CN106140510A - A kind of electrostatic spraying apparatus and prepare the device of nesa coating - Google Patents

A kind of electrostatic spraying apparatus and prepare the device of nesa coating Download PDF

Info

Publication number
CN106140510A
CN106140510A CN201610817904.2A CN201610817904A CN106140510A CN 106140510 A CN106140510 A CN 106140510A CN 201610817904 A CN201610817904 A CN 201610817904A CN 106140510 A CN106140510 A CN 106140510A
Authority
CN
China
Prior art keywords
electrostatic spraying
nozzle
spraying apparatus
nesa coating
base material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610817904.2A
Other languages
Chinese (zh)
Other versions
CN106140510B (en
Inventor
杨诚
李子衡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Sunroll Technology Co ltd
Shenzhen International Graduate School of Tsinghua University
Original Assignee
Shenzhen Graduate School Tsinghua University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Graduate School Tsinghua University filed Critical Shenzhen Graduate School Tsinghua University
Priority to CN201610817904.2A priority Critical patent/CN106140510B/en
Publication of CN106140510A publication Critical patent/CN106140510A/en
Application granted granted Critical
Publication of CN106140510B publication Critical patent/CN106140510B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/025Discharge apparatus, e.g. electrostatic spray guns
    • B05B5/053Arrangements for supplying power, e.g. charging power
    • B05B5/0533Electrodes specially adapted therefor; Arrangements of electrodes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B13/00Machines or plants for applying liquids or other fluent materials to surfaces of objects or other work by spraying, not covered by groups B05B1/00 - B05B11/00
    • B05B13/02Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work
    • B05B13/0278Arrangement or mounting of spray heads
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B13/00Machines or plants for applying liquids or other fluent materials to surfaces of objects or other work by spraying, not covered by groups B05B1/00 - B05B11/00
    • B05B13/02Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work
    • B05B13/04Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work the spray heads being moved during spraying operation
    • B05B13/0405Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work the spray heads being moved during spraying operation with reciprocating or oscillating spray heads
    • B05B13/041Means for supporting work; Arrangement or mounting of spray heads; Adaptation or arrangement of means for feeding work the spray heads being moved during spraying operation with reciprocating or oscillating spray heads with spray heads reciprocating along a straight line
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B15/00Details of spraying plant or spraying apparatus not otherwise provided for; Accessories
    • B05B15/20Arrangements for agitating the material to be sprayed, e.g. for stirring, mixing or homogenising
    • B05B15/25Arrangements for agitating the material to be sprayed, e.g. for stirring, mixing or homogenising using moving elements, e.g. rotating blades
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B16/00Spray booths
    • B05B16/20Arrangements for spraying in combination with other operations, e.g. drying; Arrangements enabling a combination of spraying operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/08Plant for applying liquids or other fluent materials to objects
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/16Arrangements for supplying liquids or other fluent material
    • B05B5/1608Arrangements for supplying liquids or other fluent material the liquid or other fluent material being electrically conductive

Abstract

The invention discloses a kind of electrostatic spraying apparatus and prepare the device of nesa coating.Electrostatic spraying apparatus includes unwinding and rewinding system, positive high voltage generator, negative high-voltage generator, negative plate, liquid-supplying system, driving means, nozzle;Described unwinding and rewinding system is for carrying out unwinding and rewinding operation to base material, and running roller and guide rail in described unwinding and rewinding system are conductive material;Described positive high voltage generator connects described nozzle, and described negative high-voltage generator connects described negative plate, and described nozzle and described negative plate lay respectively at the both sides of base material, and described nozzle distance base material 0~250mm, described negative plate contacts with base material;Described liquid-supplying system is used for providing electrocondution slurry to described nozzle;Described driving means connects described nozzle, for driving the motion of described nozzle.The electrostatic spraying apparatus equipment cost of the present invention is low, and the product yields prepared is high, and electric conductivity is preferable.

Description

A kind of electrostatic spraying apparatus and prepare the device of nesa coating
[technical field]
The present invention relates to the preparation of nesa coating, particularly relate to a kind of electrostatic spraying apparatus.
[background technology]
Along with people are swift and violent for the demand of thinner, lighter, the photoelectric device of lower cost and associated electrical display device Increase, especially photovoltaic industry and touch control display application, such as mobile phone, notebook computer, All-In-One computer etc., thoroughly Bright conducting membrane material market explosion.The most common transparent conductive film includes that ITO (mix by Indium Tin Oxides stannum Miscellaneous three Indium sesquioxide .s), GZO (Gallium Zinc Oxides Ga-doped zinc oxide), AZO (mix by Aluminum Zinc Oxides aluminum Miscellaneous zinc oxide) etc., these oxides only absorb ultraviolet light, do not absorb visible ray.For a long time, ITO is that opto-electronics uses For transparent conductive membrane material widely.But ITO exists that reserves are limited, processing cost is high, more crisp frangible, poisonous etc. the most fatal Shortcoming, gradually limit it in the application of following opto-electronics and development.
For high-side capacitance formula touch screen, the scientific research personnel of the U.S., Japan, Korea S and China etc. just pays special attention to use newly Material and the technology of grain husk replace ito transparent electrode material, thus reduce cost, put forward high performance purpose.The most existing The new scheme about conductive film.
When preparing nesa coating, the general mode used is first to configure electrocondution slurry, then uses the side of precision coating Electrocondution slurry is coated with on a transparent substrate by formula, then dries and prepares nesa coating.Make general by precision in this way Coating apparatus manufacture obtains.But precision coating apparatus there is problems in that (1) apparatus expensive, cost is high.(2) product yield Low.The accurate coating of contact is easily subject to the impact of particulates, forms the longest cut on the product of coating, Strong influence product yield.(3) electric conductivity of the nesa coating prepared needs to be improved further.(4) it is merely able to be coated with Cloth is at even curface, it is impossible to enough adapt to complex surface.
[summary of the invention]
The technical problem to be solved is: make up above-mentioned the deficiencies in the prior art, proposes a kind of electrostatic application Putting and prepare the device of nesa coating, equipment cost is low, and the product yields prepared is high, and electric conductivity is preferable.
The technical problem of the present invention is solved by following technical scheme:
A kind of electrostatic spraying apparatus for preparing nesa coating, including unwinding and rewinding system, positive high voltage generator, negative height Pressure generator, negative plate, liquid-supplying system, driving means, nozzle;Described unwinding and rewinding system is for carrying out unwinding and rewinding behaviour to base material Making, running roller and guide rail in described unwinding and rewinding system are conductive material;Described positive high voltage generator connects described nozzle, described negative High tension generator connects described negative plate, and described nozzle and described negative plate lay respectively at the both sides of base material, described nozzle distance Base material 0~250mm, described negative plate contacts with base material;Described liquid-supplying system is used for providing electrocondution slurry to described nozzle;Described Driving means connects described nozzle, for driving the motion of described nozzle.
A kind of device preparing nesa coating, including electrostatic spraying apparatus as above.
The present invention is compared with the prior art and provides the benefit that:
The electrostatic spraying apparatus of the present invention, by unwinding and rewinding system, positive high voltage generator, negative high-voltage generator, negative plate, Liquid-supplying system, being equipped with of nozzle etc., electrocondution slurry electrostatic spraying can be realized to base material.First, the electrostatic of the present invention The amount of nano-silver thread having only to control during coating device processing nesa coating be sprayed on base material just can control conductive layer Thickness, it is not necessary to rely on as accurate coating apparatus the machining accuracy of precision to realize the coating of specific thicknesses, enough accuracy, because of Without regard to processing component accurate especially, therefore equipment cost is greatly reduced.Secondly, assembly of the invention passes through electrostatic spraying Realize the spray coating of electrocondution slurry, the longest cut will not be caused because of the molecule in air, reduce and produced Requirement to environment in journey, is conducive to improving the yield of product.Furthermore, electrostatic spraying mode can make nano-silver thread fill as much as possible Point random distribution on a transparent substrate, thus is overlapped to form conductive network efficiently, prepared nesa coating electric conductivity more preferably, The light transmission of product is preferable simultaneously.Finally, assembly of the invention is coated by electrostatic spraying mode, also can adapt to various multiple Miscellaneous surface.The electrostatic spraying apparatus of the present invention, the Multi needle of comprehensive nozzle and unwinding and rewinding technology, it is possible to realize long wide cut, roll up right Volume ground large-scale production.
[accompanying drawing explanation]
Fig. 1 is a kind of structural representation of the electrostatic spraying apparatus of the specific embodiment of the invention;
Fig. 2 is the another kind of structural representation of the electrostatic spraying apparatus of the specific embodiment of the invention;
Fig. 3 is the structural representation of the liquid-supplying system in the electrostatic spraying apparatus of the specific embodiment of the invention;
Fig. 4 is the structural representation of the needle-carrier in the electrostatic spraying apparatus of the specific embodiment of the invention;
Fig. 5 is the preferred structure schematic diagram of the needle-carrier in the electrostatic spraying apparatus of the specific embodiment of the invention;
Fig. 6 is nano-silver thread electrically conducting transparent membrane sample prepared by the electrostatic spraying apparatus of the specific embodiment of the invention SEM photograph.
[detailed description of the invention]
Below in conjunction with detailed description of the invention and compare accompanying drawing the present invention is described in further details.
As illustrated in fig. 1 and 2, two kinds of structural representations of the electrostatic spraying apparatus of this detailed description of the invention it are respectively.Electrostatic Spray equipment includes unwinding and rewinding system, positive high voltage generator 200, negative high-voltage generator (not shown), negative plate 400, supplies Liquid system 500, driving means 600, nozzle 700.
Unwinding and rewinding system for carrying out unwinding and rewinding operation to base material, and running roller and guide rail in described unwinding and rewinding system are conduction Material.In this detailed description of the invention, unwinding and rewinding system is provided with let off roll 8, tenslator 9, guide reel 10, antistatic Roller 11, deviation correcting device 12, active force, wind-up roll 13.In unwinding and rewinding system antistatic roller 11 and all be coated with conductive paste The guide rail material of material contact all selects conductive material, and ensures good contact, such as stainless steel rider, the conductive silicon rubber roller of chromium plating Deng, so that unnecessary static guiding is walked.Meanwhile, electrostatic spraying apparatus integral ground, the lubricating oil used in running roller also conducts electricity.Receive The vehicle speed range unreeled can realize 0.1m/min~100m/min, and actual speed can be according to required nesa coating product Adjusting performance.The wide cut of unwinding and rewinding system can determine according to actual needs, to meet need different between 100mm~1000mm Ask.
Positive high voltage generator 200 connects nozzle 700, and negative high-voltage generator connects negative plate 400, nozzle 700 and negative plate 400 both sides laying respectively at base material 100, nozzle 700 is 0~250mm apart from the distance of base material 100, negative plate 400 and base material 100 contact.Positive high voltage generator 200 be available positive high voltage scope 0~+100kV voltage generator, negative high voltage is sent out Raw device be available range of negative pressure 0~-100kV voltage generator.Voltage can be that direct current is alternatively pulse, pulse voltage Scalable frequency range is 0.1Hz~10MHz.Negative plate 400 can be one block of smooth square metal plate, and material is the most stainless Steel, size is wider than the base material 100 used, and both sides respectively reserve the wide cut of 20~50mm.
Liquid-supplying system 500 is used for providing electrocondution slurry to nozzle 700.The concrete knot of the liquid-supplying system of this detailed description of the invention Structure schematic diagram is as it is shown on figure 3, liquid-supplying system 500 includes three parts: device for storing liquid, liquid feed device, liquid distributing device.Decomposable asymmetric choice net in detail For agitating device, fluid reservoir 503, peristaltic pump 504, feed flow buffer unit 505, part flow arrangement 506.Agitating device is used for stirring institute State the electrocondution slurry in fluid reservoir 503.Flexible pipe one end of peristaltic pump 504 connects fluid reservoir 503, and the other end connects feed flow buffering dress Putting 505, the outlet of feed flow buffer unit 505 connects part flow arrangement 506, and part flow arrangement 506 is for being split into many by single liquid pipe Root arm, is respectively supplied to multiple syringe needles of nozzle, it is achieved the effect of shunting.
In this detailed description of the invention, agitating device includes magnetic stirrer 501, magnetic stir bar 502.Magnetic stir bar 502 are arranged in fluid reservoir 503, and fluid reservoir 503 is placed in magnetic stirrer 501.Magnetic stirrer 501 can effectively prevent from leading The sedimentation of plasma-based material dispersion liquid.When selecting bigger fluid reservoir, for reaching optimal mixing effect, other machinery can be selected to stir Mix device.
The big I of fluid reservoir 503 is 10~500L, and material can select the material such as glass, politef.Peristaltic pump 504 Supplying liquid at nozzle, have the function controlling flow, controlling flow rate of liquid scope is 5ml/min-5000ml/min.Supply The setting of liquid buffer unit 505 can effectively buffer the pulse that peristaltic pump produces.Owing to liquid-supplying system 500 uses the mode of peristaltic pump Feed flow, peristaltic pump feed flow has undulatory property, the pressure transient of liquid, thus directly influences syringe needle and go out the liquid rate of outflow Stablize.After this buffer unit 505 is set, the impulse action of peristaltic pump can be offset, during being maintained at feed flow, be pressed onto nozzle Liquid at multiple syringe needles can keep stable pressure, and stable flow velocity, thus is effectively improved device electrostatic spraying Uniformity.Single fluid-through tube is divided into many fluid-through tubes by part flow arrangement 506.Each flexible pipe and the material selection of part flow arrangement 506 Politef, can prevent the corrosion to pipeline of the electrocondution slurry dispersion liquid.
Driving means 600 connects nozzle 700, for driving the motion of nozzle 700.In this detailed description of the invention, drive dress Put 600 height being regulated nozzle by platform 4, thus regulate the distance between the multiple syringe needles in nozzle and base material 100.Drive Device 600 can drive the quick movement in the longitudinal direction of the multiple syringe needles on nozzle, and translational speed can reach 0.001~50m/ min.The scope of movement is at 10-1000mm, thus the wide cut realizing spraying reaches 1000mm.Driver in driving means 600 Quantity can be one or select multiple driver parallel simultaneously.
The structure of nozzle 700 includes multiple syringe needle, needle-carrier.Needle-carrier can be fixed on above-mentioned platform 4.Syringe needle can root Selecting different apertures according to the viscosity of electrocondution slurry dispersion liquid, preferably pore diameter range is 0.1~3mm.
In Fig. 4, the needle-carrier of signal includes multiple sheet metal 701, and multiple needle holder portion is distributed on each sheet metal 701 702, for grafting syringe needle.Thus, by arranging quantity and the quantity in needle holder portion 702 of sheet metal 701, syringe needle can be formed The array of composition.The plug-in position of syringe needle can be set according to actual needs, thus realize multiple syringe needle arrangement mode.Needle-carrier Material can be with the engineering plastics such as aluminium alloy, politef, PMMA, ABS.It is noted that using plastic material Needle-carrier time, sheet metal can be fixed in the side of contact needle, uniformly be added on each syringe needle for by positive voltage.
Preferably, needle-carrier as shown in Figure 5 is used.Needle-carrier includes multiple sheet metal 701 and reservoir 703.Each gold Belong to and multiple needle holder portion 702 is distributed, for grafting syringe needle on sheet 701.The sidepiece of sheet metal 701 is provided with inclined-plane 704, liquid storage Groove 703 is arranged on the lowest part on each inclined-plane 704, for receiving the electrocondution slurry flowed down from each inclined-plane 704.By arranging Inclined-plane, thus unnecessary liquid is directed in the reservoir 703 on side, so can prevent electrocondution slurry liquid from resting on syringe needle Burn in frame.Be arranged on the lower section of base material 100 especially for nozzle, negative plate 400 is arranged on the top of base material 100 Situation.Having unnecessary liquid during nozzle injection to overflow, after using the needle-carrier on band inclined-plane, liquid can be along syringe needle and inclined-plane stream Dynamic, directed fluid in reservoir by inclined-plane, thus prevent liquid from remaining near syringe needle.For the device shown in Fig. 2 In the setting that sprays downwards of syringe needle, liquid overflows and can drip directly down, from without remaining near syringe needle, thus at pin The headstock can be arranged, it is possible to be not provided with this ramp structure, it is only necessary to needle-carrier can fixed needle.
In this detailed description of the invention, multiple syringe needles are fixed in needle-carrier the nozzle constituting electrostatic spraying device.Nozzle Needle-carrier is fixed on a platform 4 that can move up and down regulation height, and meanwhile, platform 4 lower end is same can the most front and back be moved Dynamic driving means 600 connects.Driving means 600 makes array that syringe needle forms according to the motion set.Feed flow system Multiple syringe needles that system 500 is nozzle provide the electrocondution slurry of injection.Positive high voltage provides the multiple syringe needles to nozzle, and negative high voltage is same Negative plate 400 connects.Electrocondution slurry solution flows out from nozzle, scatter and move to negative pole under high-tension effect, Spray to transparent base under the effect of electrostatic eventually.
Preferably, electrocondution slurry selects the electrocondution slurry of metallic particles.Electrostatic spraying apparatus also includes electrode slice 14 and height Pressure generator (not shown), electrode slice 14 with spraying electrocondution slurry after base material 1000 be oppositely arranged, be spaced 1~5mm, height Pressure generator connects electrode slice 14, for providing 7~20kV voltages for electrode slice 14.The high pressure that high tension generator provides is at base material Corona is produced, so that the charged ion being ionized in air, ozone molecule etc. exist with continuous discharge in the gap of electrode slice 14 Base material is rushed at, so that occurring low-temperature sintering to make on base material between the metallic particles in the electrocondution slurry of spraying under the acceleration of high pressure With so that metallic particles forms continuous print film layer structure, so that the electric conductivity of the conducting film prepared is higher.Further preferably Ground, electrocondution slurry selects nanometer silver paste.Specialty, under corona effect, the polyvinylpyrrolidone on nano-silver thread surface is removed, with Time nano-silver thread between occur low-temperature sintering effect, so can improve the electric conductivity of conducting film.
In the electrostatic spraying apparatus of this detailed description of the invention, electrocondution slurry is uniformly to fall at base by the way of electrostatic spraying On material, it is only necessary to the amount of the electrocondution slurry that control is sprayed on base material just can control thickness, and the amount regulating electrocondution slurry can With easily by the flow velocity of liquid, the walking speed of unwinding and rewinding system when the concentration of regulation electrocondution slurry dispersion liquid, spraying Regulating, therefore the electrostatic spraying apparatus processing nesa coating of this detailed description of the invention comes real not against accurate machining accuracy Existing specific thicknesses, the coating of enough accuracy, because without regard to processing component accurate especially, therefore equipment cost is greatly reduced. The device selecting this detailed description of the invention is processed, and general cost is below 500,000.And existing accurate coating relies on precision Coating head can be coated with out the coating of enough accuracy, therefore apparatus expensive, substantially 150~3,000,000.It is coated with additionally, accurate During cloth electrocondution slurry, such as nano-silver thread, it has the draw ratio of superelevation, readily along the direction orientations of coating, causes Being overlapped to form the inefficient of conductive network, electric conductivity is poor.The device of this detailed description of the invention is by electrostatic spraying mode then Nano-silver thread as much as possible fully random distribution can be made on a transparent substrate, thus be overlapped to form conductive network efficiently, prepared Nesa coating electric conductivity is more preferably.It addition, the device of this detailed description of the invention is also beneficial to improve the yield of product, prepared The light transmission of product is also preferable, also can adapt to various complex surface, can realize long wide cut, volume to volume ground large-scale production.
As shown in Figure 6, for the nano-silver thread nesa coating using the electrostatic spraying device of this detailed description of the invention to prepare Sample.It is seen that nano-silver thread is a kind of random distribution state spatially on a transparent substrate.Nano-silver thread is random The overlap joint state of distribution so that the electric conductivity of prepared conducting film is relatively good.After tested, use four probe machines to record its sheet resistance to be 50 Ω/sq, recording light transmittance with printing opacity mist degree instrument is 85%.
Above-mentioned electrostatic spraying apparatus may be provided in the system preparing nesa coating, in substrate surface spraying conduction Slurry.In preparation facilities, apparatus for baking 15 can be set in the rear end of electrostatic spraying apparatus, with to electrostatic spraying apparatus spraying conduction Base material after slurry carries out baking process at 30~200 DEG C so that film forming after electrocondution slurry drying.The baking that apparatus for baking is constituted Roasting line length is 0.5~50m.Drying mode can be hot air drying, infrared drying etc., be dried road form can be flat, Air-flotation type, bridge-type etc., blower fan is selected explosion-proof fan, can be installed hazardous gas detecting devices every 1~3m in baking line.
Further, equipment for coating film 16 can be set after apparatus for baking 15.Equipment for coating film 16 can select cold cover, heat is covered Mode.The film covered preferably has and can conduct electricity or anlistatig performance.Hereafter, electrostatic spraying apparatus can be set in a device Wind-up roll part, the nesa coating prepared with rolling.
Additionally, humiture detector 17 can be arranged on the top of electrostatic spraying apparatus, detector for hazardous gas 18, temperature, Humidity regulation and air interchanger 19.Syringe needle can be installed automatic flame and detects and siren 20, carbon dioxide jet go out near running Firearm 21.
Humiture detector 17 is detectable in the range of temperature 5~100 DEG C, humidity 1~100%.
Detector for hazardous gas 18 can detect the vapour pressure of device interior solvent in time, thus passes to signal control system System, makes rapidly corresponding.Primary solvent typically, for nano-silver thread dispersion liquid is ethanol, and the explosion limit of ethanol is 3.3%~19%, thus preferably detection range is 3.3%, will trigger logical when device interior concentration of alcohol is close to 3.3% Wind apparatus, thus in time concentration of alcohol is reduced.
Temperature, humidity regulation and air interchanger 19 are by compressor of air conditioner, humidifier, blower fan synergic adjustment temperature, humidity, molten Agent vapour pressure, it is possible to regulation temperature humidity range is respectively as follows: temperature 20~80 DEG C, humidity 10~90%.Explosion-proof fan selected by blower fan.
Automatic flame detection system 20 can select open flame detector or warming fire detector, when naked light or temperature being detected Degree by detector perception, thus can be shut down rapidly when drastically raising, and carbon dioxide jet device 21 is opened in alarm of sounding simultaneously.
Carbon dioxide jet device 21 is connected with gas cylinder by a replaceable carbon dioxide extinguisher bottle and one Gate-controlled switch nozzle system.When automatic flame detection system 20 has detected that naked light occurs, it is possible to trigger rapidly carbon dioxide Electromagnetic valve switch on injection apparatus 21, thus eject carbon dioxide, eliminate flame.
Above content is to combine concrete preferred implementation further description made for the present invention, it is impossible to assert Being embodied as of the present invention is confined to these explanations.For general technical staff of the technical field of the invention, Without departing from making some replacements or obvious modification on the premise of present inventive concept, and performance or purposes are identical, all should be considered as Belong to protection scope of the present invention.

Claims (10)

1. the electrostatic spraying apparatus being used for preparing nesa coating, it is characterised in that: including unwinding and rewinding system, positive high voltage is sent out Raw device, negative high-voltage generator, negative plate, liquid-supplying system, driving means, nozzle;Described unwinding and rewinding system is for carrying out base material Unwinding and rewinding operate, and running roller and guide rail in described unwinding and rewinding system are conductive material;Described positive high voltage generator connects described spray Mouth, described negative high-voltage generator connects described negative plate, and described nozzle and described negative plate lay respectively at the both sides of base material, described Nozzle distance base material 0~250mm, described negative plate contacts with base material;Described liquid-supplying system is used for providing electrocondution slurry to described Nozzle;Described driving means connects described nozzle, for driving the motion of described nozzle.
Electrostatic spraying apparatus for preparing nesa coating the most according to claim 1, it is characterised in that: described nozzle Including multiple syringe needles, needle-carrier, described needle-carrier includes multiple sheet metal, and multiple needle holder portion is distributed on each sheet metal, uses In grafting syringe needle.
Electrostatic spraying apparatus for preparing nesa coating the most according to claim 1, it is characterised in that: described nozzle Including multiple syringe needles, needle-carrier;Described needle-carrier includes multiple sheet metal and reservoir, and multiple syringe needle is distributed on each sheet metal Seat portion, for grafting syringe needle;The sidepiece of described sheet metal is provided with inclined-plane, and described reservoir is arranged on the minimum of each inclined-plane Place, for receiving the electrocondution slurry flowed down from each inclined-plane.
Electrostatic spraying apparatus for preparing nesa coating the most according to claim 1, it is characterised in that: described conduction Slurry is the electrocondution slurry of metallic particles;Described electrostatic spraying apparatus also includes electrode slice and high tension generator, described electrode slice With spraying electrocondution slurry after base material be oppositely arranged, be spaced 1~5mm, described high tension generator connect described electrode slice, be used for be Described electrode slice provides the voltage of 7~20kV.
Electrostatic spraying apparatus for preparing nesa coating the most according to claim 4, it is characterised in that: described conduction Slurry is nanometer silver paste.
Electrostatic spraying apparatus for preparing nesa coating the most according to claim 1, it is characterised in that: described feed flow System includes agitating device, fluid reservoir, peristaltic pump, feed flow buffer unit and part flow arrangement;Described agitating device is used for stirring institute State the electrocondution slurry in fluid reservoir;Flexible pipe one end of described peristaltic pump connects described fluid reservoir, and the other end connects described feed flow and delays Flushing device, the outlet of described feed flow buffer unit connects described part flow arrangement, and described part flow arrangement is for shunting single liquid pipe Cheng Duogen arm, is respectively supplied to described nozzle.
Electrostatic spraying apparatus for preparing nesa coating the most according to claim 6, it is characterised in that: described stirring Device includes magnetic stir bar and magnetic stirrer;Described magnetic stir bar is arranged in described fluid reservoir, and described fluid reservoir is put In described magnetic stirrer.
Electrostatic spraying apparatus for preparing nesa coating the most according to claim 1, it is characterised in that: described syringe needle A diameter of 0.1~3mm.
9. the device preparing nesa coating, it is characterised in that: include the electrostatic as described in any one of claim 1~8 Spray equipment.
The device preparing nesa coating the most according to claim 9, it is characterised in that: also include apparatus for baking, described Apparatus for baking is for carrying out baking process to the base material after described electrostatic spraying apparatus spraying electrocondution slurry at 30~200 DEG C.
CN201610817904.2A 2016-09-12 2016-09-12 A kind of electrostatic spraying apparatus and the device for preparing transparent conductive film Active CN106140510B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610817904.2A CN106140510B (en) 2016-09-12 2016-09-12 A kind of electrostatic spraying apparatus and the device for preparing transparent conductive film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610817904.2A CN106140510B (en) 2016-09-12 2016-09-12 A kind of electrostatic spraying apparatus and the device for preparing transparent conductive film

Publications (2)

Publication Number Publication Date
CN106140510A true CN106140510A (en) 2016-11-23
CN106140510B CN106140510B (en) 2018-12-28

Family

ID=57340794

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610817904.2A Active CN106140510B (en) 2016-09-12 2016-09-12 A kind of electrostatic spraying apparatus and the device for preparing transparent conductive film

Country Status (1)

Country Link
CN (1) CN106140510B (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106683795A (en) * 2017-03-02 2017-05-17 苏州维业达触控科技有限公司 Coating method of transparent conducting film and device for forming hydrophobic and oleophobic substance
CN108405254A (en) * 2018-05-16 2018-08-17 江苏优腾超导科技有限公司 The process equipment of high temperature superconducting materia
CN108492929A (en) * 2018-03-13 2018-09-04 深圳市善柔科技有限公司 A kind of device and method preparing transparent flexible conductive film
CN108897082A (en) * 2018-07-27 2018-11-27 厦门理工学院 A kind of diffusion sheet diffusion particle preparation facilities and method
CN110355033A (en) * 2019-06-04 2019-10-22 江西力能新能源科技有限公司 A kind of apparatus for coating for positive electrode plate and negative electrode plate of lithium ion battery
CN111646708A (en) * 2020-07-07 2020-09-11 浙江山蒲照明电器有限公司 Spraying mechanism for inner wall of glass tube
CN112090659A (en) * 2019-12-26 2020-12-18 深圳市中欧新材料有限公司 Spraying equipment with precise coating structure for conductive film production
CN114250013A (en) * 2020-09-22 2022-03-29 宸鸿科技(厦门)有限公司 Sprayable conductive ink and conductive element
CN114558735A (en) * 2022-02-25 2022-05-31 合肥晶澳太阳能科技有限公司 Film supplementing equipment, photovoltaic power station and film supplementing method for photovoltaic module in photovoltaic power station

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6012156A (en) * 1983-07-01 1985-01-22 R H Service:Kk Electrostatic painting apparatus
JPH06246194A (en) * 1993-02-22 1994-09-06 Nkk Corp Process and apparatus for production of metallic reflection plate
CN102294317A (en) * 2010-06-28 2011-12-28 无锡华润上华半导体有限公司 Photoresist spraying device and method
WO2013115125A1 (en) * 2012-02-02 2013-08-08 株式会社カネカ Method for manufacturing substrate having transparent electrode
CN203678562U (en) * 2014-01-27 2014-07-02 中原工学院 Electrostatic PTC film coating machine
US20140272199A1 (en) * 2013-03-14 2014-09-18 Yi-Jun Lin Ultrasonic spray coating of conducting and transparent films from combined graphene and conductive nano filaments
JP2014240462A (en) * 2013-06-12 2014-12-25 コニカミノルタ株式会社 Gas barrier film, method for manufacturing gas barrier film, and apparatus for manufacturing gas barrier film
CN104254823A (en) * 2012-04-26 2014-12-31 国立大学法人大阪大学 Transparent conductive substrate fabrication method, transparent conductive substrate and electrostatic capacitance-type touch panel
CN104008819B (en) * 2014-05-27 2016-03-30 东莞市鑫聚光电科技有限公司 A kind of production method of nano-silver thread nesa coating

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6012156A (en) * 1983-07-01 1985-01-22 R H Service:Kk Electrostatic painting apparatus
JPH06246194A (en) * 1993-02-22 1994-09-06 Nkk Corp Process and apparatus for production of metallic reflection plate
CN102294317A (en) * 2010-06-28 2011-12-28 无锡华润上华半导体有限公司 Photoresist spraying device and method
WO2013115125A1 (en) * 2012-02-02 2013-08-08 株式会社カネカ Method for manufacturing substrate having transparent electrode
CN104254823A (en) * 2012-04-26 2014-12-31 国立大学法人大阪大学 Transparent conductive substrate fabrication method, transparent conductive substrate and electrostatic capacitance-type touch panel
US20140272199A1 (en) * 2013-03-14 2014-09-18 Yi-Jun Lin Ultrasonic spray coating of conducting and transparent films from combined graphene and conductive nano filaments
CN105492126A (en) * 2013-03-14 2016-04-13 纳米技术仪器公司 Ultrasonic spray coating of conducting and transparent films from combined graphene and conductive nano filaments
JP2014240462A (en) * 2013-06-12 2014-12-25 コニカミノルタ株式会社 Gas barrier film, method for manufacturing gas barrier film, and apparatus for manufacturing gas barrier film
CN203678562U (en) * 2014-01-27 2014-07-02 中原工学院 Electrostatic PTC film coating machine
CN104008819B (en) * 2014-05-27 2016-03-30 东莞市鑫聚光电科技有限公司 A kind of production method of nano-silver thread nesa coating

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106683795A (en) * 2017-03-02 2017-05-17 苏州维业达触控科技有限公司 Coating method of transparent conducting film and device for forming hydrophobic and oleophobic substance
CN108492929A (en) * 2018-03-13 2018-09-04 深圳市善柔科技有限公司 A kind of device and method preparing transparent flexible conductive film
CN108405254A (en) * 2018-05-16 2018-08-17 江苏优腾超导科技有限公司 The process equipment of high temperature superconducting materia
CN108897082A (en) * 2018-07-27 2018-11-27 厦门理工学院 A kind of diffusion sheet diffusion particle preparation facilities and method
CN110355033A (en) * 2019-06-04 2019-10-22 江西力能新能源科技有限公司 A kind of apparatus for coating for positive electrode plate and negative electrode plate of lithium ion battery
CN112090659A (en) * 2019-12-26 2020-12-18 深圳市中欧新材料有限公司 Spraying equipment with precise coating structure for conductive film production
CN111646708A (en) * 2020-07-07 2020-09-11 浙江山蒲照明电器有限公司 Spraying mechanism for inner wall of glass tube
CN114250013A (en) * 2020-09-22 2022-03-29 宸鸿科技(厦门)有限公司 Sprayable conductive ink and conductive element
CN114558735A (en) * 2022-02-25 2022-05-31 合肥晶澳太阳能科技有限公司 Film supplementing equipment, photovoltaic power station and film supplementing method for photovoltaic module in photovoltaic power station

Also Published As

Publication number Publication date
CN106140510B (en) 2018-12-28

Similar Documents

Publication Publication Date Title
CN106140510A (en) A kind of electrostatic spraying apparatus and prepare the device of nesa coating
Kim et al. Time-resolved high-speed camera observation of electrospray
US20090224437A1 (en) Electrostatic spray apparatus and method of electrostatic spray
CN103895345A (en) System and method for multifunctional electric fluid ink-jet printing
EP1870169B1 (en) Coater of electric insulating sheet and method for producing electric insulating sheet with coated film
CN102284390B (en) Control method of automated control multi-jet flow static spraying system to achieve stable state
Martin et al. Effect of the collector voltage on the stability of the cone-jet mode in electrohydrodynamic spraying
Wang et al. Visualization of periodic emission of drops with micro-dripping mode in electrohydrodynamic (EHD) atomization
CN203360646U (en) Fusion electrostatic spinning nozzle device
CN108097487A (en) A kind of powder coatings system
CN201157812Y (en) Coating apparatus for color coated steel plate surface coating
Wang et al. Dynamics of droplet formation with oscillation of meniscus in electric periodic dripping regime
CN107716182A (en) Viscose spray equipment
Lee et al. Preparation of monodisperse charged droplets via electrohydrodynamic device for the removal of fine dust particles smaller than 10 μm
CN109732902B (en) Multi-mode printing method and device
Kong et al. Dynamics of electrified jets in electrohydrodynamic atomization
CN102654690B (en) Dry-type dispensing device
TW201002427A (en) Electrostatic coating apparatus
Roncallo et al. Evaluation of different deposition conditions on thin films deposited by electrostatic spray deposition using a uniformity test
US20130302595A1 (en) Super-hydrophobic and oleophobic transparent coatings for displays
Seong et al. A hybrid aerodynamic and electrostatic atomization system for enhanced uniformity of thin film
CN106460218A (en) Capacitive metal porous body-forming apparatus and capacitive metal porous body-forming method using same
CN105773965B (en) A kind of three-dimensional jet printing appts of inversion type single electrode electrofluid
CN100528569C (en) Liquid jetting device, liquid jetting method, and method of forming wiring pattern on circuit board
CN103753939B (en) The method of film prepared by showering nano metal ink

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
CB03 Change of inventor or designer information
CB03 Change of inventor or designer information

Inventor after: Yang Cheng

Inventor after: Li Ziheng

Inventor after: Wu Cheng

Inventor before: Yang Cheng

Inventor before: Li Ziheng

GR01 Patent grant
GR01 Patent grant
CP01 Change in the name or title of a patent holder
CP01 Change in the name or title of a patent holder

Address after: 518055 Guangdong city of Shenzhen province Nanshan District Xili of Tsinghua

Patentee after: Shenzhen International Graduate School of Tsinghua University

Address before: 518055 Guangdong city of Shenzhen province Nanshan District Xili of Tsinghua

Patentee before: GRADUATE SCHOOL AT SHENZHEN, TSINGHUA University

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20230103

Address after: 1301, Unit 1, Building 1, Xinchen New Materials Pilot Production Industrialization Base, No. 300, Shutianpu Road, Shutianpu Community, Matian Street, Guangming District, Shenzhen, Guangdong 518000

Patentee after: SHENZHEN SUNROLL TECHNOLOGY Co.,Ltd.

Address before: 518055 Guangdong city of Shenzhen province Nanshan District Xili of Tsinghua

Patentee before: Shenzhen International Graduate School of Tsinghua University