CN106117904A - A kind of high intensity antibacterial polyvinyl chloride film formulation - Google Patents

A kind of high intensity antibacterial polyvinyl chloride film formulation Download PDF

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Publication number
CN106117904A
CN106117904A CN201610615032.1A CN201610615032A CN106117904A CN 106117904 A CN106117904 A CN 106117904A CN 201610615032 A CN201610615032 A CN 201610615032A CN 106117904 A CN106117904 A CN 106117904A
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parts
high intensity
polyvinyl chloride
pentachlorophenol
bpo
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CN201610615032.1A
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Chinese (zh)
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陈林美
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2461/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
    • C08J2461/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

The invention discloses a kind of high intensity antibacterial polyvinyl chloride film formulation, including the raw material of following weight portion: polrvinyl chloride 78 90 parts, 10 15 parts of amino resins, chlorosulfonated polyethylene 10 14 parts, gas-phase silica 23 parts, methyl methacrylate 10 15 parts, white carbon black 15 parts, Ammonium persulfate. 20 30 parts, ethyl acetate 30 50 parts, BPO 48 parts, 11 16 parts of acrylic acid, carbon tetrachloride 36 parts, pentachlorophenol 25 parts, 100 120 parts of water.High intensity antibacterial polyvinyl chloride thin film of the present invention has suppression antibacterial, kills the advantage such as antibacterial and environmental protection, and after life-time service, effect is unaffected, and its intensity, toughness, fine heat-resisting performance.

Description

A kind of high intensity antibacterial polyvinyl chloride film formulation
Technical field
The invention belongs to polymeric material field, be specifically related to a kind of high intensity antibacterial polyvinyl chloride film formulation.
Background technology
The yield of Chinese Plastics thin film accounts for the 20% of plastic total output, is that in plastic increase of production is faster One of classification.In terms of the application of China's plastic sheeting (thickness is 0.06mm～0.26mm), consumption is maximum, kind is most, Most widely used is packaging industry, and its consumption accounts for 2/3, next to that agricultural accounts for 30%, then to have be exactly functional membrane, such as micropore Film, screened film, geomembrane etc..If adding suitable plastic additive in resin matrix, it is possible to prepare required various merits Can property thin film.Production method on plastic film industry has rolling process and extrusion molding, and wherein extrusion molding is divided into again extrusion blown film, squeezes Go out curtain coating, extrusion stretching (also known as post forming) etc..
Along with development and the adjustment of the structure of rural undertaking of China's economic, the China all trades and professions market to plastic sheeting Demand constantly rises.Predict that global plastic sheetings in 2015 and sheet material apparent consumption are expected to reach 50,700,000 tons, wherein Asia-Pacific Area is anticipated will become fastest-rising regional markets.Chinese Plastics thin film industry is currently in flourish rank Section, 2001-2011 market scale average annual growth rate reaches more than 18%, it is contemplated that within 2012, be up to 350,000,000,000 yuan.
Chinese Plastics film industry is in a flourish stage, it is reported, the demand of Chinese Plastics thin film is every Year by with more than 9% speed increment.And along with various new materials, new equipment and new technology are constantly emerged in large numbers, in promoting The plastic sheeting of state is towards diversification of varieties, customizations and possesses multi-functional composite membrane direction and develops.
Plastic sheeting, is used for packing, and is used as coating layer.Plastics package and plastic packet product are commercially shared Share is increasing, particularly composite plastic flexible package, has been widely used for the fields such as food, medicine, chemical industry, Qi Zhongyou Maximum with packaging for foodstuff proportion, such as beverage packaging, quick frozen food packaging, cooking food packaging, fast food packaging etc., These products all bring great convenience to people's life.
The light resistance of polrvinyl chloride book film, resistance to ag(e)ing are relatively good and have reasonable tear-resistant performance, can breathe freely, be A kind of cleaning, colourless, transparent thin film, typically add plasticizer, and it dissolves in acetone, cyclohexanone equal solvent.Therefore, it can use The ink printing of polyvinyl chloride resin.It is applicable to packaging bag, cover etc..It is deeply to be liked in the world today, rather flow Row and a kind of synthetic material being also widely used.The global usage amount of PVC film is in second in various synthetic materials. But it is low that existing PVC film exists intensity, the problem such as easily it is contaminated by bacterial, receives certain restriction to its use.
In sum, the deficiency solving prior art existence has become the technical problem that this area is urgently to be resolved hurrily.
Summary of the invention
It is an object of the invention to provide a kind of high intensity antibacterial polyvinyl chloride film formulation.
To achieve these goals, the invention provides a kind of high intensity antibacterial polyvinyl chloride film formulation, by following heavy The raw material of amount part prepares: polrvinyl chloride 78-90 part, amino resins 10-15 part, chlorosulfonated polyethylene 10-14 part, gas-phase silica 2-3 part, methyl methacrylate 10-15 part, white carbon black 1-5 part, Ammonium persulfate. 20-30 part, ethyl acetate 30-50 part, BPO4-8 Part, acrylic acid 11-16 part, carbon tetrachloride 3-6 part, pentachlorophenol 2-5 part, water 100-120 part.
Preferred version is to be prepared by the raw material of following weight portion: polrvinyl chloride 78 parts, 10 parts of amino resins, the poly-second of chlorosulfonation 10 parts of alkene, gas-phase silica 2 parts, methyl methacrylate 10 parts, white carbon black 1 part, Ammonium persulfate. 20 parts, ethyl acetate 30 parts, BPO 4 parts, 11 parts of acrylic acid, carbon tetrachloride 3 parts, pentachlorophenol 2 parts, 100 parts of water.
Preferred version is to be prepared by the raw material of following weight portion: polrvinyl chloride 90 parts, 15 parts of amino resins, the poly-second of chlorosulfonation 14 parts of alkene, gas-phase silica 3 parts, methyl methacrylate 15 parts, white carbon black 5 parts, Ammonium persulfate. 30 parts, ethyl acetate 50 parts, BPO 8 parts, 16 parts of acrylic acid, carbon tetrachloride 6 parts, pentachlorophenol 5 parts, 120 parts of water.
Preferred version is to be prepared by the raw material of following weight portion: polrvinyl chloride 80 parts, 12 parts of amino resins, the poly-second of chlorosulfonation 12 parts of alkene, gas-phase silica 2 parts, methyl methacrylate 12 parts, white carbon black 2 parts, Ammonium persulfate. 22 parts, ethyl acetate 35 parts, BPO 5 parts, 12 parts of acrylic acid, carbon tetrachloride 4 parts, pentachlorophenol 3 parts, 110 parts of water.
Preferred version is to be prepared by the raw material of following weight portion: polrvinyl chloride 85 parts, 14 parts of amino resins, the poly-second of chlorosulfonation 13 parts of alkene, gas-phase silica 3 parts, methyl methacrylate 14 parts, white carbon black 4 parts, Ammonium persulfate. 28 parts, ethyl acetate 45 parts, BPO 6 parts, 15 parts of acrylic acid, carbon tetrachloride 5 parts, pentachlorophenol 4 parts, 115 parts of water.
Its preparation method is: weigh each component by weight ratio, puts in reactor, and in nitrogen atmosphere, heating is anti- Should, it being then fed into double screw extruder, twin-screw extrusion batten is water cooled, air-dried, pelletizing, obtains master batch, is finally put by master batch Enter plastic film blowing machine extrusion blown film, i.e. obtain finished product.
The method have the advantages that high intensity antibacterial polyvinyl chloride thin film of the present invention has suppression antibacterial, kills The advantage such as antibacterial and environmental protection, after life-time service, effect is unaffected, and its intensity, toughness, fine heat-resisting performance.
Detailed description of the invention
Embodiment 1
A kind of high intensity antibacterial polyvinyl chloride film formulation of the present embodiment, is prepared by the raw material of following weight portion: polychlorostyrene Ethylene 78 parts, 10 parts of amino resins, chlorosulfonated polyethylene 10 parts, gas-phase silica 2 parts, methyl methacrylate 10 parts, white carbon black 1 Part, Ammonium persulfate. 20 parts, ethyl acetate 30 parts, BPO 4 parts, 11 parts of acrylic acid, carbon tetrachloride 3 parts, pentachlorophenol 2 parts, water 100 Part.Preparation method is: weigh each component by weight ratio, puts in reactor, reacting by heating in nitrogen atmosphere, then Sending into double screw extruder, twin-screw extrusion batten is water cooled, air-dried, pelletizing, obtains master batch, finally master batch is put into plastics and blows Film machine extrusion blown film, i.e. obtains finished product.
Embodiment 2
A kind of high intensity antibacterial polyvinyl chloride film formulation of the present embodiment, is prepared by the raw material of following weight portion: polychlorostyrene Ethylene 90 parts, 15 parts of amino resins, chlorosulfonated polyethylene 14 parts, gas-phase silica 3 parts, methyl methacrylate 15 parts, white carbon black 5 Part, Ammonium persulfate. 30 parts, ethyl acetate 50 parts, BPO 8 parts, 16 parts of acrylic acid, carbon tetrachloride 6 parts, pentachlorophenol 5 parts, water 120 Part.Preparation method is: weigh each component by weight ratio, puts in reactor, reacting by heating in nitrogen atmosphere, then Sending into double screw extruder, twin-screw extrusion batten is water cooled, air-dried, pelletizing, obtains master batch, finally master batch is put into plastics and blows Film machine extrusion blown film, i.e. obtains finished product.
Embodiment 3
A kind of high intensity antibacterial polyvinyl chloride film formulation of the present embodiment, is prepared by the raw material of following weight portion: polychlorostyrene Ethylene 80 parts, 12 parts of amino resins, chlorosulfonated polyethylene 12 parts, gas-phase silica 2 parts, methyl methacrylate 12 parts, white carbon black 2 Part, Ammonium persulfate. 22 parts, ethyl acetate 35 parts, BPO 5 parts, 12 parts of acrylic acid, carbon tetrachloride 4 parts, pentachlorophenol 3 parts, water 110 Part.Preparation method is: weigh each component by weight ratio, puts in reactor, reacting by heating in nitrogen atmosphere, then Sending into double screw extruder, twin-screw extrusion batten is water cooled, air-dried, pelletizing, obtains master batch, finally master batch is put into plastics and blows Film machine extrusion blown film, i.e. obtains finished product.
Embodiment 4
A kind of high intensity antibacterial polyvinyl chloride film formulation of the present embodiment, is prepared by the raw material of following weight portion: polychlorostyrene Ethylene 85 parts, 14 parts of amino resins, chlorosulfonated polyethylene 13 parts, gas-phase silica 3 parts, methyl methacrylate 14 parts, white carbon black 4 Part, Ammonium persulfate. 28 parts, ethyl acetate 45 parts, BPO 6 parts, 15 parts of acrylic acid, carbon tetrachloride 5 parts, pentachlorophenol 4 parts, water 115 Part.Preparation method is: weigh each component by weight ratio, puts in reactor, reacting by heating in nitrogen atmosphere, then Sending into double screw extruder, twin-screw extrusion batten is water cooled, air-dried, pelletizing, obtains master batch, finally master batch is put into plastics and blows Film machine extrusion blown film, i.e. obtains finished product.

Claims (5)

1. a high intensity antibacterial polyvinyl chloride film formulation, it is characterised in that include the raw material of following weight portion: polrvinyl chloride 78-90 part, amino resins 10-15 part, chlorosulfonated polyethylene 10-14 part, gas-phase silica 2-3 part, methyl methacrylate 10- 15 parts, white carbon black 1-5 part, Ammonium persulfate. 20-30 part, ethyl acetate 30-50 part, BPO 4-8 part, acrylic acid 11-16 part, four chlorinations Carbon 3-6 part, pentachlorophenol 2-5 part, water 100-120 part.
A kind of high intensity antibacterial polyvinyl chloride film formulation the most according to claim 1, it is characterised in that by following weight The raw material of part prepares: polrvinyl chloride 78 parts, 10 parts of amino resins, chlorosulfonated polyethylene 10 parts, gas-phase silica 2 parts, methyl-prop E pioic acid methyl ester 10 parts, white carbon black 1 part, Ammonium persulfate. 20 parts, ethyl acetate 30 parts, BPO 4 parts, 11 parts of acrylic acid, carbon tetrachloride 3 Part, pentachlorophenol 2 parts, 100 parts of water.
A kind of high intensity antibacterial polyvinyl chloride film formulation the most according to claim 1, it is characterised in that by following weight The raw material of part prepares: polrvinyl chloride 90 parts, 15 parts of amino resins, chlorosulfonated polyethylene 14 parts, gas-phase silica 3 parts, methyl-prop E pioic acid methyl ester 15 parts, white carbon black 5 parts, Ammonium persulfate. 30 parts, ethyl acetate 50 parts, BPO 8 parts, 16 parts of acrylic acid, carbon tetrachloride 6 Part, pentachlorophenol 5 parts, 120 parts of water.
A kind of high intensity antibacterial polyvinyl chloride film formulation the most according to claim 1, it is characterised in that by following weight The raw material of part prepares: polrvinyl chloride 80 parts, 12 parts of amino resins, chlorosulfonated polyethylene 12 parts, gas-phase silica 2 parts, methyl-prop E pioic acid methyl ester 12 parts, white carbon black 2 parts, Ammonium persulfate. 22 parts, ethyl acetate 35 parts, BPO 5 parts, 12 parts of acrylic acid, carbon tetrachloride 4 Part, pentachlorophenol 3 parts, 110 parts of water.
A kind of high intensity antibacterial polyvinyl chloride film formulation the most according to claim 1, it is characterised in that by following weight The raw material of part prepares: polrvinyl chloride 85 parts, 14 parts of amino resins, chlorosulfonated polyethylene 13 parts, gas-phase silica 3 parts, methyl-prop E pioic acid methyl ester 14 parts, white carbon black 4 parts, Ammonium persulfate. 28 parts, ethyl acetate 45 parts, BPO 6 parts, 15 parts of acrylic acid, carbon tetrachloride 5 Part, pentachlorophenol 4 parts, 115 parts of water.
CN201610615032.1A 2016-07-28 2016-07-28 A kind of high intensity antibacterial polyvinyl chloride film formulation Pending CN106117904A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107619556A (en) * 2017-10-20 2018-01-23 天津市宝德包装有限公司 A kind of high-strength and ageing resistance plastic sheeting formula
CN108250470A (en) * 2017-11-27 2018-07-06 广德粤华塑业制品有限公司 A kind of soft coated thin films of PVC

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819833A (en) * 2012-11-16 2014-05-28 无锡市黄盛包装制品有限公司 Preparation method of antimicrobial packing bag for grains
CN104877268A (en) * 2015-05-22 2015-09-02 苏州市贝克生物科技有限公司 Preparation method of environment-friendly bacteriostatic medical film

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819833A (en) * 2012-11-16 2014-05-28 无锡市黄盛包装制品有限公司 Preparation method of antimicrobial packing bag for grains
CN104877268A (en) * 2015-05-22 2015-09-02 苏州市贝克生物科技有限公司 Preparation method of environment-friendly bacteriostatic medical film

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107619556A (en) * 2017-10-20 2018-01-23 天津市宝德包装有限公司 A kind of high-strength and ageing resistance plastic sheeting formula
CN108250470A (en) * 2017-11-27 2018-07-06 广德粤华塑业制品有限公司 A kind of soft coated thin films of PVC

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Application publication date: 20161116