CN106118525A - A kind of nano-oxide doped and compounded microporous membrane insulating bag band - Google Patents

A kind of nano-oxide doped and compounded microporous membrane insulating bag band Download PDF

Info

Publication number
CN106118525A
CN106118525A CN201610473246.XA CN201610473246A CN106118525A CN 106118525 A CN106118525 A CN 106118525A CN 201610473246 A CN201610473246 A CN 201610473246A CN 106118525 A CN106118525 A CN 106118525A
Authority
CN
China
Prior art keywords
nano
minute
compounded
deionized water
polrvinyl chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610473246.XA
Other languages
Chinese (zh)
Inventor
王喜东
琚雄
琚一雄
周建军
郜海文
张君君
陈玲
张爱华
宋志威
琚辉
琚一辉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Deren Electronic Devices Co Ltd
Original Assignee
Hefei Deren Electronic Devices Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Deren Electronic Devices Co Ltd filed Critical Hefei Deren Electronic Devices Co Ltd
Priority to CN201610473246.XA priority Critical patent/CN106118525A/en
Publication of CN106118525A publication Critical patent/CN106118525A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/26—Porous or cellular plastics
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C08K7/26—Silicon- containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/245—Vinyl resins, e.g. polyvinyl chloride [PVC]
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/385—Acrylic polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2423/10—Homopolymers or copolymers of propene
    • C08J2423/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/10—Peculiar tacticity
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/302—Applications of adhesives in processes or use of adhesives in the form of films or foils for bundling cables
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/41—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the carrier layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00—Presence of polyolefin
    • C09J2423/10—Presence of homo or copolymers of propene
    • C09J2423/106—Presence of homo or copolymers of propene in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2427/00—Presence of halogenated polymer
    • C09J2427/006—Presence of halogenated polymer in the substrate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00—Presence of (meth)acrylic polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Insulating Bodies (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention discloses a kind of nano-oxide doped and compounded microporous membrane insulating bag band, it is made up of the raw material of following weight portion: halloysite nanotubes 1.5 1.6, silane coupler kh5700.75 0.77, deionized water is appropriate, dehydrated alcohol is appropriate, sodium lauryl sulphate 1.2 1.4, alkylphenol polyoxyethylene 1.4 1.5, butyl acrylate 55 60, Isooctyl acrylate monomer 40 43, isotactic polypropylene 40 44, polrvinyl chloride 53 55, dibenzylidene sorbitol 34, dioctyl phthalate is appropriate, aluminum isopropylate. 18 20, four n-pro-pyl zirconates 23, N, N, dimethyl acetylamide 0.3 0.4, calcium stearate 23, glycerol 34.The product viscosity that the present invention makes is good, will not be layered, warpage, applied widely.

Description

A kind of nano-oxide doped and compounded microporous membrane insulating bag band
Technical field
The present invention relates to technical field of electricity, particularly relate to a kind of nano-oxide doped and compounded microporous membrane insulating wrapping Band.
Background technology
Insulating bag band is mainly used as looping electric wire, the joint of cable, interface, in addition to for the insulation of common electrical, also Be widely used in engineering pipeline protection, in peep route protection and automotive wire bundle ties up the fields such as protection.The fabricbase of prior art is exhausted Edge adhesive tape is made up of fabricbase and rubber, Colophonium, filler coatings glue, has preferable mechanical strength and an insulation effect, but cloth Base adhesive tape is the most aging, water proofing property, poor sealing performance, and at high temperature under high pressure, the shielding properties of adhesive tape is greatly reduced, and causing cannot For more field.Existing poly-nitrogen ethylene pressure-sensitive tape is a kind of universal electric sticking tape, and it is cheap, has Excellent electric property and physical and mechanical property, electrical strength is up to 60kV/mm, and specific insulation is high, has soft and easy-to-draw The feature such as stretch, also there is the features such as excellent acid and alkali-resistance, ageing-resistant, cold-resistant and moisture-proof, be widely used in the company of alternating current-direct current electric wire Connect winding and being wrapped of insulation protection, the manufacture of electrical equipment, various wire harness and cable, its shortcoming be heatproof rank not Height, heat dispersion is poor.
" be applicable to emulsion pressure-sensitive adhesive and the manufacture method thereof of flexible PVC electric adhesive tape " article, although The advantages such as the adhesive tape softening point made is low, cohesive force strong, quick solidifying, but owing to the straight-chain molecular structure of polyacrylate determines Its performance such as thermostability and mechanical strength is not enough, in addition development of Acrylate Emulsion Pressure-Sensitive Adhesive coating and rate of drying is slow, be dried The shortcomings such as energy consumption is high and surface tension is higher make it apply to be restricted, for widening its range, improve its combination property, There is a need to polrvinyl chloride base material and acrylate pressure-sensitive adhesive are modified.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of nano-oxide doped and compounded micropore is thin Film insulating bag band.
The present invention is achieved by the following technical solutions:
A kind of nano-oxide doped and compounded microporous membrane insulating bag band, is made up of the raw material of following weight portion: Ai Luo Stone nanotube 1.5-1.6, silane coupler kh5700.75-0.77, deionized water is appropriate, dehydrated alcohol is appropriate, dodecyl sulfur Acid sodium 1.2-1.4, alkylphenol polyoxyethylene 1.4-1.5, butyl acrylate 55-60, Isooctyl acrylate monomer 40-43, isotactic gather Propylene 40-44, polrvinyl chloride 53-55, dibenzylidene sorbitol 3-4, dioctyl phthalate are appropriate, aluminum isopropylate. 18- 20, four n-pro-pyl zirconate 2-3, N, N ,-dimethyl acetylamide 0.3-0.4, calcium stearate 2-3, glycerol 3-4.
Described a kind of nano-oxide doped and compounded microporous membrane insulating bag band, is made up of step in detail below:
(1) ultrasonic disperse in the dehydrated alcohol of addition 30-35 times amount in galapectite is obtained suspension in 40-50 minute, then add Enter the deionized water with dehydrated alcohol equivalent and silane coupler kh570, be heated to 70-75 DEG C, after stirring is reacted 24 hours Mixture is centrifuged with the speed of 4000 revs/min, and washs to neutral, the product obtained in vacuum drying oven with 90- 100 DEG C of drying, obtain modified halloysite nanotubes；
(2) by modified halloysite nanotubes ultrasonic disperse in the deionized water of 80-85 times amount, be subsequently adding butyl acrylate, Isooctyl acrylate monomer, sodium lauryl sulphate, stir on magnetic stirrer, then heats to 80-85 DEG C, adds half The alkylphenol polyoxyethylene of amount, continuously adds remaining alkylphenol polyoxyethylene after being incubated 30-60 minute, is warming up to 90- 95 DEG C, it is cooled to room temperature after being incubated 60-90 minute, obtains modified acrylic acid emulsion；
(3) by aluminum isopropylate., four n-pro-pyl zirconates, N, N ,-dimethyl acetylamide mixes, and is heated to 60-70 DEG C and stirs, It is subsequently adding the deionized water of total amount equivalent, after being warming up to 350-380 DEG C of reaction 40-60 minute, system is distilled, obtain Nano-oxide dispersion liquid；
(4) polrvinyl chloride, isotactic polypropylene mixing are put in reactor, be subsequently adding the O-phthalic of total amount 3.5-4 times amount Dioctyl phthalate and remaining residual components, add step (3) after stirring 60-90 minute at 180 DEG C and obtain under nitrogen protective condition The nano-oxide dispersion liquid arrived, continues insulation and forms casting solution in 2-3 hour, by knifing machine, casting solution is made Flat Membrane, Controlling to scrape film temperature is 180 DEG C, finally by Thermal inactive technology, immerses 25 DEG C of solidification water-baths through Flat Membrane and divides mutually From, then extract through dehydrated alcohol, obtain polypropylene polrvinyl chloride composite micro porous film after drying；
(5) modified acrylic acid emulsion coating device is uniformly coated on polypropylene polrvinyl chloride composite micro porous film surface, is put Toast 3-4 minute at 75-80 DEG C of baking oven, be subsequently placed in 40 DEG C of constant temperature ageing ovens aging 24 hours, finally cut into banding, i.e. ?.
The invention have the advantage that Thermal inactive method is applied to pressure sensitive insulating wrapping band base film by the present invention In preparation, the composite microporous thin film of polypropylene polrvinyl chloride made, the advantage having polypropylene and polrvinyl chloride concurrently, waterproof, heat-resisting Property is good, resistance to chemical attack, and porosity is moderate simultaneously, is evenly distributed, and micropore communicates with air, can form air insulation structure, Heat dispersion is excellent simultaneously；Polyacrylate dispersion is changed by the present invention also by the mode adding modified halloysite nanotubes Property, the activeness and quietness of modified halloysite nanotubes and the strong interaction with polymeric substrate thereof, so that polymer molecule Chain mobility is deteriorated so that the pressure sensitive adhesive cohesive strength made and creep-resistant property are remarkably reinforced, and the heat that improve pressure sensitive adhesive is steady Qualitative and heat-resisting quantity, has good peel strength and initial bonding strength simultaneously.
The present invention has prepared zirconium oxide by a series of technique and has compounded the micropore laminated film of nano aluminium oxide doping, Improve heat dispersion further, improve the resistance to sparking energy of thin polymer film simultaneously, solve existing insulating bag band easily quilt Surge voltage punctures the problem burnt, it is ensured that product has pliability, puncture resistance and the electrical insulating property of excellence, and makes Product viscosity good, will not be layered, warpage, applied widely.
Detailed description of the invention
A kind of nano-oxide doped and compounded microporous membrane insulating bag band, is prepared by the raw material of following weight portion (kilogram) Make: halloysite nanotubes 1.5, silane coupler kh5700.75, deionized water is appropriate, dehydrated alcohol is appropriate, dodecyl sulfur Acid sodium 1.2, alkylphenol polyoxyethylene 1.4, butyl acrylate 55, Isooctyl acrylate monomer 40, isotactic polypropylene 40, polrvinyl chloride 53, dibenzylidene sorbitol 3, dioctyl phthalate be appropriate, aluminum isopropylate. 18, four n-pro-pyl zirconate 2, N, N, diformazan Yl acetamide 0.3, calcium stearate 2, glycerol 3.
Described a kind of nano-oxide doped and compounded microporous membrane insulating bag band, is made up of step in detail below:
(1) within 40 minutes, obtain suspension by galapectite adds ultrasonic disperse in the dehydrated alcohol of 30 times amount, be subsequently adding and nothing The deionized water of water-ethanol equivalent and silane coupler kh570, be heated to 70 DEG C, stirring reaction 24 hours after by mixture with The speed of 4000 revs/min is centrifuged, and washs to neutral, and the product obtained with 90 DEG C of drying, obtains in vacuum drying oven Modified halloysite nanotubes；
(2) by modified halloysite nanotubes ultrasonic disperse in the deionized water of 80 times amount, it is subsequently adding butyl acrylate, propylene Acid different monooctyl ester, sodium lauryl sulphate, stir on magnetic stirrer, then heat to 80 DEG C, adds the alkane of half amount Base phenol polyethenoxy ether, continuously adds remaining alkylphenol polyoxyethylene after being incubated 30 minutes, is warming up to 90 DEG C, is incubated 60 points It is cooled to room temperature after clock, obtains modified acrylic acid emulsion；
(3) by aluminum isopropylate., four n-pro-pyl zirconates, N, N, dimethyl acetylamide mixes, is heated to 60 DEG C and stirs, then Add the deionized water of total amount equivalent, after being warming up to 350 DEG C of reactions 40 minutes, system is distilled, obtain nano-oxide and divide Dissipate liquid；
(4) polrvinyl chloride, isotactic polypropylene mixing are put in reactor, be subsequently adding the phthalic acid of total amount 3.5 times amount Dioctyl ester and remaining residual components, what after stirring 60 minutes at 180 DEG C under nitrogen protective condition, addition step (3) obtained receives Rice oxidate dispersion solution, continues insulation and forms casting solution in 2 hours, by knifing machine, casting solution is made Flat Membrane, controls knifing Temperature is 180 DEG C, finally by Thermal inactive technology, immerses 25 DEG C of solidification water-baths through Flat Membrane and is separated, then through nothing Water-ethanol extracts, and obtains polypropylene polrvinyl chloride composite micro porous film after drying；
(5) modified acrylic acid emulsion coating device is uniformly coated on polypropylene polrvinyl chloride composite micro porous film surface, is put Toast 3 minutes at 75 DEG C of baking ovens, be subsequently placed in 40 DEG C of constant temperature ageing ovens aging 24 hours, finally cut into banding, to obtain final product.
The insulating bag band that the present invention makes, by test, the hot strength of product more than 15 newton/centimetre, meet state Family's standard；Take appropriate amount of sample when being pasted onto on sample board, with the speed rolling three times back and forth of 300 millis m/min, deposit 30 minutes, 180 ° of peel strengths are up to state standards.

Claims (2)

1. a nano-oxide doped and compounded microporous membrane insulating bag band, it is characterised in that by the raw material of following weight portion Preparation is made: halloysite nanotubes 1.5-1.6, silane coupler kh5700.75-0.77, deionized water is appropriate, dehydrated alcohol is suitable Amount, sodium lauryl sulphate 1.2-1.4, alkylphenol polyoxyethylene 1.4-1.5, butyl acrylate 55-60, Isooctyl acrylate monomer 40-43, isotactic polypropylene 40-44, polrvinyl chloride 53-55, dibenzylidene sorbitol 3-4, dioctyl phthalate be appropriate, Aluminum isopropylate. 18-20, four n-pro-pyl zirconate 2-3, N, N ,-dimethyl acetylamide 0.3-0.4, calcium stearate 2-3, glycerol 3-4.
A kind of nano-oxide doped and compounded microporous membrane insulating bag band, it is characterised in that by Step is made in detail below:
(1) ultrasonic disperse in the dehydrated alcohol of addition 30-35 times amount in galapectite is obtained suspension in 40-50 minute, then add Enter the deionized water with dehydrated alcohol equivalent and silane coupler kh570, be heated to 70-75 DEG C, after stirring is reacted 24 hours Mixture is centrifuged with the speed of 4000 revs/min, and washs to neutral, the product obtained in vacuum drying oven with 90- 100 DEG C of drying, obtain modified halloysite nanotubes；
(2) by modified halloysite nanotubes ultrasonic disperse in the deionized water of 80-85 times amount, be subsequently adding butyl acrylate, Isooctyl acrylate monomer, sodium lauryl sulphate, stir on magnetic stirrer, then heats to 80-85 DEG C, adds half The alkylphenol polyoxyethylene of amount, continuously adds remaining alkylphenol polyoxyethylene after being incubated 30-60 minute, is warming up to 90- 95 DEG C, it is cooled to room temperature after being incubated 60-90 minute, obtains modified acrylic acid emulsion；
(3) by aluminum isopropylate., four n-pro-pyl zirconates, N, N ,-dimethyl acetylamide mixes, and is heated to 60-70 DEG C and stirs, It is subsequently adding the deionized water of total amount equivalent, after being warming up to 350-380 DEG C of reaction 40-60 minute, system is distilled, obtain Nano-oxide dispersion liquid；
(4) polrvinyl chloride, isotactic polypropylene mixing are put in reactor, be subsequently adding the O-phthalic of total amount 3.5-4 times amount Dioctyl phthalate and remaining residual components, add step (3) after stirring 60-90 minute at 180 DEG C and obtain under nitrogen protective condition The nano-oxide dispersion liquid arrived, continues insulation and forms casting solution in 2-3 hour, by knifing machine, casting solution is made Flat Membrane, Controlling to scrape film temperature is 180 DEG C, finally by Thermal inactive technology, immerses 25 DEG C of solidification water-baths through Flat Membrane and divides mutually From, then extract through dehydrated alcohol, obtain polypropylene polrvinyl chloride composite micro porous film after drying；
(5) modified acrylic acid emulsion coating device is uniformly coated on polypropylene polrvinyl chloride composite micro porous film surface, is put Toast 3-4 minute at 75-80 DEG C of baking oven, be subsequently placed in 40 DEG C of constant temperature ageing ovens aging 24 hours, finally cut into banding, i.e. ?.
CN201610473246.XA 2016-06-24 2016-06-24 A kind of nano-oxide doped and compounded microporous membrane insulating bag band Pending CN106118525A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610473246.XA CN106118525A (en) 2016-06-24 2016-06-24 A kind of nano-oxide doped and compounded microporous membrane insulating bag band

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610473246.XA CN106118525A (en) 2016-06-24 2016-06-24 A kind of nano-oxide doped and compounded microporous membrane insulating bag band

Publications (1)

Publication Number Publication Date
CN106118525A true CN106118525A (en) 2016-11-16

Family

ID=57265568

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610473246.XA Pending CN106118525A (en) 2016-06-24 2016-06-24 A kind of nano-oxide doped and compounded microporous membrane insulating bag band

Country Status (1)

Country Link
CN (1) CN106118525A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112186382A (en) * 2020-10-12 2021-01-05 南京瑞敬自动化科技有限公司 Ultra-small sealed high-temperature high-pressure connector

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102228804A (en) * 2011-04-15 2011-11-02 天津科技大学 Method for preparing hydrophobic microporous membrane and membrane prepared by method
CN103120933A (en) * 2011-11-18 2013-05-29 中国石油化工股份有限公司 Preparation method of nanometer TiO2/ZrO2 composite material
CN104548950A (en) * 2013-10-16 2015-04-29 中国石油化工股份有限公司 Inorganic nanoparticle enhanced type polypropylene hollow fiber microporous membrane and preparation method thereof
CN105255403A (en) * 2015-11-01 2016-01-20 上海晶华胶粘新材料股份有限公司 Water-based adhesive, preparation method, adhesive tape and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102228804A (en) * 2011-04-15 2011-11-02 天津科技大学 Method for preparing hydrophobic microporous membrane and membrane prepared by method
CN103120933A (en) * 2011-11-18 2013-05-29 中国石油化工股份有限公司 Preparation method of nanometer TiO2/ZrO2 composite material
CN104548950A (en) * 2013-10-16 2015-04-29 中国石油化工股份有限公司 Inorganic nanoparticle enhanced type polypropylene hollow fiber microporous membrane and preparation method thereof
CN105255403A (en) * 2015-11-01 2016-01-20 上海晶华胶粘新材料股份有限公司 Water-based adhesive, preparation method, adhesive tape and preparation method thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
刘康: "改性水性丙烯酸酯压敏胶的研究", 《中国优秀博硕士学位论文全文数据库(硕士) 工程科技Ⅰ辑》 *
张军营 等: "《丙烯酸酯胶黏剂》", 30 April 2006, 化学工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112186382A (en) * 2020-10-12 2021-01-05 南京瑞敬自动化科技有限公司 Ultra-small sealed high-temperature high-pressure connector
CN112186382B (en) * 2020-10-12 2021-04-13 南京瑞敬自动化科技有限公司 Ultra-small sealed high-temperature high-pressure connector

Similar Documents

Publication Publication Date Title
CN105950052A (en) Rare-earth-modified-montmorillonite-added modified PVC (polyvinyl chloride) microporous insulation binder
CN103483823B (en) A kind of rubber composition and the technique using its production organic silicon self-adhesive tape
CN105315887A (en) Preparation method of insulating layer of power transformer
CN106118524A (en) The micropore radiating insulating binder that a kind of waterproof mildew-resistant strengthens
CN103980855A (en) Preparation method of silicon-titanium composite modified epoxy adhesive
CN106084513A (en) A kind of New-style electrical wire insulant
CN105176468B (en) Resin combination, the adhesive containing the resin combination, the stack bus bar insulated rubber film and preparation method thereof using the adhesive
CN101962519A (en) Liquid insulating glue for cable joint
CN106118525A (en) A kind of nano-oxide doped and compounded microporous membrane insulating bag band
CN106010333A (en) Microporous compound insulation binder with enhanced heat radiation performance
CN106147663A (en) Adhesive, superelevation heatproof two-sided tape and preparation method thereof
CN110283566B (en) Solvent-free silicone pressure-sensitive adhesive and preparation and application thereof
CN106118527A (en) A kind of Kaolin heat resist modification composite microporous insulating bag band
CN105219292A (en) A kind of electric insulating tape and preparation method thereof
CN105969236A (en) Insect and rat bite preventing micropore insulated binding band
CN106118523A (en) A kind of cold-resistant insulation binder that can use in the presence of a harsh environment
CN107267114A (en) A kind of high-temperature resistant silicone pressure sensitive adhesive and preparation method thereof
CN106117866A (en) A kind of anti abrasive micropore pressure-sensitive insulating bag band
CN106009390A (en) Anti-light aging weather-resistant microporous polymer insulated binding band
CN105295302A (en) High-temperature-resistant and ageing-resistant cable insulation layer
CN107418507A (en) A kind of cold-resistant thermal shock electric insulation glue of anti-high pressure and preparation method thereof
CN106118526A (en) A kind of flame-retardant smoke inhibition pore type pressure-sensitive tape
CN103421465A (en) Silicon rubber used for organic silicon self-adhesive tape and synthesis process of silicon rubber
CN202632915U (en) Composite insulating material and cable
CN201584182U (en) Polyimide and polyester fiber non-woven fabric combined insulating material and wire cable formed by same

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20161116