CN107383822A - A kind of anti-freezing anti-cracking reinforcing agent for cable - Google Patents
A kind of anti-freezing anti-cracking reinforcing agent for cable Download PDFInfo
- Publication number
- CN107383822A CN107383822A CN201710657159.4A CN201710657159A CN107383822A CN 107383822 A CN107383822 A CN 107383822A CN 201710657159 A CN201710657159 A CN 201710657159A CN 107383822 A CN107383822 A CN 107383822A
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- China
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- parts
- cable
- reinforcing agent
- freezing
- age resister
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/08—Polyesters modified with higher fatty oils or their acids, or with resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
A kind of anti-freezing anti-cracking reinforcing agent for cable, it is made up of the component of following weight：20 30 parts of modified alkyd resin, 8 15 parts of polyurethane-modified acrylic acid emulsion, 10 15 parts of ethylene glycol, 5 10 parts of maleic anhydride inoculated polypropylene, 48 parts of sodium chloride, 7 15 parts of isopropanol, 8 12 parts of rosin, 24 parts of chliorinated polyvinyl chloride, 5 10 parts of C5 hydrogenated petroleum resins, 13 parts of palm oil, 46 parts of age resister.The reinforcing agent that the present invention makes enhances toughness, ductility, rotproofness, glossy property, has excellent anti-freezing anti-cracking effect after being added in cable manufacturing process.
Description
Technical field
The present invention relates to new material technology field, and in particular to a kind of anti-freezing anti-cracking reinforcing agent for cable.
Background technology
Cable is typically by several or the cable of similar rope that several groups of wire strandings form, mutually exhausted between every group of wire
Edge, and be often twisted into around a center, whole outside is surrounded by the coating of high-insulation.It is be erected in the air or mounted in ground more
Under, it is water-bed, for telecommunication or power Transmission.
Due to cable exposure in atmosphere, the easy bursting by freezing of cable, electricity can be caused by adverse circumstances such as sleet in the winter time
The damage of cable, have a strong impact on the transmission of telecommunication and the operation of power equipment, the waste of electric power resource, it is also possible to cause danger.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of anti-freezing anti-cracking reinforcing agent for cable.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of anti-freezing anti-cracking reinforcing agent for cable, it is made up of the component of following weight：Modified alkyd resin 20-30
Part, polyurethane-modified acrylic acid emulsion 8-15 parts, ethylene glycol 10-15 parts, maleic anhydride inoculated polypropylene 5-10 parts, sodium chloride 4-
8 parts, isopropanol 7-15 parts, rosin 8-12 parts, chliorinated polyvinyl chloride 2-4 parts, C5 hydrogenated petroleum resin 5-10 parts, palm oil 1-3
Part, age resister 4-6 parts.
The above-mentioned anti-freezing anti-cracking reinforcing agent for cable, the component of preferably following weight are made：25 parts of modified alkyd resin,
13 parts of polyurethane-modified acrylic acid emulsion, 12 parts of ethylene glycol, 8 parts of maleic anhydride inoculated polypropylene, 6 parts of sodium chloride, isopropanol 11
Part, 10 parts of rosin, 3 parts of chliorinated polyvinyl chloride, 7 parts of C5 hydrogenated petroleum resins, 2 parts of palm oil, 5 parts of age resister.
The age resister is made up of the component of following weight：Asbestos 4-8 parts, nano zine oxide 1-2 parts, nano aluminium oxide
0.5-0.8 parts, nano-calcium carbonate 2-3 parts, chitin 1-3 parts, Vitamin C palmitate 3-5 parts.
The component of the preferably following weight of the age resister is made：6 parts of asbestos, 2 parts of nano zine oxide, nano aluminium oxide
0.6 part, 2.5 parts of nano-calcium carbonate, 2 parts of chitin, 4 parts of Vitamin C palmitate.
The preparation method of the above-mentioned anti-freezing anti-cracking reinforcing agent for cable is as follows：
A, modified alkyd resin, ethylene glycol, maleic anhydride inoculated polypropylene, isopropanol are mixed, are heated to molten condition,
Reaction is stirred, mixing time is 20-30 minutes；
B, by polyurethane-modified acrylic acid emulsion, sodium chloride, rosin, chliorinated polyvinyl chloride, C5 hydrogenated petroleum resins, palm
Oil is added in reactor, and temperature setting is reacted, the reaction time is 30-40 minutes in 120-150 degree；
C, step a mixtures and b mixture are added in mixer and are stirred, mixing speed 800-1000r/
Min, temperature setting 80-90, mixing time are 20-30 minutes；
D, age resister is added in step c mixer, continues to stir, mixing speed 1200-1400r/min,
Temperature setting is 40-60, and mixing time is 30-40 minutes；
E, the mixture for handling step d well, five segmentation grindings is carried out, that is, obtain finished product.
It is described five times segmentation grinding speed be respectively：40-50/rpm, 60-80/rpm, 90-100/rpm, 100-120/
rpm。
The beneficial effects of the invention are as follows：The present invention using modified alkyd resin, polyurethane-modified acrylic acid emulsion, ethylene glycol as
Primary raw material, and with the addition of maleic anhydride inoculated polypropylene, sodium chloride, isopropanol, rosin, chliorinated polyvinyl chloride, C5 hydrogenation stones
As modifying agent, the reinforcing agent that the present invention makes strengthens after being added in cable manufacturing process for oleoresin, palm oil, age resister
Toughness, ductility, rotproofness, glossy property, there is excellent anti-freezing anti-cracking effect.
Embodiment：
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
A kind of anti-freezing anti-cracking reinforcing agent for cable, it is made up of the component of following weight：20 parts of modified alkyd resin, gather
8 parts of urethane modified acrylate emulsion, 10 parts of ethylene glycol, 5 parts of maleic anhydride inoculated polypropylene, 4 parts of sodium chloride, 7 parts of isopropanol, pine
Fragrant 8 parts, 2 parts of chliorinated polyvinyl chloride, 5 parts of C5 hydrogenated petroleum resins, 1 part of palm oil, 4 parts of age resister.
The age resister is made up of the component of following weight：4 parts of asbestos, 1 part of nano zine oxide, nano aluminium oxide 0.5
Part, 2 parts of nano-calcium carbonate, 1 part of chitin, 3 parts of Vitamin C palmitate.
The preparation method of the above-mentioned anti-freezing anti-cracking reinforcing agent for cable is as follows：
A, modified alkyd resin, ethylene glycol, maleic anhydride inoculated polypropylene, isopropanol are mixed, are heated to molten condition,
Reaction is stirred, mixing time is 20 minutes；
B, polyurethane-modified acrylic acid emulsion, sodium chloride, rosin, chliorinated polyvinyl chloride, C5 hydrogenated petroleum resins, palm oil
It is added in reactor, temperature setting is reacted at 120 degree, and the reaction time is 30 minutes；
C, step a mixtures and b mixture are added in mixer and are stirred, mixing speed 800r/min, temperature
Degree is arranged to 80, and mixing time is 20 minutes；
D, age resister is added in step c mixer, continues to stir, mixing speed 1200r/min, temperature is set
40 are set to, mixing time is 30 minutes；
E, the mixture for handling step d well, carries out five segmentation grindings, and the speed of five segmentation grindings is respectively：40/
Rpm, 60/rpm, 90/rpm, 100/rpm, that is, obtain finished product.
Embodiment 2
A kind of anti-freezing anti-cracking reinforcing agent for cable, it is made up of the component of following weight：30 parts of modified alkyd resin, gather
15 parts of urethane modified acrylate emulsion, 15 parts of ethylene glycol, 10 parts of maleic anhydride inoculated polypropylene, 8 parts of sodium chloride, isopropanol 15
Part, 12 parts of rosin, 4 parts of chliorinated polyvinyl chloride, 10 parts of C5 hydrogenated petroleum resins, 3 parts of palm oil, 6 parts of age resister.
The age resister is made up of the component of following weight：8 parts of asbestos, 2 parts of nano zine oxide, nano aluminium oxide 0.8
Part, 3 parts of nano-calcium carbonate, 3 parts of chitin, Vitamin C palmitate 3-5 parts.
The preparation method of the above-mentioned anti-freezing anti-cracking reinforcing agent for cable is as follows：
A, modified alkyd resin, ethylene glycol, maleic anhydride inoculated polypropylene, isopropanol are mixed, are heated to molten condition,
Reaction is stirred, mixing time is 30 minutes；
B, polyurethane-modified acrylic acid emulsion, sodium chloride, rosin, chliorinated polyvinyl chloride, C5 hydrogenated petroleum resins, palm oil
It is added in reactor, temperature setting is reacted at 150 degree, and the reaction time is 40 minutes；
C, step a mixtures and b mixture are added in mixer and are stirred, mixing speed 1000r/min, temperature
Degree is arranged to 90, and mixing time is 30 minutes；
D, age resister is added in step c mixer, continues to stir, mixing speed 1400r/min, temperature is set
60 are set to, mixing time is 40 minutes；
E, the mixture for handling step d well, carries out five segmentation grindings, and the speed of five segmentation grindings is respectively：50/
Rpm, 80/rpm, 100/rpm, 120/rpm, that is, obtain finished product.
Control group 1
A kind of anti-freezing anti-cracking reinforcing agent for cable, it is made up of the component of following weight：20 parts of modified alkyd resin, gather
8 parts of urethane modified acrylate emulsion, 10 parts of ethylene glycol, 5 parts of maleic anhydride inoculated polypropylene, 4 parts of sodium chloride, 7 parts of isopropanol, pine
Fragrant 8 parts, 2 parts of chliorinated polyvinyl chloride, 5 parts of C5 hydrogenated petroleum resins, 1 part of palm oil, 4 parts of age resister.
The age resister is common age resister.
The preparation method of the above-mentioned anti-freezing anti-cracking reinforcing agent for cable is as follows：
A, modified alkyd resin, ethylene glycol, maleic anhydride inoculated polypropylene, isopropanol are mixed, are heated to molten condition,
Reaction is stirred, mixing time is 20 minutes；
B, polyurethane-modified acrylic acid emulsion, sodium chloride, rosin, chliorinated polyvinyl chloride, C5 hydrogenated petroleum resins, palm oil
It is added in reactor, temperature setting is reacted at 120 degree, and the reaction time is 30 minutes；
C, step a mixtures and b mixture are added in mixer and are stirred, mixing speed 800r/min, temperature
Degree is arranged to 80, and mixing time is 20 minutes；
D, age resister is added in step c mixer, continues to stir, mixing speed 1200r/min, temperature is set
40 are set to, mixing time is 30 minutes；
E, the mixture for handling step d well, carries out five segmentation grindings, and the speed of five segmentation grindings is respectively：40/
Rpm, 60/rpm, 90/rpm, 100/rpm, that is, obtain finished product.
Embodiment 2
A kind of anti-freezing anti-cracking reinforcing agent for cable, it is made up of the component of following weight：30 parts of modified alkyd resin, gather
15 parts of urethane modified acrylate emulsion, 15 parts of ethylene glycol, 10 parts of maleic anhydride inoculated polypropylene, 8 parts of sodium chloride, isopropanol 15
Part, 12 parts of rosin, 4 parts of chliorinated polyvinyl chloride, 10 parts of C5 hydrogenated petroleum resins, 3 parts of palm oil, 6 parts of age resister.
The age resister is made up of the component of following weight：8 parts of asbestos, 2 parts of nano zine oxide, nano aluminium oxide 0.8
Part, 3 parts of nano-calcium carbonate, 3 parts of chitin, Vitamin C palmitate 3-5 parts.
The preparation method of the above-mentioned anti-freezing anti-cracking reinforcing agent for cable is as follows：
A, modified alkyd resin, ethylene glycol, maleic anhydride inoculated polypropylene, isopropanol are mixed, are heated to molten condition,
Reaction is stirred, mixing time is 30 minutes；
B, polyurethane-modified acrylic acid emulsion, sodium chloride, rosin, chliorinated polyvinyl chloride, C5 hydrogenated petroleum resins, palm oil
It is added in reactor, temperature setting is reacted at 100 degree, and the reaction time is 40 minutes；
C, step a mixtures and b mixture are added in mixer and are stirred, mixing speed 600r/min, temperature
Degree is arranged to 90, and mixing time is 30 minutes；
D, age resister is added in step c mixer, continues to stir, mixing speed 800r/min, temperature is set
60 are set to, mixing time is 40 minutes；
E, the mixture for handling step d well, it is ground, that is, obtains finished product.
Table 1 adds cable with control group for the present invention and made, manufactured cable performance test
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (6)
1. a kind of anti-freezing anti-cracking reinforcing agent for cable, it is made up of the component of following weight：Modified alkyd resin 20-30 parts,
Polyurethane-modified acrylic acid emulsion 8-15 parts, ethylene glycol 10-15 parts, maleic anhydride inoculated polypropylene 5-10 parts, sodium chloride 4-8
Part, isopropanol 7-15 parts, rosin 8-12 parts, chliorinated polyvinyl chloride 2-4 parts, C5 hydrogenated petroleum resin 5-10 parts, palm oil 1-3
Part, age resister 4-6 parts.
2. the anti-freezing anti-cracking reinforcing agent according to claim 1 for cable, it is characterised in that the group of preferred following weight
Divide and be made：25 parts of modified alkyd resin, 13 parts of polyurethane-modified acrylic acid emulsion, 12 parts of ethylene glycol, maleic anhydride grafting poly- third
8 parts of alkene, 6 parts of sodium chloride, 11 parts of isopropanol, 10 parts of rosin, 3 parts of chliorinated polyvinyl chloride, 7 parts of C5 hydrogenated petroleum resins, palm oil 2
Part, 5 parts of age resister.
3. the anti-freezing anti-cracking reinforcing agent according to claim 1 for cable, it is characterised in that the age resister by with
The component of lower weight is made：Asbestos 4-8 parts, nano zine oxide 1-2 parts, nano aluminium oxide 0.5-0.8 parts, nano-calcium carbonate 2-3
Part, chitin 1-3 parts, Vitamin C palmitate 3-5 parts.
4. the anti-freezing anti-cracking reinforcing agent according to claim 1 for cable, it is characterised in that the age resister is preferred
The component of following weight is made：6 parts of asbestos, 2 parts of nano zine oxide, 0.6 part of nano aluminium oxide, 2.5 parts of nano-calcium carbonate, crust
Plain 2 parts, 4 parts of Vitamin C palmitate.
5. a kind of anti-freezing anti-cracking reinforcing agent for preparing any one of claim 1-2 and being used for cable, it is characterised in that including step such as
Under：
A, modified alkyd resin, ethylene glycol, maleic anhydride inoculated polypropylene, isopropanol are mixed, is heated to molten condition, carried out
Stirring reaction, mixing time are 20-30 minutes；
B, polyurethane-modified acrylic acid emulsion, sodium chloride, rosin, chliorinated polyvinyl chloride, C5 hydrogenated petroleum resins, palm oil are added
Enter into reactor, temperature setting is reacted, the reaction time is 30-40 minutes in 120-150 degree；
C, step a mixtures and b mixture are added in mixer and are stirred, mixing speed 800-1000r/min, temperature
Degree is arranged to 80-90, and mixing time is 20-30 minutes；
D, age resister is added in step c mixer, continues to stir, mixing speed 1200-1400r/min, temperature
40-60 is arranged to, mixing time is 30-40 minutes；
E, the mixture for handling step d well, five segmentation grindings is carried out, that is, obtain finished product.
6. according to the method for claim 5, it is characterised in that it is described five times segmentation grinding speed be respectively：40-50/
Rpm, 60-80/rpm, 90-100/rpm, 100-120/rpm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710657159.4A CN107383822A (en) | 2017-08-03 | 2017-08-03 | A kind of anti-freezing anti-cracking reinforcing agent for cable |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710657159.4A CN107383822A (en) | 2017-08-03 | 2017-08-03 | A kind of anti-freezing anti-cracking reinforcing agent for cable |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107383822A true CN107383822A (en) | 2017-11-24 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710657159.4A Pending CN107383822A (en) | 2017-08-03 | 2017-08-03 | A kind of anti-freezing anti-cracking reinforcing agent for cable |
Country Status (1)
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|---|---|
| CN (1) | CN107383822A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108329680A (en) * | 2018-02-24 | 2018-07-27 | 四会市启德信息咨询服务有限公司 | A kind of anticracking reinforcing agent for new-energy automobile cable |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103382334A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Alkyd modified acrylic acid emulsion paint with high weatherability |
| CN105037962A (en) * | 2015-08-05 | 2015-11-11 | 安徽电信器材贸易工业有限责任公司 | Processable cable material for high power and preparation method thereof |
-
2017
- 2017-08-03 CN CN201710657159.4A patent/CN107383822A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103382334A (en) * | 2013-07-08 | 2013-11-06 | 吴江市物华五金制品有限公司 | Alkyd modified acrylic acid emulsion paint with high weatherability |
| CN105037962A (en) * | 2015-08-05 | 2015-11-11 | 安徽电信器材贸易工业有限责任公司 | Processable cable material for high power and preparation method thereof |
Non-Patent Citations (3)
| Title |
|---|
| 于新，等: "《天然食品添加剂》", 31 March 2014, 中国轻工业出版社 * |
| 吴庆定，等: "《非金属材料及应用》", 31 May 2016, 机械工业出版社 * |
| 钱逢麟，等: "《涂料助剂》", 30 November 1990, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108329680A (en) * | 2018-02-24 | 2018-07-27 | 四会市启德信息咨询服务有限公司 | A kind of anticracking reinforcing agent for new-energy automobile cable |
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Application publication date: 20171124 |