CN106147334A - A kind of metal magnetic Plumbum preparatium antirusting paint - Google Patents

A kind of metal magnetic Plumbum preparatium antirusting paint Download PDF

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Publication number
CN106147334A
CN106147334A CN201610580712.4A CN201610580712A CN106147334A CN 106147334 A CN106147334 A CN 106147334A CN 201610580712 A CN201610580712 A CN 201610580712A CN 106147334 A CN106147334 A CN 106147334A
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parts
plumbum preparatium
metal magnetic
naphthenate
antirusting paint
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CN201610580712.4A
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沈旭源
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/082Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/084Inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/23Magnetisable or magnetic paints or lacquers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of metal magnetic Plumbum preparatium antirusting paint, raw material is: red lead powder, Biformyl, titanium dioxide, trimethylolpropane, Plumbum preparatium, blanc fixe, Ketohexamethylene, lead naphthenate, manganese naphthenate and silicon dioxide;Fineness 60 80 microns, viscosity 80 100s, covering power 200 240g/cm2;Pliability 1 3mm, water-fast 15 35d are without exception, and resistance to salt water 5 25d is non-foaming, do not fall off;Surface drying 10 50min, does solid work 10 14h.

Description

A kind of metal magnetic Plumbum preparatium antirusting paint
Technical field
The present invention relates to metal field of material technology, particularly relate to a kind of metal magnetic Plumbum preparatium antirusting paint.
Background technology
Antirust paint is a kind of chemistry protecting metal surfaces from air, sea water etc. or the coating of electrochemical corrosion.Main Physical property to be divided into and the big class of chemically antirust paint two.The former is by the suitable cooperation of pigment and paint vehicle, formed fine and close paint film with Stop the intrusion of corrosive substance, such as iron oxide red, aluminium powder, graphite antirust paint etc.;The latter presses down rust effect by the chemistry of rust resisting pigment, as Plumbum preparatium, zinc chromate anti-rust paint etc..Antirust for metals such as bridge, boats and ships, pipelines.
The antirust paint substantially oiliness used and aqueous two kinds.Oily antirust varniss makes the greasy difficulty of removing of material surface, It is rarely employed.Oily antirust varniss is easy to use, cheap, but because of containing the noxious substance such as nitrite, chromate, to operation Personnel's harm is relatively big, and country has limited use, and these type of properties of product are single, it is impossible to meets the antirust of magnetic alloy material and wants Ask.The ferrous metal surface bottoming that alkyd red lead anti-corrosive paint is mainly used in the slight and ocean of moderate corrosion and industrial environment is prevented Rust, is not useable for portion under water.
Water-based metal antirust paint selects metal strength chelating agen inositol hexaphosphate to be main component, with other several aqueouss Additive compound forms.Inositol hexaphosphate is the Nantural non-toxic Organic chemical products extracted from cereal crops, when it is as magnetic Property material antirust agent use time, can chelate rapidly with metal on surface, form one layer of fine and close unimolecule complex protecting film, can Effectively suppress corrosion of metal.Material surface after this product treatment keeps primary colors, it is not necessary to washing can enter under application etc. Procedure.
Rust resisting pigment is the important component part of antirust paint. physics rust resisting pigment is that an own chemical property of class is relatively stable Pigment, they are the physical properties by itself, and stable chemical performance, quality is hard, and granule is trickle, excellent fillibility, carries The consistency of high paint film, reduces the permeable of paint film thus plays antirust effect. and iron oxide red just belongs to this kind of material. and metal The rust-preventing characteristic of aluminium powder is owing to aluminium powder has sclay texture, forms paint film tight, also has the energy of stronger uv reflectance light Power, can improve paint film aging-resistant ability.Lead red alcohol acid antirust paint be by alkyd resin, red lead powder, extender pigment, drier, Organic solvent mixed grinding forms.Lead red alcohol acid antirust paint good antirust property, fast drying, adhesive force is strong.
The main component of antirust paint is rust resisting pigment and film forming matter.Generally name with the title of rust resisting pigment, such as: red Red anticorrosive paint, iron oxide red anticorrosive paint etc..If divided with its rust inhibition, it is broadly divided into four big classes: physical action Anticorrosive paint, chemical action anticorrosive paint, electrochemical action anticorrosive paint, comprehensive function anticorrosive paint.
Summary of the invention
The present invention provides the metal magnetic Plumbum preparatium antirusting paint that a kind of fast drying, adhesive force are good, solves existing metal and uses Material is dried the technical problems such as slow and covering power is low.
The present invention is by the following technical solutions: a kind of metal magnetic Plumbum preparatium antirusting paint, its raw material is joined by mass fraction Ratio is as follows: red lead powder 100 parts, Biformyl 10-50 part, titanium dioxide 15-55 part, trimethylolpropane 20-40 part, Plumbum preparatium 1-5 Part, blanc fixe 10-30 part, Ketohexamethylene 16-20 part, lead naphthenate 5-25 part, manganese naphthenate 25-45 part, silicon dioxide 25- 65 parts.
As a preferred technical solution of the present invention: mass parts pressed by the raw material of described metal magnetic Plumbum preparatium antirusting paint Number proportioning is as follows: red lead powder 100 parts, Biformyl 20-40 part, titanium dioxide 25-45 part, trimethylolpropane 25-35 part, Plumbum preparatium 2-4 part, blanc fixe 15-25 part, Ketohexamethylene 17-19 part, lead naphthenate 10-20 part, manganese naphthenate 30-40 part, titanium dioxide Silicon 35-55 part.
As a preferred technical solution of the present invention: mass parts pressed by the raw material of described metal magnetic Plumbum preparatium antirusting paint Number proportioning is as follows: red lead powder 100 parts, Biformyl 20 parts, titanium dioxide 25 parts, trimethylolpropane 25 parts, 2 parts of Plumbum preparatium, precipitation 15 parts of barium sulfate, Ketohexamethylene 17 parts, lead naphthenate 10 parts, manganese naphthenate 30 parts, silicon dioxide 35 parts.
As a preferred technical solution of the present invention: mass parts pressed by the raw material of described metal magnetic Plumbum preparatium antirusting paint Number proportioning is as follows: red lead powder 100 parts, Biformyl 40 parts, titanium dioxide 45 parts, trimethylolpropane 35 parts, 4 parts of Plumbum preparatium, precipitation 25 parts of barium sulfate, Ketohexamethylene 19 parts, lead naphthenate 20 parts, manganese naphthenate 40 parts, silicon dioxide 55 parts.
As a preferred technical solution of the present invention: mass parts pressed by the raw material of described metal magnetic Plumbum preparatium antirusting paint Number proportioning is as follows: red lead powder 100 parts, Biformyl 30 parts, titanium dioxide 35 parts, trimethylolpropane 30 parts, 3 parts of Plumbum preparatium, precipitation 20 parts of barium sulfate, Ketohexamethylene 18 parts, lead naphthenate 15 parts, manganese naphthenate 35 parts, silicon dioxide 45 parts.
Beneficial effect
A kind of metal magnetic Plumbum preparatium antirusting paint of the present invention uses above technical scheme compared with prior art, tool There is a techniques below effect: 1, fineness 60-80 micron, viscosity 80-100s, covering power 200-240g/cm2;2, pliability 1-3mm, Water-fast 15-35d is without exception, and resistance to salt water 5-25d is non-foaming, do not fall off;3, surface drying 10-50min, does solid work 10-14h, preparation side Method is simple, and raw material is simple and easy to get, can be with the widespread production not division of history into periods for current material.
Detailed description of the invention
Below in conjunction with example, the invention will be further described, and embodiment is only used for that the present invention will be described, not Constituting the restriction to right, other alternative means that it may occur to persons skilled in the art that, all in right of the present invention In claimed range.
Embodiment 1:
The first step: weigh red lead powder 100 parts, Biformyl 10 parts, titanium dioxide 15 parts, three hydroxyl first according to mass fraction proportioning 20 parts of base propane, 1 part of Plumbum preparatium, blanc fixe 10 parts, Ketohexamethylene 16 parts, lead naphthenate 5 parts, manganese naphthenate 25 parts, titanium dioxide Silicon 25 parts.
Second step: red lead powder, Biformyl, titanium dioxide, trimethylolpropane and blanc fixe are put in reactor, It is heated to 150 DEG C, stirs 30min with 400r/min speed.
3rd step: the liquid after stirring stands 100min, adds Plumbum preparatium, Ketohexamethylene, lead naphthenate, manganese naphthenate And silicon dioxide, after 175 DEG C of mix homogeneously, put into grinder grind 20h, pack after filtration.
Fineness 60 microns, viscosity 80s, covering power 200g/cm2;Pliability 3mm, water-fast 15d is without exception, resistance to salt water 5d Non-foaming, do not fall off;Surface drying 50min, does solid work 14h.
Embodiment 2:
The first step: weigh red lead powder 100 parts, Biformyl 50 parts, titanium dioxide 55 parts, three hydroxyl first according to mass fraction proportioning 40 parts of base propane, 5 parts of Plumbum preparatium, blanc fixe 30 parts, Ketohexamethylene 20 parts, lead naphthenate 25 parts, manganese naphthenate 45 parts, titanium dioxide Silicon 65 parts.
Second step: red lead powder, Biformyl, titanium dioxide, trimethylolpropane and blanc fixe are put in reactor, It is heated to 170 DEG C, stirs 50min with 600r/min speed.
3rd step: the liquid after stirring stands 140min, adds Plumbum preparatium, Ketohexamethylene, lead naphthenate, manganese naphthenate And silicon dioxide, after 195 DEG C of mix homogeneously, put into grinder grind 24h, pack after filtration.
Fineness 65 microns, viscosity 85s, covering power 210g/cm2;Pliability 2.5mm, water-fast 20d is without exception, resistance to salt water 10d is non-foaming, do not fall off;Surface drying 40min, does solid work 13h.
Embodiment 3:
The first step: weigh red lead powder 100 parts, Biformyl 20 parts, titanium dioxide 25 parts, three hydroxyl first according to mass fraction proportioning 25 parts of base propane, 2 parts of Plumbum preparatium, blanc fixe 15 parts, Ketohexamethylene 17 parts, lead naphthenate 10 parts, manganese naphthenate 30 parts, titanium dioxide Silicon 35 parts.
Second step: red lead powder, Biformyl, titanium dioxide, trimethylolpropane and blanc fixe are put in reactor, It is heated to 150 DEG C, stirs 0min with 400r/min speed.
3rd step: the liquid after stirring stands 100min, adds Plumbum preparatium, Ketohexamethylene, lead naphthenate, manganese naphthenate And silicon dioxide, after 175 DEG C of mix homogeneously, put into grinder grind 20h, pack after filtration.
Fineness 70 microns, viscosity 90s, covering power 220g/cm2;Pliability 2mm, water-fast 25d is without exception, resistance to salt water 15d Non-foaming, do not fall off;Surface drying 30min, does solid work 12h.
Embodiment 4:
The first step: weigh red lead powder 100 parts, Biformyl 40 parts, titanium dioxide 45 parts, three hydroxyl first according to mass fraction proportioning 35 parts of base propane, 4 parts of Plumbum preparatium, blanc fixe 25 parts, Ketohexamethylene 19 parts, lead naphthenate 20 parts, manganese naphthenate 40 parts, titanium dioxide Silicon 55 parts.
Second step: red lead powder, Biformyl, titanium dioxide, trimethylolpropane and blanc fixe are put in reactor, It is heated to 170 DEG C, stirs 50min with 600r/min speed.
3rd step: the liquid after stirring stands 140min, adds Plumbum preparatium, Ketohexamethylene, lead naphthenate, manganese naphthenate And silicon dioxide, after 195 DEG C of mix homogeneously, put into grinder grind 24h, pack after filtration.
Fineness 75 microns, viscosity 95s, covering power 210g/cm2;Pliability 1.5mm, water-fast 30d is without exception, resistance to salt water 20d is non-foaming, do not fall off;Surface drying 20min, does solid work 11h.
Embodiment 5:
The first step: weigh red lead powder 100 parts, Biformyl 30 parts, titanium dioxide 35 parts, three hydroxyl first according to mass fraction proportioning 30 parts of base propane, 3 parts of Plumbum preparatium, blanc fixe 20 parts, Ketohexamethylene 18 parts, lead naphthenate 15 parts, manganese naphthenate 35 parts, titanium dioxide Silicon 45 parts.
Second step: red lead powder, Biformyl, titanium dioxide, trimethylolpropane and blanc fixe are put in reactor, It is heated to 160 DEG C, stirs 40min with 500r/min speed.
3rd step: the liquid after stirring stands 120min, adds Plumbum preparatium, Ketohexamethylene, lead naphthenate, manganese naphthenate And silicon dioxide, after 185 DEG C of mix homogeneously, put into grinder grind 22h, pack after filtration.
Fineness 80 microns, viscosity 100s, covering power 240g/cm2;Pliability 1mm, water-fast 35d is without exception, resistance to salt water 25d is non-foaming, do not fall off;Surface drying 10min, does solid work 10h.

Claims (5)

1. a metal magnetic Plumbum preparatium antirusting paint, it is characterised in that the raw material of described metal magnetic Plumbum preparatium antirusting paint As follows by mass fraction proportioning: red lead powder 100 parts, Biformyl 10-50 part, titanium dioxide 15-55 part, trimethylolpropane 20- 40 parts, Plumbum preparatium 1-5 part, blanc fixe 10-30 part, Ketohexamethylene 16-20 part, lead naphthenate 5-25 part, manganese naphthenate 25-45 Part, silicon dioxide 25-65 part.
A kind of metal magnetic Plumbum preparatium antirusting paint the most according to claim 1, it is characterised in that described metal magnetic It is as follows that mass fraction proportioning pressed by the raw material of Plumbum preparatium antirusting paint: red lead powder 100 parts, Biformyl 20-40 part, titanium dioxide 25-45 Part, trimethylolpropane 25-35 part, Plumbum preparatium 2-4 part, blanc fixe 15-25 part, Ketohexamethylene 17-19 part, lead naphthenate 10- 20 parts, manganese naphthenate 30-40 part, silicon dioxide 35-55 part.
A kind of metal magnetic Plumbum preparatium antirusting paint the most according to claim 1, it is characterised in that described metal magnetic It is as follows that mass fraction proportioning pressed by the raw material of Plumbum preparatium antirusting paint: red lead powder 100 parts, Biformyl 20 parts, titanium dioxide 25 parts, three hydroxyls Methylpropane 25 parts, 2 parts of Plumbum preparatium, blanc fixe 15 parts, Ketohexamethylene 17 parts, lead naphthenate 10 parts, manganese naphthenate 30 parts, dioxy SiClx 35 parts.
A kind of metal magnetic Plumbum preparatium antirusting paint the most according to claim 2, it is characterised in that described metal magnetic It is as follows that mass fraction proportioning pressed by the raw material of Plumbum preparatium antirusting paint: red lead powder 100 parts, Biformyl 40 parts, titanium dioxide 45 parts, three hydroxyls Methylpropane 35 parts, 4 parts of Plumbum preparatium, blanc fixe 25 parts, Ketohexamethylene 19 parts, lead naphthenate 20 parts, manganese naphthenate 40 parts, dioxy SiClx 55 parts.
A kind of metal magnetic Plumbum preparatium antirusting paint the most according to claim 1, it is characterised in that: described metal magnetic It is as follows that mass fraction proportioning pressed by the raw material of Plumbum preparatium antirusting paint: red lead powder 100 parts, Biformyl 30 parts, titanium dioxide 35 parts, three hydroxyls Methylpropane 30 parts, 3 parts of Plumbum preparatium, blanc fixe 20 parts, Ketohexamethylene 18 parts, lead naphthenate 15 parts, manganese naphthenate 35 parts, dioxy SiClx 45 parts.
CN201610580712.4A 2016-07-20 2016-07-20 A kind of metal magnetic Plumbum preparatium antirusting paint Withdrawn CN106147334A (en)

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CN201610580712.4A CN106147334A (en) 2016-07-20 2016-07-20 A kind of metal magnetic Plumbum preparatium antirusting paint

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CN201610580712.4A CN106147334A (en) 2016-07-20 2016-07-20 A kind of metal magnetic Plumbum preparatium antirusting paint

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1179168A (en) * 1967-12-15 1970-01-28 Ass Lead Mfg Ltd Improvements in Paints.
CN104927611A (en) * 2015-06-30 2015-09-23 苏州乔纳森新材料科技有限公司 Medical red lead antirust paint and preparation method therefor
CN105017927A (en) * 2015-06-30 2015-11-04 苏州乔纳森新材料科技有限公司 Medical magnetic red lead antirust paint and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1179168A (en) * 1967-12-15 1970-01-28 Ass Lead Mfg Ltd Improvements in Paints.
CN104927611A (en) * 2015-06-30 2015-09-23 苏州乔纳森新材料科技有限公司 Medical red lead antirust paint and preparation method therefor
CN105017927A (en) * 2015-06-30 2015-11-04 苏州乔纳森新材料科技有限公司 Medical magnetic red lead antirust paint and preparation method thereof

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