method
CN110777292A (en) * 2019-10-22 2020-02-11 山东力得汽车科技股份有限公司 Production method for performing tip passivation on flake graphite of flake graphite cast iron

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