CN106147192A - A kind of transparent flame-retarding glass fiber reinforcement PC material and preparation method thereof - Google Patents
A kind of transparent flame-retarding glass fiber reinforcement PC material and preparation method thereof Download PDFInfo
- Publication number
- CN106147192A CN106147192A CN201610768033.XA CN201610768033A CN106147192A CN 106147192 A CN106147192 A CN 106147192A CN 201610768033 A CN201610768033 A CN 201610768033A CN 106147192 A CN106147192 A CN 106147192A
- Authority
- CN
- China
- Prior art keywords
- temperature
- district
- parts
- glass fiber
- fiber reinforcement
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/524—Esters of phosphorous acids, e.g. of H3PO3
- C08K5/526—Esters of phosphorous acids, e.g. of H3PO3 with hydroxyaryl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/22—Halogen free composition
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of transparent flame-retarding glass fiber reinforcement PC material and preparation method thereof, it is prepared under following group by weight: major ingredient 100 parts, 0.1～0.3 part of antioxidant, lubricant 0.05～0.3 part, described major ingredient is to be prepared from by weight by following components: Merlon 80～90 parts, 6～12 parts of glass fibre, halogen-free flame retardants 4～8 parts.Resin material refractive index and glass fibre prepared by the present invention match, transparent effect can be realized, the light transmittance of its 2.0mm is up to 86%, there is anti-flammability, good processing characteristics and the heat endurance of uniqueness simultaneously, injecting products has high-transmittance, preparation technology is simple and environmentally-friendly simultaneously, can be applicable in the outer appearnce goods of household electrical appliances, in the products such as TV set front frame ornamental strip, air-conditioning panel.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of transparent flame-retarding glass fiber reinforcement PC material and
Its preparation method.
Background technology
Merlon (PC) is a kind of transparent thermoplastic, its light transmittance up to more than 95%, and have concurrently rigidity and
The characteristic of toughness, impact strength is high, have simultaneously excellent dimensional stability and higher heat resistance, good electrical insulating property and
Nontoxicity, can be by injection, extrusion molding.The use temperature range of PC is wide, can make for a long time between-100 DEG C～130 DEG C
With.Fiber glass thermoplastics is the composite of a kind of high-strength light, wherein content of glass fiber be generally 10～
50wt%, has good stretching, bending, modulus of elasticity in comperssion and a creep-resistant property, and good processability and size steady
Qualitative, molding cycle is short simultaneously, production efficiency is high, thus its application is constantly widened, be widely used to electrical equipment, automobile,
The department such as boats and ships, Aero-Space and high-technology field.
With social development, people are more and more diversified, personalized to the appearance requirement of material, as transparent, translucent
Deng, but during PC modified with glass fibre, the transparency of PC can be affected, be essentially all opaque or translucent, already can not
Adapt to the new market demand.
Exploitation to transparent enhancing PC material, in recent years existing part achievement in research, patent CN200610105462.5 was once
Reported in aromatic copolycarbonate (PC), added fatty poly-ester carbonate (PCCD), thus adjusted the refraction of resin compound
Rate matches with glass fibre, it is achieved translucent effect, but PCCD cost is high, and practicality is strong, and transparency also not high, do not have
There is anti-flammability.Resin material prepared by the present invention can have anti-flammability and high light transmittance concurrently simultaneously.
Content of the invention
It is an object of the invention to provide a kind of transparent flame-retarding glass fiber reinforcement PC material and preparation method thereof.
For achieving the above object, the technical solution used in the present invention is:
A kind of transparent flame-retarding glass fiber reinforcement PC material, is prepared under its following group by weight:
Major ingredient 100 parts
0.1～0.3 part of antioxidant
Lubricant 0.05～0.3 part,
Described major ingredient is to be prepared from by weight by following components:
Merlon 80～90 parts,
6～12 parts of glass fibre,
Halogen-free flame retardants 4～8 parts.
Further scheme, described antioxidant be three-(2,4-di-tert-butyl-phenyl) phosphite esters, β-(3,5-di-t-butyls-
4-hydroxy phenyl) propionic acid positive octadecanol ester or four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester.
Further scheme, described halogen-free flame retardants is bisphenol-A double (diphenyl phosphoester) or resorcinol (diphenylphosphine
Acid esters).
Further scheme, described lubricant is pentaerythritol stearate, silicone or N, N '-ethylene bis stearamide.
Another goal of the invention of the present invention is to provide the preparation of above-mentioned a kind of transparent flame-retarding glass fiber reinforcement PC material
Merlon 80～90 parts, halogen-free flame retardants 4～8 parts, antioxidant 0.1～0.3 and lubricant 0.05～0.3 part are mixed by method
Close uniformly, send in double screw extruder, 6～12 parts of glass fibre is fed by side and adds, through melt extruding, granulating, dry
Obtain transparent glass fiber reinforced flame retardant PC material.
Further scheme, the feeding rotational frequency of described double screw extruder is 10Hz, and each section of temperature is set to district's temperature
Spend 170～190 DEG C, two district's temperature 210～230 DEG C, three district's temperature 230～250 DEG C, four district's temperature 230～250 DEG C, five district's temperature
Spend 230～250 DEG C, six district's temperature 220～240 DEG C, seven district's temperature 220～240 DEG C, eight district's temperature 210～230 DEG C, nine district's temperature
Spending 210～230 DEG C, head temperature 230 DEG C, engine speed is 300～500r/min, and negative pressure of vacuum controls at 0.06-1.0MPa.
The present invention uses Merlon, glass fibre, halogen-free flame retardants, antioxidant and lubricant to be blended and is prepared for one thoroughly
Bright combustion-proof glass fiber strengthens PC material, and this alloy material has the anti-flammability of uniqueness, good processing characteristics and heat endurance.
And the amount of the halogen-free flame retardants adding is less, but reach good fire resistance；In addition, the halogen-free flameproof used by the present invention
Agent is all water white transparency, and its refractive index is close with PC raw material, in process by control vacuum be 0.06-1.0MPa come
Removal small molecular weight impurity is to ensure transparent effect, and prepared material has high-transmittance, can meet the market demand.
The refractive index of PC material prepared by the present invention matches with glass fibre, can realize transparent effect, and its 2.0mm's is saturating
Light rate, up to 86%, has anti-flammability, good processing characteristics and the heat endurance of uniqueness simultaneously, and injecting products has high printing opacity
Degree, preparation technology is simple and environmentally-friendly simultaneously, can be applicable in the outer appearnce goods of household electrical appliances, such as TV set front frame ornamental strip, conditioned surface
In the products such as plate.
Detailed description of the invention
It in order to be more fully understood that the present invention, is further elucidated with present disclosure below in conjunction with embodiment, but the present invention
Content is not limited solely to the following examples.
Embodiment 1
By Merlon 90 parts, halogen-free flame retardants bisphenol-A double (diphenyl phosphoester) 4 parts, antioxidant three-(2,4-bis-uncles
Butyl phenyl) phosphite ester 0.3 and lubricant pentaerythritol stearate 0.3 part mix, and sends in double screw extruder,
6 parts of glass fibre is fed by side and adds, through melt extruding, granulating, dry and obtain transparent glass fiber reinforced flame retardant PC material
Material.
Wherein the feeding rotational frequency of double screw extruder is 10Hz, and each section of temperature is set to district's temperature 170～190
DEG C, two district's temperature 210～230 DEG C, three district's temperature 230～250 DEG C, four district's temperature 230～250 DEG C, five district's temperature 230～250
DEG C, six district's temperature 220～240 DEG C, seven district's temperature 220～240 DEG C, eight district's temperature 210～230 DEG C, nine district's temperature 210～230
DEG C, head temperature 230 DEG C, engine speed is 300～500r/min, and negative pressure of vacuum controls at 0.06-1.0MPa.
Embodiment 2
By Merlon 88 parts, halogen-free flame retardants bisphenol-A double (diphenyl phosphoester) 5 parts, antioxidant three-(2,4-bis-uncles
Butyl phenyl) phosphite ester 0.3 and lubricant pentaerythritol stearate 0.3 part mix, and sends in double screw extruder,
7 parts of glass fibre is fed by side and adds, through melt extruding, granulating, dry and obtain transparent glass fiber reinforced flame retardant PC material
Material.
Wherein the feeding rotational frequency of double screw extruder is 10Hz, and each section of temperature is set to district's temperature 170～190
DEG C, two district's temperature 210～230 DEG C, three district's temperature 230～250 DEG C, four district's temperature 230～250 DEG C, five district's temperature 230～250
DEG C, six district's temperature 220～240 DEG C, seven district's temperature 220～240 DEG C, eight district's temperature 210～230 DEG C, nine district's temperature 210～230
DEG C, head temperature 230 DEG C, engine speed is 300～500r/min, and negative pressure of vacuum controls at 0.06-1.0MPa.
Embodiment 3
By Merlon 86 parts, halogen-free flame retardants resorcinol (diphenyl phosphoester) 6 parts, antioxidant β-(3,5-bis-uncle
Butyl-4-hydroxy phenyl) propionic acid positive octadecanol ester 0.2 and lubricant silicone or 0.2 part mixes, and sends into twin-screw extrusion
In machine, 8 parts of glass fibre is fed by side and adds, through melt extruding, granulating, dry and obtain transparent glass fiber reinforced flame retardant
PC material.
Wherein the feeding rotational frequency of double screw extruder is 10Hz, and each section of temperature is set to district's temperature 170～190
DEG C, two district's temperature 210～230 DEG C, three district's temperature 230～250 DEG C, four district's temperature 230～250 DEG C, five district's temperature 230～250
DEG C, six district's temperature 220～240 DEG C, seven district's temperature 220～240 DEG C, eight district's temperature 210～230 DEG C, nine district's temperature 210～230
DEG C, head temperature 230 DEG C, engine speed is 300～500r/min, and negative pressure of vacuum controls at 0.06-1.0MPa.
Embodiment 4
By Merlon 83 parts, halogen-free flame retardants bisphenol-A double (diphenyl phosphoester) 7 parts, antioxidant β-(tertiary fourth of 3,5-bis-
Base-4-hydroxy phenyl) propionic acid positive octadecanol ester 0.2 and lubricant silicone or 0.1 part mixes, and sends into double screw extruder
In, 10 parts of glass fibre is fed by side and adds, through melt extruding, granulating, dry and obtain transparent glass fiber reinforced flame retardant
PC material.
Wherein the feeding rotational frequency of double screw extruder is 10Hz, and each section of temperature is set to district's temperature 170～190
DEG C, two district's temperature 210～230 DEG C, three district's temperature 230～250 DEG C, four district's temperature 230～250 DEG C, five district's temperature 230～250
DEG C, six district's temperature 220～240 DEG C, seven district's temperature 220～240 DEG C, eight district's temperature 210～230 DEG C, nine district's temperature 210～230
DEG C, head temperature 230 DEG C, engine speed is 300～500r/min, and negative pressure of vacuum controls at 0.06-1.0MPa.
Embodiment 5
By Merlon 81 parts, halogen-free flame retardants resorcinol (diphenyl phosphoester) 8 parts, antioxidant four [β-(3,5-bis-
Tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester 0.1 and lubricant N, N '-ethylene bis stearamide 0.15 part mixing is all
Even, send in double screw extruder, 11 parts of glass fibre is fed by side and adds, through melt extruding, granulating, drying obtains transparent
Glass fiber reinforced flame retardant PC material.
Wherein the feeding rotational frequency of double screw extruder is 10Hz, and each section of temperature is set to district's temperature 170～190
DEG C, two district's temperature 210～230 DEG C, three district's temperature 230～250 DEG C, four district's temperature 230～250 DEG C, five district's temperature 230～250
DEG C, six district's temperature 220～240 DEG C, seven district's temperature 220～240 DEG C, eight district's temperature 210～230 DEG C, nine district's temperature 210～230
DEG C, head temperature 230 DEG C, engine speed is 300～500r/min, and negative pressure of vacuum controls at 0.06-1.0MPa.
Embodiment 6
By Merlon 80 parts, halogen-free flame retardants resorcinol (diphenyl phosphoester) 8 parts, antioxidant four [β-(3,5-bis-
Tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester 0.1 and lubricant N, N '-ethylene bis stearamide 0.05 part mixing is all
Even, send in double screw extruder, 12 parts of glass fibre is fed by side and adds, through melt extruding, granulating, drying obtains transparent
Glass fiber reinforced flame retardant PC material.
Wherein the feeding rotational frequency of double screw extruder is 10Hz, and each section of temperature is set to district's temperature 170～190
DEG C, two district's temperature 210～230 DEG C, three district's temperature 230～250 DEG C, four district's temperature 230～250 DEG C, five district's temperature 230～250
DEG C, six district's temperature 220～240 DEG C, seven district's temperature 220～240 DEG C, eight district's temperature 210～230 DEG C, nine district's temperature 210～230
DEG C, head temperature 230 DEG C, engine speed is 300～500r/min, and negative pressure of vacuum controls at 0.06-1.0MPa.
According to professional standard, the transparent flame-retarding glass fiber reinforcement PC material preparing embodiment 1～6 respectively is carried out substantially
Performance test, takes its mean value.Test result is as shown in table 1:
The key property test result of table 1 alloy material
As seen from Table 1, the excellent in mechanical performance of the transparent flame-retarding glass fiber reinforcement PC material that the present invention prepares, has height
Light transmittance, and fire resistance all reaches V0 level.
Above the present invention is described in detail, its object is to allow those of ordinary skill in the art will appreciate that this
Invention content and be carried out, can not limit the scope of the invention with this, all Spirit Essence institutes according to the present invention
The equivalence change made or modification, all should cover within the scope of the present invention.
Claims (6)
1. a transparent flame-retarding glass fiber reinforcement PC material, it is characterised in that: it is prepared from by weight under its following group:
Major ingredient 100 parts
0.1～0.3 part of antioxidant
Lubricant 0.05～0.3 part,
Described major ingredient is to be prepared from by weight by following components:
Merlon 80～90 parts,
6～12 parts of glass fibre,
Halogen-free flame retardants 4～8 parts.
2. a kind of transparent flame-retarding glass fiber reinforcement PC material according to claim 1, it is characterised in that: described antioxidant
Be three-(2,4-di-tert-butyl-phenyl) phosphite esters, β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid positive octadecanol ester or
Four [β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester.
3. a kind of transparent flame-retarding glass fiber reinforcement PC material according to claim 1, it is characterised in that: described Halogen
Fire retardant is bisphenol-A double (diphenyl phosphoester) or resorcinol (diphenyl phosphoester).
4. a kind of transparent flame-retarding glass fiber reinforcement PC material according to claim 1, it is characterised in that: described lubrication
Agent is pentaerythritol stearate, silicone or N, N '-ethylene bis stearamide.
5. the preparation method of a kind of transparent flame-retarding glass fiber reinforcement PC material as described in any one of claim 1-4, it is special
Levy and be: by Merlon 80～90 parts, halogen-free flame retardants 4～8 parts, antioxidant 0.1～0.3 and lubricant 0.05～0.3 part
Mix, send in double screw extruder, 6～12 parts of glass fibre is fed by side and adds, through melt extruding, granulating, dry
Dry obtain transparent glass fiber reinforced flame retardant PC material.
6. preparation method according to claim 5, it is characterised in that: the feeding rotational frequency of described double screw extruder is
10Hz, each section of temperature be set to district's temperature 170～190 DEG C, two district's temperature 210～230 DEG C, three district's temperature 230～250 DEG C,
Four district's temperature 230～250 DEG C, five district's temperature 230～250 DEG C, six district's temperature 220～240 DEG C, seven district's temperature 220～240 DEG C,
Eight district's temperature 210～230 DEG C, nine district's temperature 210～230 DEG C, head temperature 230 DEG C, engine speed is 300～500 r/min,
Negative pressure of vacuum controls at 0.06-1.0MPa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610768033.XA CN106147192A (en) | 2016-08-29 | 2016-08-29 | A kind of transparent flame-retarding glass fiber reinforcement PC material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610768033.XA CN106147192A (en) | 2016-08-29 | 2016-08-29 | A kind of transparent flame-retarding glass fiber reinforcement PC material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106147192A true CN106147192A (en) | 2016-11-23 |
Family
ID=57345083
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610768033.XA Pending CN106147192A (en) | 2016-08-29 | 2016-08-29 | A kind of transparent flame-retarding glass fiber reinforcement PC material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106147192A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110218429A (en) * | 2019-05-21 | 2019-09-10 | 品诚塑胶科技（上海）有限公司 | A kind of transparent glass fibre enhancing PC plate material and preparation method thereof |
| CN111853652A (en) * | 2020-06-30 | 2020-10-30 | 圣晖系统集成集团股份有限公司 | Emergency lamp and manufacturing method thereof |
| CN112876830A (en) * | 2021-01-20 | 2021-06-01 | 金旸（厦门）新材料科技有限公司 | Transparent glass fiber reinforced flame-retardant PC material and preparation method thereof |
| CN113134986A (en) * | 2020-01-20 | 2021-07-20 | 华硕电脑股份有限公司 | Light-transmitting plastic shell and manufacturing method thereof |
| CN114231003A (en) * | 2021-12-09 | 2022-03-25 | 金发科技股份有限公司 | Transparent flame-retardant polycarbonate composite material and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101089046A (en) * | 2007-06-08 | 2007-12-19 | 深圳市科聚新材料有限公司 | Transparent polycarbonate alloy composite material and its prepn process |
| CN104672883A (en) * | 2015-03-05 | 2015-06-03 | 安徽科聚新材料有限公司 | Polycarbonate composite as well as preparation method and application thereof |
-
2016
- 2016-08-29 CN CN201610768033.XA patent/CN106147192A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101089046A (en) * | 2007-06-08 | 2007-12-19 | 深圳市科聚新材料有限公司 | Transparent polycarbonate alloy composite material and its prepn process |
| CN104672883A (en) * | 2015-03-05 | 2015-06-03 | 安徽科聚新材料有限公司 | Polycarbonate composite as well as preparation method and application thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110218429A (en) * | 2019-05-21 | 2019-09-10 | 品诚塑胶科技（上海）有限公司 | A kind of transparent glass fibre enhancing PC plate material and preparation method thereof |
| CN113134986A (en) * | 2020-01-20 | 2021-07-20 | 华硕电脑股份有限公司 | Light-transmitting plastic shell and manufacturing method thereof |
| CN111853652A (en) * | 2020-06-30 | 2020-10-30 | 圣晖系统集成集团股份有限公司 | Emergency lamp and manufacturing method thereof |
| CN112876830A (en) * | 2021-01-20 | 2021-06-01 | 金旸（厦门）新材料科技有限公司 | Transparent glass fiber reinforced flame-retardant PC material and preparation method thereof |
| CN114231003A (en) * | 2021-12-09 | 2022-03-25 | 金发科技股份有限公司 | Transparent flame-retardant polycarbonate composite material and preparation method and application thereof |
| CN114231003B (en) * | 2021-12-09 | 2024-05-07 | 金发科技股份有限公司 | Transparent flame-retardant polycarbonate composite material and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106147192A (en) | A kind of transparent flame-retarding glass fiber reinforcement PC material and preparation method thereof | |
| CN101798460B (en) | Composite flame retardant glass fibre reinforced nylon 66 insulating strip and preparation method thereof | |
| CN104497536B (en) | A kind of flame retardant polycarbonate composition and preparation method thereof | |
| CN101580632B (en) | High-gloss high-performance fiber glass reinforced PBT material and preparation method thereof | |
| CN103289294B (en) | transparent flame-retardant ABS material, preparation method and application thereof | |
| CN103289293B (en) | Transparent flame-retardant antistatic ABS material, preparation method and application thereof | |
| CN102532849B (en) | PC/ASA/PBT (poly carbonate/ acrylonitrile-styrene-acrylate/polybutylene terephthalate) alloy material and preparation method thereof | |
| CN102690515A (en) | Flame-retardant composite material with easy dyeing and laser marking and preparation method thereof | |
| CN110105738B (en) | Flame-retardant PC/ABS material and preparation method and application thereof | |
| CN105440596A (en) | Highly weather-proof PBT (polybutylene terephthalate)/ASA (acrylonitrile styrene acrylate) wire for 3D printing and preparation method of PBT/ASA wire | |
| CN106147156A (en) | Halogen-free flame-retardant long fiber glass reinforced PBT composite and preparation method thereof | |
| CN102993669A (en) | High-performance and low-warpage IMD (In-Mold Decoration) injection molding material and preparation method thereof | |
| CN104672883A (en) | Polycarbonate composite as well as preparation method and application thereof | |
| CN102719071B (en) | Buckling deformation-resistant glass fiber reinforced polycarbonate resin and preparation method thereof | |
| CN114426763A (en) | Flame-retardant reinforced PBT (polybutylene terephthalate) material with high CTI (comparative tracking index) and high GWIT (glow wire ignition temperature) and preparation method thereof | |
| CN108976752B (en) | Method for improving flame retardance of polycarbonate thin-wall part | |
| CN102702672B (en) | High-light-transmission high-light-shading ABS (acrylonitrile butadiene styrene) material and preparation method thereof | |
| CN103289341A (en) | Reinforced polycarbonate composite material | |
| CN102352088A (en) | Thermoplastic halogen-free flame-retardant alloy and preparation method thereof | |
| CN104910601A (en) | High-gloss high-heat-resistance high-fluidity halogen-free flame-retardant glass-fiber-reinforced PC material and preparation method thereof | |
| CN104419190A (en) | Transparent enhanced halogen-free flame-retardant PC material and preparation method thereof | |
| CN106751537A (en) | A kind of fiber reinforcement flame retardant plastics and preparation method thereof | |
| CN102863749B (en) | Low-warpage glass fiber reinforced polyester composite and preparation method thereof | |
| CN107686613A (en) | A kind of polyvinyl chloride composite materials and its preparation technology | |
| CN104387711A (en) | Ceramic fiber reinforced flame-retardant PBT/AS alloy and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20161123 |
|
| WD01 | Invention patent application deemed withdrawn after publication |