CN106145857A - A kind of composition type permeation-proof corrosion-proof building material - Google Patents
A kind of composition type permeation-proof corrosion-proof building material Download PDFInfo
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- CN106145857A CN106145857A CN201610519178.6A CN201610519178A CN106145857A CN 106145857 A CN106145857 A CN 106145857A CN 201610519178 A CN201610519178 A CN 201610519178A CN 106145857 A CN106145857 A CN 106145857A
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- building material
- modifying agent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a kind of composition type permeation-proof corrosion-proof building material, following components raw material is comprised: bentonite 100～200 parts according to ratio of weight and number, perlite 10～15 parts, paraffin 5～15 parts, Gypsum Fibrosum 1～2 parts, sodium sulfate 1～3 parts, Fructus Citri Sarcodactylis (Bergamot) 0.2～1.2 part, modifying agent 3～5 parts.Composition type permeation-proof corrosion-proof building material quality of the present invention is good, antiseepage, water-fast, and anticorrosion effect is splendid, further, rule of origin used by the present invention extensively, be easy to get, low cost, preparation technology is simple and direct, easily operate.
Description
Technical field
The present invention relates to a kind of construction material, particularly to a kind of composition type permeation-proof corrosion-proof building material.
Background technology
At present, construction material of a great variety, function varies, and is therefore used for building or the structure of different characteristic
Build and thing plays its application.But, a lot of Architectural Equipments, due to the specific use of himself, has special wanting to construction material
Ask.The such as industry such as chemical industry, metallurgy, electric power is both needed to as facilities such as Factory Building, workshop terrace, metope and various storage tank, platforms
Want antiseepage corrosion-proof building material.For the research of this type of construction material, year once used macromolecular material to be covered in cement flooring
On, delay corrosion and seepage, but fundamentally cannot solve the etching problem such as acid, alkali.
Bentonite is as the wider clay mineral materials of current range of application, the dilatancy good due to it and hyposmosis
Property, has the functions such as environment remediation, the depollution of environment and environment replacement, stable chemical nature is good, abundant raw material source, price just
Preferably, it is to be suitable for impervious material the most.But, himself absorption property of bentonite and mechanical property are the best, meanwhile, do not have resistance to
Acid, caustic corrosion, therefore, need badly a kind of with bentonite as base material, has acid-alkali-corrosive-resisting, the building of performance that antiseepage is water-fast simultaneously
Build material.
The information being disclosed in this background section is merely intended to increase the understanding of the general background to the present invention, and should not
When being considered to recognize or imply in any form this information structure prior art well known to persons skilled in the art.
Summary of the invention
The present invention is directed to above-mentioned technical problem, a kind of composition type permeation-proof corrosion-proof building material of invention, it is desirable to provide Yi Zhongzhi
Measure good, there is the construction material of antiseepage, corrosion resistant performance, low cost simultaneously.
For achieving the above object, the technical scheme that the present invention provides is as follows:
A kind of composition type permeation-proof corrosion-proof building material, comprises following components raw material according to ratio of weight and number: bentonite 100～
200 parts, perlite 10～15 parts, paraffin 5～15 parts, Gypsum Fibrosum 1～2 parts, sodium sulfate 1～3 parts, Fructus Citri Sarcodactylis (Bergamot) 0.2
～1.2 parts and modifying agent 3～5 parts.
Wherein, described modifying agent is by sulphuric acid, phenolic resin, thioacetamide, surfactant and stabilizer composition.
Wherein, described modifying agent according to ratio of weight and number by sulphuric acid 100～200 parts, phenolic resin 10～20 parts, sulfur generation
Acetamide 0.1～0.5 part, surfactant 1～3 parts and stabilizer 1～2 parts of compositions.
Wherein, described surfactant is the one in magnesium stearate, dodecylbenzene sodium sulfonate or peregal.
Wherein, described stabilizer is PAMC (CPAM) or benzalkonium chloride.
The preparation method of a kind of composition type permeation-proof corrosion-proof building material described above, comprises following operating procedure:
(1) required each component raw material is weighed according to ratio of weight and number: bentonite 100～200 parts, perlite 10～15
Part, paraffin 5～15 parts, Gypsum Fibrosum 1～2 parts, sodium sulfate 1～3 parts, Fructus Citri Sarcodactylis (Bergamot) 0.2～1.2 part, modifying agent 3～5
Part, then by bentonite 450～650 DEG C of roastings 3～5 hours, it is cooled to room temperature；
(2) perlite, paraffin, Gypsum Fibrosum are clayed into power respectively, and standby after 200～220 mesh sieves excessively；
(3) by gained bentonite after cooling in step (1) and the perlite powder of gained, paraffin powder, stone in step (2)
Cream powder mixing and stirring, then mixes with Fructus Citri Sarcodactylis, modifying agent, keeps temperature to be 30～40 DEG C and impregnates 8～12 hours, dries
Dry, to obtain final product.
Wherein, drying temperature in step (3) is 80～90 DEG C, dries 0.5～2.5 hour.
Wherein, before modifying agent uses in step (3), add ethanol, form the modifying agent second that mass concentration is 60～70%
Alcoholic solution.
Compared with prior art, there is advantages that
Composition type permeation-proof corrosion-proof building material quality of the present invention is good, antiseepage, water-fast, and anticorrosion effect is splendid, further,
Rule of origin used by the present invention extensively, be easy to get, low cost, preparation technology is simple and direct, easily operate.
Detailed description of the invention
It is described in detail below in conjunction with detailed description of the invention, it is to be understood that protection scope of the present invention is not by concrete
The restriction of embodiment.
Embodiment 1
A kind of preparation method of composition type permeation-proof corrosion-proof building material, operating procedure is as follows:
(1) required each component raw material is weighed according to ratio of weight and number: bentonite 100 parts, perlite 10 parts, 5 parts of paraffin,
1 part of Gypsum Fibrosum, 1 part of sodium sulfate, Fructus Citri Sarcodactylis 0.2 part and modifying agent 3 parts, then by 450 DEG C of roastings of bentonite 5 hours, be cooled to room
Temperature；Wherein, modifying agent according to ratio of weight and number by 100 parts of sulphuric acid, 10 parts of phenolic resin, thioacetamide 0.1 part, surface activity
Agent 1 part and stabilizer 1 part composition；Surfactant is magnesium stearate；Stabilizer is PAMC (CPAM)；
(2) perlite, paraffin, Gypsum Fibrosum are clayed into power respectively, and standby after 200 mesh sieves excessively；
(3) by gained bentonite after cooling in step (1) and the perlite powder of gained, paraffin powder, stone in step (2)
Cream powder mixing and stirring, then mixes with Fructus Citri Sarcodactylis, modifying agent, keeps temperature to be 30 DEG C and impregnates 12 hours, 80 DEG C of drying
2.5 hours, to obtain final product；Before modifying agent uses, adding volumetric concentration is the ethanol of 50%, forms the modifying agent that mass concentration is 65%
Ethanol solution.
Embodiment 2
A kind of preparation method of composition type permeation-proof corrosion-proof building material, operating procedure is as follows:
(1) required each component raw material is weighed according to ratio of weight and number: bentonite 200 parts, perlite 15 parts, paraffin 15
Part, 2 parts of Gypsum Fibrosum, 3 parts of sodium sulfate, Fructus Citri Sarcodactylis 1.2 parts and modifying agent 5 parts, then by 650 DEG C of roastings of bentonite 3 hours, it is cooled to
Room temperature；Wherein, modifying agent is lived by 200 parts of sulphuric acid, 20 parts of phenolic resin, thioacetamide 0.5 part, surface according to ratio of weight and number
Property agent 3 parts and stabilizer 2 parts composition；Surfactant is dodecylbenzene sodium sulfonate；Stabilizer is benzalkonium chloride；
(2) perlite, paraffin, Gypsum Fibrosum are clayed into power respectively, and standby after 220 mesh sieves excessively；
(3) by gained bentonite after cooling in step (1) and the perlite powder of gained, paraffin powder, stone in step (2)
Cream powder mixing and stirring, then mixes with Fructus Citri Sarcodactylis, modifying agent, keeps temperature to be 40 DEG C and impregnates 8 hours, 90 DEG C of drying
0.5 hour, to obtain final product；Before modifying agent uses, adding volumetric concentration is the ethanol of 60%, forms the modifying agent that mass concentration is 70%
Ethanol solution.
Embodiment 3
A kind of preparation method of composition type permeation-proof corrosion-proof building material, operating procedure is as follows:
(1) required each component raw material is weighed according to ratio of weight and number: bentonite 150 parts, perlite 12 parts, paraffin 10
Part, 2 parts of Gypsum Fibrosum, 2 parts of sodium sulfate, Fructus Citri Sarcodactylis (Bergamot) 0.7 part and modifying agent 4 parts, then by 550 DEG C of roastings 4 of bentonite
Hour, it is cooled to room temperature；Wherein, modifying agent according to ratio of weight and number by 150 parts of sulphuric acid, 15 parts of phenolic resin, thioacetamide
0.3 part, 2 parts of surfactant and stabilizer 1 part composition；Surfactant is peregal；Stabilizer is benzalkonium chloride；
(2) perlite, paraffin, Gypsum Fibrosum are clayed into power respectively, and standby after 210 mesh sieves excessively；
(3) by gained bentonite after cooling in step (1) and the perlite powder of gained, paraffin powder, stone in step (2)
Cream powder mixing and stirring, then mixes with Fructus Citri Sarcodactylis, modifying agent, keeps temperature to be 35 DEG C and impregnates 10 hours, 85 DEG C of drying
1.5 hours, to obtain final product；Before modifying agent uses, adding volumetric concentration is the ethanol of 55%, forms the modifying agent that mass concentration is 60%
Ethanol solution.
Embodiment 4
A kind of preparation method of composition type permeation-proof corrosion-proof building material, operating procedure is as follows:
(1) required each component raw material is weighed according to ratio of weight and number: bentonite 150 parts, perlite 12 parts, paraffin 10
Part, 2 parts of Gypsum Fibrosum, 2 parts of sodium sulfate, Fructus Citri Sarcodactylis (Bergamot) 0.7 part, modifying agent 4 parts and ammonium chloride 0.01 part, then by swelling
550 DEG C of roastings of soil 4 hours, are cooled to room temperature；Wherein, modifying agent according to ratio of weight and number by 150 parts of sulphuric acid, phenolic resin 15
Part, thioacetamide 0.3 part, 2 parts of surfactant and stabilizer 1 part composition；Surfactant is peregal；Stabilizer is chlorine
Change zephiran；
(2) perlite, paraffin, Gypsum Fibrosum are clayed into power respectively, and standby after 210 mesh sieves excessively；
(3) by gained bentonite after cooling in step (1) and the perlite powder of gained, paraffin powder, stone in step (2)
Cream powder mixing and stirring, then mixes with Fructus Citri Sarcodactylis, modifying agent, ammonium chloride, keeps temperature to be 35 DEG C of dippings 10 hours, and 85
DEG C dry 1.5 hours, to obtain final product；Before modifying agent uses, adding volumetric concentration is the ethanol of 55%, and forming mass concentration is 60%
Modifying agent ethanol solution.
Comparative example 1
According to ratio of weight and number bentonite 200 parts, 20 parts of sulphuric acid, by bentonite 450～550 DEG C of roastings 5～6 hours, so
Impregnate with sulphuric acid afterwards, dry 12～24 hours, to obtain final product for 30～45 DEG C.
Embodiment 3, embodiment 4, comparative example 1 gained construction material are mixed with water respectively, puts in little section mould plate
Make module, maintenance 28 days, test as follows:
Test example 1 acid rain resistance is tested
1, test material and method
1.1 material
Test material embodiment 3, embodiment 4,28 days gained modules of comparative example 1 maintenance；
Preparation mass concentration be 1% sulfuric acid solution (pH value is 0.675), mass concentration be 2.5% sulfuric acid solution (pH
Value is 0.610), mass concentration be 2% sulfuric acid solution and the salpeter solution mixed liquor (pH value is 0.452) of 0.5%, quality dense
Degree is the sulfurous acid solution (pH value is 0.615) of 3%, for Simulated Acid Rain.
1.2 method
Take each module, with paraffin and rosin blend (mass ratio 1:1), sheet material edge and the back side are closed.Then will
In the acid solution of 1/2 immersion room temperature of sheet material area, observe, till foaming, efflorescence, peeling occurs in surface.
2. test results and analysis
Table 1 acid resisting test
As can be seen from the above table, to prepare the performance of gained its acid rain resistant of construction material more preferable for the present invention.
Test example 2 alkaline resistance test
1. materials and methods
Test material embodiment 3, embodiment 4,28 days gained modules of comparative example 1 maintenance；
At ambient temperature, 0.12g calcium hydroxide and 100mL distilled water preparation alkaline solution, prepared pH value of solution are used
Value is 13.
Take each template, with paraffin and rosin blend (mass ratio 1:1), sheet material edge and the back side are closed.Then
By in the alkaline solution of 1/2 immersion room temperature of sheet material area, observe, till foaming, efflorescence, peeling occurs in surface.
2. result of the test and analysis
Table 2 alkaline resistance test
As can be seen from the above table, the performance of gained its alkali resistance of construction material of the present invention is more preferable.
Test example 3 Water Resistance Test
1. test material and method
Test material embodiment 3, embodiment 4,28 days gained modules of comparative example 1 maintenance；
Take each template, with paraffin and rosin blend (mass ratio 1:1), sheet material edge and the back side are closed.Then
By in the tap water of 1/2 immersion room temperature of sheet material area, observe, till foaming, efflorescence, peeling occurs in surface
2. test results and analysis
As can be seen from the above table, to prepare its resistance to water of gained construction material more preferable for the present invention.
From data in table 1, table 2, table 3, embodiment 4 acquired results display properties is optimal, is because embodiment 4
Himself structure of the ammonium chloride of middle interpolation interacts with this life invention component raw material, promotes the solidification of construction material, and increases
Its intensity big, moreover it is possible to effectively strengthen its resistance to water, acid and alkali-resistance, corrosion resistance；Product construction material of the present invention uses safer, ring
Protect, quality good.
The aforementioned description to the specific illustrative embodiment of the present invention illustrates that and the purpose of illustration.These describe
It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to above-mentioned teaching, can much change
And change.The purpose selected exemplary embodiment and describe is to explain that the certain principles of the present invention and reality thereof should
With so that those skilled in the art be capable of and utilize the present invention various different exemplary and
Various different selections and change.The scope of the present invention is intended to be limited by claims and equivalents thereof.
Claims (8)
1. a composition type permeation-proof corrosion-proof building material, it is characterised in that comprise following components raw material according to ratio of weight and number: swollen
Profit soil 100～200 parts, perlite 10～15 parts, paraffin 5～15 parts, Gypsum Fibrosum 1～2 parts, sodium sulfate 1～3 parts, Fructus Citri Sarcodactylis 0.2～
1.2 parts and modifying agent 3～5 parts.
Composition type permeation-proof corrosion-proof building material the most according to claim 1, it is characterised in that: described modifying agent by sulphuric acid,
Phenolic resin, thioacetamide, surfactant and stabilizer composition.
Composition type permeation-proof corrosion-proof building material the most according to claim 1, it is characterised in that described modifying agent is according to weight
Portion rate is by sulphuric acid 100～200 parts, phenolic resin 10～20 parts, thioacetamide 0.1～0.5 part, surfactant 1～3 parts
With stabilizer 1～2 parts of compositions.
Composition type permeation-proof corrosion-proof building material the most according to claim 1, it is characterised in that: described surfactant is hard
One in fatty acid magnesium, dodecylbenzene sodium sulfonate or peregal.
Composition type permeation-proof corrosion-proof building material the most according to claim 1, it is characterised in that: described stabilizer is cation
Polyacrylamide or benzalkonium chloride.
6. the preparation method of a composition type permeation-proof corrosion-proof building material as claimed in claim 1, it is characterised in that comprise with
Lower operating procedure:
(1) required each component raw material is weighed according to ratio of weight and number: bentonite 100～200 parts, perlite 10～15 parts, stone
Wax 5～15 parts, Gypsum Fibrosum 1～2 parts, sodium sulfate 1～3 parts, Fructus Citri Sarcodactylis 0.2～1.2 parts and modifying agent 3～5 parts, then by bentonite
450～650 DEG C of roastings 3～5 hours, be cooled to room temperature；
(2) perlite, paraffin, Gypsum Fibrosum are clayed into power respectively, and standby after 200～220 mesh sieves excessively；
(3) by gained bentonite after cooling in step (1) and the perlite powder of gained, paraffin powder, Gypsum Fibrosum powder in step (2)
End mixing and stirring, then mixes with Fructus Citri Sarcodactylis, modifying agent, keeps temperature to be 30～40 DEG C and impregnates 8～12 hours, dries,
Obtain.
The preparation method of composition type permeation-proof corrosion-proof building material the most according to claim 1, it is characterised in that: step (3)
Middle drying temperature is 80～90 DEG C, dries 0.5～2.5 hour.
The preparation method of composition type permeation-proof corrosion-proof building material the most according to claim 1, it is characterised in that: step (3)
Before middle modifying agent uses, add ethanol, form the modifying agent ethanol solution that mass concentration is 60～70%.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610519178.6A CN106145857A (en) | 2016-07-01 | 2016-07-01 | A kind of composition type permeation-proof corrosion-proof building material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610519178.6A CN106145857A (en) | 2016-07-01 | 2016-07-01 | A kind of composition type permeation-proof corrosion-proof building material |
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| CN106145857A true CN106145857A (en) | 2016-11-23 |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102531506A (en) * | 2011-07-05 | 2012-07-04 | 江苏尼高科技有限公司 | Gypsum-based paraffin phase-change energy-storage wallboard and preparation method thereof |
| KR101275732B1 (en) * | 2011-07-19 | 2013-06-17 | 정덕훈 | Panel Composition, Preparing Method of Panel and Panel Prepared Thereby |
| CN104119051A (en) * | 2014-07-15 | 2014-10-29 | 冯广义 | Anti-cracking concrete and preparation method thereof |
| WO2015163502A1 (en) * | 2014-04-25 | 2015-10-29 | 주식회사 경동원 | Inorganic expandable refractory composition |
| CN105130370A (en) * | 2015-08-24 | 2015-12-09 | 广州市建筑科学研究院有限公司 | Light phase change energy-saving insulating wall material and preparation method therefor |
-
2016
- 2016-07-01 CN CN201610519178.6A patent/CN106145857A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102531506A (en) * | 2011-07-05 | 2012-07-04 | 江苏尼高科技有限公司 | Gypsum-based paraffin phase-change energy-storage wallboard and preparation method thereof |
| KR101275732B1 (en) * | 2011-07-19 | 2013-06-17 | 정덕훈 | Panel Composition, Preparing Method of Panel and Panel Prepared Thereby |
| WO2015163502A1 (en) * | 2014-04-25 | 2015-10-29 | 주식회사 경동원 | Inorganic expandable refractory composition |
| CN104119051A (en) * | 2014-07-15 | 2014-10-29 | 冯广义 | Anti-cracking concrete and preparation method thereof |
| CN105130370A (en) * | 2015-08-24 | 2015-12-09 | 广州市建筑科学研究院有限公司 | Light phase change energy-saving insulating wall material and preparation method therefor |
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Application publication date: 20161123 |