CN106120340A - A kind of cotton anti-corrosive pulp containing nm-class boron nitride of flame-proof antibiotic - Google Patents
A kind of cotton anti-corrosive pulp containing nm-class boron nitride of flame-proof antibiotic Download PDFInfo
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- CN106120340A CN106120340A CN201610475552.7A CN201610475552A CN106120340A CN 106120340 A CN106120340 A CN 106120340A CN 201610475552 A CN201610475552 A CN 201610475552A CN 106120340 A CN106120340 A CN 106120340A
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- boron nitride
- minute
- stirring
- cotton
- flame
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- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 229920000742 Cotton Polymers 0.000 title claims abstract description 27
- 229910052582 BN Inorganic materials 0.000 title claims abstract description 25
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 16
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229960000935 dehydrated alcohol Drugs 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 10
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 8
- 239000002135 nanosheet Substances 0.000 claims abstract description 8
- -1 polyoxyethylene Polymers 0.000 claims abstract description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 7
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 7
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims abstract description 7
- 239000003921 oil Substances 0.000 claims abstract description 7
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 7
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 claims abstract description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000839 emulsion Substances 0.000 claims abstract description 5
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 5
- 239000010703 silicon Substances 0.000 claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 32
- 239000002002 slurry Substances 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 229920002125 Sokalan® Polymers 0.000 claims description 5
- 239000004584 polyacrylic acid Substances 0.000 claims description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 230000033228 biological regulation Effects 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000000376 reactant Substances 0.000 claims description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims 1
- 229920000056 polyoxyethylene ether Polymers 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 4
- 230000002421 anti-septic effect Effects 0.000 abstract description 4
- 239000003063 flame retardant Substances 0.000 abstract description 3
- 230000000149 penetrating effect Effects 0.000 abstract description 3
- 241000219146 Gossypium Species 0.000 description 19
- 239000000463 material Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/80—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
- D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses the cotton anti-corrosive pulp containing nm-class boron nitride of a kind of flame-proof antibiotic, it is made up of the raw material of following weight portion: boron nitride nanosheet 56, 18-amine. 78, dehydrated alcohol is appropriate, dodecylbenzene sodium sulfonate 2.5 3, alkylphenol polyoxyethylene 0.8 1, Ammonium persulfate. 0.5 0.55, acrylic acid 20 22, ethyl acrylate 50 53, methyl methacrylate 28 30, volution phosphinylidyne imidazate 78, phosphoric acid 0.5 0.6, pure water is appropriate, hydroxy terminated fluorosilicone oil 1 1.2, organic silicon emulsion 67, penetrating agent JFC 2 2.5, nano zine oxide 45, polyvinyl alcohol 23.The product treatment cotton made by the present invention, not only antiseptic property is excellent, and fire-retardant, antibacterial, resistance to water, free from extraneous odour, technique is easy to Industry Control, is worthy to be popularized.
Description
Technical field
The present invention relates to textile technology field, particularly relate to the slurry of the cotton anticorrosion containing nm-class boron nitride of a kind of flame-proof antibiotic
Material.
Background technology
Cotton have wear soft comfortable, warming, moisture absorption, breathability is strong, be prone to the features such as dyeing and finishing processing, due to it this
A little natural characteristics, are liked by people already, become indispensable basic articles for use in life.Cotton is in people's daily life
Necessary, the aspect such as it is taken in the dress of people, bedding, indoor article, interior decoration has purposes widely,
Additionally also it is widely used at packaging, the aspect such as industrial, medical, military.But cotton deficiency the most acidproof, elastic, easily rises
Wrinkle, easy moldy metamorphism, cotton often runs into antiseptical problem after making ready-made clothes, and this is accomplished by many cottons and carries out preservative treatment,
But time traditional preservative not only affect the chemical characteristic of linen-cotton, also affect the naturality of garment products simultaneously, and have tight
The abnormal flavour of weight.In patent documentation " a kind of for linen-cotton antiseptical environment protection additive ", utilize the Cortex Eucommiae, Herba thymi vulgaris, meson etc.
The additive that composition is made is in the making of linen-cotton, although solve the question-and-answer problems such as the abnormal flavour of anticorrosive additive, environmental protection, but
Owing to being the effective ingredient using plant, inherently antiseptic effect is had a greatly reduced quality after repeatedly washing.For this problem,
It is accomplished by developing a kind of impregnating fluid processing cotton, not only there is safe antiseptic property, simultaneously can be antibacterial, crease-resistant etc..
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of flame-proof antibiotic containing nm-class boron nitride
Cotton anti-corrosive pulp.
The present invention is achieved by the following technical solutions:
The cotton anti-corrosive pulp containing nm-class boron nitride of a kind of flame-proof antibiotic, is made up of the raw material of following weight portion: nitridation
Boron nanometer sheet 5-6,18-amine. 7-8, dehydrated alcohol are appropriate, dodecylbenzene sodium sulfonate 2.5-3, alkylphenol polyoxyethylene 0.8-
1, Ammonium persulfate. 0.5-0.55, acrylic acid 20-22, ethyl acrylate 50-53, methyl methacrylate 28-30, volution phosphinylidyne miaow
Azoles ester 7-8, phosphoric acid 0.5-0.6, pure water are appropriate, hydroxy terminated fluorosilicone oil 1-1.2, organic silicon emulsion 6-7, penetrating agent JFC 2-2.5, receive
Rice zinc oxide 4-5, polyvinyl alcohol 2-3.
The cotton anti-corrosive pulp containing nm-class boron nitride of described a kind of flame-proof antibiotic, is made up of step in detail below:
(1) mix with 18-amine. after boron nitride nanosheet being vacuum dried 3-4 hour at 80-90 DEG C, under nitrogen protection,
Stir process 2-3 hour under the oil bath of 170-180 DEG C, is subsequently adding the dehydrated alcohol of reactant 2-2.5 times amount, after stirring
Supersound process 30-40 minute, continues to be heated to 80-90 DEG C, evaporates dehydrated alcohol, continues to be heated to 170-180 DEG C, and stirring is anti-
It is cooled to room temperature after answering 24 hours, filters to isolate solid particle, rinse 2-3 time with dehydrated alcohol, be finally putting into vacuum drying oven
In, it is dried to constant weight at 80-90 DEG C, obtains surface modification boron nitride；
(2) being mixed homogeneously with alkylphenol polyoxyethylene by dodecylbenzene sodium sulfonate, be divided into two parts, a copy of it is dissolved in 10-
In the pure water of 12 times amount, the modified boron nitride made with step (1) after stirring mixes, and stirs 30-40 minute and forms dispersion
Liquid is stand-by；Another part mixes with acrylic acid, ethyl acrylate, methyl methacrylate, stirs with the speed of 150-200 rev/min
Add above-mentioned dispersion liquid after 20-30 minute, after continuing stirring 10-15 minute, be slowly added dropwise Ammonium persulfate., completion of dropwise addition post-heating
To 80-85 DEG C and isothermal reaction 90-120 minute, being cooled to room temperature, regulation pH, to neutral, obtains nano silicon nitride boron modification poly-third
Olefin(e) acid slurry；
(3) by adding the pure water of 20-30 times amount in polyvinyl alcohol, being heated to 90-100 DEG C, stirring, to being completely dissolved, is subsequently adding
Volution phosphinylidyne imidazate, phosphoric acid, add the nanometer that step (2) obtains with the speed of 150-200 rev/min after stirring 15-20 minute
Boron nitride modified polyacrylic acid slurry, after continuing stirring 60-90 minute, adds remaining residual components, raise speed to 300-400 turn/
Divide stirring 10-12 minute and get final product.
The invention have the advantage that boron nitride nanosheet is carried out surface modification by a series of technique and adds to by the present invention
In the preparation of polyacrylic acid size, improve boron nitride nanosheet dispersibility in polyacrylic acid size, improve boron nitride
Nanometer sheet and the compatibility of slurry, improve the high-temperature stability of slurry, corrosion resistance, it is possible to reduces heat and glues phenomenon again；Well
Greasy property, be conducive to protect serous coat integrity, and contribute to increase serous coat obdurability；Anticorrosion of the present invention is utilized to starch
Cotton after material processes not only has good decay resistance, simultaneously cloth good hand touch, resistance to water.
The present invention also with the addition of volution phosphinylidyne imidazate, phosphoric acid, synergism in preparation process, it is possible to is processing cotton
It expand into charcoal when surface is heated, form protective layer, stop heat inwardly to transmit, reduce the thermal decomposition rate of material, reduce flammable
The release of property material, thus reach fire-retardant purpose；Add nano zine oxide and organic silicon emulsion complex role, slurry can be significantly improved
The multiple performance such as antibacterial, washable of material；The product treatment cotton made by the present invention, not only antiseptic property is excellent, and fire-retardant,
Antibacterial, resistance to water, free from extraneous odour, technique is easy to Industry Control, is worthy to be popularized.
Detailed description of the invention
The cotton anti-corrosive pulp containing nm-class boron nitride of a kind of flame-proof antibiotic, is prepared by the raw material of following weight portion (kilogram)
Make: boron nitride nanosheet 5,18-amine. 7, dehydrated alcohol are appropriate, dodecylbenzene sodium sulfonate 2.5, alkylphenol polyoxyethylene
0.8, Ammonium persulfate. 0.5, acrylic acid 20, ethyl acrylate 50, methyl methacrylate 28, volution phosphinylidyne imidazate 7, phosphoric acid
0.5, pure water is appropriate, hydroxy terminated fluorosilicone oil 1, organic silicon emulsion 6, penetrating agent JFC 2, nano zine oxide 4, polyvinyl alcohol 2.
The cotton anti-corrosive pulp containing nm-class boron nitride of described a kind of flame-proof antibiotic, is made up of step in detail below:
(1) mix with 18-amine. after boron nitride nanosheet being vacuum dried 3 hours at 80 DEG C, under nitrogen protection, 170 DEG C
Stir process 2 hours under oil bath, are subsequently adding the dehydrated alcohol of reactant 2 times amount, and after stirring, supersound process 30 minutes, continue
Continuing and be heated to 80 DEG C, evaporate dehydrated alcohol, continue to be heated to 170 DEG C, stirring reaction was cooled to room temperature after 24 hours, filters and divides
Separate out solid particle, rinse 2 times with dehydrated alcohol, be finally putting in vacuum drying oven, be dried to constant weight at 80 DEG C, obtain surface
Modified boron nitride；
(2) being mixed homogeneously with alkylphenol polyoxyethylene by dodecylbenzene sodium sulfonate, be divided into two parts, a copy of it is dissolved in 10 times
In the pure water of amount, the modified boron nitride made with step (1) after stirring mixes, and stirs 30 minutes formation dispersion liquids stand-by；
Another part mixes with acrylic acid, ethyl acrylate, methyl methacrylate, adds after stirring 20 minutes with the speed of 150 revs/min
Above-mentioned dispersion liquid, is slowly added dropwise Ammonium persulfate. after continuing stirring 10 minutes, completion of dropwise addition post-heating to 80 DEG C isothermal reaction 90
Minute, it being cooled to room temperature, regulation pH, to neutral, obtains nm-class boron nitride modified polyacrylic acid slurry；
(3) will add the pure water of 20 times amount in polyvinyl alcohol, be heated to 90 DEG C, stirring, to being completely dissolved, is subsequently adding volution phosphorus
Acyl imidazate, phosphoric acid, add the nano silicon nitride boron modification poly-third that step (2) obtains with the speed of 150 revs/min after stirring 15 minutes
Olefin(e) acid slurry, after continuing stirring 60 minutes, adds remaining residual components, raises speed to 300 revs/min and stirs 10 minutes and get final product.
Utilize product of the present invention that cotton is processed, use two leachings two to roll (pick-up 80%), the mode dried, warp
Cotton after measurement processing is dry/and hygrometric state creasy recovery angle promoted, and soft, breaking strength retention warp-wise is
83.8%, broadwise is 84.1%, and Tear strength retention rate warp-wise is 86.2%, and broadwise is 88.4%, hence it is evident that be better than untreated cotton.
Claims (2)
1. the cotton anti-corrosive pulp containing nm-class boron nitride of a flame-proof antibiotic, it is characterised in that by the raw material of following weight portion
Preparation is made: boron nitride nanosheet 5-6,18-amine. 7-8, dehydrated alcohol are appropriate, dodecylbenzene sodium sulfonate 2.5-3, alkyl phenol
Polyoxyethylene ether 0.8-1, Ammonium persulfate. 0.5-0.55, acrylic acid 20-22, ethyl acrylate 50-53, methyl methacrylate
28-30, volution phosphinylidyne imidazate 7-8, phosphoric acid 0.5-0.6, pure water are appropriate, hydroxy terminated fluorosilicone oil 1-1.2, organic silicon emulsion 6-7, ooze
Agent JFC2-2.5, nano zine oxide 4-5, polyvinyl alcohol 2-3 thoroughly.
A kind of cotton anti-corrosive pulp containing nm-class boron nitride of flame-proof antibiotic, it is characterised in that by
Step is made in detail below:
(1) mix with 18-amine. after boron nitride nanosheet being vacuum dried 3-4 hour at 80-90 DEG C, under nitrogen protection,
Stir process 2-3 hour under the oil bath of 170-180 DEG C, is subsequently adding the dehydrated alcohol of reactant 2-2.5 times amount, after stirring
Supersound process 30-40 minute, continues to be heated to 80-90 DEG C, evaporates dehydrated alcohol, continues to be heated to 170-180 DEG C, and stirring is anti-
It is cooled to room temperature after answering 24 hours, filters to isolate solid particle, rinse 2-3 time with dehydrated alcohol, be finally putting into vacuum drying oven
In, it is dried to constant weight at 80-90 DEG C, obtains surface modification boron nitride；
(2) being mixed homogeneously with alkylphenol polyoxyethylene by dodecylbenzene sodium sulfonate, be divided into two parts, a copy of it is dissolved in 10-
In the pure water of 12 times amount, the modified boron nitride made with step (1) after stirring mixes, and stirs 30-40 minute and forms dispersion
Liquid is stand-by；Another part mixes with acrylic acid, ethyl acrylate, methyl methacrylate, stirs with the speed of 150-200 rev/min
Add above-mentioned dispersion liquid after 20-30 minute, after continuing stirring 10-15 minute, be slowly added dropwise Ammonium persulfate., completion of dropwise addition post-heating
To 80-85 DEG C and isothermal reaction 90-120 minute, being cooled to room temperature, regulation pH, to neutral, obtains nano silicon nitride boron modification poly-third
Olefin(e) acid slurry；
(3) by adding the pure water of 20-30 times amount in polyvinyl alcohol, being heated to 90-100 DEG C, stirring, to being completely dissolved, is subsequently adding
Volution phosphinylidyne imidazate, phosphoric acid, add the nanometer that step (2) obtains with the speed of 150-200 rev/min after stirring 15-20 minute
Boron nitride modified polyacrylic acid slurry, after continuing stirring 60-90 minute, adds remaining residual components, raise speed to 300-400 turn/
Divide stirring 10-12 minute and get final product.
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| CN201610475552.7A CN106120340A (en) | 2016-06-27 | 2016-06-27 | A kind of cotton anti-corrosive pulp containing nm-class boron nitride of flame-proof antibiotic |
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| CN201610475552.7A CN106120340A (en) | 2016-06-27 | 2016-06-27 | A kind of cotton anti-corrosive pulp containing nm-class boron nitride of flame-proof antibiotic |
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| CN115538166A (en) * | 2022-11-01 | 2022-12-30 | 上海题桥江苏纺织科技有限公司 | Preparation method of wear-resistant, washable and corrosion-resistant self-repairing hydrophobic cotton fabric |
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| CN109338762A (en) * | 2018-08-28 | 2019-02-15 | 苏州印丝特纺织数码科技有限公司 | A kind of preparation method of the digit printing ink modified based on boron nitride nanosheet |
| CN109652984A (en) * | 2018-12-12 | 2019-04-19 | 上海雅运新材料有限公司 | A kind of fabrics flame resistance coating finishing agent composition and preparation method thereof |
| CN109652984B (en) * | 2018-12-12 | 2021-07-20 | 太仓宝霓实业有限公司 | Fabric flame-retardant coating finishing agent composition and preparation method thereof |
| CN115538166A (en) * | 2022-11-01 | 2022-12-30 | 上海题桥江苏纺织科技有限公司 | Preparation method of wear-resistant, washable and corrosion-resistant self-repairing hydrophobic cotton fabric |
| CN115538166B (en) * | 2022-11-01 | 2024-01-30 | 上海题桥江苏纺织科技有限公司 | Preparation method of wear-resistant, wash-resistant and corrosion-resistant self-repairing hydrophobic cotton fabric |
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