CN106116693B - It is a kind of suitable for the high-strength interfacial agents of composite polymer lotion of vitrified tile and preparation - Google Patents
It is a kind of suitable for the high-strength interfacial agents of composite polymer lotion of vitrified tile and preparation Download PDFInfo
- Publication number
- CN106116693B CN106116693B CN201610451384.8A CN201610451384A CN106116693B CN 106116693 B CN106116693 B CN 106116693B CN 201610451384 A CN201610451384 A CN 201610451384A CN 106116693 B CN106116693 B CN 106116693B
- Authority
- CN
- China
- Prior art keywords
- small particle
- interfacial agents
- acrylic emulsion
- styrene
- composite polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/82—Coating or impregnation with organic materials
- C04B41/83—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/48—Macromolecular compounds
- C04B41/4857—Other macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B41/4861—Polyalkenes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Finishing Walls (AREA)
Abstract
The invention belongs to interfacial agents technical fields, disclose a kind of high-strength interfacial agents of composite polymer lotion and preparation method thereof suitable for vitrified tile.Interfacial agents of the present invention include the component of following mass fraction：Small particle styrene-acrylic emulsion 45~65%；Pure-acrylic emulsion 15~25%；Small particle styrene-butadiene emulsion 5~10%；Synergist 0.2~0.5%；Dispersant 0.1~0.3%；Wetting agent 0.3~1.0%；Remaining water.The present invention uses the styrene-acrylic emulsion of small particle, the styrene-butadiene emulsion of cooperation more small particle is as bleeding agent, collocation uses aqueous synergist, is effectively improved the water solubility of above two lotion, improves the compatibility of lotion, increase the bonding force and stability of boundary material, not only it may be implemented to infiltrate through the effect at the low water absorption ceramic tile back side, but also increase the pull strength of material, and give full play to the resultant effect of acrylic emulsion, two-way penetration completely plays the bonding force of cement-based material.
Description
Technical field
The invention belongs to interfacial agents technical field, more particularly to a kind of composite polymer lotion suitable for vitrified tile is high
Strong interface agent and preparation method thereof.
Background technology
Now due to the raising of living standards of the people, is to represent high-compactness and low water absorption (water absorption rate with vitrified tile etc.
Less than 0.5%) porcelain tapestry brick, large-scale application has been in the decorative engineering on wall ground, and low due to the type tapestry brick
The difference of water absorption rate, laying method also causes its paving effect difference very huge.The method master of paving the type ceramic tile at present
Will there are two types of：1, using ceramic tile adhesive paving；2, coordinate paving using cement and generic interface agent.Porcelain is used for the first
The laying method of brick adhesive, although the ceramic tile adhesive for having small part high bond strength can preferably solve high-compactness
The paving of low water absorption ceramic tile, however there are following defects for the type laying method：(1) ceramic tile adhesive is to such as vitrified tile
Etc low water absorption ceramic tile sticking effect it is totally undesirable, the bonding force of ceramic tile adhesive itself is not sufficient to make to paste
Ceramic tile do not generate hollowing and peeling phenomenon；(2) there are Multiple Types for ceramic tile adhesive, and the glue for tile of a large amount of low adhesion strengths
Stick floods market, and makes construction personnel at a loss as to what to do, pastes the ineffective of low water absorption ceramic tile；(3) paving is of high cost, can be compared with
The commercially available price of ceramic tile adhesive for solving high-compactness low water absorption adhesion strength well is generally higher, therefore paving is of high cost；
(4) it needs to give construction personnel training using the construction of thin method, if constructed without using thin method, be constructed using traditional thick laid process,
Except material utilization amount greatly in addition to, paving cost is too high.For second of paving side using interfacial agents and cement paste or mortar mix
Method has the following problems：(1) adhesion strength is low, and hollowing peeling phenomenon is serious.There are many current interface treating agent existing on the market,
Most of interfacial agents are not specific to the ceramic tile research and development of high-compactness low water absorption, the bonding between interface treating agent and ceramic tile
Intensity is low, if being applied to the interface processing at the type ceramic tile back side, reuses ceramic tile adhesive or conventional method paving, easily
Because interface processing is not in place, and hollowing is caused to peel off phenomena such as.(2) most of interfacial agents that there are durabilities is poor, not water-fast, intolerant to
It waits, there is a possibility that the shortcomings of serious aging, there is serious using the ceramic tile of this method paving high-compactness low water absorption
Hidden danger.
Invention content
In order to overcome the shortcomings and deficiencies of the prior art described above, the primary purpose of the present invention is that providing a kind of suitable for glass
The high-strength interfacial agents of composite polymer lotion for changing brick, for solve high-compactness, low water absorption (water absorption rate be less than 0.5%),
The problem of vitrified tile paving hardly possible.Interfacial agents of the present invention are composite polymer emulsion material, are suitable for high-compactness low water absorption
The materials such as polished brick in porcelain character, vitrified tile, large-stone paving.The present invention can be directly used, cement base can also be coordinated
Powder brushes as two-component materials and arrives the ceramic tile back side, as good interfacial agents.
Another object of the present invention is to provide a kind of above-mentioned high strong interface of composite polymer lotion suitable for vitrified tile
The preparation method of agent.
Still a further object of the present invention is to provide the above-mentioned high-strength interfacial agents of composite polymer lotion suitable for vitrified tile
Using.
The purpose of the present invention is realized by following proposal：
A kind of high-strength interfacial agents of composite polymer lotion suitable for vitrified tile include the component of following mass fraction：
Small particle styrene-acrylic emulsion 45~65%；Pure-acrylic emulsion 15~25%；Small particle styrene-butadiene emulsion 5~10%；Synergist 0.2~
0.5%；Dispersant 0.1~0.3%；Wetting agent 0.3~1.0%；Remaining water.
Preferably, the composite polymer lotion high-strength interfacial agents of the present invention suitable for vitrified tile, including following matter
Measure the component of score：Small particle styrene-acrylic emulsion 55~65%；Pure-acrylic emulsion 20~25%；Small particle styrene-butadiene emulsion 5~10%；Increase
Imitate agent 0.3%；Dispersant 0.1%；Wetting agent 0.5%；Remaining water.
The synergist is preferably mixed by the component including mannose, wetting tackifier, glucuronic acid, pyruvic acid, water
Conjunction obtains.More preferably by including 15~20wt%D- mannoses, 25~30wt% wettings tackifier, 10~20wt%D- glucose sugar
Aldehydic acid, 1~1.5wt% pyruvic acid, remaining is mixed to get for the component of water.
The wetting tackifier can be commonly used in the art wetting tackifier, such as can be SM-20,713.
Synergist of the present invention is water-based material, dissolves in interfacial agents, is effectively improved the water-soluble of above two lotion
Property, the compatibility of lotion is improved, the bonding force and stability of boundary material are increased.
The high-strength interfacial agents of composite polymer lotion suitable for vitrified tile of the present invention, the small particle styrene-acrylic emulsion
Concentration be preferably 50~55wt%, particle size range is preferably between 30~60nm.
The concentration of the pure-acrylic emulsion is preferably 51~56wt%.
The concentration of the small particle styrene-butadiene emulsion is preferably 50~55wt%；Particle size range is preferably between 50~120nm.
The dispersant is dispersant commonly used in the art, such as can be P-10,5040.
The wetting agent is wetting agent commonly used in the art, such as can be LCN407, LCN405.
The present invention also provides a kind of preparation sides of the above-mentioned high-strength interfacial agents of composite polymer lotion suitable for vitrified tile
Method is obtained by the way that the component to be uniformly mixed.
The high-strength interfacial agents of composite polymer lotion suitable for vitrified tile of the present invention are suitable for the low water suction of high-compactness
Interfacial agents of the present invention are painted on the brick back side by the paving of the materials such as polished brick in porcelain character, vitrified tile, the large-stone of rate, wait for that it is dry
It conventional cement net slurry, mortar can be used to carry out paving after dry, can get high-strength cohesive force, it is water-fast weather-proof, it avoids due to paving
Prevent hollowing, peeling phenomenon caused by material.
The present invention mechanism be：
The present invention is using the styrene-acrylic emulsion of small particle as the main material for realizing adhesive effect, cooperation more small particle
Styrene-butadiene emulsion as bleeding agent, collocation uses aqueous synergist, dissolves in interfacial agents, is effectively improved above two lotion
Water solubility, improve the compatibility of lotion, increase the bonding force and stability of boundary material, while solving stability,
Not only it may be implemented to infiltrate through the effect at the low water absorption ceramic tile back side, but also increase the pull strength of material, and give full play to acrylic acid
The resultant effect of lotion, two-way penetration completely play the bonding force of cement-based material.
The present invention compared with the existing technology, has the following advantages and advantageous effect：
The back side of high-compactness low water absorption ceramic tile is painted on using material of the present invention, it is only necessary to use ordinary cement or general
Splendid paving intensity can be realized with traditional laying method for water flowing cement mortar, be not necessarily to other material or new laying method,
Satisfactorily resolve the hollowing spallation problems caused by being bonded force difference；Material is uniform, stable quality.
Specific implementation mode
With reference to embodiment, the present invention is described in further detail, and embodiments of the present invention are not limited thereto.
The reagent used in the following example can be commercially available from commercial channel.
Embodiment 1
A kind of high-strength interfacial agents of composite polymer lotion suitable for vitrified tile include the component of following mass fraction：
Small particle styrene-acrylic emulsion 65%；Pure-acrylic emulsion 20%；Small particle styrene-butadiene emulsion 10%；Synergist 0.3%；Dispersant 0.1%；Profit
Humectant 0.5%；Remaining water.
Wherein, a concentration of 55wt% of small particle styrene-acrylic emulsion, the particle size range of small particle styrene-acrylic emulsion is preferably 30~
Between 60nm；A concentration of 55wt% of pure-acrylic emulsion, small particle styrene-butadiene emulsion concentration 50wt%, particle size range is preferably 50~
Between 120nm；Dispersant is 5040；Wetting agent is LCN407；Synergist：Increase including 15wt%D- mannoses, 30wt% wettings
Stick SM-20,10wt%D- glucuronic acid, 1.0wt% pyruvic acid, remaining is mixed to get for the component of water.
It mixes the above components evenly, the high-strength interfacial agents of composite polymer lotion suitable for vitrified tile is obtained, by it
It directly is painted on the vitrified tile back side, conventional cement net slurry, mortar can be used to carry out paving after its drying, obtain high-strength bonding
The paving effect of power.
Using meeting JC/T 907-2002《Concrete interface treating agent》In 7d and 14d shear bond strengths and stretching
Testing result of the adhesive strength (untreated) as this material, the results are shown in Table 1.
The performance indicator of 1 interfacial agents of the present invention of table
As seen from Table 1, that treated is viscous for the high-strength interfacial agents of composite polymer lotion suitable for vitrified tile of the invention
Relay effect is ideal.
Embodiment 2
A kind of high-strength interfacial agents of composite polymer lotion suitable for vitrified tile include the component of following mass fraction：
Small particle styrene-acrylic emulsion 45%；Pure-acrylic emulsion 20%；Small particle styrene-butadiene emulsion 10%；Synergist 0.3%；Dispersant 0.1%；Profit
Humectant 0.5%；Remaining water.
Wherein, a concentration of 55wt% of small particle styrene-acrylic emulsion, the particle size range of small particle styrene-acrylic emulsion is preferably 30~
Between 60nm；A concentration of 55wt% of pure-acrylic emulsion, small particle styrene-butadiene emulsion concentration 50wt%, particle size range is preferably 50~
Between 120nm；Dispersant is 5040；Wetting agent is LCN407；Synergist：Increase including 20wt%D- mannoses, 25wt% wettings
Stick, 10wt%D- glucuronic acids, 1.5wt% pyruvic acid, remaining is mixed to get for the component of water.
It mixes the above components evenly, obtains the high-strength interfacial agents of composite polymer lotion suitable for vitrified tile.
It is directly painted on to the vitrified tile back side, conventional cement net slurry, mortar can be used to carry out paving after its drying,
Obtain the paving effect of high-strength cohesive force.
Using meeting JC/T 907-2002《Concrete interface treating agent》In 7d and 14d shear bond strengths and stretching
Testing result of the adhesive strength (untreated) as this material, the results are shown in Table 2.
The performance indicator of 2 interfacial agents of the present invention of table
As seen from Table 2, that treated is viscous for the high-strength interfacial agents of composite polymer lotion suitable for vitrified tile of the invention
Relay effect is ideal.
Embodiment 3
A kind of high-strength interfacial agents of composite polymer lotion suitable for vitrified tile include the component of following mass fraction：
Small particle styrene-acrylic emulsion 55%；Pure-acrylic emulsion 20%；Small particle styrene-butadiene emulsion 8%；Synergist 0.3%；Dispersant 0.1%；Profit
Humectant 0.5%；Remaining water.
Wherein, a concentration of 55wt% of small particle styrene-acrylic emulsion, the particle size range of small particle styrene-acrylic emulsion is preferably 30~
Between 60nm；A concentration of 55wt% of pure-acrylic emulsion, small particle styrene-butadiene emulsion concentration 50wt%, particle size range is preferably 50~
Between 120nm；Dispersant is 5040；Wetting agent is LCN407；Synergist：Increase including 18wt%D- mannoses, 27wt% wettings
Stick, 15wt%D- glucuronic acids, 1.2wt% pyruvic acid, remaining is mixed to get for the component of water.
It mixes the above components evenly, obtains the high-strength interfacial agents of composite polymer lotion suitable for vitrified tile.
It is directly painted on to the vitrified tile back side, conventional cement net slurry, mortar can be used to carry out paving after its drying,
Obtain high-strength cohesive force, water-fast weather-proof paving effect.
Using meeting JC/T 907-2002《Concrete interface treating agent》In 7d and 14d shear bond strengths and stretching
Testing result of the adhesive strength (untreated) as this material, the results are shown in Table 3.
The performance indicator of 3 interfacial agents of the present invention of table
As seen from Table 3, that treated is viscous for the high-strength interfacial agents of composite polymer lotion suitable for vitrified tile of the invention
Relay effect is ideal.
Embodiment 4
A kind of high-strength interfacial agents of composite polymer lotion suitable for vitrified tile include the component of following mass fraction：
Small particle styrene-acrylic emulsion 55%；Pure-acrylic emulsion 15%；Small particle styrene-butadiene emulsion 10%；Synergist 0.3%；Dispersant 0.1%；Profit
Humectant 0.5%；Remaining water.
Wherein, a concentration of 50wt% of small particle styrene-acrylic emulsion, the particle size range of small particle styrene-acrylic emulsion is preferably 30~
Between 60nm；A concentration of 51wt% of pure-acrylic emulsion, small particle styrene-butadiene emulsion concentration 55wt%, particle size range is preferably 50~
Between 120nm；Dispersant is 5040；Wetting agent is LCN407；Synergist：Increase including 18wt%D- mannoses, 27wt% wettings
Stick, 20wt%D- glucuronic acids, 1.2wt% pyruvic acid, remaining is mixed to get for the component of water.
It mixes the above components evenly, obtains the high-strength interfacial agents of composite polymer lotion suitable for vitrified tile.By its
It directly is painted on the vitrified tile back side, conventional cement net slurry, mortar can be used to carry out paving after its drying, obtain high-strength bonding
Power, water-fast weather-proof paving effect.
Embodiment 5
A kind of high-strength interfacial agents of composite polymer lotion suitable for vitrified tile include the component of following mass fraction：
Small particle styrene-acrylic emulsion 55%；Pure-acrylic emulsion 25%；Small particle styrene-butadiene emulsion 5%；Synergist 0.3%；Dispersant 0.1%；Profit
Humectant 0.5%；Remaining water.
Wherein, a concentration of 52wt% of small particle styrene-acrylic emulsion, the particle size range of small particle styrene-acrylic emulsion is preferably 30~
Between 60nm；A concentration of 56wt% of pure-acrylic emulsion, small particle styrene-butadiene emulsion concentration 52wt%, particle size range is preferably 50~
Between 120nm；Dispersant is 5040；Wetting agent is LCN407；Synergist：Increase including 18wt%D- mannoses, 27wt% wettings
Stick, 10wt%D- glucuronic acids, 1.2wt% pyruvic acid, remaining is mixed to get for the component of water.
It mixes the above components evenly, obtains the high-strength interfacial agents of composite polymer lotion suitable for vitrified tile.By its
It directly is painted on the vitrified tile back side, conventional cement net slurry, mortar can be used to carry out paving after its drying, obtain high-strength bonding
Power, water-fast weather-proof paving effect.
The above embodiment is a preferred embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment
Limitation, it is other it is any without departing from the spirit and principles of the present invention made by changes, modifications, substitutions, combinations, simplifications,
Equivalent substitute mode is should be, is included within the scope of the present invention.
Claims (8)
1. a kind of high-strength interfacial agents of composite polymer lotion suitable for vitrified tile, it is characterised in that including following mass fraction
Component：45~65 % of small particle styrene-acrylic emulsion；15~25 % of pure-acrylic emulsion；5~10 % of small particle styrene-butadiene emulsion；Synergist
0.2~0.5 %；0.1~0.3 % of dispersant；0.3~1.0 % of wetting agent；Remaining water；
The particle size range of the small particle styrene-acrylic emulsion is between 30~60 nm；
The particle size range of the small particle styrene-butadiene emulsion is between 50~120 nm；
The synergist is mixed to get by the component including mannose, wetting tackifier, glucuronic acid, pyruvic acid, water；
The synergist is by including 15~20 wt% D-MANNOSEs, 25~30 wt% wettings tackifier, 10~20 wt% D-
Glucuronic acid, 1~1.5 wt% pyruvic acid, remaining is mixed to get for the component of water.
2. the composite polymer lotion high-strength interfacial agents according to claim 1 suitable for vitrified tile, it is characterised in that
Include the component of following mass fraction：55~65 % of small particle styrene-acrylic emulsion；20~25 % of pure-acrylic emulsion；Small particle styrene-butadiene emulsion
5~10 %；0.3 % of synergist；0.1 % of dispersant；0.5 % of wetting agent；Remaining water.
3. the composite polymer lotion high-strength interfacial agents according to claim 1 suitable for vitrified tile, it is characterised in that：
The wetting tackifier are at least one of SM-20 and 713.
4. the composite polymer lotion high-strength interfacial agents according to claim 1 suitable for vitrified tile, it is characterised in that：
A concentration of 50~55 wt% of the small particle styrene-acrylic emulsion.
5. the composite polymer lotion high-strength interfacial agents according to claim 1 suitable for vitrified tile, it is characterised in that：
A concentration of 51~56 wt% of the pure-acrylic emulsion.
6. the composite polymer lotion high-strength interfacial agents according to claim 1 suitable for vitrified tile, it is characterised in that：
A concentration of 50~55 wt% of the small particle styrene-butadiene emulsion.
7. the composite polymer lotion high-strength interfacial agents according to claim 1 suitable for vitrified tile, it is characterised in that：
The dispersant is 5040；The wetting agent is LCN407.
8. a kind of claim 1~7 any one of them is suitable for the high-strength interfacial agents of composite polymer lotion of vitrified tile
Preparation method, it is characterised in that obtained by the way that the component to be uniformly mixed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610451384.8A CN106116693B (en) | 2016-06-20 | 2016-06-20 | It is a kind of suitable for the high-strength interfacial agents of composite polymer lotion of vitrified tile and preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610451384.8A CN106116693B (en) | 2016-06-20 | 2016-06-20 | It is a kind of suitable for the high-strength interfacial agents of composite polymer lotion of vitrified tile and preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106116693A CN106116693A (en) | 2016-11-16 |
| CN106116693B true CN106116693B (en) | 2018-11-13 |
Family
ID=57470407
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610451384.8A Active CN106116693B (en) | 2016-06-20 | 2016-06-20 | It is a kind of suitable for the high-strength interfacial agents of composite polymer lotion of vitrified tile and preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106116693B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107083215B (en) * | 2017-04-25 | 2019-02-01 | 广东银洋环保新材料有限公司 | A kind of ceramic tile gum produced by pure acrylate elastic emulsion and styrene-acrylic emulsion and technique |
| CN107130750A (en) * | 2017-06-10 | 2017-09-05 | 东莞市华美乐建材超市有限公司 | A kind of brushing method of pair of putty layer |
| CN107601985A (en) * | 2017-09-30 | 2018-01-19 | 易义清 | A kind of ceramic tile interface agent |
| CN109650775A (en) * | 2019-01-18 | 2019-04-19 | 武汉科技大学 | A kind of preparation method of the high-strength ceramic tile gum for high-temperature region |
| CN110451886A (en) * | 2019-08-23 | 2019-11-15 | 四川蓝筹建材有限公司 | A kind of cement base high bond strength interfacial agents |
| CN113003986A (en) * | 2021-04-23 | 2021-06-22 | 湖南永恒建筑节能材料有限公司 | Special interface agent for gypsum mortar and construction method thereof |
| CN114854265B (en) * | 2021-06-24 | 2023-08-29 | 安徽牛元新材料有限公司 | Interfacial agent for interface treatment of waterproof system and preparation method thereof |
| CN117886629B (en) * | 2024-03-14 | 2024-06-11 | 蒙娜丽莎集团股份有限公司 | Treating agent for overcoming lotus beads caused by hydrophobic/super-hydrophobic bottom surface of building ceramic, preparation method and use method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101935507A (en) * | 2009-07-02 | 2011-01-05 | 余春冠 | Water-proof back adhesive for stone |
| CN102167549A (en) * | 2011-01-13 | 2011-08-31 | 余春冠 | Vitrified brick gum |
| CN102674769A (en) * | 2009-07-02 | 2012-09-19 | 余春冠 | Waterproof gum for stone |
| CN104446251A (en) * | 2014-11-27 | 2015-03-25 | 久筑节能科技（天津）有限公司 | Adhesion agent as well as preparation method and application thereof |
-
2016
- 2016-06-20 CN CN201610451384.8A patent/CN106116693B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101935507A (en) * | 2009-07-02 | 2011-01-05 | 余春冠 | Water-proof back adhesive for stone |
| CN102674769A (en) * | 2009-07-02 | 2012-09-19 | 余春冠 | Waterproof gum for stone |
| CN102167549A (en) * | 2011-01-13 | 2011-08-31 | 余春冠 | Vitrified brick gum |
| CN104446251A (en) * | 2014-11-27 | 2015-03-25 | 久筑节能科技（天津）有限公司 | Adhesion agent as well as preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106116693A (en) | 2016-11-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106116693B (en) | It is a kind of suitable for the high-strength interfacial agents of composite polymer lotion of vitrified tile and preparation | |
| CN107513125A (en) | Ceramic tile gum silicone modified styrene-acrylate emulsion and preparation method thereof | |
| CN104446251A (en) | Adhesion agent as well as preparation method and application thereof | |
| CN105777027B (en) | A kind of emulsion modified cement ceramic tile bond of early-strength two-component polymer and its application method | |
| CN104402367B (en) | Without the high-strength ceramic tile adhesive of the accumulation of salt in the surface soil | |
| CN106905744B (en) | A kind of crack resistance type exterior wall powder of lacquer putty for use on | |
| WO2012007057A1 (en) | Redispersible dry composition of polymer finish | |
| CN106117420B (en) | A kind of modified cement mortar styrene-acrylic emulsion and preparation method thereof | |
| CN106189640A (en) | A kind of preparation method of modified aqueous acrylic acid cold coating | |
| CN106497473B (en) | A kind of environment protection type single-component vitrified brick gum and preparation method thereof | |
| CN106186960B (en) | A kind of high-performance environment-friendly spraying mortar and preparation method thereof | |
| CN108165109A (en) | A kind of environmental protection wall surface strengthening agent and preparation method thereof | |
| CN106893532A (en) | A kind of liquid glue for tile and preparation method thereof | |
| CN106495572B (en) | A kind of vitrified brick gum and preparation method thereof | |
| CN108341633A (en) | A kind of glue for tile | |
| CN106699064A (en) | Economical environment-friendly polymer cement waterproof paint | |
| CN106673540A (en) | Super-strength ceramic tile interface agent | |
| CN108640600B (en) | Colored foam concrete | |
| CN106381098A (en) | Special adhesive for ceramic tiles and preparation method thereof | |
| WO2014063480A1 (en) | Interface agent for binding vitrified tiles and construction method therefor | |
| CN102408213B (en) | Adhesive special for vitrified tile | |
| CN108624206A (en) | A kind of bi-component waterborne woodenware water resistant coating | |
| CN104293180A (en) | Protecting reinforcing solution for ancient colored paintings on unplastered wooden buildings, and preparation method and reinforcing protection method thereof | |
| CN105985676A (en) | Paint remover comprising attapulgite, and preparation method thereof | |
| CN104861896A (en) | Environmentally-friendly wood adhesive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20201104 Address after: Shop no.04-05, block 11, Cihai international trading center, No.168 Jihua West Road, Nanzhuang Town, Chancheng District, Foshan City, Guangdong Province Patentee after: Guangdong yigubi'an Paste Technology Co., Ltd Address before: 511483, No. 1342, Liang Liang Road, Panyu District, Guangdong, Guangzhou Patentee before: GUANGZHOU PANYU POLYTECHNIC |