CN101497253A - Metal and non-metal composite board - Google Patents
Metal and non-metal composite board Download PDFInfo
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- CN101497253A CN101497253A CNA2009100028966A CN200910002896A CN101497253A CN 101497253 A CN101497253 A CN 101497253A CN A2009100028966 A CNA2009100028966 A CN A2009100028966A CN 200910002896 A CN200910002896 A CN 200910002896A CN 101497253 A CN101497253 A CN 101497253A
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- film
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- metal decking
- fiber
- glue
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- 239000002184 metal Substances 0.000 title claims abstract description 63
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 63
- 229910052755 nonmetal Inorganic materials 0.000 title abstract 3
- 239000002905 metal composite material Substances 0.000 title 1
- 239000002131 composite material Substances 0.000 claims abstract description 31
- 238000010030 laminating Methods 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 239000011347 resin Substances 0.000 claims abstract description 9
- 238000007731 hot pressing Methods 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 6
- 239000000835 fiber Substances 0.000 claims description 23
- 239000003292 glue Substances 0.000 claims description 21
- 229920000914 Metallic fiber Polymers 0.000 claims description 12
- 238000002360 preparation method Methods 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 11
- 239000011248 coating agent Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 10
- 229910052752 metalloid Inorganic materials 0.000 claims description 10
- 150000002738 metalloids Chemical class 0.000 claims description 10
- 229910000831 Steel Inorganic materials 0.000 claims description 9
- 239000010959 steel Substances 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 239000010410 layer Substances 0.000 claims description 6
- 239000003063 flame retardant Substances 0.000 claims description 5
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 239000003365 glass fiber Substances 0.000 claims description 4
- 229920001568 phenolic resin Polymers 0.000 claims description 4
- 229910001220 stainless steel Inorganic materials 0.000 claims description 4
- 239000010935 stainless steel Substances 0.000 claims description 4
- 239000002344 surface layer Substances 0.000 claims description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 3
- 229920002521 macromolecule Polymers 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 3
- -1 phenolic aldehyde Chemical class 0.000 claims description 3
- 229920000647 polyepoxide Polymers 0.000 claims description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229920000742 Cotton Polymers 0.000 claims description 2
- 239000010425 asbestos Substances 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- 239000011490 mineral wool Substances 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 239000005011 phenolic resin Substances 0.000 claims description 2
- 229910052895 riebeckite Inorganic materials 0.000 claims description 2
- 235000013824 polyphenols Nutrition 0.000 claims 2
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 abstract description 8
- 238000013329 compounding Methods 0.000 abstract 2
- 239000000463 material Substances 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 8
- 239000011521 glass Substances 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
- 238000001723 curing Methods 0.000 description 4
- 230000008602 contraction Effects 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920002522 Wood fibre Polymers 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 150000002118 epoxides Chemical class 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 235000015110 jellies Nutrition 0.000 description 1
- 239000008274 jelly Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 1
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- Laminated Bodies (AREA)
Abstract
The invention relates to a metal and nonmetal composite plate, which is formed by compounding a metal panel, rubber sheets A and rubber sheets B on a hot pressing and laminating machine. The specific surface area of the inner surface of the metal panel is enlarged, and the inner surface is coated with a thin layer of high-performance resin rubber. After being overlapped according to a proper order, the metal panel and the plurality of the rubber sheets A and the rubber sheets B are placed on the hot pressing and laminating machine together, and are once solidified and molded integrally by adopting a proper compounding process. The metal and nonmetal composite plate has the advantages of high cost performance, good temperature toleration, high planeness and wide application field.
Description
Technical field:
The present invention relates to a kind of metal covering composite board sectional material material, refer to the lamination composite board of sheet metal and non-metallic fibers semi-solid preparation film especially.
Background technology:
Existing metal species composite board wide in variety all has different shortcomings.Soft as aluminium-plastic panel board core material matter, plate face intensity is low, easily scratches not anti-accidental impact; The difficult control of " sheet metal and glass cement cloth lamination composite material for decoration " described material of ZL97235972.9, Forming Quality, flatness is on the low side, and price is relatively costly; " sheet metal and non-glass fibre film composite material for decoration " described material of ZL98213436.3, flatness are difficult to guarantee that peel strength is on the low side that prescription is mixed and disorderly, is unfavorable for producing in batches.Apply for a patent 200810074243.4 " metal and metalloid composite panel ", the part description is clear inadequately in the literary composition, and is comprehensive inadequately.
Summary of the invention:
Purpose of the present invention: provide a kind of and be convenient to that suitability for industrialized production, cost are suitable, plate surface evenness height, metal and metalloid composite panel that the compound interface peel strength is high.
Technical scheme of the present invention: adopt physics or chemical method to handle the inner surface of metal decking (or two), behind the purge drying, apply the anti-high performance resin glue of very thin one deck (or glued membrane); Press thermal coefficient of expansion and calculate principle I, II and symmetry principle, calculate A film, the B film quantity selected for use, superimposed in certain sequence; Be placed on the hot pressing laminating machine, adopt suitable hot pressing combination process, the disposable integral curing molding.
Metal decking among the present invention is the thin plate of stainless steel or copper, aluminium, coated steel, coating steel, coating aluminium etc., and thickness is 0.1-2MM.
The metal decking inner surface adopts physics or chemical method to handle, and as mechanical hacking, chemical attack, electrochemical treatments etc., purpose is that the specific area of inner surface is enlarged, and to increase bond area, improves adhesion strength; Purify then, drying.
Glue in the prepreg and metal decking adhesion strength are not fine, metal decking inner surface coating high performance resin glue (or glued membrane) among the present invention, this glue penetration is gone into the metal decking inner surface that has enlarged through the specific area handled in advance, can guarantee high stable adhesion strength.The characteristics of this high performance resin glue (or glued membrane): normal temperature and contact are not generally solidified under the pressure, solidify under higher pressure and temperature, have higher bonding strength, cold and hot stability preferably.Its kind comprises: high performance polyesters glue, polyurethanes glue, epoxies glue, phenolic glue, epoxide modified glue, phenol aldehyde modified glue or the like.
The semi-solid preparation film of the non-metallic fibers among the present invention comprises the film of glass film, chemical fabric film, papery film, diablement fort film, wooden film, other Inorganic Non-metallic Materials.
The used base material of non-metallic fibers prepreg divides two types:
1), have the non-metallic fibers of expansion and contraction property, comprising: paper fiber, cotton fibriia, wood-fibred, asbestos fibre, rock wool fibers or the like are called the A fiber; Semi-solid preparation film with non-metallic fibers of expansion and contraction property is called the A film; The A film is a semi-solid preparation film a kind of, that two kinds or two or more A fiber are made.
2), non-metallic fibers with the cold character that rises of pyrocondensation, comprising: glass fibre, chemical fibre (choosing resistant to elevated temperatures kind among the present invention), carbon fiber, some ceramic fibre or the like are called the B fiber; Semi-solid preparation film with non-metallic fibers of the cold character that rises of pyrocondensation is called the B film; The B film is a semi-solid preparation film a kind of, that two kinds or two or more B fiber are made.
Among the present invention, making the used glue of semi-solid preparation film is macromolecule resin glues such as epoxy resin, phenolic resins, epoxy novolac, phenolic aldehyde butyraldehyde, pollopas, modified epoxy, phenol-formaldehyde resin modified; Maybe can add fire retardant in the glue, maybe can select corresponding flame retardant type macromolecule resin glue for use.
Among the present invention, metal decking can be a panel, also can be two identical panels, also can be two different panels.Divide three kinds of situations, adopt three kinds of different calculating principles (implication of calculating principle sees for details in the specific embodiment), determine film quantity, superimposed order:
1), during a panel, calculate principle I, determine the number of A film, the number of B film according to thermal coefficient of expansion, metal decking, A film, B film is superimposed successively;
2), when two identical panels are done up and down surface layer respectively, with symmetrical staggered layer of metal decking 1, A film and B film, metal decking 2 is superimposed successively;
3), when two different panels are done up and down surface layer respectively, calculate principle II, determine the number of A film, the number of B film according to thermal coefficient of expansion, metal decking 1, A film, B film, metal decking 2 is superimposed successively;
Among the present invention, after the raw material that said method is chosen is superimposed, together be positioned on the hot pressing laminating machine compoundly, technological parameters such as the compound temperature of lamination, pressure, time are determined according to the kind of film, quantity etc.
Among the present invention, metal decking situation no matter, part A film and part B film also can interlock superimposed.
The gross thickness of composite board of the present invention is 0.4-20MM.
Metallic plate outer surface of the present invention can cover the diaphragm that one deck is conveniently thrown off again.
Advantage of the present invention:
1), the metal decorative material with single material compares minimizing metal consumption, material price ratio height.2), with other types combinations or composite material for decoration (as foam sandwich, aluminium-plastic panel etc.) relatively, specific strength height, temperature tolerance are good, application is extensive.3) and ZL97235972.9, and the material among the ZL98213436.3 relatively, flatness height, peel strength height, is fit to suitability for industrialized production.
Description of drawings:
Fig. 1, for coating steel sheet and two kinds of non-metallic fibers films compound before, generalized section when superimposed.Among the figure: 1, diaphragm; 2, coating steel sheet; 3, the metallic plate inner surface of handling; 4, high-performance glued membrane; 5, several papers rubber sheets (A film); 6, several glass films (B film).
Fig. 2 is stainless sheet steel and two kinds of non-metallic fibers films generalized section after compound.Among the figure: 1, diaphragm; 2, stainless steel steel sheet; 3, stainless steel inner surface, high-performance glued membrane, papers rubber sheet (A film) compound interface; 4, papers rubber sheet (A film) cementing layer; 5, A film, B film compound interface; 6, glass film (B film) cementing layer.
The specific embodiment:
We find:
Metal has the phenomenon of expanding with heat and contract with cold, and the thermal coefficient of expansion of metal is lower than general nonmetallic materials.
The fiber of general paper fiber, diablement fort fiber, wood fibre, most of Inorganic Non-metallic Materials has expansion and contraction property; And the fiber of glass/glass fiber, most of chemical fibre, fraction Inorganic Non-metallic Materials has the cold character that rises of pyrocondensation.The different separately characteristic of non-metallic fibers also can correspondingly pass to semi-solid preparation film separately and solidify after finished product.
Various material coefficient of thermal expansion coefficients are inequality, and this has just determined: their random superimposed heating is compound, after the cooling, and vary with temperature in the daily use, and serious out-of-flatness, warping phenomenon can appear in composite board.
So, through complicated calculation of thermodynamics design as can be known: after adopting suitable superimposed order compound according to rational proportion the film of the non-metallic fibers of two class opposite nature, its macroscopic property (as thermal coefficient of expansion) can be near sheet metal in certain temperature range (under-20-50 ℃ of states).
The present invention is exactly in conjunction with above-mentioned principle, solves the difficult problem of the composite board flatness that how to guarantee multiple material.
Concrete calculating principle is as follows:
1), during a metal decking, adopt thermal coefficient of expansion to calculate principle I:
Suppose: the thermal coefficient of expansion a after the A film solidifies, thickness Ha; Thermal coefficient of expansion b after the B film solidifies, thickness Hb; The thermal coefficient of expansion c of metal decking, thickness Hc; Composite board gross thickness H.
Require: composite board keeps smooth, angularity＜3% substantially under-20-50 ℃ normal temperature state.Also promptly require: in the said temperature scope, the thermal coefficient of expansion behind two kinds of film composite curings is near the thermal coefficient of expansion of metal decking.
Step: according to numerical value a, b, c, Hc, H, determine the numerical value of Ha, Hb,, thereby know the number that to select for use separately again by the thickness of sheet film.Metal decking, A film, B film is superimposed successively.
2), during two different metal deckings, adopt thermal coefficient of expansion to calculate principle II:
Suppose: the thermal coefficient of expansion a after the A film solidifies, thickness Ha; Thermal coefficient of expansion b after the B film solidifies, thickness Hb; The thermal coefficient of expansion c1 of metal decking 1, thickness Hc1; The thermal coefficient of expansion c2 of metal decking 2, thickness Hc2; Composite board gross thickness H.
Require: composite board keeps smooth, angularity＜3% substantially under-20-50 ℃ normal temperature state.Also promptly require: in the said temperature scope, the thermal coefficient of expansion behind two kinds of film composite curings can be coordinated with the thermal coefficient of expansion of two metal deckings, guarantees the composite board top and the bottom basically identical that expands with heat and contract with cold.
Step: according to numerical value a, b, c1, c2, Hc1, Hc2, H, determine the numerical relation of Ha, Hb,, know the number that to select for use separately again by the thickness of sheet film.With metal decking 1, A film, B film, metal decking 2 is superimposed successively.
3), during two identical metal deckings, adopt symmetry principle:
Require: with the intermediate layer is benchmark, and the distributing order of two type films can interlock arbitrarily, but will guarantee symmetry up and down, because symmetrical structure can guarantee that generally composite board has flatness preferably.
Step: the quantity of A film and B film can be chosen arbitrarily, and symmetrical staggered layer, the metal decking 2 of metal decking 1, A film and B film is superimposed successively;
Adopt the aforementioned calculation principle to know that the material of following kind, quantity is a kind of proper selection:
As shown in Figure 1, with the coating steel sheet of the thickness inner surface that is 0.3MM through the chemical attack cleaning-drying, high-performance epoxy jelly membrane, 8 on the thick paper flame-proof phenolic aldehyde film (A film) of 0.2MM, 0.18MM 5 on thick glass flame retardant epoxy film (B film) is superimposed successively; Place in the template of laminating machine, according to the hot pressing laminating technology, control uniform temperature, pressure, time, composite curing takes out the back and cuts out the unhairing limit, and diaphragm is covered in the metal surface on laminating machine.
Claims (7)
1, a kind of metal and metalloid composite panel are composited on laminating machine by the semi-solid preparation film of metal decking and non-metallic fibers, it is characterized in that:
The metal decking inner surface makes specific area enlarge through handling;
The high performance resin glue of one deck that the inner surface coating is very thin;
Metal decking is a panel, perhaps two identical panels, perhaps two different panels:
During a panel, calculate principle I, determine the number of A film, the number of B film according to thermal coefficient of expansion, metal decking, A film, B film is superimposed successively;
When two identical panels are done up and down surface layer respectively, that metal decking 1, A film and B film symmetrical staggered layer, metal decking 2 is superimposed successively;
When two different panels are done up and down surface layer respectively, calculate principle II, determine the number of A film, the number of B film according to thermal coefficient of expansion, metal decking 1, A film, B film, metal decking 2 is superimposed successively;
After superimposed, be placed on the hot pressing laminating machine, adopt the hot pressing combination process, the disposable integral curing molding;
The total thickness of composite board is 0.4-20MM.
2, a kind of metal according to claim 1 and metalloid composite panel is characterized in that:
Metal decking is the thin plate of stainless steel or copper, aluminium, coated steel, coating steel, coating aluminium, and thickness is 0.1-2MM.
3, a kind of metal according to claim 1 and metalloid composite panel is characterized in that:
The high performance resin glue of metal decking inner surface coating is modified epoxy or modified phenolic glue.
4, a kind of metal according to claim 1 and metalloid composite panel is characterized in that:
The used A fiber of A film is the paper fiber, perhaps cotton fibriia, wood-fibred, asbestos fibre, rock wool fibers;
The used B fiber of B film is a glass fibre, perhaps resistant to elevated temperatures chemical fibre, carbon fiber, ceramic fibre;
The used glue of two type films is epoxy resin, perhaps phenolic resins, epoxy phenolics, phenolic aldehyde butyral resin, pollopas, modified epoxy, phenol-formaldehyde resin modified;
In the glue or add fire retardant, or directly select corresponding flame retardant type macromolecule resin glue for use.
5, a kind of metal according to claim 1 and metalloid composite panel is characterized in that:
The A film is the semi-solid preparation film of two kinds or two or more different A fiber.
6, a kind of metal according to claim 1 and metalloid composite panel is characterized in that:
The B film is the semi-solid preparation film of two kinds or two or more different B fiber.
7, according to a kind of metal and the metalloid composite panel described in the claim 1 and 5,6, it is characterized in that:
Part A film and part B film are staggered superimposed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200910002896 CN101497253B (en) | 2008-02-02 | 2009-01-23 | Metal and non-metal composite board |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200810074243.4 | 2008-02-02 | ||
| CNA2008100742434A CN101224651A (en) | 2008-02-02 | 2008-02-02 | Sheet metal and non-metal fiber film compound material |
| CN 200910002896 CN101497253B (en) | 2008-02-02 | 2009-01-23 | Metal and non-metal composite board |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101497253A true CN101497253A (en) | 2009-08-05 |
| CN101497253B CN101497253B (en) | 2013-06-05 |
Family
ID=39856958
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008100742434A Pending CN101224651A (en) | 2008-02-02 | 2008-02-02 | Sheet metal and non-metal fiber film compound material |
| CN 200910002896 Expired - Fee Related CN101497253B (en) | 2008-02-02 | 2009-01-23 | Metal and non-metal composite board |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2008100742434A Pending CN101224651A (en) | 2008-02-02 | 2008-02-02 | Sheet metal and non-metal fiber film compound material |
Country Status (1)
| Country | Link |
|---|---|
| CN (2) | CN101224651A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102776478A (en) * | 2012-08-10 | 2012-11-14 | 昆山乔锐金属制品有限公司 | Metal composite coating with ceramic serving as basic body |
| CN102886935A (en) * | 2011-07-21 | 2013-01-23 | 联想(北京)有限公司 | Composite material and preparation method thereof and electronic device with composite material |
| CN103585957A (en) * | 2013-11-26 | 2014-02-19 | 洛阳天宝环保科技有限公司 | Active carbon fiber and metal substrate compounded adsorbing material and production method thereof |
| CN110077042A (en) * | 2019-05-08 | 2019-08-02 | 浙江可信竹木有限公司 | A kind of highly resistance using flexible compound adhesive covers diaphragm plate and its production technology |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101224651A (en) * | 2008-02-02 | 2008-07-23 | 徐跃 | Sheet metal and non-metal fiber film compound material |
| CN102367689A (en) * | 2011-10-11 | 2012-03-07 | 常熟市华夏建筑节能材料有限公司 | Fireproof phenolic aldehyde board |
| CN102582206A (en) * | 2012-02-28 | 2012-07-18 | 苏州东亚欣业节能照明有限公司 | Preparation method of copper-clad plate made from nano composite plastic |
| CN103302711B (en) * | 2013-05-31 | 2015-06-03 | 中南林业科技大学 | Method for manufacturing heavy bridge panel |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4514450A (en) * | 1983-11-01 | 1985-04-30 | Union Carbide Corporation | Peg supported thermal insulation panel |
| CN2340627Y (en) * | 1997-05-06 | 1999-09-29 | 徐跃 | Composite decorative materials with thin metal sheet and glass fabric laminating structure |
| CN2369857Y (en) * | 1998-02-25 | 2000-03-22 | 徐跃 | Metal thin plate and non-glass fibre film composite decorative material |
| CN201064960Y (en) * | 2006-11-21 | 2008-05-28 | 王春鸣 | Metallic and non-metallic article composite artificial board |
| CN101224651A (en) * | 2008-02-02 | 2008-07-23 | 徐跃 | Sheet metal and non-metal fiber film compound material |
-
2008
- 2008-02-02 CN CNA2008100742434A patent/CN101224651A/en active Pending
-
2009
- 2009-01-23 CN CN 200910002896 patent/CN101497253B/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102886935A (en) * | 2011-07-21 | 2013-01-23 | 联想(北京)有限公司 | Composite material and preparation method thereof and electronic device with composite material |
| CN102886935B (en) * | 2011-07-21 | 2015-07-29 | 联想(北京)有限公司 | A kind of composite, its preparation method and there is the electronic equipment of this composite |
| CN102776478A (en) * | 2012-08-10 | 2012-11-14 | 昆山乔锐金属制品有限公司 | Metal composite coating with ceramic serving as basic body |
| CN103585957A (en) * | 2013-11-26 | 2014-02-19 | 洛阳天宝环保科技有限公司 | Active carbon fiber and metal substrate compounded adsorbing material and production method thereof |
| CN103585957B (en) * | 2013-11-26 | 2016-01-20 | 洛阳天宝环保科技有限公司 | Sorbing material of a kind of activated carbon fiber and metal substrate compound and preparation method thereof |
| CN110077042A (en) * | 2019-05-08 | 2019-08-02 | 浙江可信竹木有限公司 | A kind of highly resistance using flexible compound adhesive covers diaphragm plate and its production technology |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101497253B (en) | 2013-06-05 |
| CN101224651A (en) | 2008-07-23 |
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