CN106147688A - A kind of antistatic protection film glue and a kind of antistatic protection film - Google Patents

A kind of antistatic protection film glue and a kind of antistatic protection film Download PDF

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Publication number
CN106147688A
CN106147688A CN201510149316.1A CN201510149316A CN106147688A CN 106147688 A CN106147688 A CN 106147688A CN 201510149316 A CN201510149316 A CN 201510149316A CN 106147688 A CN106147688 A CN 106147688A
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CN
China
Prior art keywords
protection film
antistatic protection
antistatic
glue
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510149316.1A
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Chinese (zh)
Inventor
孙攀
王玺
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shanghai Jingjing New Materials Co., Ltd.
Original Assignee
SHANGHAI PLUSCO TECH Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SHANGHAI PLUSCO TECH Co Ltd filed Critical SHANGHAI PLUSCO TECH Co Ltd
Priority to CN201510149316.1A priority Critical patent/CN106147688A/en
Publication of CN106147688A publication Critical patent/CN106147688A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of antistatic protection film glue and a kind of antistatic protection film.By adding liquid antistatic agent, solve the problem that antistatic agent separates out from glue-line.Glue the most provided by the present invention has good tack, excellent venting quality to plastic film substrates such as PET, PE, PC so that protecting film, on the basis of having excellent electrostatic-proof function, also has good product stability and the characteristic without cull.

Description

A kind of antistatic protection film glue and a kind of antistatic protection film
Technical field
The present invention relates to antistatic protection film field, particularly to a kind of antistatic protection film glue and A kind of antistatic protection film.
Background technology
Electronic apparatus series products is during carrying or production and application, and its surface is highly prone to contact staining Or produce polishing scratch to scratch, need to use protecting film that its surface carries out covering and make it from getting dirty or being subject to Damage.And protecting film used by electronics or electric type product must also have a characteristic: can not produce when removing Electrostatic, in order to avoid causing damage to electronic apparatus series products.
The mode of production of antistatic protection film in the market mainly has three kinds: (one) is at protecting film base material The back side be coated with one layer of antistatic backing.The protecting film anti-static effect of this kind of method production is poor, leads simultaneously Cause production process and production cost increases.(2) on protecting film base material, antistatic bottom first it is coated with, It is coated glue.There is the situation that anti-static effect weakens with bondline thickness increase in this kind of method, and And the attachment of glue-line and antistatic backing is loosely, there is also production process simultaneously and production cost increases asks Topic.(3) in glue, conductive agent is added.The method is current main stream approach, both can lower production Operation and cost, can reach again good anti-static effect, but exist under extreme climate antistatic agent from Glue-line separates out, the problem polluting protected object.How to solve this problem and become PU antistatic protection One major subjects in film research and development field.
Summary of the invention
For overcoming the deficiencies in the prior art, the invention provides a kind of antistatic protection film glue and one Plant antistatic protection film.By adding the antistatic agent of liquid in glue, solve antistatic agent from The problem separated out in glue-line.
Antistatic protection film glue provided by the present invention, is 30%-60%'s by percentage by weight After host, and the lytic agent mixing that percentage by weight is 30%-60%, adding percentage by weight is The firming agent of 5%-20%, adds the liquid antistatic agent that percentage by weight is 0.5%-3% and makes.
It is further preferred that described antistatic agent is the fluorine system conductive material being dissolved in described lytic agent.
It is further preferred that described fluorine system conductive material is metal ion is potassium, sodium, lithium class sulfonate Or potassium, sodium, lithium class sulfimide salt.
It is further preferred that described host is polyhydric alcohol, described polyhydric alcohol is fats polyhydric alcohol or virtue The one or more of which mixture of fragrant class polyhydric alcohol.
It is further preferred that described lytic agent is ethyl acetate, butyl acetate, toluene, acetone, fourth One or more mixture of ketone.
It is further preferred that described firming agent is isocyanates firming agent.
It is further preferred that the molecular weight of the polyurethane of described antistatic protection film glue is 90000-160000。
The antistatic protection film of the carried offer of the present invention, is coated with according to any one of claim 1-9 institute The antistatic protection film glue stated.
It is further preferred that the thickness of coated antistatic protection film glue is 4-50um.
It is further preferred that described protecting film be mylar, polycarbonate film, polyethylene film, Any one in polyvinyl chloride film.
Beneficial effects of the present invention is as follows:
Antistatic protection film glue provided by the present invention, uses suitable proportioning raw materials, levelability Good, coating difficulty is low, and Painting effect is good, and film forming final vacuum is excellent, tears rear noresidue;Simultaneously Owing to the addition of the antistatic agent of liquid, there is excellent anti-static effect.
Antistatic protection film provided by the present invention above-mentioned with the addition of liquid antistatic agent owing to being coated with Glue, its anti-static effect will not be affected by coating layer thickness, and this antistatic agent is extremely Under weather the most extremely stable, will not from glue-line separate out cause protected object be contaminated.
Detailed description of the invention
Below the present invention is described in further detail.
Antistatic protection film glue provided by the present invention, is the master of 30%-60% by percentage by weight Agent, and after the lytic agent that percentage by weight is 30%-60% is sufficiently mixed, adding percentage by weight is The firming agent of 5%-20% is sufficiently mixed, then is added immediately the liquid that percentage by weight is 0.5%-3% and prevents quiet Electricity agent prepares after stirring.
Described antistatic agent is the fluorine system conductive material being dissolved in described lytic agent, includes but not limited to metal Ion is potassium, sodium, lithium class sulfonate, potassium, sodium, lithium class sulfimide salt.
Described host is polyhydric alcohol, and described polyhydric alcohol is its of fats polyhydric alcohol or aromatics polyhydric alcohol In one or more mixtures.Described lytic agent be ethyl acetate, butyl acetate, toluene, acetone, One or more mixture of butanone.Described firming agent is isocyanates firming agent.Described anti- The molecular weight of the polyurethane of electrostatic protection film glue is 90000-160000.
Antistatic protection film provided by the present invention, coats by above-mentioned antistatic protection film glue, and The thickness of coating is 4-50um.
Described antistatic protection film can be mylar, polycarbonate film, polyethylene film or poly- Vinyl chloride film.
Embodiment one
Antistatic protection film glue provided by the present invention, is the host of 30% by percentage by weight, After being sufficiently mixed with the lytic agent that percentage by weight is 64%, adding percentage by weight is the firming agent of 5% It is sufficiently mixed, then is added immediately after the antistatic agent that percentage by weight is 1% stirs prepared.
Antistatic protection film provided by the present invention coats by above-mentioned prepared antistatic protection film glue Water, coating thickness is 45um.
Embodiment two
Antistatic protection film glue provided by the present invention, is the host of 40% by percentage by weight, After being sufficiently mixed with the lytic agent that percentage by weight is 48%, adding percentage by weight is the solidification of 10% Agent is sufficiently mixed, then is added immediately after the antistatic agent that percentage by weight is 2% stirs prepared.
Antistatic protection film provided by the present invention coats by above-mentioned prepared antistatic protection film glue Water, coating thickness is 15um.
Embodiment three
Antistatic protection film glue provided by the present invention, is the host of 40% by percentage by weight, After being sufficiently mixed with the lytic agent that percentage by weight is 37%, adding percentage by weight is the solidification of 20% Agent is sufficiently mixed, then is added immediately after the antistatic agent that percentage by weight is 3% stirs prepared.
Antistatic protection film provided by the present invention coats by above-mentioned prepared antistatic protection film glue Water, coating thickness is 8um.
Following table is antistatic protection film provided by the present invention and common antistatic polyurethane protective film Data Comparison table, therefrom visible compared to prior art, antistatic protection film provided by the present invention is prevented Electrostatic efficiency is good, without cull, and is antistatic agent rather than the conducting particles of liquid due to add, Thus antistatic agent also will not separate out from glue-line under extreme climate, pollution protected object will not be produced Problem.
Antistatic protection film Data Comparison catalog
Note: 1, JP001/002/003/004/005/006 is the common antistatic polyurethane protective film sold on market
2, CH001/002 is antistatic protection film provided by the present invention
Antistatic protection film provided by the present invention can be used for the electronic apparatus such as display screen, touch screen and produces Product are it can also be used to the process during electrical type other products manufactures is protected.
It is of the art it will be recognized by the skilled artisan that above example of the present invention is only this One of preferred embodiment of invention, limits for length, can not enumerate all embodiments here one by one, Any enforcement that can embody the claims in the present invention technical scheme, all in protection scope of the present invention In.
It should be noted that above content be combine specific embodiment made for the present invention enter one Step describes in detail, it is impossible to assert that the detailed description of the invention of the present invention is only limitted to this, above-mentioned in the present invention Under guidance, those skilled in the art can carry out various improvement and change on the basis of above-described embodiment Shape, and these improve or deformation is within the scope of the present invention.

Claims (10)

1. an antistatic protection film glue, is the host of 30%-60% by percentage by weight, and After percentage by weight is the lytic agent mixing of 30%-60%, adding percentage by weight is the solidification of 5%-20% Agent, adds the liquid antistatic agent that percentage by weight is 0.5%-3% and makes.
Antistatic protection film glue the most according to claim 1, it is characterised in that: described anti- Electrostatic agent is the fluorine system conductive material being dissolved in described lytic agent.
Antistatic protection film glue the most according to claim 1, it is characterised in that: described fluorine Be conductive material be metal ion be potassium, sodium, lithium class sulfonate or potassium, sodium, lithium class sulfimide salt.
4., according to the antistatic protection film glue described in any one of claim 1-3, its feature exists In: described host is polyhydric alcohol, and described polyhydric alcohol is its of fats polyhydric alcohol or aromatics polyhydric alcohol In one or more mixtures.
Antistatic protection film glue the most according to claim 4, it is characterised in that: described molten Solution agent is one or more mixture of ethyl acetate, butyl acetate, toluene, acetone, butanone.
Antistatic protection film glue the most according to claim 5, it is characterised in that: described solid Agent is isocyanates firming agent.
Antistatic protection film glue the most according to claim 7, it is characterised in that: described anti- The molecular weight of the polyurethane of electrostatic protection film glue is 90000-160000.
8. an antistatic protection film, it is characterised in that: it is coated with according to claim 1-9 arbitrary Antistatic protection film glue described in Xiang.
Antistatic protection film the most according to claim 8, it is characterised in that: coated is anti- The thickness of electrostatic protection film glue is 4-50um.
Antistatic protection film the most according to claim 9, it is characterised in that: described protecting film For any one in mylar, polycarbonate film, polyethylene film, polyvinyl chloride film.
CN201510149316.1A 2015-04-01 2015-04-01 A kind of antistatic protection film glue and a kind of antistatic protection film Pending CN106147688A (en)

Priority Applications (1)

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CN201510149316.1A CN106147688A (en) 2015-04-01 2015-04-01 A kind of antistatic protection film glue and a kind of antistatic protection film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510149316.1A CN106147688A (en) 2015-04-01 2015-04-01 A kind of antistatic protection film glue and a kind of antistatic protection film

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CN106147688A true CN106147688A (en) 2016-11-23

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106590460A (en) * 2016-12-30 2017-04-26 东莞市尼的科技股份有限公司 Anti-static protective film
CN109705769A (en) * 2018-12-31 2019-05-03 上海精珅新材料有限公司 A kind of preparation method and products thereof that can tear off screen process film at a high speed
CN110951436A (en) * 2019-12-09 2020-04-03 深圳盛得莱防静电设备有限公司 Anti-static adhesive and preparation method thereof
CN112029405A (en) * 2020-08-19 2020-12-04 江苏斯瑞达材料技术股份有限公司 Anti-static polyurethane protective film and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1696230A (en) * 2004-05-14 2005-11-16 日东电工株式会社 Pressure-sensitive adhesive composition, pressure-sensitive adhesive sheets, and surface protecting film
CN101796439A (en) * 2007-09-03 2010-08-04 住友化学株式会社 Optical film with adhesive and optical laminate
CN102070990A (en) * 2009-11-16 2011-05-25 琳得科株式会社 Adhesive composition, adhesive and adhesive sheet
CN103571360A (en) * 2012-07-31 2014-02-12 日东电工株式会社 Surface protective film, optical member, and electronic member
CN104531039A (en) * 2014-12-29 2015-04-22 宁波大榭开发区综研化学有限公司 Preparation method of polyurethane pressure-sensitive adhesive composition and polyurethane protective film

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1696230A (en) * 2004-05-14 2005-11-16 日东电工株式会社 Pressure-sensitive adhesive composition, pressure-sensitive adhesive sheets, and surface protecting film
CN101796439A (en) * 2007-09-03 2010-08-04 住友化学株式会社 Optical film with adhesive and optical laminate
CN102070990A (en) * 2009-11-16 2011-05-25 琳得科株式会社 Adhesive composition, adhesive and adhesive sheet
CN103571360A (en) * 2012-07-31 2014-02-12 日东电工株式会社 Surface protective film, optical member, and electronic member
CN104531039A (en) * 2014-12-29 2015-04-22 宁波大榭开发区综研化学有限公司 Preparation method of polyurethane pressure-sensitive adhesive composition and polyurethane protective film

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106590460A (en) * 2016-12-30 2017-04-26 东莞市尼的科技股份有限公司 Anti-static protective film
CN109705769A (en) * 2018-12-31 2019-05-03 上海精珅新材料有限公司 A kind of preparation method and products thereof that can tear off screen process film at a high speed
CN110951436A (en) * 2019-12-09 2020-04-03 深圳盛得莱防静电设备有限公司 Anti-static adhesive and preparation method thereof
CN112029405A (en) * 2020-08-19 2020-12-04 江苏斯瑞达材料技术股份有限公司 Anti-static polyurethane protective film and preparation method thereof

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Effective date of registration: 20190523

Address after: Nine Blocks 288 Jinhe Road, Jinshan Industrial Zone, Jinshan District, Shanghai

Applicant after: Shanghai Jingjing New Materials Co., Ltd.

Address before: 201316 Three Blocks 118 Hangtou Road, Hangtou Town, Pudong New Area, Shanghai

Applicant before: SHANGHAI PLUSCO TECH CO., LTD.

WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20161123