CN106119644A - Preferable medical magnesium base alloy material of biocompatibility and preparation method thereof - Google Patents
Preferable medical magnesium base alloy material of biocompatibility and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C23/00—Alloys based on magnesium
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L27/00—Materials for grafts or prostheses or for coating grafts or prostheses
- A61L27/02—Inorganic materials
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- A61L27/047—Other specific metals or alloys not covered by A61L27/042 - A61L27/045 or A61L27/06
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/02—Inorganic materials
- A61L31/022—Metals or alloys
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L31/00—Materials for other surgical articles, e.g. stents, stent-grafts, shunts, surgical drapes, guide wires, materials for adhesion prevention, occluding devices, surgical gloves, tissue fixation devices
- A61L31/14—Materials characterised by their function or physical properties, e.g. injectable or lubricating compositions, shape-memory materials, surface modified materials
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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Abstract
The invention belongs to medical alloy Material Field, relate to a kind of preferable medical magnesium base alloy material of biocompatibility and preparation method thereof, described medical magnesium base alloy material includes that Ti, W, V, Ni, Cr, Ag, Sc, Nb, surplus are Mg.Preparation method comprises the following steps (1) and takes metal powder material, high speed machine mix homogeneously respectively;(2) throw to by high-temperature vacuum smelting furnace, vacuum melting in-furnace temperature is risen to 660 700 DEG C from room temperature, melting 2h after temperature stabilization;(3) Raise vacuum melting in-furnace temperature is 940 970 DEG C, molten 3h after temperature stabilization;(4) Raise vacuum melting in-furnace temperature is 1,135 1175 DEG C, melting 3h after temperature stabilization;(5) reducing vacuum melting in-furnace temperature is 550 580 DEG C, is incubated 2h;(6) again vacuum melting in-furnace temperature is down to room temperature, for medical magnesium base alloy material.
Description
Technical field
The invention belongs to medical alloy Material Field, relate to a kind of magnesium base alloy material and preparation method thereof, particularly relate to
And a kind of medical magnesium base alloy material and preparation method thereof.
Background technology
The medical metal material of clinical practice at present mainly has rustless steel, cobalt-base alloys, titanium alloy, medical noble metal, doctor
With marmem, simple metal tantalum, niobium, zirconium etc..In recent years, along with processing method, process for treating surface etc. development with become
Ripe, can be greatly improved in terms of mechanical property improving corrosion resistance of magnesium alloy, researcher starts to carry out further magnesium
And magnesium alloy is as the research of Srgery grafting material.It is currently being developed to the porous bio-ceramic of hard tissue engineering support at present and has gathered
Polymer scaffold grows in can promoting sclerotin and being organized in its hole, makes damage comparatively fast recover, but poor mechanical property.Therefore, development
New bone tissue engineering stent material, needs it should have good mechanical property, have again be similar to bone loose structure and
Biodegradable properties.Recent studies have indicated that, the performance of magnesium substantially conforms to the requirement of osseous tissue engineering stephanoporate support, the most relatively low
Elastic modelling quantity and suitable intensity, good biocompatibility, biodegradable and absorbability etc..Therefore magnesium and magnesium alloy
Have ready conditions and become the engineering scaffold material of a kind of preferable replacement osseous tissue.
Summary of the invention
Solve the technical problem that: magnesium base alloy material has more application at biomedical sector, when magnesium base alloy material
Material when being used for fixing material, needs have more excellent hardness, hot strength and comprcssive strength, also needs to have good simultaneously
Biocompatibility, it is therefore desirable to improve the mechanical strength of magnesium base alloy material, improves magnesium base alloy material further and cures at biology
Range of application in field.
Technical scheme: in order to solve the problems referred to above, the invention discloses a kind of medical magnesium base alloy material and preparation side thereof
Method, described medical magnesium base alloy gold copper-base alloy includes following composition by weight:
Ti 3.2wt%-5.6wt%、
W 0.3wt%-0.8wt%、
V 0.2wt%-0.7wt%、
Ni 1.2wt%-3.4wt%、
Cr 0.3wt%-1.1wt%、
Ag 0.2wt%-0.6wt%、
Sc 0.3wt%-0.8wt%、
Nb 0.2wt%-0.8wt%、
Surplus is Mg.
Further, the medical magnesium base alloy material of described one, include following composition by weight:
Ti 3.8wt%-5.2wt%、
W 0.4wt%-0.7wt%、
V 0.3wt%-0.6wt%、
Ni 1.6wt%-3.0wt%、
Cr 0.5wt%-0.9wt%、
Ag 0.3wt%-0.5wt%、
Sc 0.4wt%-0.7wt%、
Nb 0.3wt%-0.7wt%、
Surplus is Mg.
Further, the medical magnesium base alloy material of described one, include following composition by weight:
Ti 4.5wt%、
W 0.6wt%、
V 0.4wt%、
Ni 2.3wt%、
Cr 0.7wt%、
Ag 0.4wt%、
Sc 0.6wt%、
Nb 0.5wt%、
Surplus is Mg.
The preparation method of a kind of medical magnesium base alloy material, comprises the following steps:
(1) take respectively metal powder material, by weight percentage take Ti be 3.2wt%-5.6wt%, W be that 0.3wt%-0.8wt%, V are
0.2wt%-0.7wt%, Ni be 1.2wt%-3.4wt%, Cr be 0.3wt%-1.1wt%, Ag be that 0.2wt%-0.6wt%, Sc are
0.3wt%-0.8wt%, Nb are 0.2wt%-0.8wt%, surplus is Mg, by above-mentioned metal powder material high-speed mixer machinery
Mixing, mixing is to metal dust mix homogeneously;
(2) after mix homogeneously, metal powder material being thrown to by high-temperature vacuum smelting furnace, in vacuum melting furnace, pressure is 100-
500Pa, rises to 660-700 DEG C by vacuum melting in-furnace temperature from room temperature, melting 2h after temperature stabilization;
(3) Raise vacuum melting in-furnace temperature is 940-970 DEG C, molten 3h after temperature stabilization;
(4) Raise vacuum melting in-furnace temperature is 1135-1175 DEG C, melting 3h after temperature stabilization;
(5) reduce vacuum melting in-furnace temperature and be 550-580 DEG C, be incubated 2h;
(6) again vacuum melting in-furnace temperature is down to room temperature, for medical magnesium base alloy material.
Preferably, the preparation method of described a kind of medical magnesium base alloy material, pressure in vacuum melting furnace in step (2)
For 300Pa.
Preferably, the preparation method of described a kind of medical magnesium base alloy material, by temperature in vacuum melting furnace in step (2)
Degree rises to 680 DEG C from room temperature.
Preferably, the preparation method of described a kind of medical magnesium base alloy material, in step (3) in Raise vacuum smelting furnace
Temperature is 955 DEG C.
Preferably, the preparation method of described a kind of medical magnesium base alloy material, in step (4) in Raise vacuum smelting furnace
Temperature is 1155 DEG C.
Preferably, the preparation method of described a kind of medical magnesium base alloy material, reduces in vacuum melting furnace in step (5)
Temperature is 570 DEG C.
Beneficial effect: the medical magnesium base alloy material of the present invention belongs to biomedical sector, the stretching prominent due to it is strong
Degree, hardness and comprcssive strength, it is adaptable to preparation medical science fixes the materials such as material.And in use there is good bio-compatible
Property, have no side effect.The magnesium base alloy material of the present invention is by its preparation technology and elementary composition optimization, prepared magnesium base alloy
Material has excellent performance.
Detailed description of the invention
Embodiment 1
(1) take respectively metal powder material, by weight percentage take Ti be 5.6wt%, W be 0.3wt%, V be that 0.2wt%, Ni are
3.4wt%, Cr be 1.1wt%, Ag be 0.2wt%, Sc be 0.8wt%, Nb be 0.8wt%, surplus be Mg, by above-mentioned metal dust
Material high-speed mixer mechanical mixture, mixing is to metal dust mix homogeneously;
(2) after mix homogeneously, metal powder material being thrown to by high-temperature vacuum smelting furnace, in vacuum melting furnace, pressure is
500Pa, rises to 700 DEG C by vacuum melting in-furnace temperature from room temperature, melting 2h after temperature stabilization;
(3) Raise vacuum melting in-furnace temperature is 940 DEG C, molten 3h after temperature stabilization;
(4) Raise vacuum melting in-furnace temperature is 1175 DEG C, melting 3h after temperature stabilization;
(5) reducing vacuum melting in-furnace temperature is 580 DEG C, is incubated 2h;
(6) again vacuum melting in-furnace temperature is down to room temperature, for medical magnesium base alloy material.
Embodiment 2
(1) take respectively metal powder material, by weight percentage take Ti be 3.2wt%, W be 0.8wt%, V be that 0.7wt%, Ni are
1.2wt%, Cr be 0.3wt%, Ag be 0.6wt%, Sc be 0.3wt%, Nb be 0.2wt%, surplus be Mg, by above-mentioned metal dust
Material high-speed mixer mechanical mixture, mixing is to metal dust mix homogeneously;
(2) after mix homogeneously, metal powder material being thrown to by high-temperature vacuum smelting furnace, in vacuum melting furnace, pressure is
100Pa, rises to 660 DEG C by vacuum melting in-furnace temperature from room temperature, melting 2h after temperature stabilization;
(3) Raise vacuum melting in-furnace temperature is 970 DEG C, molten 3h after temperature stabilization;
(4) Raise vacuum melting in-furnace temperature is 1135 DEG C, melting 3h after temperature stabilization;
(5) reducing vacuum melting in-furnace temperature is 550 DEG C, is incubated 2h;
(6) again vacuum melting in-furnace temperature is down to room temperature, for medical magnesium base alloy material.
Embodiment 3
(1) take respectively metal powder material, by weight percentage take Ti be 5.2wt%, W be 0.7wt%, V be that 0.3wt%, Ni are
3.0wt%, Cr be 0.5wt%, Ag be 0.5wt%, Sc be 0.7wt%, Nb be 0.3wt%, surplus be Mg, by above-mentioned metal dust
Material high-speed mixer mechanical mixture, mixing is to metal dust mix homogeneously;
(2) after mix homogeneously, metal powder material being thrown to by high-temperature vacuum smelting furnace, in vacuum melting furnace, pressure is
500Pa, rises to 700 DEG C by vacuum melting in-furnace temperature from room temperature, melting 2h after temperature stabilization;
(3) Raise vacuum melting in-furnace temperature is 940 DEG C, molten 3h after temperature stabilization;
(4) Raise vacuum melting in-furnace temperature is 1175 DEG C, melting 3h after temperature stabilization;
(5) reducing vacuum melting in-furnace temperature is 580 DEG C, is incubated 2h;
(6) again vacuum melting in-furnace temperature is down to room temperature, for medical magnesium base alloy material.
Embodiment 4
(1) take respectively metal powder material, by weight percentage take Ti be 3.8wt%, W be 0.4wt%, V be that 0.6wt%, Ni are
1.6wt%, Cr be 0.9wt%, Ag be 0.3wt%, Sc be 0.4wt%, Nb be 0.7wt%, surplus be Mg, by above-mentioned metal dust
Material high-speed mixer mechanical mixture, mixing is to metal dust mix homogeneously;
(2) after mix homogeneously, metal powder material being thrown to by high-temperature vacuum smelting furnace, in vacuum melting furnace, pressure is
100Pa, rises to 660 DEG C by vacuum melting in-furnace temperature from room temperature, melting 2h after temperature stabilization;
(3) Raise vacuum melting in-furnace temperature is 970 DEG C, molten 3h after temperature stabilization;
(4) Raise vacuum melting in-furnace temperature is 1135 DEG C, melting 3h after temperature stabilization;
(5) reducing vacuum melting in-furnace temperature is 550 DEG C, is incubated 2h;
(6) again vacuum melting in-furnace temperature is down to room temperature, for medical magnesium base alloy material.
Embodiment 5
(1) take respectively metal powder material, by weight percentage take Ti be 4.5wt%, W be 0.6wt%, V be that 0.4wt%, Ni are
2.3wt%, Cr be 0.7wt%, Ag be 0.4wt%, Sc be 0.6wt%, Nb be 0.5wt%, surplus be Mg, by above-mentioned metal dust
Material high-speed mixer mechanical mixture, mixing is to metal dust mix homogeneously;
(2) after mix homogeneously, metal powder material being thrown to by high-temperature vacuum smelting furnace, in vacuum melting furnace, pressure is
300Pa, rises to 680 DEG C by vacuum melting in-furnace temperature from room temperature, melting 2h after temperature stabilization;
(3) Raise vacuum melting in-furnace temperature is 955 DEG C, molten 3h after temperature stabilization;
(4) Raise vacuum melting in-furnace temperature is 1155 DEG C, melting 3h after temperature stabilization;
(5) reducing vacuum melting in-furnace temperature is 570 DEG C, is incubated 2h;
(6) again vacuum melting in-furnace temperature is down to room temperature, for medical magnesium base alloy material.
Comparative example 1
(1) take respectively metal powder material, by weight percentage take Ti be 5.6wt%, W be 0.3wt%, V be that 0.2wt%, Ni are
3.4wt%, Cr be 1.1wt%, Ag be 0.2wt%, surplus be Mg, above-mentioned metal powder material high-speed mixer machinery is mixed
Closing, mixing is to metal dust mix homogeneously;
(2) after mix homogeneously, metal powder material being thrown to by high-temperature vacuum smelting furnace, in vacuum melting furnace, pressure is
500Pa, rises to 700 DEG C by vacuum melting in-furnace temperature from room temperature, melting 2h after temperature stabilization;
(3) Raise vacuum melting in-furnace temperature is 940 DEG C, molten 3h after temperature stabilization;
(4) Raise vacuum melting in-furnace temperature is 1175 DEG C, melting 3h after temperature stabilization;
(5) reducing vacuum melting in-furnace temperature is 580 DEG C, is incubated 2h;
(6) again vacuum melting in-furnace temperature is down to room temperature, for medical magnesium base alloy material.
Determine embodiments of the invention and the hot strength of medical magnesium base alloy material of comparative example, comprcssive strength, dimension
Family name's hardness.Result is as follows:
Claims (1)
1. the preparation method of a medical magnesium base alloy material, it is characterised in that the preparation side of described medical magnesium base alloy material
Method comprises the following steps:
(1) take respectively metal powder material, by weight percentage take Ti be 3.2wt%-5.6wt%, W be that 0.3wt%-0.8wt%, V are
0.2wt%-0.7wt%, Ni be 1.2wt%-3.4wt%, Cr be 0.3wt%-1.1wt%, Ag be that 0.2wt%-0.6wt%, Sc are
0.3wt%-0.8wt%, Nb are 0.2wt%-0.8wt%, surplus is Mg, by above-mentioned metal powder material high-speed mixer machinery
Mixing, mixing is to metal dust mix homogeneously;
(2) after mix homogeneously, metal powder material being thrown to by high-temperature vacuum smelting furnace, in vacuum melting furnace, pressure is
300Pa, rises to 680 DEG C by vacuum melting in-furnace temperature from room temperature, melting 2h after temperature stabilization;
(3) Raise vacuum melting in-furnace temperature is 940-970 DEG C, molten 3h after temperature stabilization;
(4) Raise vacuum melting in-furnace temperature is 1135-1175 DEG C, melting 3h after temperature stabilization;
(5) reduce vacuum melting in-furnace temperature and be 550-580 DEG C, be incubated 2h;
(6) again vacuum melting in-furnace temperature is down to room temperature, for medical magnesium base alloy material.
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CN201610540380.7A Pending CN106011569A (en) | 2015-04-15 | 2015-04-15 | Medical magnesium base alloy material with good mechanical strength and biocompatibility |
CN201610540563.9A Pending CN106048347A (en) | 2015-04-15 | 2015-04-15 | Medical magnesium-based alloy material with relatively good mechanical strength and biocompatibility |
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CN106048346A (en) * | 2015-04-15 | 2016-10-26 | 丁永新 | Medical magnesium-based alloy material and preparation method thereof |
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CN105238976A (en) * | 2015-09-25 | 2016-01-13 | 苏州蔻美新材料有限公司 | Medical magnesium base alloy material and preparation method thereof |
US20180291483A1 (en) * | 2015-10-13 | 2018-10-11 | Tohoku University | Magnesium alloy that exhibits superelastic effect and/or shape-memory effect |
CN105925860B (en) * | 2016-06-10 | 2018-02-09 | 广州市欧美斯金利汽车座椅有限公司 | A kind of alloy for automotive seat and preparation method thereof and automotive seat |
CN107779708B (en) * | 2017-12-08 | 2019-08-23 | 浙江海洋大学 | A kind of high intensity super-light Mg-Li alloy and preparation method thereof |
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CN104831136A (en) | 2015-08-12 |
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CN106011569A (en) | 2016-10-12 |
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