CN106147193A - The halogen-free flame retardant PC of a kind of weather resistant/ASA alloy and preparation method thereof - Google Patents

The halogen-free flame retardant PC of a kind of weather resistant/ASA alloy and preparation method thereof Download PDF

Info

Publication number
CN106147193A
CN106147193A CN201610832721.8A CN201610832721A CN106147193A CN 106147193 A CN106147193 A CN 106147193A CN 201610832721 A CN201610832721 A CN 201610832721A CN 106147193 A CN106147193 A CN 106147193A
Authority
CN
China
Prior art keywords
halogen
free flame
asa
flame retardant
weather resistant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610832721.8A
Other languages
Chinese (zh)
Inventor
彭耀
张电海
瞿锡娟
郭洪涛
何宏武
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NANJING DELLON ENGINEERING PLASTICS Co Ltd
Original Assignee
NANJING DELLON ENGINEERING PLASTICS Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NANJING DELLON ENGINEERING PLASTICS Co Ltd filed Critical NANJING DELLON ENGINEERING PLASTICS Co Ltd
Priority to CN201610832721.8A priority Critical patent/CN106147193A/en
Publication of CN106147193A publication Critical patent/CN106147193A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Fireproofing Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Halogen-free flame retardant PC/ASA alloy that the present invention relates to a kind of weather resistant and preparation method thereof, it is made up of the raw material of following mass percentage content: regular grade PC 10 60%, copolymeric siloxane PC 10 60%, methyl methacrylate acrylate Organosiliconcopolymere 3 10%, ASA 5 20%, the ternary atactic copolymer 1 5% of styrene-acrylonitrile glycidyl methacrylate, PX 200 5 15%, first antioxidant 0.1 0.5%, second antioxidant 0.1 0.5%, UV absorbent UV 234 0.1 0.5%, anti-dripping agent 0.1 0.5%, lubricant PETS 0.1 0.5%.The preparation method of the present invention has raw material and is conveniently easy to get, and preparation method is simple, and the product prepared is more prominent than the performance of conventional PC/ASA alloy.

Description

The halogen-free flame retardant PC of a kind of weather resistant/ASA alloy and preparation method thereof
Technical field
The invention belongs to modified engineered plastic field, be specifically related to a kind of weather resistant halogen-free flame retardant PC/ASA alloy and Preparation method.
Background technology
At present, the PC/ASA alloy material that market uses, is all most basic alloy material, and the performance of these materials is all The requirement using environment, such as cold-resistant, fast light, aging and anti-flammability cannot be met.This invention proposes the Halogen of weather resistant first Fire retardation PC/ASA alloy, can meet above-mentioned requirements, and halogen-free flameproof meets environment protection requirement simultaneously, reduces environmental pollution, does Develop to Sustainable type.
Summary of the invention
Halogen-free flame retardant PC/ASA alloy that it is an object of the invention to provide a kind of weather resistant and preparation method thereof, it is possible to meet Use the requirement of environment.
For reaching above-mentioned purpose, present invention provide the technical scheme that
The halogen-free flame retardant PC of a kind of weather resistant/ASA alloy, is made up of the raw material of following mass percentage content:
Further, the halogen-free flame retardant PC of described weather resistant/ASA alloy is by the raw material group of following mass percentage content Become:
Wherein, described PX-200 is phosphorus series non-halogen fire retardant.
Further, described anti-dripping agent is fluorine-containing anti-dripping agent.
Further, the first described antioxidant is Hinered phenols antioxidant, and the second described antioxidant is phosphite ester Kind antioxidant.
The present invention also provides for the preparation method of the halogen-free flame retardant PC/ASA alloy of above-mentioned weather resistant, comprises the following steps:
(1) by raw material with certain proportion in high-speed mixer and mixing；
(2) pelletizing is extruded by extruder after mixing；
(3) it is molded into batten test performance after drying.
Beneficial effect:
The present invention is with PC, ASA for raw material, and methyl methacrylate-acrylate-Organosiliconcopolymere is toughener, The ternary atactic copolymer of styrene-acrylonitrile-glycidyl methacrylate is compatilizer, and PX-200 is fire retardant.PC Poor with the cold tolerance of ASA, need to add toughener, the toughener sold on the market has MBS, ACR type, and the increasing of silicon system Tough dose, first two contains butadiene rubber and acrylate rubber respectively, photooxidation aging property can be made to decline, and silicon system toughener can To meet both requirements simultaneously, change a part of regular grade PC into copolymeric siloxane PC simultaneously, improve cold tolerance further. The ternary atactic copolymer of styrene-acrylonitrile-glycidyl methacrylate, as compatilizer, can increase PC and ASA The compatibility, improve material combination property.
The preparation method of the present invention has raw material and is conveniently easy to get, and preparation method is simple, and the product prepared is than routine The performance of PC/ASA alloy is more prominent.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described.
The halogen-free flame retardant PC of a kind of weather resistant/ASA alloy, is made up of the raw material of following mass percentage content:
By above raw material with certain proportion in high-speed mixer and mixing；Pelletizing is extruded by extruder after mixing；
Batten test performance it is molded into after drying.
The alloy property measurement result of embodiment is as follows:
-30 DEG C of simply supported beam notch impact strengths 30KJ/
UL94 fire resistance 1.6mmV0
Xenon lamp aging measurement result:
Total irradiation energy KJ/m2 aberration color fastness
1500 1.1 4-5
2000 1.8 3-4
The above, be only presently preferred embodiments of the present invention, and the present invention not makees any pro forma restriction, any ripe Know professional and technical personnel, in the range of without departing from technical solution of the present invention, according to the technical spirit of the present invention, to above real Execute any simple amendment, equivalent and improvement etc. that example made, all still fall within technical solution of the present invention protection domain it In.

Claims (6)

1. the halogen-free flame retardant PC of a weather resistant/ASA alloy, it is characterised in that: by the raw material group of following mass percentage content Become:
2. halogen-free flame retardant PC/ASA the alloy of weather resistant as claimed in claim 1, it is characterised in that: by following mass percent The raw material composition of content:
3. halogen-free flame retardant PC/ASA the alloy of weather resistant as claimed in claim 1, it is characterised in that: described PX-200 is phosphorus It it is halogen-free flame retardants.
4. halogen-free flame retardant PC/ASA the alloy of weather resistant as claimed in claim 1, it is characterised in that: described anti-dripping agent is Fluorine-containing anti-dripping agent.
5. halogen-free flame retardant PC/ASA the alloy of weather resistant as claimed in claim 1, it is characterised in that: the first described antioxidant For Hinered phenols antioxidant, the second described antioxidant is phosphite ester kind antioxidant.
6. the preparation method of the halogen-free flame retardant PC of the weather resistant described in claim 1/ASA alloy, it is characterised in that: include following Step:
(1) by raw material with certain proportion in high-speed mixer and mixing；
(2) pelletizing is extruded by extruder after mixing；
(3) it is molded into batten test performance after drying.
CN201610832721.8A 2016-09-19 2016-09-19 The halogen-free flame retardant PC of a kind of weather resistant/ASA alloy and preparation method thereof Pending CN106147193A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610832721.8A CN106147193A (en) 2016-09-19 2016-09-19 The halogen-free flame retardant PC of a kind of weather resistant/ASA alloy and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610832721.8A CN106147193A (en) 2016-09-19 2016-09-19 The halogen-free flame retardant PC of a kind of weather resistant/ASA alloy and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106147193A true CN106147193A (en) 2016-11-23

Family

ID=57340821

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610832721.8A Pending CN106147193A (en) 2016-09-19 2016-09-19 The halogen-free flame retardant PC of a kind of weather resistant/ASA alloy and preparation method thereof

Country Status (1)

Country Link
CN (1) CN106147193A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107759914A (en) * 2017-10-19 2018-03-06 中广核俊尔（上海）新材料有限公司 A kind of automobile-used modified ASA material and preparation method thereof
CN109486147A (en) * 2018-10-14 2019-03-19 金旸（厦门）新材料科技有限公司 A kind of anti-wire drawing fire retardation PC-ASA alloy and preparation method thereof
CN112724635A (en) * 2020-12-29 2021-04-30 金旸（厦门）新材料科技有限公司 Halogen-free flame-retardant low-dielectric weather-resistant PC/AES alloy material and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101056942A (en) * 2004-10-04 2007-10-17 通用电气公司 Flame retardant thermoplastic polycarbonate compositions, use thereof and method of its manufacture
CN104497532A (en) * 2014-12-17 2015-04-08 安徽科聚新材料有限公司 Halogen-free flame-retardant high-gloss high-glass fiber reinforced PC material and preparation method thereof
CN104693772A (en) * 2015-03-04 2015-06-10 安徽科聚新材料有限公司 Glass fiber-mica mixed enhanced polycarbonate material and preparation method thereof
CN104962059A (en) * 2015-06-18 2015-10-07 金发科技股份有限公司 Polycarbonate composition and method for preparing same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101056942A (en) * 2004-10-04 2007-10-17 通用电气公司 Flame retardant thermoplastic polycarbonate compositions, use thereof and method of its manufacture
CN104497532A (en) * 2014-12-17 2015-04-08 安徽科聚新材料有限公司 Halogen-free flame-retardant high-gloss high-glass fiber reinforced PC material and preparation method thereof
CN104693772A (en) * 2015-03-04 2015-06-10 安徽科聚新材料有限公司 Glass fiber-mica mixed enhanced polycarbonate material and preparation method thereof
CN104962059A (en) * 2015-06-18 2015-10-07 金发科技股份有限公司 Polycarbonate composition and method for preparing same

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107759914A (en) * 2017-10-19 2018-03-06 中广核俊尔（上海）新材料有限公司 A kind of automobile-used modified ASA material and preparation method thereof
CN109486147A (en) * 2018-10-14 2019-03-19 金旸（厦门）新材料科技有限公司 A kind of anti-wire drawing fire retardation PC-ASA alloy and preparation method thereof
CN109486147B (en) * 2018-10-14 2020-12-11 金旸（厦门）新材料科技有限公司 Anti-wiredrawing flame-retardant PC-ASA alloy and preparation method thereof
CN112724635A (en) * 2020-12-29 2021-04-30 金旸（厦门）新材料科技有限公司 Halogen-free flame-retardant low-dielectric weather-resistant PC/AES alloy material and preparation method thereof

Similar Documents

Publication Publication Date Title
CN106633762B (en) A kind of low temperature resistant low-smoke and flame retardant photodiffusion polycarbonate composite material
CN104610711B (en) A kind of PBT material with good epoxy bond and preparation method thereof
CN103467954B (en) A kind of polycarbonate compositions and application thereof
CN101486825A (en) Preparation of weather resistant PC and ASA copolymer alloy
CN106147193A (en) The halogen-free flame retardant PC of a kind of weather resistant/ASA alloy and preparation method thereof
CN102516738A (en) Halogen-free flame-retardant and cold-resistant PC/ABS (Poly Carbonate/Acrylonitrile Butadiene Styrene) material and preparation method thereof
CN103724971A (en) Transparent halogen-free low smoke antiflaming polycarbonate composite material and preparation method thereof
CN103289294A (en) Transparent flame-retardant ABS material, and preparation method and application thereof
CN103289293A (en) Transparent flame-retardant antistatic ABS material, and preparation method and application thereof
CN108102359A (en) A kind of environmentally protective, high-performance, high CTI flame-retardant reinforced nylon materials and preparation method thereof
CN105504751A (en) Transparent flame retardant PC (Polycarbonate) material with high hardness and preparation method thereof
CN110643165A (en) High-performance ultraviolet-resistant environment-friendly flame-retardant PC/ABS composite material and preparation method thereof
CN107245235A (en) A kind of transparent flame-retardant polycarbonate material and preparation method thereof
CN105623172B (en) A kind of flame-retardant high-impact modified polystyrene resin and preparation method thereof
CN105462052A (en) 125 DEG C irradiation crosslinking low-smoke halogen-free cable material for automotive wires and preparation method thereof
CN103073855A (en) Polyester composition, preparation method and applications thereof
WO2020011058A1 (en) Polycarbonate composition and preparation method therefor and application thereof
CN104559115B (en) PC/PET halogen-free flame retarding alloy containing regenerative resin, and preparation method of PC/PET halogen-free flame retarding alloy
CN106147190A (en) PC/ASA intermingling material that a kind of low gloss high-strength halogen-free is fire-retardant and preparation method thereof
CN109851976A (en) Modified TPE fire-resistant cable material of a kind of Halogen and preparation method thereof
CN109553874A (en) A kind of low temperature resistant, light aging resisting material flame retardant polystyrene composite, preparation method and applications
CN102604236A (en) High-glow-wire flame-retardant polypropylene material for fan heater casing and preparation method for same
CN105936732A (en) High transparency and high hardness flame retardant ABS composite material and preparation method thereof
CN103772967B (en) Composite plastic of a kind of flame-resistant high-temperature-resistant and preparation method thereof
CN104725823A (en) Low-temperature-resistant flame-retardant PC (polycarbonate) composite material and preparation method thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20161123

RJ01 Rejection of invention patent application after publication