CN106122686A - A kind of vacuum heat insulation materials and core - Google Patents

A kind of vacuum heat insulation materials and core Download PDF

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Publication number
CN106122686A
CN106122686A CN201610784055.5A CN201610784055A CN106122686A CN 106122686 A CN106122686 A CN 106122686A CN 201610784055 A CN201610784055 A CN 201610784055A CN 106122686 A CN106122686 A CN 106122686A
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CN
China
Prior art keywords
core
heat insulation
vacuum heat
insulation materials
fibre
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Pending
Application number
CN201610784055.5A
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Chinese (zh)
Inventor
徐滕州
周介明
陈照峰
周燕清
祝坤
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Suzhou VIP New Material Co Ltd
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Suzhou VIP New Material Co Ltd
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Publication date
Application filed by Suzhou VIP New Material Co Ltd filed Critical Suzhou VIP New Material Co Ltd
Priority to CN201610784055.5A priority Critical patent/CN106122686A/en
Publication of CN106122686A publication Critical patent/CN106122686A/en
Pending legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00Thermal insulation in general
    • F16L59/06Arrangements using an air layer or vacuum
    • F16L59/065Arrangements using an air layer or vacuum using vacuum

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Insulation (AREA)

Abstract

The present invention relates to a kind of vacuum heat insulation materials and be prepared by core, this vacuum heat insulation materials includes core, pressure is applied along being perpendicular to core thickness direction, carry out heated at constant temperature process simultaneously, heating-up temperature is set to 0 DEG C more than 150 DEG C of core pyroplastic deformation temperature, applying pressure is no more than 1 atmospheric pressure, and the time is 1 min 25min.Core is glass fibre, or glass fibre adds one or both the combination in any in ceramic fibre, asbestos fibre, basalt fibre.This preparation technology operability is high, and vacuum heat insulation materials intensity is preferable, excellent thermal insulation performance, can be used in exterior-wall heat insulation for building, the insulation of space shuttle crust or the various fields such as cold preservation, freezing.

Description

A kind of vacuum heat insulation materials and core
Technical field
The present invention relates to a kind of vacuum heat-insulating material core material, particularly relate to a kind of vacuum heat insulation materials.
Background technology
Vacuum heat insulation materials is to be inserted in the Wrapping films with gas barrier property by internal core, subtracts inside The material that pressure, sealing obtain.Common inside core has glass cotton, glass fibre, silicon dioxide fibre, alumina fibre, stone The materials such as cotton, through decompression, the manufacturing procedure of sealing, internal core air factor reduces, and internal gas flow circulates almost not to be had, more preferably Keep the insulation of material, heat-proof quality.
Owing to vacuum heat insulation materials is high-efficiency insulated, heat insulation, electromechanics, oil, chemical industry, building and aviation are widely used in it In space industry.
Japan Patent JP2005/019496A discloses the preparation method of a kind of glass wool formed body, have employed water spray Mode carries out adding hot pressing again, and heating-up temperature is 250 DEG C-450 DEG C.
Japan Patent JP11-506708A discloses and a kind of uses the inorganic viscous of low melt glass component and boric acid etc. Knot agent, coordinates the dissolved element of fiber to obtain vacuum heat insulation materials on the intersection point of the inorfil of internal core.
Domestic patent, mainly by binding agent a small amount of for the inside core surface-coated of vacuum heat insulation materials, common have phenol The inorganic binders such as the organic binder bonds such as urea formaldehyde, epoxy resin, acrylic resin, starch or waterglass, boric acid, colloidal silica Deng.
The use of binding agent improves the operability of glass fibre and the flatness of heat-barrier material, but binding agent is led In cause glass fibre, the vacuum in follow-up work declines, it is impossible to maintain higher heat-proof quality.It addition, only by internal core Inorfil between bonding, the core insufficient strength produced, frangible, be difficult to be inserted in external film.
Although patent disclosed above is from different perspectives, uses different preparation methoies and technology, significantly widened vacuum exhausted The range of hot material.But described vacuum heat insulation materials unresolved how producing possess that intensity is suitable, operability Strong core.Therefore, these problems actually current techniques and the important topic of scientific research personnel how are solved.
Summary of the invention
The purpose of the present invention is intended to overcome the deficiencies in the prior art, it is provided that a kind of vacuum heat insulation materials and core preparation side Method, under particularly connecting fiber in core without any material, improves the heating-up temperature of core, is set to core thermoplasticity More than deformation temperature, add core surfaces planarization, improve the operability of vacuum heat insulation materials processing largely, Thus ensure that the heat-insulating property of excellence, energy-conservation to electromechanics, oil, chemical industry, building and aerospace field is made contributions.
A kind of vacuum heat insulation materials of the present invention is the technical scheme is that for realizing the purpose of the present invention, described Vacuum heat insulation materials includes core, applies pressure along being perpendicular to core thickness direction, carries out heated at constant temperature process, its feature simultaneously Being, heating-up temperature is set to 0 DEG C more than-150 DEG C of core pyroplastic deformation temperature, and applying pressure is no more than 1 air Pressure, the time is 1 min-25min.
Further, described core is glass fibre, or glass fibre adds ceramic fibre, asbestos fibre, basalt One or both combination in any in fiber.
Further, described core there occurs plastic deformation through heating pressurization rear surface few fibers, and along with fibre Dimension fracture, the generation of pulverization situation.
Further, described core thermoplasticity temperature is 500 DEG C, and arranging core heating-up temperature is 500 DEG C-650 DEG C.
A kind of core of above-mentioned vacuum heat insulation materials, it is characterised in that described core sequentially pass through cut, be dried, reduce pressure envelope The operation of dress, prepared vacuum heat insulation materials surface smoothness deviation is less than 2 millimeters.
Above-mentioned vacuum heat insulation materials is for exterior-wall heat insulation for building, the insulation of space shuttle crust or cold preservation, freezing etc. In various fields.
Application effect: the present invention compared with prior art, has the advantage that in (1) core the connection between fiber not Use binding agent, it is possible to make glass fibre closely sealed closely, non-restoring after compression and also in use, eliminate gas in binding agent Produce, keep higher vacuum.
(2) when the present invention breaks that for a long time prepared by core, the conventional setting of heating-up temperature, is disposed at core thermoplastic Property 0 DEG C more than-150 DEG C of deformation temperature so that the few fibers generation local fracture of core surfaces, efflorescence, core surfaces is put down Whole property is improved, for, in the operation of follow-up coating hot-melt adhesive, reducing operation easier so that adds glue amount and is easier to control.
(3) when carrying out extrusion forming, it is provided with suitable force value and the time ensures that the planarization of core, thickness are same Time, shorten the working time, improve production efficiency.
Accompanying drawing explanation
Fig. 1 is vacuum heat insulation materials flow sheet of the present invention
In Fig. 2, (a) (b) is the core of the present invention heating forward and backward internal cross section figure of pressurization
In figure 1, core 2, high-temperature cabinet 3, press 21, core after heating pressurization.
Detailed description of the invention
The vacuum heat insulation materials of the present invention includes internal core and is cladded with thin film, and wherein vacuum heat insulation materials is preferably vacuum Heat-insulating shield, but it is not only limited to the form of sheet material.Core is glass fibre, or glass fibre adds ceramic fibre, asbestos fibre One or both combination in any in dimension, basalt fibre.
Below in conjunction with specific embodiment, it is further elucidated with the present invention, it should be understood that these embodiments are merely to illustrate the present invention Rather than restriction the scope of the present invention, after having read the present invention, the those skilled in the art's various equivalences to the present invention The amendment of form all falls within the application claims and is limited.
Embodiment 1
Core 1 is glass fibre, by press 3 and high-temperature cabinet 2, core 1 is carried out heated at constant temperature and pressurization, and pressurization is along glass Cotton felt thickness direction, wherein pressure is 0.7-0.9 atmospheric pressure, and heating pressing time is 12min.Heating-up temperature is set to core More than pyroplastic deformation temperature 0 DEG C-18 DEG C, preferably core pyroplastic deformation temperature is 500 DEG C, and heating-up temperature is 518 DEG C.Core Through heating pressurization rear surface, few fibers there occurs plastic deformation, and along with fibrous fracture, the generation of efflorescence.Core is successively Through cutting, be dried, reduce pressure the operation of encapsulation, prepared vacuum heat insulation materials surface smoothness deviation is 2 millimeters.
Embodiment 2
Core 1 is glass fibre, by press 3 and high-temperature cabinet 2, core 1 is carried out heated at constant temperature and pressurization, and pressurization is along glass Cotton felt thickness direction, wherein pressure is 0.2-0.5 atmospheric pressure, and heating pressing time is 10min.Heating-up temperature is set to core More than pyroplastic deformation temperature 50 DEG C-80 DEG C, preferably core pyroplastic deformation temperature is 500 DEG C, and heating-up temperature is 580 DEG C of cores Through heating pressurization rear surface, few fibers there occurs plastic deformation, and along with fibrous fracture, the generation of efflorescence.Core is successively Through cutting, be dried, reduce pressure the operation of encapsulation, prepared vacuum heat insulation materials surface smoothness deviation is 2 millimeters.
Embodiment described above, is only presently preferred embodiments of the present invention, and the present invention not makees other form Limiting, any those skilled in the art are changed possibly also with the technology contents of the disclosure above or are modified as equivalent change The Equivalent embodiments changed.In every case being the content without departing from technical solution of the present invention, the technical spirit of the foundation present invention is to above real Execute any type of simple modification, equivalent variations and remodeling that example is made, still fall within the protection domain of technical solution of the present invention.

Claims (5)

1. a vacuum heat insulation materials, described vacuum heat insulation materials includes core, applies pressure along being perpendicular to core thickness direction, Carry out heated at constant temperature process simultaneously, it is characterised in that heating-up temperature be set to core pyroplastic deformation temperature 0 DEG C-150 DEG C with On, apply pressure be no more than 1 atmospheric pressure, heat pressing time be 1 min-25min.
Vacuum heat insulation materials the most according to claim 1, it is characterised in that described core is glass fibre, or glass fibre Add one or both the combination in any in ceramic fibre, asbestos fibre, basalt fibre.
Vacuum heat insulation materials the most according to claim 1 or claim 2, it is characterised in that described core is through heating pressurization rear face portion Fiber is divided to there occurs plastic deformation, and along with fibrous fracture, the generation of efflorescence.
Vacuum heat insulation materials the most according to claim 1 or claim 2, it is characterised in that described core pyroplastic deformation temperature is 500 DEG C, core heating-up temperature is set to 500 DEG C-650 DEG C.
5. one kind by the core of vacuum heat insulation materials according to any one of claim 1-4, it is characterised in that described core is successively Through cutting, be dried, reduce pressure the operation of encapsulation, prepared vacuum heat insulation materials surface smoothness deviation is less than 2 millimeters.
CN201610784055.5A 2016-08-31 2016-08-31 A kind of vacuum heat insulation materials and core Pending CN106122686A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610784055.5A CN106122686A (en) 2016-08-31 2016-08-31 A kind of vacuum heat insulation materials and core

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610784055.5A CN106122686A (en) 2016-08-31 2016-08-31 A kind of vacuum heat insulation materials and core

Publications (1)

Publication Number Publication Date
CN106122686A true CN106122686A (en) 2016-11-16

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108679370A (en) * 2018-08-20 2018-10-19 成都硕屋科技有限公司 A kind of spun-glass insulation felt and preparation method thereof
CN110319304A (en) * 2019-07-27 2019-10-11 芜湖聚创新材料有限责任公司 A kind of vacuum heat insulation materials for heat distribution pipe network system
CN110757903A (en) * 2019-09-23 2020-02-07 苏州市君悦新材料科技股份有限公司 Nano flame-retardant sound-insulation heat-insulation plate for aviation and membrane material
CN111780604A (en) * 2020-06-01 2020-10-16 东南大学 Novel basalt fiber thermal oxidizer heat accumulator
CN112178362A (en) * 2019-10-23 2021-01-05 四川迈科隆真空新材料有限公司 Vacuum insulation panel with double-fiber core material

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US20020179265A1 (en) * 2001-05-29 2002-12-05 Snyder James G. High performance fire-retardant kraft facing for fiberglass insulation
CN1609497A (en) * 2003-10-23 2005-04-27 松下电器产业株式会社 Vacuum heat insulator, and refrigerating apparatus and cooling apparatus using the insulator
CN101287944A (en) * 2005-06-07 2008-10-15 株式会社马格 Process for producing glass wool molding, glass wool molding and vacuum insulation material
CN103542234A (en) * 2012-07-16 2014-01-29 苏州维艾普新材料有限公司 Dry method extra-fine glass wool vacuum insulated panel core material and preparation method thereof
CN104628239A (en) * 2015-02-15 2015-05-20 宣汉正原微玻纤有限公司 Method for preparing vacuum insulated panel (VIP) core material by using dry process
CN105060725A (en) * 2015-08-20 2015-11-18 重庆再升科技股份有限公司 BDF board and manufacturing method and application thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020179265A1 (en) * 2001-05-29 2002-12-05 Snyder James G. High performance fire-retardant kraft facing for fiberglass insulation
CN1609497A (en) * 2003-10-23 2005-04-27 松下电器产业株式会社 Vacuum heat insulator, and refrigerating apparatus and cooling apparatus using the insulator
CN101287944A (en) * 2005-06-07 2008-10-15 株式会社马格 Process for producing glass wool molding, glass wool molding and vacuum insulation material
CN103542234A (en) * 2012-07-16 2014-01-29 苏州维艾普新材料有限公司 Dry method extra-fine glass wool vacuum insulated panel core material and preparation method thereof
CN104628239A (en) * 2015-02-15 2015-05-20 宣汉正原微玻纤有限公司 Method for preparing vacuum insulated panel (VIP) core material by using dry process
CN105060725A (en) * 2015-08-20 2015-11-18 重庆再升科技股份有限公司 BDF board and manufacturing method and application thereof

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* Cited by examiner, † Cited by third party
Title
陈照峰: "《无机非金属材料学(第2版)》", 29 February 2016 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108679370A (en) * 2018-08-20 2018-10-19 成都硕屋科技有限公司 A kind of spun-glass insulation felt and preparation method thereof
CN108679370B (en) * 2018-08-20 2023-09-15 成都硕屋科技有限公司 Glass fiber insulation felt and preparation method thereof
CN110319304A (en) * 2019-07-27 2019-10-11 芜湖聚创新材料有限责任公司 A kind of vacuum heat insulation materials for heat distribution pipe network system
CN110757903A (en) * 2019-09-23 2020-02-07 苏州市君悦新材料科技股份有限公司 Nano flame-retardant sound-insulation heat-insulation plate for aviation and membrane material
CN112178362A (en) * 2019-10-23 2021-01-05 四川迈科隆真空新材料有限公司 Vacuum insulation panel with double-fiber core material
CN111780604A (en) * 2020-06-01 2020-10-16 东南大学 Novel basalt fiber thermal oxidizer heat accumulator
CN111780604B (en) * 2020-06-01 2021-10-29 东南大学 Basalt fiber thermal oxidizer heat accumulator

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