CN106117910A - A kind of anti-corrosion type plastic-steel cable sheath material and preparation method thereof - Google Patents

A kind of anti-corrosion type plastic-steel cable sheath material and preparation method thereof Download PDF

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Publication number
CN106117910A
CN106117910A CN201610642669.XA CN201610642669A CN106117910A CN 106117910 A CN106117910 A CN 106117910A CN 201610642669 A CN201610642669 A CN 201610642669A CN 106117910 A CN106117910 A CN 106117910A
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China
Prior art keywords
parts
plasticated
raw material
corvic
steel cable
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Pending
Application number
CN201610642669.XA
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Chinese (zh)
Inventor
骆垠旭
瞿庆广
王汉才
李登军
杜超群
高德明
赵宏春
徐苏皖
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Anhui Aics Technology Group Co Ltd
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Anhui Aics Technology Group Co Ltd
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Priority to CN201610642669.XA priority Critical patent/CN106117910A/en
Publication of CN106117910A publication Critical patent/CN106117910A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/28Protection against damage caused by moisture, corrosion, chemical attack or weather
    • H01B7/2806Protection against damage caused by corrosion

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)

Abstract

A kind of anti-corrosion type plastic-steel cable sheath material, relate to cable processing technique field, be made up of the raw material of following weight portion: Corvic 150 250 parts, o-benzoic acid dioctyl ester 150 250 parts, plasticizer 68 parts, acrylic resin 15 25 parts, cellulose fibre 15 17 parts, high silicon 57 parts, ethylenediamine 68 parts, silica flour 35 parts, 24 parts of acetone, 10 20 parts of kieselguhr, lignin 35 parts, 20 30 parts of Radix Glycyrrhizae, Pericarpium Citri Reticulatae 5 15 parts, Semen Sinapis 15 25 parts, antioxidant NBC 24 parts, antioxidant MB 68 parts.The invention has the beneficial effects as follows: present invention process flow process is succinct, reasonable raw material proportioning, raw material is inexpensive and is easy to get, processing is simple, is prepared protective cover material by plastic-steel type material, it is ensured that the high intensity of sheath, use technical grade height silicon and silica flour and the effect of Chinese herbal medicine Radix Glycyrrhizae, Pericarpium Citri Reticulatae and Semen Sinapis simultaneously, the antiseptic property of sheath can also be ensured, it is adaptable to chemical field, it is simple to promote the use of.

Description

A kind of anti-corrosion type plastic-steel cable sheath material and preparation method thereof
Technical field
The present invention relates to cable processing technique field, be specifically related to a kind of anti-corrosion type plastic-steel cable sheath material and preparation side thereof Method.
Background technology
Wires and cables industry is the second largest industry that China is only second to automobile industry, product variety Service Efficiency and domestic market Occupation rate is all more than 90%.Worldwide, China's electric wire gross output value has exceeded the U.S., becomes the first big electricity in the world Line cable manufacturing country.Along with China's wires and cables industry high speed development, creation of new enterprise quantity constantly rises, industry overall technology Level is largely increased.China's economic growth continuously and healthily, provides the huge market space, city of China for cable products The allure that field intensity is strong so that the world all focuses on Chinese market sight, in the decades that reform and opening-up is short, China's cable The huge production capacity that manufacturing industry is formed allows the world regard with special esteem.Along with China electric power industry, data communication industry, city rail The continuous expansion of the industry sizes such as communications, car industry and shipbuilding, also will increase rapidly the demand of electric wire, not send a telegram here Line cable industry it also has huge development potentiality.
Cable core and the sheath being coated on outside cable core that cable mainly includes inside form, in order to ensure the safety of cable core Can, sheath typically all uses elastic relatively good plastic jacket, thus ensure that the toughness that cable is overall, but cable by Different in its regional extent applied, when being directed in some chemical enterprise use, due to the existence of chemical raw material, it is easy to electricity Cable sheath corrodes, and causes whole cable danger occur, causes immeasurable loss.
Summary of the invention:
The technical problem to be solved is to provide a kind of reasonable mixture ratio, and processing technology is simple, and antiseptic effect is bright Aobvious anti-corrosion type plastic-steel cable sheath material and preparation method thereof.
The technical problem to be solved realizes by the following technical solutions:
A kind of anti-corrosion type plastic-steel cable sheath material, it is characterised in that be made up of the raw material of following weight portion: polrvinyl chloride tree Fat 150-250 part, o-benzoic acid dioctyl ester 150-250 part, plasticizer 6-8 part, acrylic resin 15-25 part, cellulose fibre 15-17 part, high silicon 5-7 part, ethylenediamine 6-8 part, silica flour 3-5 part, acetone 2-4 part, kieselguhr 10-20 part, lignin 3-5 Part, Radix Glycyrrhizae 20-30 part, Pericarpium Citri Reticulatae 5-15 part, Semen Sinapis 15-25 part, antioxidant NBC 2-4 part, antioxidant MB 6-8 part.
The preferred weight of each raw material is: Corvic 200 parts, o-benzoic acid dioctyl ester 200 parts, plasticizer 7 parts, third Olefin(e) acid resin 20 parts, cellulose fibre 16 parts, high silicon 6 parts, ethylenediamine 7 parts, silica flour 4 parts, 3 parts of acetone, modification infusorial earth 15 Part, lignin 4 parts, 25 parts of Radix Glycyrrhizae, Pericarpium Citri Reticulatae 10 parts, Semen Sinapis 20 parts, antioxidant NBC 3 parts, antioxidant MB 7 parts.
Described modification infusorial earth is made up of following raw material: 100 parts of kieselguhr, sodium hexameta phosphate 3 parts, 35 parts of water, phosphatase 24 Part, potassium hydroxide 15 parts, Borax 2.5, Cab-O-sil 20 parts
Its preparation method is: puts into after being pulverized by kaolinite in the molten device of stirring, is joined by sodium hexameta phosphate in container, Stirring mixing, adds 20 parts of water in kaolinite, stirs 5 minutes, stand swelling dispersion 40 minutes, then by 5 parts of phosphoric acid, water, Put in stirring container, stir, stand 30 minutes, then potassium hydroxide, Borax and remaining 10 parts of water are put into wherein, Stir, stand 45 minutes, after adding Cab-O-sil, urge dry, can be prepared by modified kaolinite.
It is a further object to provide the preparation method of a kind of anti-corrosion type plastic-steel cable sheath material, it is characterised in that Comprise the following steps:
1) being plasticated at 85-90 DEG C on banbury by Corvic, the Corvic cooling plasticated is standby;
2) being plasticated at 85-90 DEG C on banbury by polyacrylic resin, the polyacrylic resin cooling plasticated is standby;
3) Corvic plasticated by step 1 gained is put into the polyacrylic resin that step 2 gained is plasticated Banbury, closes refining 15-20 minute at 100-120 DEG C;
4) after remaining component in raw material being merged, putting in grinder, mixed grinding obtains mixed powder, standby;
5), after being merged by the material in step 3 and step 4, refining 30-40min is closed;Take out;
6) material in step 5 is used double screw extruder extruding pelletization, to obtain final product.
The invention has the beneficial effects as follows: present invention process flow process is succinct, and reasonable raw material proportioning, raw material is inexpensive and is easy to get, and adds Work is simple, is prepared protective cover material by plastic-steel type material, it is ensured that the high intensity of sheath, uses technical grade height silicon and stone simultaneously English powder and the effect of Chinese herbal medicine Radix Glycyrrhizae, Pericarpium Citri Reticulatae and Semen Sinapis, it can also be ensured that the antiseptic property of sheath, it is adaptable to chemical field, It is easy to promote the use of.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below knot Close specific embodiment, the present invention is expanded on further.
Embodiment 1
Weigh: Corvic 150kg, o-benzoic acid dioctyl ester 150kg, plasticizer 6kg, acrylic resin 15kg, Cellulose fibre 15kg, high silicon 5kg, ethylenediamine 6kg, silica flour 3kg, acetone 2kg, kieselguhr 10kg, lignin 3kg, Radix Glycyrrhizae 20kg, Pericarpium Citri Reticulatae 5kg, Semen Sinapis 15kg, antioxidant NBC 2kg, antioxidant MB 6kg.
Embodiment 2
Weigh: Corvic 250 parts, o-benzoic acid dioctyl ester 250 parts, plasticizer 8 parts, acrylic resin 25 parts, Cellulose fibre 17 parts, high silicon 7 parts, ethylenediamine 8 parts, silica flour 5 parts, 4 parts of acetone, 20 parts of kieselguhr, lignin 5 parts, Radix Glycyrrhizae 30 parts, Pericarpium Citri Reticulatae 15 parts, Semen Sinapis 25 parts, antioxidant NBC 4 parts, antioxidant MB 8 parts.
Embodiment 3:
Weigh: Corvic 200kg, o-benzoic acid dioctyl ester 200kg, plasticizer 7kg, acrylic resin 20kg, Cellulose fibre 16kg, high silicon 6kg, ethylenediamine 7kg, silica flour 4kg, acetone 3kg, modification infusorial earth 15kg, lignin 4kg, Radix Glycyrrhizae 25kg, Pericarpium Citri Reticulatae 10kg, Semen Sinapis 20kg, antioxidant NBC 3kg, antioxidant MB 7kg.
The technical method preparing above-described embodiment 1-3 is:
1) being plasticated at 85-90 DEG C on banbury by Corvic, the Corvic cooling plasticated is standby;
2) being plasticated at 85-90 DEG C on banbury by polyacrylic resin, the polyacrylic resin cooling plasticated is standby;
3) Corvic plasticated by step 1 gained is put into the polyacrylic resin that step 2 gained is plasticated Banbury, closes refining 15-20 minute at 100-120 DEG C;
4) after remaining component in raw material being merged, putting in grinder, mixed grinding obtains mixed powder, standby;
5), after being merged by the material in step 3 and step 4, refining 30-40min is closed;Take out;
6) material in step 5 is used double screw extruder extruding pelletization, to obtain final product.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.The technology of the industry Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and Equivalent defines.

Claims (4)

1. an anti-corrosion type plastic-steel cable sheath material, it is characterised in that be made up of the raw material of following weight portion: Corvic 150-250 part, o-benzoic acid dioctyl ester 150-250 part, plasticizer 6-8 part, acrylic resin 15-25 part, cellulose fibre 15- 17 parts, high silicon 5-7 part, ethylenediamine 6-8 part, silica flour 3-5 part, acetone 2-4 part, kieselguhr 10-20 part, lignin 3-5 part, sweet Grass 20-30 part, Pericarpium Citri Reticulatae 5-15 part, Semen Sinapis 15-25 part, antioxidant NBC 2-4 part, antioxidant MB 6-8 part.
A kind of anti-corrosion type plastic-steel cable sheath material the most according to claim 1, it is characterised in that the preferred weight of each raw material For: Corvic 200 parts, o-benzoic acid dioctyl ester 200 parts, plasticizer 7 parts, acrylic resin 20 parts, cellulose fibre 16 parts, high silicon 6 parts, ethylenediamine 7 parts, silica flour 4 parts, 3 parts of acetone, modification infusorial earth 15 parts, lignin 4 parts, 25 parts of Radix Glycyrrhizae, old Skin 10 parts, Semen Sinapis 20 parts, antioxidant NBC 3 parts, antioxidant MB 7 parts.
A kind of anti-corrosion type plastic-steel cable sheath material the most according to claim 1, it is characterised in that: described modification infusorial earth Be made up of following raw material: 100 parts of kieselguhr, sodium hexameta phosphate 3 parts, 35 parts of water, phosphatase 24 part, potassium hydroxide 15 parts, Borax 2.5, Cab-O-sil 20 parts
Its preparation method is: puts into after being pulverized by kaolinite in the molten device of stirring, is joined by sodium hexameta phosphate in container, stirring Mixing, adds 20 parts of water in kaolinite, stir 5 minutes, stand swelling dispersion 40 minutes, then by 5 parts of phosphoric acid, water, input In stirring container, stir, stand 30 minutes, then potassium hydroxide, Borax and remaining 10 parts of water are put into wherein, stirring Uniformly, stand 45 minutes, after adding Cab-O-sil, urge dry, can be prepared by modified kaolinite.
4. a kind of method of anti-corrosion type plastic-steel cable sheath material in preparation claim 1 or 2, it is characterised in that include following step Rapid:
1) being plasticated at 85-90 DEG C on banbury by Corvic, the Corvic cooling plasticated is standby;
2) being plasticated at 85-90 DEG C on banbury by polyacrylic resin, the polyacrylic resin cooling plasticated is standby;
3) polyacrylic resin that the Corvic plasticated by step 1 gained and step 2 gained are plasticated puts into banburying Machine, closes refining 15-20 minute at 100-120 DEG C;
4) after remaining component in raw material being merged, putting in grinder, mixed grinding obtains mixed powder, standby;
5), after being merged by the material in step 3 and step 4, refining 30-40min is closed;Take out;
6) material in step 5 is used double screw extruder extruding pelletization, to obtain final product.
CN201610642669.XA 2016-08-08 2016-08-08 A kind of anti-corrosion type plastic-steel cable sheath material and preparation method thereof Pending CN106117910A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113698713A (en) * 2021-09-13 2021-11-26 宁波圣捷新材料有限公司 Preparation method of modified PVC plastic material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101412834A (en) * 2008-11-12 2009-04-22 江苏三角洲塑化有限公司 High temperature resistant environment-protective polychloroethylene material for electric wire and cable
CN103342868A (en) * 2013-07-10 2013-10-09 江苏德威新材料股份有限公司 Environment-friendly ethanol migration resistance elastomer sheathing compound and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101412834A (en) * 2008-11-12 2009-04-22 江苏三角洲塑化有限公司 High temperature resistant environment-protective polychloroethylene material for electric wire and cable
CN103342868A (en) * 2013-07-10 2013-10-09 江苏德威新材料股份有限公司 Environment-friendly ethanol migration resistance elastomer sheathing compound and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113698713A (en) * 2021-09-13 2021-11-26 宁波圣捷新材料有限公司 Preparation method of modified PVC plastic material

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Application publication date: 20161116