CN106129489A - A kind of sodium-sulphur battery group - Google Patents

A kind of sodium-sulphur battery group Download PDF

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Publication number
CN106129489A
CN106129489A CN201610681075.XA CN201610681075A CN106129489A CN 106129489 A CN106129489 A CN 106129489A CN 201610681075 A CN201610681075 A CN 201610681075A CN 106129489 A CN106129489 A CN 106129489A
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CN
China
Prior art keywords
sodium
sulphur battery
monomer
positive pole
sulphur
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610681075.XA
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Chinese (zh)
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CN106129489B (en
Inventor
鲍剑明
刘宇
龚明光
孙贤书
王佳斌
王资法
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Shanghai Electric Enterprise Development Co., Ltd
Original Assignee
Shanghai Electric Sodium Sulfur Energy Storage Technology Co Ltd
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Application filed by Shanghai Electric Sodium Sulfur Energy Storage Technology Co Ltd filed Critical Shanghai Electric Sodium Sulfur Energy Storage Technology Co Ltd
Priority to CN201610681075.XA priority Critical patent/CN106129489B/en
Publication of CN106129489A publication Critical patent/CN106129489A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/36Accumulators not provided for in groups H01M10/05-H01M10/34
    • H01M10/39Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/20Mountings; Secondary casings or frames; Racks, modules or packs; Suspension devices; Shock absorbers; Transport or carrying devices; Holders
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Secondary Cells (AREA)

Abstract

The invention discloses a kind of sodium-sulphur battery group in energy storage field, chassis body including upper opening, lifting location structure it is disposed with on the perisporium of described chassis body, the bottom of described chassis body is provided with one piece of location-plate, the end face of described location-plate is provided with some locating slots arranged in arrays, an insulation Muscovitum sleeve pipe it is fixed with on each described locating slot, it is provided with a sodium-sulphur battery monomer in each described insulation Muscovitum sleeve pipe, described sodium-sulphur battery monomer all includes shell, positive pole ear and negative lug, described sodium-sulphur battery monomer is connected to become described sodium-sulphur battery group by battery connecting piece, engaged by argon arc welding between positive pole ear and negative lug and the corresponding battery connecting piece of described sodium-sulphur battery monomer.It has the technical effect that the heating of sodium-sulfur battery module inside and temperature control electronic devices and components will not be caused damage by the assembling of sodium-sulphur battery group, and working place is big, is suitable for robot automation's welding, improves production efficiency, reduce production cost.

Description

A kind of sodium-sulphur battery group
Technical field
The present invention relates to a kind of sodium-sulphur battery group in energy storage field.
Background technology
Sodium-sulphur battery be a kind of metallic sodium as negative pole, sulfur as positive pole, β " alumina eltrolysis matter pipe as barrier film, 290 DEG C~the 360 DEG C high temperature secondary battery run.Sodium-sulphur battery is widely used in peak load shifting, emergency power supply, wind-power electricity generation Etc. the stable output of regenerative resource and improve the aspect such as power quality.In such applications, it is generally required to by sodium-sulphur battery Apply after monomer composition sodium-sulphur battery group or sodium-sulfur battery module.
Sodium-sulphur battery monomer is typically placed in couveuse by prior art, uses aluminum alloy connector by sodium-sulphur battery monomer Carry out series, parallel or serial-parallel mirror, form sodium-sulphur battery group or sodium-sulfur battery module.The method has the disadvantage that One, narrow space in couveuse, sodium-sulphur battery monomer connects is inconvenient to cause inefficiency, and is not suitable for robot automatic welding Connect;Second, aluminum alloy connector typically uses argon arc welding technique with the joint of sodium-sulphur battery monomer, the big electricity during argon arc welding The heating of couveuse inside and temperature control electronic devices and components may be caused damage by stream;3rd, different model sodium-sulfur battery module needs The quantity of sodium-sulphur battery monomer and connected mode different, cause the assembly line quantity of sodium-sulphur battery group to increase or Complexity increases, and finally considerably increases production cost.
Summary of the invention
The invention aims to overcome the deficiencies in the prior art, it is provided that a kind of sodium-sulphur battery group, its assembling will not be right The internal heating of sodium-sulfur battery module and temperature control electronic devices and components cause damage, and working place is big, is suitable for robot automation Welding, sodium-sulfur battery module assembly line is greatly simplified, and improves production efficiency, reduces production cost.
A kind of technical scheme realizing above-mentioned purpose is: a kind of sodium-sulphur battery group, including the chassis body of upper opening, institute Stating and be disposed with lifting location structure on the perisporium of chassis body, the bottom of described chassis body is provided with one piece of location-plate, described fixed The end face of position plate is provided with some locating slots arranged in arrays, and each described locating slot is fixed with an insulation Muscovitum set Pipe, is provided with a sodium-sulphur battery monomer in each described insulation Muscovitum sleeve pipe, and described sodium-sulphur battery monomer all includes shell, positive pole Lug and negative lug, described sodium-sulphur battery monomer is connected to become described sodium-sulphur battery group, described sodium sulfur by battery connecting piece Engaged by argon arc welding between positive pole ear and negative lug and the corresponding battery connecting piece of battery cell.
Further, positive pole ear and the negative lug of described sodium-sulphur battery monomer be arranged in parallel.Further, It is disposed with pressure-wire on the positive pole ear of each described sodium-sulphur battery monomer and negative lug.
Further, when the negative pole pole of positive pole ear and adjacent sodium-sulphur battery monomer of any one sodium-sulphur battery monomer When ear is parallel, by the first battery between the positive pole ear of this sodium-sulphur battery monomer and the negative lug of adjacent sodium-sulphur battery monomer Connector connects, and described first battery connecting piece includes that the first positive pole that the positive pole ear with this sodium-sulphur battery monomer engages is connected Part, the first anode connector engaged with the negative lug of adjacent sodium-sulphur battery monomer, and connect described first positive pole connection Part and described first anode connector, the first middleware of level.
Further, when the negative pole pole of positive pole ear and adjacent sodium-sulphur battery monomer of any one sodium-sulphur battery monomer When ear-lobe is straight, by the second battery between the positive pole ear of this sodium-sulphur battery monomer and the negative lug of adjacent sodium-sulphur battery monomer Connector connects, and described second battery connecting piece includes that the second positive pole that the positive pole ear with this sodium-sulphur battery monomer engages is connected Part, the second anode connector engaged with the negative lug of adjacent sodium-sulphur battery monomer, and connect described second positive pole connection Part and described second anode connector, the second middleware of L-shaped.
Further, the outer wall of the shell of each described sodium-sulphur battery monomer is all disposed with temperature sensor.
Further, four perisporiums of described chassis body all have some level troughs arranged in parallel, described lifting Location structure is positioned at the top going up most a described level trough.
Further, be filled with between described insulation Muscovitum sleeve pipe and the radial direction of described sodium-sulphur battery monomer quartz sand or Yellow sand.
Have employed the technical scheme of a kind of sodium-sulphur battery group of the present invention, including the chassis body of upper opening, described frame Being disposed with lifting location structure on the perisporium of frame body, the bottom of described chassis body is provided with one piece of location-plate, described location-plate End face be provided with some locating slots arranged in arrays, each described locating slot is fixed with one insulation Muscovitum sleeve pipe, often Being provided with a sodium-sulphur battery monomer in individual described insulation Muscovitum sleeve pipe, described sodium-sulphur battery monomer all includes shell, positive pole ear And negative lug, described sodium-sulphur battery monomer is connected to become described sodium-sulphur battery group, described sodium-sulphur battery by battery connecting piece Engaged by argon arc welding between positive pole ear and negative lug and the corresponding battery connecting piece of monomer.It has the technical effect that sodium The heating of sodium-sulfur battery module inside and temperature control electronic devices and components will not be caused damage, and working place by the assembling of sulfur set of cells Greatly, being suitable for robot automation's welding, sodium-sulfur battery module assembly line is greatly simplified, and improves production efficiency, reduces Production cost.
Accompanying drawing explanation
Fig. 1 is the structural representation of the chassis body of a kind of sodium-sulphur battery group of the present invention.
Fig. 2 is the structural representation of the location-plate of a kind of sodium-sulphur battery group of the present invention.
Fig. 3 is the structural representation of the insulation Muscovitum sleeve pipe of a kind of sodium-sulphur battery group of the present invention.
Fig. 4 is the structural representation of the sodium-sulphur battery monomer of a kind of sodium-sulphur battery group of the present invention.
Fig. 5 is the structural representation of the first battery connecting piece of a kind of sodium-sulphur battery group of the present invention.
Fig. 6 is the structural representation of the second battery connecting piece of a kind of sodium-sulphur battery group of the present invention.
Fig. 7 is five strings five structural representation of sodium-sulphur battery group embodiment of a kind of sodium-sulphur battery group of the present invention.
Fig. 8 is the structural representation of 25 string sodium-sulphur battery group embodiments of a kind of sodium-sulphur battery group of the present invention.
Fig. 9 is the enlarged diagram of Fig. 8 lower left quarter.
Detailed description of the invention
Refer to Fig. 1 to Fig. 9, the present inventor in order to enable preferably technical scheme to be understood, Below by specifically embodiment, and combine accompanying drawing and be described in detail:
Referring to Fig. 1 and Fig. 2, a kind of sodium-sulphur battery group of the present invention includes the chassis body 11 of upper opening, framework master All have some level troughs 11 arranged in parallel on four perisporiums of body 11, go up most the top of a level trough 11 and be provided with and hang Set bit architecture 12.Lifting location structure 12 be the present invention a kind of sodium-sulphur battery group handling process in the fixing of buckle or hawser Hole.
Chassis body 1 is made up of 6061 aluminium alloys, it is possible to is made up of rustless steel or other high-temperature alloy, can accommodate 25 joints Sodium-sulphur battery monomer 3.
The bottom of chassis body 1 is provided with location-plate 2, the end face of location-plate 2 is evenly equipped with 25 arranged in arrays, The corresponding sodium-sulphur battery monomer 3 of recessed locating slot 21. each locating slot 21.
Referring to Fig. 3 and Fig. 4, each sodium-sulphur battery monomer 3 is respectively positioned in an insulation Muscovitum sleeve pipe 4, and insulate Muscovitum set Pipe 4 is by body 41, and for (not shown) at the bottom of the set of body 41 bottom lock being formed, wherein body 41 is by phlogopite Paper is equipped with the adhesive of correspondence and forms through bonding winding, and quality is hard, is equipped with the adhesive of correspondence at the bottom of described set by phlogopite paper It is laminated.Insulation Muscovitum sleeve pipe 4 has good electrical insulation properties and higher mechanical strength, the height of resistance to more than 1000 DEG C Temperature.Each insulation Muscovitum sleeve pipe 4 correspondence is put in and is placed in a locating slot 21, the internal diameter of locating slot 21 and insulation Muscovitum sleeve pipe 4 External diameter corresponding, it is achieved sodium-sulphur battery monomer 3 positions.
Sodium-sulphur battery monomer 3 is in cylinder, and its external diameter is corresponding with the internal diameter of insulation Muscovitum sleeve pipe 4, sodium-sulphur battery monomer 3 Positive pole ear 31, negative lug 32 and shell 33 are made by 3003 aluminium alloys.Sodium-sulphur battery monomer 3 and corresponding insulation Muscovitum Can filled stone sand, yellow sand or other high-temperature resistant particle between the radial direction of sleeve pipe 4.
In the present embodiment, positive pole ear 31 and the negative lug 32 of sodium-sulphur battery monomer 3 be arranged in parallel.
In the present embodiment, also can be provided with the first battery connecting piece 6 and the second battery connecting piece 7.
First battery connecting piece 6 includes the first positive pole connector 61 and the first anode connector 62, the first positive pole connector 61 and first anode connector 62 be arranged in parallel, the bottom of the first positive pole connector 61 and the end of the first anode connector 62 Level the first middleware 63 it is provided with between end.
Second battery connecting piece 7 includes the second positive pole connector 71 and the second anode connector 72, the second positive pole connector 71 and first anode connector 72 be arranged in a mutually vertical manner, set between the second positive pole connector 71 and the second anode connector 72 There is the second middleware 73 of L-shaped.
The material of the first battery connecting piece 6 and the second battery connecting piece 7 is 1100 aluminium alloys.
When the positive pole ear 31 of any one sodium-sulphur battery monomer 3 is flat with the negative lug 32 of adjacent sodium-sulphur battery monomer 3 During row, connected by the first battery connecting piece 6 between two sodium-sulphur battery monomers 3.As shown in Figure 7.Five sodium-sulphur batteries in Fig. 7 Monomer 3 is connected into one group of sodium-sulphur battery string, and five groups of sodium-sulphur battery connection in series-parallel become sodium-sulphur battery group, i.e. five and five string sodium-sulphur batteries Group.First positive pole connector 61 of the first battery connecting piece 6 and the first anode connector 62 are all by argon arc welding and corresponding sodium sulfur Positive pole ear 31 and the negative lug 32 of battery cell 3 engage.
When the positive pole ear 31 of any one sodium-sulphur battery monomer 3 hangs down with the negative lug 32 of adjacent sodium-sulphur battery monomer 3 Time straight, connected by the second battery connecting piece 7 between two sodium-sulphur battery monomers 3.As shown in Figure 8 and Figure 9.In Fig. 8 and Fig. 9, 25 joint sodium-sulphur battery monomers 3 are concatenated into sodium-sulphur battery group.I.e. 25 string sodium-sulphur battery groups.First battery connecting piece 6 First positive pole connector 61 and the first anode connector 62, the second positive pole connector 71 and second of the second battery connecting piece 7 is negative Pole connector 72 is all engaged with positive pole ear 31 and the negative lug 32 of corresponding sodium-sulphur battery monomer 3 by argon arc welding.
Argon arc welding both can be manual welding, it is also possible to be that robot automation welds.
Described pressure-wire is fixed in positive pole ear 31 and the negative lug 32 of sodium-sulphur battery monomer 3, it is achieved sodium-sulphur battery The voltage of monomer 3 or the monitoring of the voltage of sodium-sulphur battery group.The shell 33 of sodium-sulphur battery monomer 3 is fixed in temperature sensor On outer wall or inside sodium-sulphur battery group, it is achieved for temperature monitoring or the prison of sodium-sulphur battery group temperature field of sodium-sulphur battery monomer 3 Survey.
A kind of sodium-sulphur battery group that the present invention proposes is by chassis body 1, location-plate 2, insulation Muscovitum sleeve pipe 4, sodium-sulphur battery Monomer the 3, first battery connecting piece the 6, second battery connecting piece 7, pressure-wire and temperature sensor composition.This sodium-sulphur battery group is adopted By standardized designs, according to the model of sodium-sulfur battery module, quantity and the connected mode of sodium-sulphur battery monomer 3 can be carried out phase Should adjust, the first battery connecting piece 6 and the second battery connecting piece 7 that aluminium alloy is made, with the argon arc welding of sodium-sulphur battery monomer 3 Joint need not carry out inside sodium-sulfur battery module, sodium-sulphur battery monomer 3, with the first battery connecting piece 6 and the second battery After the welding of connector 7 completes, then sodium-sulphur battery group is lifted into sodium sulfur galvanic battery couveuse, complete the group of sodium-sulfur battery module Dress, will not cause damage, and working place is big, is suitable for machine the heating of sodium-sulfur battery module inside and temperature control electronic devices and components People's automatic welding, sodium-sulfur battery module assembly line is greatly simplified, and improves production efficiency, reduces production cost.
Those of ordinary skill in the art it should be appreciated that above embodiment be intended merely to illustrate the present invention, And be not used as limitation of the invention, the change as long as in the spirit of the present invention, to embodiment described above Change, modification all will fall in the range of claims of the present invention.

Claims (8)

1. a sodium-sulphur battery group, it is characterised in that: include the chassis body of upper opening, cloth on the perisporium of described chassis body Being equipped with lifting location structure, the bottom of described chassis body is provided with one piece of location-plate, and the end face of described location-plate is provided with in square Some locating slots of battle array arrangement, each described locating slot is fixed with an insulation Muscovitum sleeve pipe, each described insulation Muscovitum set Being provided with a sodium-sulphur battery monomer in pipe, described sodium-sulphur battery monomer all includes shell, positive pole ear and negative lug, described sodium Sulfur battery cell is connected to become described sodium-sulphur battery group by battery connecting piece, and the positive pole ear of described sodium-sulphur battery monomer is with negative Engaged by argon arc welding between pole lug and corresponding battery connecting piece.
A kind of sodium-sulphur battery group the most according to claim 1, it is characterised in that: the positive pole ear of described sodium-sulphur battery monomer It is arranged in parallel with negative lug.
A kind of sodium-sulphur battery group the most according to claim 2, it is characterised in that: the positive pole of each described sodium-sulphur battery monomer It is disposed with pressure-wire on lug and negative lug.
A kind of sodium-sulphur battery group the most according to claim 2, it is characterised in that: when any one sodium-sulphur battery monomer just When pole lug is parallel with the negative lug of adjacent sodium-sulphur battery monomer, the positive pole ear of this sodium-sulphur battery monomer and adjacent sodium sulfur electricity Being connected by the first battery connecting piece between the negative lug of pond monomer, described first battery connecting piece includes and this sodium-sulphur battery The first positive pole connector that the positive pole ear of monomer engages, the first negative pole engaged with the negative lug of adjacent sodium-sulphur battery monomer Connector, and connect described first positive pole connector and described first anode connector, the first middleware of level.
A kind of sodium-sulphur battery group the most according to claim 2, it is characterised in that: when any one sodium-sulphur battery monomer just When pole lug is vertical with the negative lug of adjacent sodium-sulphur battery monomer, the positive pole ear of this sodium-sulphur battery monomer and adjacent sodium sulfur electricity Being connected by the second battery connecting piece between the negative lug of pond monomer, described second battery connecting piece includes and this sodium-sulphur battery The second positive pole connector that the positive pole ear of monomer engages, the second negative pole engaged with the negative lug of adjacent sodium-sulphur battery monomer Connector, and connect described second positive pole connector and described second anode connector, the second middleware of L-shaped.
A kind of sodium-sulphur battery group the most according to claim 1, it is characterised in that: the shell of each described sodium-sulphur battery monomer Outer wall on be all disposed with temperature sensor.
A kind of sodium-sulphur battery group the most according to claim 1, it is characterised in that: on four perisporiums of described chassis body all Having some level troughs arranged in parallel, described lifting location structure is positioned at the top going up most a described level trough.
A kind of sodium-sulphur battery group the most according to claim 1, it is characterised in that: described insulation Muscovitum sleeve pipe and described sodium sulfur Quartz sand or yellow sand it is filled with between the radial direction of battery cell.
CN201610681075.XA 2016-08-17 2016-08-17 A kind of sodium-sulphur battery group Active CN106129489B (en)

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CN106129489B CN106129489B (en) 2018-08-10

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102054952A (en) * 2010-12-11 2011-05-11 徐荣辉 Insulation can special for sodium-sulphur battery
CN202268405U (en) * 2010-12-11 2012-06-06 徐荣辉 Insulation can special for sodium-sulphur battery
KR20130074636A (en) * 2011-12-26 2013-07-04 주식회사 포스코 Sodium-sulfur rechargeable battery module
CN104662698A (en) * 2012-10-02 2015-05-27 日本碍子株式会社 Coated cell and module battery

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102054952A (en) * 2010-12-11 2011-05-11 徐荣辉 Insulation can special for sodium-sulphur battery
CN202268405U (en) * 2010-12-11 2012-06-06 徐荣辉 Insulation can special for sodium-sulphur battery
KR20130074636A (en) * 2011-12-26 2013-07-04 주식회사 포스코 Sodium-sulfur rechargeable battery module
CN104662698A (en) * 2012-10-02 2015-05-27 日本碍子株式会社 Coated cell and module battery

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Effective date of registration: 20200903

Address after: Room 1201, no.1346 Gonghe Xin Road, Jing'an District, Shanghai 200070

Patentee after: Shanghai Electric Enterprise Development Co., Ltd

Address before: 201815 Shanghai Jiading District City Jia Zhu Road No. 1997

Patentee before: SHANGHAI ELECTRIC SODIUM SULFUR ENERGY STORAGE TECHNOLOGY Co.,Ltd.